Jong Hun Lee , Geun Hyeong Kim , Tae In Kang , Min Soo Kwak , Jong Su Kim , Sang Jun Lee , Dong Wan Kim
{"title":"Electrical characteristic depending on the doping concentration of the AlGaSb barrier in the GaSb based dual-band nBn detector","authors":"Jong Hun Lee , Geun Hyeong Kim , Tae In Kang , Min Soo Kwak , Jong Su Kim , Sang Jun Lee , Dong Wan Kim","doi":"10.1016/j.cap.2025.06.011","DOIUrl":"10.1016/j.cap.2025.06.011","url":null,"abstract":"<div><div>This paper investigates the effect of n-type doping in the Al<sub>0.35</sub>Ga<sub>0.65</sub>Sb barrier with undoped, Te:2x10<sup>15</sup> cm<sup>−3</sup>, and Te:2x10<sup>16</sup> cm<sup>−3</sup> doping in the near-infrared (NIR)/short-wavelength infrared (SWIR) nBn detector through temperature-dependent dark current density and photocurrent density measurement. The dark current density at 80 K, 0.1 V were 0.003 A/cm<sup>2</sup> (undoped), 0.005 A/cm<sup>2</sup> (2x10<sup>15</sup> cm<sup>−3</sup>), 0.053 A/cm<sup>2</sup> (2x10<sup>16</sup> cm<sup>−3</sup>). Given the negligible diffusion current and generation-recombination (G-R) current at low temperature, the increase is attributed to increased trap-assisted tunneling (TAT). In addition, the turn-on voltage of photocurrent at 300 K were 50 mV (undoped), 55 mV (2x10<sup>15</sup> cm<sup>−3</sup>), and 70 mV (2x10<sup>16</sup> cm<sup>−3</sup>), showing no significant increase with doping. This study indicates the importance of appropriate barrier doping concentration in designing of GaSb-based nBn detector for low-noise performance.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"78 ","pages":"Pages 24-28"},"PeriodicalIF":2.4,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Revisiting LaMnO3: A density functional theory study","authors":"Ju Hyeon Lee, Bongjae Kim","doi":"10.1016/j.cap.2025.06.010","DOIUrl":"10.1016/j.cap.2025.06.010","url":null,"abstract":"<div><div>Density functional theory has been widely applied to a variety of realistic materials but often fails to accurately describe the properties of correlated systems. The DFT + <em>U</em> method, which introduces a Hubbard <em>U</em> correction to the DFT, has been instrumental in the study of systems such as transition metal oxides. However, the methodological details of DFT + <em>U</em> and its specific impact on the electronic structure and magnetic properties of correlated systems remain incompletely understood. In this study, using the prototypical transition metal oxide LaMnO<sub>3</sub> as an example, we systematically assess the performance of two distinct DFT + <em>U</em> methods: spin-polarized DFT + <em>U</em> (SDFT + <em>U</em>) and spin-unpolarized charge-only DFT + <em>U</em> (CDFT + <em>U</em>). We found that, while the Coulomb <em>U</em> acts similarly in both approaches, the Hund's <em>J</em><sub>H</sub> plays a fundamentally different role, particularly in determining the correct magnetic phases. Our investigation demonstrates the active role of <em>J</em><sub>H</sub> in the exchange splitting, leading to distinct magnetic ground states based on the different schemes. We further investigate the associated magnetic exchange interactions and compare our results with beyond-DFT methods.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"78 ","pages":"Pages 7-14"},"PeriodicalIF":2.4,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144366518","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Selective hydrogen molecule dissociation on Ca2N monolayer","authors":"Gwan Woo Kim , Soonmin Jang , Gunn Kim","doi":"10.1016/j.cap.2025.06.009","DOIUrl":"10.1016/j.cap.2025.06.009","url":null,"abstract":"<div><div>The development of efficient hydrogen conversion and storage technologies is critical for sustainable energy systems. We report the remarkable discovery of barrierless hydrogen dissociation on dicalcium nitride (Ca<sub>2</sub>N) monolayers through density functional theory calculations and ab initio molecular dynamics simulations. Our investigations reveal that molecular hydrogen adsorption occurs exclusively at a bridge site between calcium atoms (site B), while dissociated hydrogen atoms preferentially migrate to a calcium-centered hollow site (site A). Importantly, our simulations demonstrate a self-regulating mechanism wherein initial H<sub>2</sub> dissociation at B-sites inhibits subsequent molecular hydrogen adsorption, effectively controlling the dissociation process. The absence of an activation energy barrier indicates an exceptionally favorable thermodynamic pathway for hydrogen dissociation under ambient conditions. These findings establish pristine Ca<sub>2</sub>N monolayers as promising candidates for catalyzing hydrogen evolution reactions and other hydrogen-related energy applications, offering a novel direction for the development of electride-based catalysts with unprecedented hydrogen activation properties.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"78 ","pages":"Pages 15-23"},"PeriodicalIF":2.4,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Strain-dependent charge density wave stability in monolayer Kagome AV3Sb5 (A = K, Rb, Cs)","authors":"Jun-Hee Im , Chang-Jong Kang , Chang-Youn Moon","doi":"10.1016/j.cap.2025.06.008","DOIUrl":"10.1016/j.cap.2025.06.008","url":null,"abstract":"<div><div>We perform first-principles calculations based on density-functional theory to study the stability of a charge density wave (CDW) phase in Kagome metals AV<sub>3</sub>Sb<sub>5</sub> (A = K, Rb, Cs) in the monolayer form. The energy gain of the CDW formation from the pristine structure increases from A = K to Cs with the increasing lattice parameter. We find that the CDW phase is further stabilized by expanding the lattice for A = K while it is most stable around the equilibrium value in case of A = Cs, suggesting the lattice parameter as a main factor of differentiating the relative stability of the CDW phase among alkali elements for A. It is revealed that the maximum CDW stability is associated with the Fermi energy located in between two van Hove singularities each at Γ and M k-points, providing a comprehensive understanding of the CDW formation and its stability as a function of the strain as well as the alkali element in these materials.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"78 ","pages":"Pages 1-6"},"PeriodicalIF":2.4,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144364911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mengyu Guan, Ranran Bu, Haizhen Song, Changyuan Xu, Yichao Wang, Yan Zhang, Hongming Yin
{"title":"Study on the effect of different crystal forms of benzamide on the luminescence properties of Mn2+ in organic-inorganic hybrid metal halides","authors":"Mengyu Guan, Ranran Bu, Haizhen Song, Changyuan Xu, Yichao Wang, Yan Zhang, Hongming Yin","doi":"10.1016/j.cap.2025.06.007","DOIUrl":"10.1016/j.cap.2025.06.007","url":null,"abstract":"<div><div>Mn<sup>2+</sup>-based organic-inorganic hybrid metal halides were synthesized via evaporation crystallization using benzamide (BZM) and nicotinamide (NCM) as organic ligands. The DSC curve shows that the Mn<sup>2+</sup>-based organic-inorganic hybrid metal halides contain two crystal forms of BZM. Steady-state photoluminescence (PL) spectra reveal that the PL emission of Mn<sup>2+</sup> shifts from red to green as the crystal form of BZM changes. Density functional theory (DFT) calculation suggests that there is a certain rule between the transformation of BZM crystal form and the change of Mn<sup>2+</sup> luminescence characteristics.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 116-122"},"PeriodicalIF":2.4,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144298189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cheng-Di Qi , Jian-Li Ma , Ze-Qing Guo , Wei-Wen Wang , Qun Wei
{"title":"Revealing the anisotropies in elasticity, sound velocities and thermal conductivities of o-HfO2: A density functional theory investigation","authors":"Cheng-Di Qi , Jian-Li Ma , Ze-Qing Guo , Wei-Wen Wang , Qun Wei","doi":"10.1016/j.cap.2025.06.003","DOIUrl":"10.1016/j.cap.2025.06.003","url":null,"abstract":"<div><div>In this work, the first-principles calculations were used to investigate the anisotropies in elasticity, sound velocities and thermal conductivities of orthorhombic phase HfO<sub>2</sub> (termed as o-HfO<sub>2</sub>). The parameters, such as universal anisotropic index (<em>A</em><sup>U</sup>), percent anisotropy (<em>A</em><sub>comp</sub> and <em>A</em><sub>shear</sub>) and shear anisotropic factors (<em>A</em><sub>1</sub>, <em>A</em><sub>2</sub>, and <em>A</em><sub>3</sub>) were calculated to quantitatively assess the magnitude of anisotropy. Besides, the 3D surface constructions of bulk moduli and Young's moduli were employed to demonstrate graphically the anisotropy in elastic properties. Moreover, the calculated results implied the anisotropy in sound velocities. The planar projections of minimum thermal conductivities on different planes revealed the anisotropy in thermal conductivities. These results can provide a reference for the practical application of HfO<sub>2</sub>.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 108-115"},"PeriodicalIF":2.4,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144280096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Joonwoo Kim , Jaehun Cho , Si-Ho Oh , June-Seo Kim
{"title":"The significant improvements of DC magnetron sputtering plasma source via cryogenic cooling method for spintronics applications","authors":"Joonwoo Kim , Jaehun Cho , Si-Ho Oh , June-Seo Kim","doi":"10.1016/j.cap.2025.06.004","DOIUrl":"10.1016/j.cap.2025.06.004","url":null,"abstract":"<div><div>This study investigates the significant enhancement of DC magnetron sputtering plasma sources using a cryogenic cooling system to focus on its impact on thin-film deposition processes. The efficiency of magnetron-sputtering plasma sources directly depends on the in-plane magnetic fields, which are generated by permanent magnets installed inside the plasma source head. However, the permanent magnets are severely deteriorated when the system temperature is increased due to the plasma ignitions. In this case, the cryogenic cooling system effectively overcomes this limitation and it can improve the magnetic flux density and performance stability of the plasma source. Experimental results demonstrate that cryogenic cooling enhances deposition rates and film uniformity for both ferromagnetic (cobalt) and non-magnetic (tungsten) materials. Cobalt (Co) and tungsten (W) targets serve as representative examples, with deposition rates improving by approximately 27 % and 19 %, and uniformities increasing by 18 % and 19 %, respectively, compared to water-cooled systems. Additionally, the cryogenic cooling method allows for the use of thicker ferromagnetic targets that the magnetic target thickness limit is widely extended to 5.0 mm, which can reduce maintenance costs and process interruptions. From the systematic numerical simulations, one can be revealed that a strong magnetic field distortion due to a thin magnetic target is observed and it can occur the degradation of the efficiency of the plasma source. Moreover, the in-plane magnetic fields from permanent magnets are dramatically increased with decreasing the system temperatures. This study can highlight that the cryogenic cooling method of the magnetron sputtering plasma source is a transformative technology to improve the efficiency and reliability of the thin film deposition process for spintronic devices.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 100-107"},"PeriodicalIF":2.4,"publicationDate":"2025-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144262878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mincheol Kim , Hyuk Jin Kim , Byoung Ki Choi , Tae Gyu Rhee , Chris Jozwiak , Aaron Bostwick , Eli Rotenberg , Sunghun Lee , Young Jun Chang
{"title":"Dirac nodal line and pseudo-gap in 1T-VS2 single crystal","authors":"Mincheol Kim , Hyuk Jin Kim , Byoung Ki Choi , Tae Gyu Rhee , Chris Jozwiak , Aaron Bostwick , Eli Rotenberg , Sunghun Lee , Young Jun Chang","doi":"10.1016/j.cap.2025.06.005","DOIUrl":"10.1016/j.cap.2025.06.005","url":null,"abstract":"<div><div>Vanadium disulfide (VS<sub>2</sub>), one of transition metal dichalcogenide (TMDC) family, attracts elevated interests for its charge-density wave phase transition, ferromagnetism, optoelectronic switching, and catalytic reactivity, but the topological Dirac surface states have not been observed yet. Here we report the Dirac nodal line states of VS<sub>2</sub> single crystals via angle-resolved photoemission spectroscopy (ARPES) measurements. ARPES analysis reveals that Dirac nodal line surface states are extended from the Μ point toward the Γ point with energy of −1.1 eV. Comparison with the other vanadium chalcogenides shows monotonic energy shift of the Dirac states depending on the spin-orbit coupling strength of the chalcogen atoms. Furthermore, we studied the temperature-dependence of pseudo gaps near both the M and Γ points. Our observations provide experimental evidence of topological electronic structures, contributing to the understanding of the correlated TMDC systems and their potential in switching devices, optical saturable absorber, and electrocatalysis.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 94-99"},"PeriodicalIF":2.4,"publicationDate":"2025-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144254393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tran Dang Thanh , Kim T.H. My , Do Hung Manh , The-Long Phan , D.-H. Kim
{"title":"Griffiths phase and magnetocaloric behaviors of Co-doped Nd0.6Sr0.4MnO3","authors":"Tran Dang Thanh , Kim T.H. My , Do Hung Manh , The-Long Phan , D.-H. Kim","doi":"10.1016/j.cap.2025.06.001","DOIUrl":"10.1016/j.cap.2025.06.001","url":null,"abstract":"<div><div>Nd<sub>0.6</sub>Sr<sub>0.4</sub>Mn<sub>1-<em>y</em></sub>Co<sub><em>y</em></sub>O<sub>3</sub> (<em>y</em> = 0–0.09) compounds have been fabricated by using solid-state reactions. X-ray diffraction analyses reveal their monophase in the <em>Imma</em> orthorhombic structure. When <em>y</em> increases, there are gradual reductions of the unit-cell parameters and porosity. Concurrently, the Curie temperature (<em>T</em><sub><em>C</em></sub>) also reduces from 280 K (<em>y</em> = 0) to ∼232 K (<em>y</em> = 0.09). In the vicinity of <em>T</em><sub><em>C</em></sub>, we have observed the Griffiths phase that more develops as increasing <em>y</em>. The presence of this phase enhances magnetocaloric responses, corresponding to the operating range widened above 95 % and the cooling power enhanced ∼30 % for an applied field <em>H</em> = 30 kOe. All materials exhibit the characters of a second-order phase transition with a narrow hysteresis loop, suggesting their applicability in magnetic cooling devices operating below room temperature. A coexistence of Mn<sup>3+,4+</sup> and Co<sup>3+,4+</sup> ions is thought to establish randomly competing ferromagnetic and antiferromagnetic interactions in Nd<sub>0.6</sub>Sr<sub>0.4</sub>Mn<sub>1-<em>y</em></sub>Co<sub><em>y</em></sub>O<sub>3</sub> compounds that widen the Griffiths phase, short-range magnetic ordering, and magnetocaloric response.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 85-93"},"PeriodicalIF":2.4,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144242482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xueyuan Li , Yaru Du , Niqian Du , Shanshan Du , Tianxiao Liu , Kaikai Liu , Zhiyong Liu
{"title":"Improved ultraviolet resistant through the natural antioxidants in efficient perovskite photovoltaics","authors":"Xueyuan Li , Yaru Du , Niqian Du , Shanshan Du , Tianxiao Liu , Kaikai Liu , Zhiyong Liu","doi":"10.1016/j.cap.2025.05.014","DOIUrl":"10.1016/j.cap.2025.05.014","url":null,"abstract":"<div><div>Perovskite solar cells (PSCs) have attracted much attention due to their excellent photoelectric properties. However, the instability of perovskites limits its development, which resulted by degradation derived from oxygen and ultraviolet light. Herein, the contain conjugated double bonds and natural antioxidant layer provided by β-carotene and astaxanthin could constitute ligand bonds with Pb<sup>2+</sup> in the form of Lewis acid-base interactions and eliminate UV-induced free radicals during photoaging process, which passivate the surface defects and improve the crystal quality of perovskite films, improving operational stability of PSCs. The optimized PSCs arrive a champion power conversion efficiency (PCE) of 23.56 %, maintaining 88 % of the original PCE after continuous operating 140 h under UV illumination state and 89 % of the original PCE after 2400 h of operation in air environment condition. This work provides a general strategy for improving the stability of PSCs.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 123-130"},"PeriodicalIF":2.4,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144307161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}