Mohammed Usman , Joseph Akintola , Gabriel Umoh , Joseph Akpan , Ekpotu Wilson , Queen Moses , Philemon Udom , Edose Osagie
{"title":"An exergy-based analysis for the synthesis of aromatics from biomass","authors":"Mohammed Usman , Joseph Akintola , Gabriel Umoh , Joseph Akpan , Ekpotu Wilson , Queen Moses , Philemon Udom , Edose Osagie","doi":"10.1016/j.nxsust.2025.100109","DOIUrl":"10.1016/j.nxsust.2025.100109","url":null,"abstract":"<div><div>The chemical process industry has been facing rising energy costs, increasing competition due to rapid globalization, and more stringent government regulations amid growing public concern for the environment, health, and safety. In response to these challenges and considering the industry's capital-intensive nature, ongoing optimization through redesigning existing production plants has become a key strategy. This study designs and analyses a typical process plant with two routes for synthesizing aromatics from methanol and pentane. Process route 1 involves co-feeding, while process route 2 incorporates recycling and producing pentane. For methanol synthesis, cellulose (biomass) is used as the initial raw material, leading to the synthesis of aromatics through a reaction with pentanes. Exergy, exergo-economic, and pinch analyses are performed on both process routes. The routes display different overall exergy performances, with process routes 1 and 2 achieving 39.53 % and 25.43 % exergy, respectively. The highest exergetic performance is recorded in the CO<sub>2</sub> heater (67.69 %) and the biomass oxidation reactor (88.70 %) for process routes 1 and 2, respectively. Exergo-economic evaluations indicate that Benzene distillation separation experiences exergy destruction rates of 28.61 % and exergo-economic factor of 99.92 % for process 1, while the aromatics heater shows the highest exergy destruction of 56.68 % for process 2. Implementing heat integration in the process routes reveals that process route 1 achieves energy savings of 92.09 %, while process route 2 results in 51.38 % energy savings. This study demonstrates the two process routes’ long-term economic viability and efficiency, which can be further optimised in future studies to achieve sustainable process implementation.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100109"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143228671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gudaysew Tsegaye Yenesew, Clément Nicollet, Eric Quarez, Annie Le Gal La Salle, Olivier Joubert
{"title":"Scalable recycling and characterization of end-of-life solid oxide cell ceramic component materials","authors":"Gudaysew Tsegaye Yenesew, Clément Nicollet, Eric Quarez, Annie Le Gal La Salle, Olivier Joubert","doi":"10.1016/j.nxsust.2025.100110","DOIUrl":"10.1016/j.nxsust.2025.100110","url":null,"abstract":"<div><div>By recycling solid oxide cells (SOCs) end-life materials, the environmental impact can be reduced, and the materials' closed-loop life cycle can help preserve natural resources and create a sustainable and circular system. This study presents a technique for recovering NiO, La<sub>x</sub>Sr<sub>1-x</sub>CoO<sub>3</sub> (LSC) and Zr<sub>1-x</sub>Y<sub>x</sub>O<sub>2-x/2</sub> (YSZ) components from SOC end-of-life products. First, the entire cell components, including the electrolyte, fuel and air electrodes were crushed, ball-milled, and leached with nitric acid. Following the maximum dissolution of cations, centrifugation was used to remove the non-leached YSZ as a sediment. The leached solution, which is rich in nickel, cobalt, strontium, and lanthanum ions was treated with dimethylglyoxime (C<sub>4</sub>H<sub>8</sub>N<sub>2</sub>O<sub>2</sub> DMG) and Ni is preferentially precipitated as C<sub>8</sub>H<sub>14</sub>N<sub>4</sub>NiO<sub>4</sub>. LSC is then recovered from thermal treatment of solution leftover from C<sub>8</sub>H<sub>14</sub>N<sub>4</sub>NiO<sub>4</sub> centrifugation and filtration. About 90 wt% of the ceramic components were successfully recovered. The compositions of recovered materials show a commercial-grade purity i.e about 99 at% for NiO, 96 at% for LSC and 97 at% for YSZ.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100110"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Katherine E.S. Locock , Andrew Terhorst , Sarah King , Kymberley R. Scroggie
{"title":"Disruptive technologies that deliver a circular economy for plastics","authors":"Katherine E.S. Locock , Andrew Terhorst , Sarah King , Kymberley R. Scroggie","doi":"10.1016/j.nxsust.2025.100098","DOIUrl":"10.1016/j.nxsust.2025.100098","url":null,"abstract":"<div><div>Plastics are ubiquitous and integral to modern life with global production doubling in the next 20 years. Only minimal amounts, however, are reused or recycled with the common methods of dealing with plastic waste i.e., incineration and landfill, and leaking into the environment (pollution) all resulting in a loss of plastic from the economy. A circular economy for plastics reduces plastic pollution and climate effects and provides social and economic benefits. This article reviews the patent landscape and identifies disruptive technologies that contribute to a circular economy for plastics. Using a collaboration between subject matter experts and ChatGPT, we identified five distinct disruptive technology categories and associated keywords that support a circular economy: bioplastics, chemical recycling, synthetic biology, traceable plastics and waste separation. Using the associated keywords, we categorised patents from 2018 to 2022 into these disruptive technologies to assess current trends. The patent landscape was challenging to navigate due to the deliberately broad language used to construct patents, leading to many irrelevant patents being categorised. Low technology readiness levels of some patents examined also limits the current disruptiveness of these technologies. Adequate financial funding and economic incentives were the most evident barriers to disruptive technology maturity and uptake.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100098"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biomass (Amritsagar) derived efficient solid base catalyst for eco-friendly biodiesel synthesis: A study on synthesis, reaction kinetics, and thermodynamic properties","authors":"Bidangshri Basumatary , Biswajit Nath , Bipul Das , Anjana Dhar , Sanjay Basumatary","doi":"10.1016/j.nxsust.2025.100127","DOIUrl":"10.1016/j.nxsust.2025.100127","url":null,"abstract":"<div><div>This study examines the effectiveness of a heterogeneous catalyst derived from the Amritsagar (AAA) banana plant in the synthesis of biodiesel using <em>Jatropha curcas</em> oil. The fruit peel, rhizome, and stem of the post-harvest Amritsagar (AAA) plant were calcined at 550°C and utilized as catalysts for transesterification. The catalysts are characterized using advanced analytical instruments and techniques such as FESEM, HRTEM, EDX, FT-IR, XPS, XRD, and BET. The most effective catalyst identified in this work is the Amritsagar calcined peel catalyst at 550 °C (ACP-550). Its characterization confirms the existence of Ca, K, Si, Fe, Na, Sr, Mn, Mg, and Zn metal oxides and carbonates, and it reveals a BET surface area of 26.104 m²/g. The catalyst ACP-550 outperformed the other catalysts, delivering a biodiesel yield of 97.58 % at 65 °C under optimal conditions, which comprised a 9:1 methanol to oil molar ratio, 7 wt% catalyst, and a 20 min reaction time. The study also includes an investigation of basicity, turnover frequency, soluble alkalinity, pH measurement of catalysts, reaction kinetics, thermodynamic parameters, reusability tests, and a comparison of catalytic activity of the catalysts in the production of biodiesel. The synthesized biodiesel was characterized through GC-MS NMR, and FT-IR analysis. Moreover, the assessment of fuel characteristics of biodiesel obtained from <em>Jatropha curcas</em> oil (JCO) was documented and compared with international standards and the properties were found to be within the specified limits.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100127"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143705374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermodynamic and kinetic analysis of waste plastic pyrolysis: Synergistic effects and sustainability perspectives","authors":"Prathwiraj Meena, Rohidas Bhoi","doi":"10.1016/j.nxsust.2025.100132","DOIUrl":"10.1016/j.nxsust.2025.100132","url":null,"abstract":"<div><div>In this study, low-density polyethylene (LDPE), polypropylene (PP), polystyrene (PS), waste mixed plastics (WMPs) and WMPs with spent fluid catalytic cracking (sFCC) catalyst (WMPs/ sFCC) were investigated to simulate real-life pyrolysis and catalytic pyrolysis of waste plastics using Thermogravimetric analysis (TGA). TGA was performed under different heating rates i.e., 5, 10, 15 and 20 ˚C/min) in an inert nitrogen atmosphere. The pyrolysis kinetics are assessed using three model-free methods, Flynn–Wall–Ozawa (FWO), Kissinger–Akahira–Sunose (KAS), and Starink, as well as two model-fitting methods, Coats–Redfern (CR) and Criado methods (master plots). The results showed that the WMPs exhibited a positive synergetic effect among the different types of plastics, leading to a notable reduction in degradation temperature and required activation energy. Moreover, adding sFCC catalysts significantly lowered the initial pyrolysis temperature (approximately 47 ˚C) of WMPs compared to direct pyrolysis. Moreover, the average activation energy of WMPs decreased by approximately 13.41 kJ/mole with the inclusion of the sFCC catalyst. The thermodynamic properties such <em>ΔH</em><sup><em>‡</em></sup>, <em>ΔG</em><sup><em>‡</em></sup> and <em>ΔS</em><sup><em>‡</em></sup> suggested that the process was endothermic, non-spontaneous and decreased in randomness during pyrolysis. This study promotes sustainability through a circular economy to convert waste into wealth. These findings offer valuable theoretical insights for reducing energy consumption in plastic pyrolysis and expanding the applications of sFCC catalyst.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100132"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143859242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A comprehensive review of production and utilisation of ammonia as potential fuel for compression ignition engines","authors":"Jaffar Hussain , Marutholi Mubarak , Duraisamy Boopathi , Ravikumar Jayabal","doi":"10.1016/j.nxsust.2025.100116","DOIUrl":"10.1016/j.nxsust.2025.100116","url":null,"abstract":"<div><div>For centuries, internal combustion engines (ICEs) have powered cars using gasoline and diesel as the primary fuel. Bio-derived fuels have been blended with conventional fuels to address the depletion of fossil fuels and their associated greenhouse effect. The researchers focus on finding new technology that leads to carbon-free mobility. Renewable energy sources such as ammonia, hydrogen, and CNG are becoming increasingly popular as efficient substitutes for traditional fuels. Due to the concern about the production and storage of hydrogen, ammonia is gaining momentum due to its better hydrogen-storing capacity. This review paper aims to discuss the various ammonia production processes, the possibilities of ammonia as fuel in conventional CI engines, and the use of ammonia in internal combustion engines. Research has shown that the addition of ammonia to CI enhances its performance, and the use of dual fuel can boost the output's economic efficiency. However, it is important to note that this approach may also lead to increased NOₓ emissions. Some of the most important things that the review showed were that ammonia works well in dual fuel mode, 40–60 % diesel fuel energy is needed for maximum fuel efficiency, and NO emissions go down if ammonia replaces less than 40 % of the energy. For this reason, ammonia could potentially serve as a fuel for CI engines, leading to improved performance and a reduction in NOₓ emissions.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100116"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study of bioethanol production from sorghum residue by optimization of pre-treatment and enzymatic degradation: Co-culturing of Saccharomyces cerevisiae and Pichia stipitis as fermentation approach","authors":"Pallavi Punia, Sumeet Kumar","doi":"10.1016/j.nxsust.2025.100131","DOIUrl":"10.1016/j.nxsust.2025.100131","url":null,"abstract":"<div><div>The co-utilization of pentose and hexose in lignocellulosic biomass hydrolysate is the core for economically fermentative production of the second-generation bioethanol as a sustainable biofuel candidate. In this research, the production of bioethanol by co-culturing <em>S. cerevisiae</em> (MTCC174) and <em>P. stipitis</em> (NCIM 3497) with the SHF (separate hydrolysis and fermentation) process was reported. Enzymatic the saccharification process for fermentable sugars is induced by NaOH pre-treated SSR, as evidenced by the data. The optimal Box-Behnken Design parameters for pre-treated and hydrolyzed SSR were reported with 2 % concentration of NaOH, 1 mm with particle size, and 50 min duration were explored and showed a maximum cellulose concentration of 62.7 % as a response. The variables investigated in the model for hydrolysis found the maximal concentration of reducing sugar of 42.7 ± 2.117 mg/g, at ∼50℃ with 1:2 enzymes loading at a time of ∼72hrs. The physical and structural analysis can be done with FTIR, XRD, and FESEM techniques. The highest concentration of bioethanol of 16.8 g/L was attained in 72hrs fermentation time. The study infers that SHF has great potential for producing high-titer ethanol commercially and supports waste-to-energy strategies.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100131"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143839772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Md. Abul Hashem , Forhad Ahammad , Bishwajit Chandra Das , Eshtiyaq Tauhid Enan , Modinatul Maoya , Mohammad Jakir Hossain Khan , Md. Mukimujjaman Miem
{"title":"Dye adsorption on fish scale biosorbent from tannery wastewater","authors":"Md. Abul Hashem , Forhad Ahammad , Bishwajit Chandra Das , Eshtiyaq Tauhid Enan , Modinatul Maoya , Mohammad Jakir Hossain Khan , Md. Mukimujjaman Miem","doi":"10.1016/j.nxsust.2025.100112","DOIUrl":"10.1016/j.nxsust.2025.100112","url":null,"abstract":"<div><div>In leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influence on the aquatic ecosystem. This research concerns the suitability of fish biowaste adsorbent for dye removal from tannery wastewater. The obtained biosorbent was analyzed through Fourier Transform Infrared (FTIR) Spectroscopy, pH point of zero charge (pHpzc), Energy Dispersive Spectroscopy (EDS), and Scanning Electron Microscope (SEM). The dye removal efficiency was evaluated by monitoring the biosorbent dose, settling time, stirring time, and temperature effect. The dye adsorption mechanism was characterized using Freundlich and Langmuir’s regression models. The maximum dye removal efficiency (81.8 %) was achieved with a 2 g biosorbent dose per 50 mL of wastewater, 25 min stirring time, 30°C temperature, and 20 h settling time at pH 4.8. The adsorption kinetics demonstrated that the pseudo-second-order reaction (PSO) model shows a good regression coefficient (<em>R</em><sup><em>2</em></sup>=0.94). The removal of Total Dissolved Solids (TDS), Biochemical Oxygen Demand (BOD), turbidity, and Chemical Oxygen Demand (COD) were 39.8 %, 69.7 %, 48.1 %, and 90.1 %, respectively. Hence, the fish scale biosorbent could be a feasible adsorbent for leather dyeing wastewater treatment, and further research can be conducted to explore its potential for large-scale application.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100112"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143377915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Sustainable 3D printing of bone scaffolds using animal biowaste feedstocks","authors":"A. Dukle, M. Ravi Sankar","doi":"10.1016/j.nxsust.2025.100099","DOIUrl":"10.1016/j.nxsust.2025.100099","url":null,"abstract":"<div><div>Numerous 3D printing feedstocks are currently being studied for the 3D printing of bone scaffolds for bone regeneration, with differing degrees of success. Most of these feedstocks are produced using ceramics, polymers, and composites. However, the currently available feedstocks are costly and have a significant impact on the environment during production and distribution. On the other hand, every day, a large amount of biowaste is produced from plant, animal, and microbial sources, which are becoming increasingly difficult to manage. Therefore, there is always a demand for efficient disposal and recycling methods. This study provides an overview of the use of biowaste-derived 3D printing feedstocks for bone tissue engineering applications. In recent years, biowaste, which is a renewable and cost-effective source, has been explored as a potential alternative to conventional feedstocks. This paper covers various types of animal derived biowastes and highlights their potential advantages for bone tissue engineering. It also discusses different properties, including rheology, mechanical strength, printability, and bioactivity for bone tissue engineering applications. The study also addresses the challenges and future perspectives of biowaste-derived feedstocks for bone tissue engineering, including regulatory hurdles, biocompatibility, and scalability.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100099"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143379096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Forecasting of municipal solid waste generation in Türkiye and techno-economic-environmental assessment of electricity generation via incineration till 2032","authors":"Mehmet Melikoglu","doi":"10.1016/j.nxsust.2024.100092","DOIUrl":"10.1016/j.nxsust.2024.100092","url":null,"abstract":"<div><div>This paper develops a forecasting model for municipal solid waste (MSW) generation and its potential for energy recovery through incineration in Türkiye. MSW generation in 81 provinces of Türkiye are forecasted till 2032 using novel semi-empirical models based on two different scenarios. It is forecasted that Türkiye’s MSW generation in 2032 will reach up to 36.2 million tonnes and from incineration of this MSW up to 16.8 TWh of electricity worth 2.1 billion US$ (based on 2024 June wholesale industrial prices) can be generated. Nationwide greenhouse gas (GHG) emissions from incineration of MSW for electricity generation can reach 19.7 million tonnes of carbon dioxide in 2032. Root mean squared error and mean absolute percentage error values indicated high goodness of fit and accuracy for the forecasting models. As future research it is suggested that the methodology given in this study can be used by others for forecasting MSW generation with energy recovery as electricity via incineration and associated GHG emissions calculations in different countries conditional that historic geographical per capita data is available and associated model parameters are calculated based on existing circumstances.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100092"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143140691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}