Katherine E.S. Locock , Andrew Terhorst , Sarah King , Kymberley R. Scroggie
{"title":"Disruptive technologies that deliver a circular economy for plastics","authors":"Katherine E.S. Locock , Andrew Terhorst , Sarah King , Kymberley R. Scroggie","doi":"10.1016/j.nxsust.2025.100098","DOIUrl":"10.1016/j.nxsust.2025.100098","url":null,"abstract":"<div><div>Plastics are ubiquitous and integral to modern life with global production doubling in the next 20 years. Only minimal amounts, however, are reused or recycled with the common methods of dealing with plastic waste i.e., incineration and landfill, and leaking into the environment (pollution) all resulting in a loss of plastic from the economy. A circular economy for plastics reduces plastic pollution and climate effects and provides social and economic benefits. This article reviews the patent landscape and identifies disruptive technologies that contribute to a circular economy for plastics. Using a collaboration between subject matter experts and ChatGPT, we identified five distinct disruptive technology categories and associated keywords that support a circular economy: bioplastics, chemical recycling, synthetic biology, traceable plastics and waste separation. Using the associated keywords, we categorised patents from 2018 to 2022 into these disruptive technologies to assess current trends. The patent landscape was challenging to navigate due to the deliberately broad language used to construct patents, leading to many irrelevant patents being categorised. Low technology readiness levels of some patents examined also limits the current disruptiveness of these technologies. Adequate financial funding and economic incentives were the most evident barriers to disruptive technology maturity and uptake.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100098"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biomass (Amritsagar) derived efficient solid base catalyst for eco-friendly biodiesel synthesis: A study on synthesis, reaction kinetics, and thermodynamic properties","authors":"Bidangshri Basumatary , Biswajit Nath , Bipul Das , Anjana Dhar , Sanjay Basumatary","doi":"10.1016/j.nxsust.2025.100127","DOIUrl":"10.1016/j.nxsust.2025.100127","url":null,"abstract":"<div><div>This study examines the effectiveness of a heterogeneous catalyst derived from the Amritsagar (AAA) banana plant in the synthesis of biodiesel using <em>Jatropha curcas</em> oil. The fruit peel, rhizome, and stem of the post-harvest Amritsagar (AAA) plant were calcined at 550°C and utilized as catalysts for transesterification. The catalysts are characterized using advanced analytical instruments and techniques such as FESEM, HRTEM, EDX, FT-IR, XPS, XRD, and BET. The most effective catalyst identified in this work is the Amritsagar calcined peel catalyst at 550 °C (ACP-550). Its characterization confirms the existence of Ca, K, Si, Fe, Na, Sr, Mn, Mg, and Zn metal oxides and carbonates, and it reveals a BET surface area of 26.104 m²/g. The catalyst ACP-550 outperformed the other catalysts, delivering a biodiesel yield of 97.58 % at 65 °C under optimal conditions, which comprised a 9:1 methanol to oil molar ratio, 7 wt% catalyst, and a 20 min reaction time. The study also includes an investigation of basicity, turnover frequency, soluble alkalinity, pH measurement of catalysts, reaction kinetics, thermodynamic parameters, reusability tests, and a comparison of catalytic activity of the catalysts in the production of biodiesel. The synthesized biodiesel was characterized through GC-MS NMR, and FT-IR analysis. Moreover, the assessment of fuel characteristics of biodiesel obtained from <em>Jatropha curcas</em> oil (JCO) was documented and compared with international standards and the properties were found to be within the specified limits.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100127"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143705374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A comprehensive review of production and utilisation of ammonia as potential fuel for compression ignition engines","authors":"Jaffar Hussain , Marutholi Mubarak , Duraisamy Boopathi , Ravikumar Jayabal","doi":"10.1016/j.nxsust.2025.100116","DOIUrl":"10.1016/j.nxsust.2025.100116","url":null,"abstract":"<div><div>For centuries, internal combustion engines (ICEs) have powered cars using gasoline and diesel as the primary fuel. Bio-derived fuels have been blended with conventional fuels to address the depletion of fossil fuels and their associated greenhouse effect. The researchers focus on finding new technology that leads to carbon-free mobility. Renewable energy sources such as ammonia, hydrogen, and CNG are becoming increasingly popular as efficient substitutes for traditional fuels. Due to the concern about the production and storage of hydrogen, ammonia is gaining momentum due to its better hydrogen-storing capacity. This review paper aims to discuss the various ammonia production processes, the possibilities of ammonia as fuel in conventional CI engines, and the use of ammonia in internal combustion engines. Research has shown that the addition of ammonia to CI enhances its performance, and the use of dual fuel can boost the output's economic efficiency. However, it is important to note that this approach may also lead to increased NOₓ emissions. Some of the most important things that the review showed were that ammonia works well in dual fuel mode, 40–60 % diesel fuel energy is needed for maximum fuel efficiency, and NO emissions go down if ammonia replaces less than 40 % of the energy. For this reason, ammonia could potentially serve as a fuel for CI engines, leading to improved performance and a reduction in NOₓ emissions.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100116"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143455050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Md. Abul Hashem , Forhad Ahammad , Bishwajit Chandra Das , Eshtiyaq Tauhid Enan , Modinatul Maoya , Mohammad Jakir Hossain Khan , Md. Mukimujjaman Miem
{"title":"Dye adsorption on fish scale biosorbent from tannery wastewater","authors":"Md. Abul Hashem , Forhad Ahammad , Bishwajit Chandra Das , Eshtiyaq Tauhid Enan , Modinatul Maoya , Mohammad Jakir Hossain Khan , Md. Mukimujjaman Miem","doi":"10.1016/j.nxsust.2025.100112","DOIUrl":"10.1016/j.nxsust.2025.100112","url":null,"abstract":"<div><div>In leather processing, dyeing is an essential operation to make it attractive for fashion style. Emitted dyeing wastewater contains dye, fixing agent, syntan, resin, and fat. Dye removal from real wastewater is challenging because it includes other matrices. Dyes in wastewater have an adverse influence on the aquatic ecosystem. This research concerns the suitability of fish biowaste adsorbent for dye removal from tannery wastewater. The obtained biosorbent was analyzed through Fourier Transform Infrared (FTIR) Spectroscopy, pH point of zero charge (pHpzc), Energy Dispersive Spectroscopy (EDS), and Scanning Electron Microscope (SEM). The dye removal efficiency was evaluated by monitoring the biosorbent dose, settling time, stirring time, and temperature effect. The dye adsorption mechanism was characterized using Freundlich and Langmuir’s regression models. The maximum dye removal efficiency (81.8 %) was achieved with a 2 g biosorbent dose per 50 mL of wastewater, 25 min stirring time, 30°C temperature, and 20 h settling time at pH 4.8. The adsorption kinetics demonstrated that the pseudo-second-order reaction (PSO) model shows a good regression coefficient (<em>R</em><sup><em>2</em></sup>=0.94). The removal of Total Dissolved Solids (TDS), Biochemical Oxygen Demand (BOD), turbidity, and Chemical Oxygen Demand (COD) were 39.8 %, 69.7 %, 48.1 %, and 90.1 %, respectively. Hence, the fish scale biosorbent could be a feasible adsorbent for leather dyeing wastewater treatment, and further research can be conducted to explore its potential for large-scale application.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100112"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143377915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Sustainable 3D printing of bone scaffolds using animal biowaste feedstocks","authors":"A. Dukle, M. Ravi Sankar","doi":"10.1016/j.nxsust.2025.100099","DOIUrl":"10.1016/j.nxsust.2025.100099","url":null,"abstract":"<div><div>Numerous 3D printing feedstocks are currently being studied for the 3D printing of bone scaffolds for bone regeneration, with differing degrees of success. Most of these feedstocks are produced using ceramics, polymers, and composites. However, the currently available feedstocks are costly and have a significant impact on the environment during production and distribution. On the other hand, every day, a large amount of biowaste is produced from plant, animal, and microbial sources, which are becoming increasingly difficult to manage. Therefore, there is always a demand for efficient disposal and recycling methods. This study provides an overview of the use of biowaste-derived 3D printing feedstocks for bone tissue engineering applications. In recent years, biowaste, which is a renewable and cost-effective source, has been explored as a potential alternative to conventional feedstocks. This paper covers various types of animal derived biowastes and highlights their potential advantages for bone tissue engineering. It also discusses different properties, including rheology, mechanical strength, printability, and bioactivity for bone tissue engineering applications. The study also addresses the challenges and future perspectives of biowaste-derived feedstocks for bone tissue engineering, including regulatory hurdles, biocompatibility, and scalability.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100099"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143379096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Forecasting of municipal solid waste generation in Türkiye and techno-economic-environmental assessment of electricity generation via incineration till 2032","authors":"Mehmet Melikoglu","doi":"10.1016/j.nxsust.2024.100092","DOIUrl":"10.1016/j.nxsust.2024.100092","url":null,"abstract":"<div><div>This paper develops a forecasting model for municipal solid waste (MSW) generation and its potential for energy recovery through incineration in Türkiye. MSW generation in 81 provinces of Türkiye are forecasted till 2032 using novel semi-empirical models based on two different scenarios. It is forecasted that Türkiye’s MSW generation in 2032 will reach up to 36.2 million tonnes and from incineration of this MSW up to 16.8 TWh of electricity worth 2.1 billion US$ (based on 2024 June wholesale industrial prices) can be generated. Nationwide greenhouse gas (GHG) emissions from incineration of MSW for electricity generation can reach 19.7 million tonnes of carbon dioxide in 2032. Root mean squared error and mean absolute percentage error values indicated high goodness of fit and accuracy for the forecasting models. As future research it is suggested that the methodology given in this study can be used by others for forecasting MSW generation with energy recovery as electricity via incineration and associated GHG emissions calculations in different countries conditional that historic geographical per capita data is available and associated model parameters are calculated based on existing circumstances.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100092"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143140691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nyiko M. Chauke , Richard M. Moutloali , James Ramontja
{"title":"Enhanced flux and fouling performance via H2N@ZSM-22 infused thin-film composite membranes on ZSM-22/PES-UF support","authors":"Nyiko M. Chauke , Richard M. Moutloali , James Ramontja","doi":"10.1016/j.nxsust.2024.100097","DOIUrl":"10.1016/j.nxsust.2024.100097","url":null,"abstract":"<div><div>In this study, advanced polyamide thin-film composite (PA-TFC) membranes incorporating zeolite (ZSM-22) and amine-zeolite (H<sub>2</sub>N@ZSM-22) fillers were synthesised <em>via</em> interfacial polymerisation (IP) to enhance water permeability performance and anti-fouling behaviour. The incorporation of zeolite and amine-zeolite ZSM-22 in the selective PA layer resulted in distinct ridge-like and valley-like surface morphologies, contributing to improved hydrophilicity and fouling resistance. Comprehensive characterisation using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and water contact angle (WCA) analysis confirmed the successful incorporation and uniform dispersion of zeolite and amine-zeolites fillers within the PA layer. The functionalised PA layers demonstrated superior hydrophilicity, resulting in significant improvements in water flux, high anti-fouling ratios and salt rejection compared to the zeolite PA-TFC membranes. The obtained PA-TFC membrane structural design, supported on ZSM-22/polyethersulfone ultrafiltration (ZSM-22/PES UF) substrate, played a crucial role in ensuring mechanical stability and promoting interfacial bonding. The amine-zeolites PA-TFC membranes achieved exceptional water fluxes, reaching up to 48.92 L·m⁻²·h⁻¹ ·bar⁻¹ , and exhibited fouling ratios ranging from 65.78 % to 73.68 % as well as salt rejection to about 77 %. Notably, the H<sub>2</sub>N@T60-ZSM-22/PA@ZSM-22/PES configuration showed the lowest fouling ratio of 65.78 % and higher salt rejection, demonstrating the potential for selective filtration under low-pressure conditions. Despite minimal performance variations among the different membrane configurations, consistent and robust antifouling behavior was observed across all samples. These findings underscore the promise of amine-zeolite ZSM-22 PA-TFC membranes as high-performance candidates for achieving enhanced flux, fouling resistance, and selective separation, contributing valuable insights for the advancement of membrane technology in water treatment applications.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100097"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pasupati Nath Khan , Sumit Pahan , A. Sengupta , Tessy Vincent
{"title":"Recovery of radio chemically pure 90Sr suitable for milking clinical grade 90Y from high level liquid waste: A process developmental investigation","authors":"Pasupati Nath Khan , Sumit Pahan , A. Sengupta , Tessy Vincent","doi":"10.1016/j.nxsust.2025.100111","DOIUrl":"10.1016/j.nxsust.2025.100111","url":null,"abstract":"<div><div>Radio chemically pure <sup>90</sup>Y is desired for its use as radio therapeutic agent. As a modern practice <sup>90</sup>Y, is milked from its parent <sup>90</sup>Sr, thus the radiochemical purity of resulted <sup>90</sup>Y will be governed by the purity of its parent Sr. High level liquid waste (HLLW) generated from the spent nuclear fuel reprocessing contains ample quantity of <sup>90</sup>Sr, the parent of its β decaying product <sup>90</sup>Y. In our previous studies it was explored that BOC8A/ Nitrooctane can be preferably used to recover <sup>90</sup>Sr in 0.01 M HNO<sub>3</sub> from HLLW with ∼1 % Am (III) & Eu (III) contamination. Thus, <sup>90</sup>Sr recovered needs multi step purification before milking <sup>90</sup>Y. To minimise the number of step in purification to obtain ultrapure <sup>90</sup>Sr (10<sup>−9</sup> Ci alpha / Ci Sr) a well-known hydrophilic supramolecule 18C6 is introduced in the stripping step. A new process scheme has been developed using BOC8A, 18C6 and Tetra-2-ethylhexyl diglycolamide etc. CHON based extractant to obtain highly pure <sup>90</sup>Sr product. The mechanism and effect of different parameters on stripping of Sr with 18C6 have also been investigated in detail. The stripping phenomenon has been found to be spontaneous at 298 K and the change in Gibb’s free energy was found to be - 22.9 kJ mol<sup>−1</sup>K<sup>−1</sup></div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100111"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143403021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Path of carbon dioxide capture technologies: An overview","authors":"Ashokkumar Shyam , Kalilur Rahiman Arshad Ahmed , Jeyaraman Prasanna Naveen Kumar , Selvarasan Iniyan , Ranko Goic","doi":"10.1016/j.nxsust.2025.100118","DOIUrl":"10.1016/j.nxsust.2025.100118","url":null,"abstract":"<div><div>Global warming and climate change is a critical issue worldwide. Carbon dioxide (CO<sub>2</sub>) emissions from human activities are considered to be one of the major pollutants among all the anthropogenic greenhouse gases (GHGs) contributing to global warming. The total carbon dioxide emissions can be reduced either by efficient use of low carbon fuels and also by using hydrogen and renewable energy systems and also by employing efficient carbon capture technologies. Among the aforesaid three approaches, carbon dioxide capture and storage is the most promising approach. There are literally around 50–60 different ways of carbon dioxide capture technologies available as from traditional approaches like physical absorption, chemical absorption, mixed solvents, and membrane based absorption to modern methodologies like cryogenic separation, gas hydrates, advanced membrane, mineral carbonation, biological fixation, direct air capture and storage. This review paper tries to address all the key available carbon capture technologies from lab-scale prototypes to commercial practices. In addition, this article attempts to provide a clear introduction and cumulative comparison of all the carbon dioxide capture technologies.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100118"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143479281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohamed A. Yassin , Sani I. Abba , A.G. Usman , Syed Muzzamil Hussain Shah , Isam H. Aljundi , Shafik S. Shafik , Zaher Mundher Yaseen
{"title":"Integrating experimental-based vulnerability mapping with intelligent identification of multi-aquifer groundwater salinization","authors":"Mohamed A. Yassin , Sani I. Abba , A.G. Usman , Syed Muzzamil Hussain Shah , Isam H. Aljundi , Shafik S. Shafik , Zaher Mundher Yaseen","doi":"10.1016/j.nxsust.2025.100115","DOIUrl":"10.1016/j.nxsust.2025.100115","url":null,"abstract":"<div><div>Groundwater salinization is a pressing global issue, threatening water security and sustainable development in many regions. In alignment with Saudi Vision 2030 and the Sustainable Development Goals (SDGs), this study addresses groundwater salinity challenges in the coastal regions of eastern Saudi Arabia through comprehensive experimental analysis and advanced mapping techniques. Groundwater samples were analyzed using ion chromatography (IC) and inductively coupled plasma mass spectrometry (ICP-MS) to determine salinity levels. The data were processed using ArcGIS 10.3 software to create vulnerability maps, supported by five artificial intelligence (AI)-based models for robust predictions and enhanced insights. Model performance was assessed using statistical parameters, including Nash–Sutcliffe efficiency (NSE), root mean square error (RMSE), Pearson correlation coefficient (PCC), and mean square error (MSE). Among the models, interactive learning (ILR-M3) delivered the best results (RMSE=0.0385; MSE=0.0015), while all models were validated as satisfactory. This research highlights the potential of combining experimental data with AI-driven approaches for effective water resource management. The outcomes directly support Saudi Vision 2030 and contribute to achieving the SDGs by advancing sustainable and intelligent solutions for global water security challenges.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100115"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143487382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}