{"title":"Review of starch-based coagulants for water treatment: Mechanisms, extraction and surface modification","authors":"","doi":"10.1016/j.nxsust.2024.100083","DOIUrl":"10.1016/j.nxsust.2024.100083","url":null,"abstract":"<div><div>As the UN Sustainable Development Goal 6 emphasizes, sustainable and equitable access to clean water is paramount to improving public health and minimizing waterborne disease transmission. Due to rapid urbanization and population growth, freshwater resources are depleted, and approximately two-thirds of the world’s population will experience severe water scarcity by 2050. The coagulation-flocculation method demonstrates a viable solution for water treatment due to the minimal technical requirements, short treatment duration, and low material cost. Recently, starch-based coagulants have garnered significant attention due to their non-toxic nature, abundance, and cost-effectiveness. However, the coagulation efficiency of starch can be further enhanced through surface modification. The performance efficiency of starch-based coagulants largely depends on the modification technique, as it may influence the density of the surface charge. This review paper comprehensively discusses the coagulation mechanism of starch-based coagulants and the distinct methods for starch extraction. The removal efficacy of starch-based coagulants primarily depends on various physicochemical properties such as surface functional groups, zeta potential, and the elemental and morphological properties of the coagulant. Tailoring these properties is essential for developing a promising starch-based coagulant capable of effectively removing pollutants from water. Finally, the future prospects of starch-based coagulants are provided to highlight the exciting opportunities for sustainable water treatment and alignment with circular economy principles.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142442332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Use of EDS/EDX to evaluate heavy metals pollution in water sources","authors":"","doi":"10.1016/j.nxsust.2024.100082","DOIUrl":"10.1016/j.nxsust.2024.100082","url":null,"abstract":"<div><div>The objective of the study was to evaluate the role of brick kilns in contaminating water bodies with heavy metals in Punjab, India. The energy-dispersive x-ray spectroscopy (EDS/EDX) machine effectively tested heavy metals in water samples. The research revealed that the surface water near the brick kilns was extensively polluted with heavy metals. Their Pollution Load Index (PLI) values varied between 2.83 and 52.98, and their degree of contamination was “Progressive deterioration”. The PLI values for groundwater ranged between 0.089 and 3.68, and the degree of contamination varied from “Baseline levels of pollutants” to “Progressive deterioration”. In general, the groundwater of the studied area had a PLI value of 0.477 (Baseline levels of pollutants), whereas the surface water had a PLI value of 11.453 (Progressive deterioration). The Water Quality Index (WQI) of groundwater was highly influenced by heavy metals, notably Arsenic (As) from lithologic origins, and Lead (Pb) from the burning of fuels in the brick kilns. In descending order, Pb>Zn>As>Cr>Ni metals were influencing the PLI, and the correlation matrixes demonstrated that the presence of heavy metals was associated with the PLI and WQI values. Therefore, there is evidence that brick kilns are polluting water bodies with heavy metals. EDS proved to be one of the instruments to evaluate the chemical elements in water. It was recommended to enforce the law governing the use of biomass to reduce vast quantities of coal used in baking bricks.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142442333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Incorporating industrial residue of submerged arc welding (SAW) in cement-based mortar matrices as a green strategy","authors":"","doi":"10.1016/j.nxsust.2024.100080","DOIUrl":"10.1016/j.nxsust.2024.100080","url":null,"abstract":"<div><div>The construction industry, a key player in the fight against greenhouse gas emissions and solid waste generation, is actively seeking sustainable solutions to mitigate environmental impacts. This study investigates the technical feasibility of incorporating submerged arc slag, a byproduct rich in calcium and silicon oxides, into the mechanical properties of mortars. Three mixtures with a water/cement ratio of 1.4 were prepared: a reference mixture, one with the addition of 10 % slag, and another with 10 % cement replaced by slag. Compressive strength tests were carried out at 7, 14, and 28 days and revealed average losses of 12.4 %, 18.9 %, and 22.9 % in the mixture with replaced cement, while the mixture with slag addition showed lower losses of 2.6 %, 4.9 %, and 5.3 %. Although partial replacement of cement affects strength, levels remain within regulatory limits, and slag contributes to reducing CO<sub>2</sub> emissions, minimizes waste generation, and promotes the valorization of industrial byproducts. This study underscores the role of the construction industry in mitigating environmental impacts and the potential of submerged arc slag as a sustainable and effective alternative, balancing mechanical performance and environmental impact in civil construction.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Copper-catalyzed plastic waste synthesized graphene nanosheets/polypyrrole nanocomposites for efficient thermoelectric applications","authors":"","doi":"10.1016/j.nxsust.2024.100081","DOIUrl":"10.1016/j.nxsust.2024.100081","url":null,"abstract":"<div><div>Presently, various catalysts have been reported for the synthesis of carbon nanomaterials from a variety of plastic waste, which needs to be removed at the end of the synthesis process by using chemical techniques and hence make the process more typical from the aspect of cost-benefit and circular economic aspects. Herewith, we report copper turnings as the cost-effective and greener catalytic templates for synthesizing highly conducting graphene nanosheets (GNs). The synthesis of the GNs from plastic waste was done as we previously reported in the steps of the pyrolytic process, where the copper turnings are used as catalytic templates in the present study. Because of the excellent catalytic efficiency towards breaking old carbon-carbon bonds and forming new carbon-carbon bonds, the copper turnings act as an excellent degradation catalyst and promote the growth of graphitic skeletons and, consequently, graphene nanosheets. The synthesized GNs showed a high conductivity of ∼ 1730 S/m. GNs thus synthesized is implemented for synthesizing GNs/polypyrrole nanocomposites, which is later investigated for the TE applications. The values of the Seebeck coefficient showed that the composite of GNs/polypyrrole performs as a p-type semiconductor. The TE figure of merit (ZT) for GNs/polypyrrole demonstrated good thermoelectric characteristics and showed a value of 3.75 × 10<sup>−6</sup> at the temperature. Thus, the present method of synthesis of GNs showed a more convenient, industrial friendly technique for the production of plastic waste derived graphene nanosheets and its application for thermal energy conversion applications.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"BIM-based parametric energy analysis of green building components for the roofs and facades","authors":"","doi":"10.1016/j.nxsust.2024.100078","DOIUrl":"10.1016/j.nxsust.2024.100078","url":null,"abstract":"<div><div>Buildings are distinguished by their high energy demand over their lifespan. Iimproving energy efficiency in buildings necessitates mitigating the operation energy performance by evaluating more sustainable building components such as green infrastructures. The novelty herein is to conduct a BIM-based parametric energy analysis of green building components for the roofs and facades, taking into consideration the climate classification and orientation of the building. The proposed framework of this study uses Autodesk Revit software and Autodesk Green Building Studio as BIM tools, and Minitab software as a parametric analysis tool to estimate the energy performance of several alternative components based on Energy Use Intensity (EUI) and Annual Peak Demand (APD). A case study of a residential building is examined in four cities within different climate zones in Brazil; Rio de Janeiro (climate zone 08), Macaé (climate zone 05), Petrópolis (climate zone 03), and Nova Friburgo (climate zone 02). The base model design of components of the building includes a reinforced concrete roof and ceramic masonry façade. The utilized alternatives are roof components (i.e. green roofs and expanded clay roofs), and green façade. This work insight using green façade for all elevations and green roofs to enhance energy efficiency in terms of EUI by (10,17 %) in Rio de Janeiro, (6,67 %) in Macaé, (11,43 %) in Pertópolis, and (16,43 %) in Nova Friburgo. While the efficiency in terms of APD would be about (28,07 %) in Rio de Janeiro, (22,79 %) in Macaé, (21,67 %) in Pertópolis, and (12,58 %) in Nova Friburgo. When the construction project is designed to install a green façade to the main elevation only, this work recommends using green roofs rather than the expanded clay roof or the base model design roofs to increase energy efficiency in such types of buildings. This work contributes to integrating green building components into building designs to improve energy efficiency and empower decision-making and sustainability in buildings.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Combination of the degrading bacterium Bacillus cereus MZ-1 and corn straw biochar enhanced the removal of imazethapyr from water solutions","authors":"","doi":"10.1016/j.nxsust.2024.100077","DOIUrl":"10.1016/j.nxsust.2024.100077","url":null,"abstract":"<div><div>Long residual herbicide imazethapyr has caused a serious threat to subsequent sensitive crop plants and ecological security. Efficient immobilized microorganism technology offers a sustainable solution for remediating pesticides contamination. In this study, three corn straw biochars produced at 300℃, 500℃, and 700℃ were used as carriers to immobilize the imazethapyr degrading strain <em>Bacillus cereus</em> MZ-1, aiming to efficiently remove imazethapyr from the water environment. Response surface methodology was employed to optimize the best immobilization conditions based on the efficiency of imazethapyr removal. The results indicate that the biochar produced at 500 ℃ was the most effective carrier for immobilization, despite having a lower imazethapyr removal capacity compared to the biochar produced at 700 ℃. Additionally, the optimal strain addition amount was a suspension of strain MZ-1 (OD<sub>600</sub>=1) in a 3.5-fold biochar solution, and the best immobilized time was 18 h. The prepared immobilized MZ-1 achieved a maximum imazethapyr removal efficiency of 79.85 %. Moreover, the immobilized MZ-1 demonstrated enhanced detoxification efficacy against imazethapyr-induced harm in sensitive oilseed rape crops, surpassing the effects of using MZ-1 or biochar alone. Results of this work suggests biochar immobilized degradation strain MZ-1 is a highly effective in-situ remediation strategy for bioremediation of imazethapyr contamination.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Simultaneous removal of heavy metals and Escherichia coli from water using silver-doped hydroxyapatite-coated activated carbon nano composite-alginate beads","authors":"","doi":"10.1016/j.nxsust.2024.100076","DOIUrl":"10.1016/j.nxsust.2024.100076","url":null,"abstract":"<div><div>The scarcity of clean water due to heavy metal and microbial contamination is a global issue. In many parts of the world, heavy metals such as Pb, Cd, and U, along with bacteria like <em>Escherichia coli</em>, have been found to exceed permissible limits in groundwater and other water sources that the public depends on for daily drinking water. To address this, we have synthesized a novel composite material consisting of Ag-impregnated hydroxyapatite-coated activated carbon nanoparticles embedded in alginate beads, for the simultaneous removal of heavy metals (U, Pb, and Cd) and <em>Escherichia coli</em> from drinking water. The material's efficiency was evaluated through a series of batch and column experiments. Batch studies indicate 90 % sequestration of U within 5 hours and Pb and Cd within 7 hours, while <em>Escherichia coli</em> (10<sup>7</sup> cfu/mL) was eradicated instantly. The study confirms that sorption follows pseudo-second-order kinetics via chemisorption and ion-exchange mechanisms. Fixed-bed column studies, using a logistic growth model, showed strong agreement between theoretical and experimental parameters for the Bohart-Adams, Thomas, and Yoon-Nelson models. The beads demonstrated a high affinity for heavy metals, achieving complete removal and disinfection within an empty bed contact time of 1.12 minutes. Reusability studies indicate that even after the third regeneration and reuse cycle, removal efficiency remained about 95 % for U and Pb, and 85 % for Cd. Furthermore, the effects of variations in water quality parameters such as pH, dissolved carbonates, humic acid, and ionic strength (except for Cd) on removal efficiency were minimal. In summary, the study revealed that the Ag-impregnated hydroxyapatite-coated activated carbon nanoparticles embedded in alginate beads are an efficient, sustainable, and cost-effective material for the simultaneous removal of Pb, Cd, U, and <em>Escherichia coli</em> from water with diverse physicochemical properties.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and structural analysis of calcined poultry manure for hydroxyapatite development","authors":"","doi":"10.1016/j.nxsust.2024.100079","DOIUrl":"10.1016/j.nxsust.2024.100079","url":null,"abstract":"<div><div>This study investigates the viability of utilizing poultry manure, an abundant and low-cost waste material, for the synthesis of hydroxyapatite (HAp), a critical biomaterial for bone regeneration. Calcination of poultry manure was conducted at 750°C, 800°C, and 850°C for 5 h to produce HAp. The processed poultry manure was then characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) with energy dispersive X-ray spectrometry (EDS), X-ray fluorescence (XRF), and X-ray diffraction (XRD) analyses. The FTIR analysis confirmed the formation of HAp through characteristic phosphate absorption bands, with the highest purity observed at 850°C. SEM analysis revealed that increasing calcination temperature enhanced the crystallinity and particle uniformity of the samples. XRF analysis showed a significant increase in CaO (40.229–43.328 %) and P<sub>2</sub>O<sub>5</sub> (17.905–19.239 %) content with rising temperatures, crucial for HAp synthesis. The Ca/P ratios were determined to be 1.28, 1.54, and 1.71, respectively, indicating variations in purity and phase composition. The 800°C provides a near-ideal Ca/P ratio while the 850°C achieves a ratio slightly above the ideal, indicating a high-purity HAp phase. XRD analysis corroborated these findings, identifying hydroxyapatite (Ca<sub>10</sub>P<sub>6</sub>O<sub>26</sub>H<sub>2</sub>), as the predominant phase with minimal secondary phases. These results suggest that calcination at 850°C is optimal for producing high-purity HAp from poultry manure, offering a sustainable and cost-effective alternative to synthetic HAp production for biomedical applications.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A comprehensive review on the properties of hemp incorporated concrete: An approach to low carbon footprint construction","authors":"","doi":"10.1016/j.nxsust.2024.100075","DOIUrl":"10.1016/j.nxsust.2024.100075","url":null,"abstract":"<div><div>As the demand for sustainable construction materials rises, hemp-infused concrete has emerged as a promising solution to reduce carbon emissions and promote eco-friendly building practices. This review critically assesses hemp concrete's mechanical, thermal, and durability properties, highlighting its potential for widespread adoption in various industries. Hemp's porous structure contributes to improved thermal insulation, soundproofing, and biological resistance, making it suitable for in-fill materials, plastering, and insulation applications. However, its low compressive and flexural strength remains challenging, limiting mainstream use. Hemp content and composition variations have resulted in differing properties, necessitating further research to optimize the material. The study identifies the growing collaboration among countries to promote bio-based materials but acknowledges the lack of standardized norms for hemp concrete in general construction. It stresses the importance of developing uniform standards to ensure consistent quality, performance, and regulatory compliance. This study explores the properties of hemp-infused concrete. It assesses its potential as a sustainable building material while identifying gaps in research and standardization needed for its widespread adoption in the construction industry.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142416007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Data driven-based machine learning modelling and empirical correlations for predicting snow-covered area in the Swat Region, Pakistan","authors":"","doi":"10.1016/j.nxsust.2024.100074","DOIUrl":"10.1016/j.nxsust.2024.100074","url":null,"abstract":"<div><div>In recent decades, global and regional climate change has emerged as a significant challenge with potential catastrophic consequences, including hurricanes, floods, sea level rise, and temperature shifts. Snow-covered area (SCA) serves as a crucial climatic parameter reflecting climate changes, yet accurately determining SCA proves to be a challenging and time-consuming task. This study aims to develop robust prediction models for SCA by employing three machine learning (ML) approaches using readily available climatic data from Swat, Pakistan, spanning two decades. The climate data encompass precipitation, daily maximum/minimum temperatures, and SCA measurements. Three ML methods—artificial neural networks (ANN), functional networks (FN), and adaptive neuro-fuzzy inference systems (ANFIS)—were employed to model SCA. Accuracy measures, including coefficient of determination (R<sup>2</sup>), average absolute percentage error (AAPE), and root mean squared error (RMSE) were utilized to evaluate model performance. All three ML models exhibited superior performance, with high R<sup>2</sup> values and low errors. Accuracy indicators of the ANN model are better than FN and ANFIS models, yielding the highest R<sup>2</sup> (0.956) and minimum RMSE and AAPE values (0.61 and 0.91). ANFIS demonstrated slightly better performance than FN, with RMSE, AAPE, and R<sup>2</sup> values of 0.65, 1.1, and 0.950, respectively. FN yielded RMSE, AAPE, and R values of 1.14, 1.72, and 0.85, respectively. Additionally, two empirical correlations were derived from the optimized FN and ANN models for SCA prediction using the same input variables. This study underscores the efficacy of ML techniques in accurately and consistently predicting SCA parameters, offering valuable insights into climate change and its consequences.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142357032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}