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Comparative study on sunlight induced surfactants system in photogalvanics for solar energy conversion and storage
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100101
Mohan Lal Mohan, KM Gangotri
{"title":"Comparative study on sunlight induced surfactants system in photogalvanics for solar energy conversion and storage","authors":"Mohan Lal Mohan,&nbsp;KM Gangotri","doi":"10.1016/j.nxsust.2025.100101","DOIUrl":"10.1016/j.nxsust.2025.100101","url":null,"abstract":"<div><div>The aim of the study is to harness and store solar energy through photogalvanic (PG) cells. The mixed surfactant pairs, i.e., NaLS+Brij-35 and NaLS+Tween-80, with photosensitizer methylene blue and reductant D-xylose have been used for PG cells. The resulting photoelectrochemical process in photogalvanics leads to energy conversion for sustainable development in the field of solar energy. The electrical outcomes, i.e., V<sub>OC</sub>, SPP, SPC, SP, and SCE, were studied for a sunlight-induced PG cell for photocatalytic conversion. The observed V<sub>OC</sub>, SPP, SPC, SP, and SCE with NaLS+Tween-80 surfactant is of the order of 1120 mV, 867 mV 238.00 µA, 206.34 µW, and 1.3012 %, respectively. The observed V<sub>OC</sub>, SPP, SPC, SP, and SCE with NaLS+Brij-35 surfactant is of the order of 1123 mV, 870 mV, 240.00 µA, 208.80 µW, and 1.3112 %, respectively. Conclusively, PG cells with NaLS+Brij-35 surfactant are better than PG cells with NaLS+Tween-80. This new combination of surfactants still has the scope to achieve the enhanced electrical results of PG cells for sustainable development.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100101"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crayfish shell biochar for methyl violet adsorption: Equilibrium and kinetic studies
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2024.100093
Azrul Nurfaiz Mohd Faizal , Chew Hui Wen , Nicky Rahmana Putra , Ahmad Syahmi Zaini , Augustine Agi , Abu Hassan Nordin , Muhammad Abbas Ahmad Zaini
{"title":"Crayfish shell biochar for methyl violet adsorption: Equilibrium and kinetic studies","authors":"Azrul Nurfaiz Mohd Faizal ,&nbsp;Chew Hui Wen ,&nbsp;Nicky Rahmana Putra ,&nbsp;Ahmad Syahmi Zaini ,&nbsp;Augustine Agi ,&nbsp;Abu Hassan Nordin ,&nbsp;Muhammad Abbas Ahmad Zaini","doi":"10.1016/j.nxsust.2024.100093","DOIUrl":"10.1016/j.nxsust.2024.100093","url":null,"abstract":"<div><div>This work was aimed to establish the equilibrium and kinetics of methyl violet removal onto crayfish shell biochars. The biochars were prepared through pyrolysis at 500, 650 and 800 <span><math><mi>℃</mi></math></span> for 1.5 h. The biochars were labelled as CS500, CS650 and CS800, respectively. All biochars are highly mesoporous with CS650 exhibits a higher surface area of 665 m<sup>2</sup>/g. The adsorption results are tied up with the physiochemical properties of biochars. The CS800 displays the maximum dye capacity at 1079 mg/g. The performance of biochars is given in the order of, CS800 &gt; CS650 &gt; CS500. The equilibrium of methyl violet adsorption was best described by modified Langmuir isotherm, while the kinetic data obeyed pseudo-second-order model. The removal of methyl violet is governed partly by precipitation onto crayfish shell biochars. To conclude, the crayfish shell is a potential feedstock of biochar for dye wastewater treatment.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100093"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Continuous electrocoagulation treatment of chromium from tannery wastewater in a cylindrical column
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100113
Nahid M. Genawi , Nafis Mahmud , Elfatih A. Hassan , Muftah H. El-Naas
{"title":"Continuous electrocoagulation treatment of chromium from tannery wastewater in a cylindrical column","authors":"Nahid M. Genawi ,&nbsp;Nafis Mahmud ,&nbsp;Elfatih A. Hassan ,&nbsp;Muftah H. El-Naas","doi":"10.1016/j.nxsust.2025.100113","DOIUrl":"10.1016/j.nxsust.2025.100113","url":null,"abstract":"<div><div>Discharging tannery wastewater into the water resources can lead to several environmental implications due to its high chromium and pollutants content, adversely affecting both aquatic and human life. Consequently, researchers are focusing on the development of efficient treatment methods for post-tanning effluents with the target of removing chromium to alleviate this pollution problem. In this regard, electrocoagulation has emerged as a leading technology for chromium removal from tannery wastewater. In this study, a continuous electrocoagulation column was applied for the removal of chromium ions from tannery wastewater collected from local industry. The effect of current density, pH, and effluent chromium concentration were studied for the removal of chromium ions. The results showed that a maximum chromium removal (99.94 %) was achieved within one hour in batch mode at current density, pH, and effluent concentration of 10 mA/cm<sup>2</sup>, 6.5, and 500 mg/L, respectively. The continuous electrocoagulation system was used to evaluate the process dynamics and steady-state stability of the reactor system by introducing step changes in operating conditions (flow rate, pH, current density, and concentration). The experiments of the continuous electrocoagulation reactor system were conducted at a flow rate of 50 ml/min (HRT = 34 min) with the results promise effective removal of chromium ions from tannery wastewater using the electrocoagulation system.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100113"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143377916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Closing the PET plastic recycling loop: A sustainable transformation from plastic to fiber
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2024.100095
Theresa Massoud , Jacinta Dsilva
{"title":"Closing the PET plastic recycling loop: A sustainable transformation from plastic to fiber","authors":"Theresa Massoud ,&nbsp;Jacinta Dsilva","doi":"10.1016/j.nxsust.2024.100095","DOIUrl":"10.1016/j.nxsust.2024.100095","url":null,"abstract":"<div><div>Universities and colleges are becoming models for the rest of the world in sustainability initiatives. A Dubai-based university has taken action by collaborating with two industry entities in the application of the 3 R Model to promote sustainability. This article aims to investigate each phase of this collaboration, which includes a waste management company to collect the community’s mixed plastic; a material recovery facility to segregate the polyethylene terephthalate (PET) plastic; and a sustainable manufacturing solutions entity called DGrade to sustainably transform the PET plastic into fibers that produce over 200 types of fabrics. DGrade synthesizes clothing and supplies from these fabrics that are sold back to the University. This process uses 76 % less energy, 20 % less water (remaining 80 % is recycled back), and lowers carbon emissions by 79 %. Giving PET plastic a second life provides a practical solution to the challenges posed by the global plastic waste crisis and successfully closes the loop on the recycling of PET plastic.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100095"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163060","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioengineering in Solid-State Fermentation for next sustainable food bioprocessing
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100105
Muyideen Olaitan Bamidele, Micheal Bola Bamikale, Eliseo Cárdenas-Hernández, Motolani Adepeju Bamidele, Guillermo Castillo-Olvera, José Sandoval-Cortes, Cristóbal Noe Aguilar
{"title":"Bioengineering in Solid-State Fermentation for next sustainable food bioprocessing","authors":"Muyideen Olaitan Bamidele,&nbsp;Micheal Bola Bamikale,&nbsp;Eliseo Cárdenas-Hernández,&nbsp;Motolani Adepeju Bamidele,&nbsp;Guillermo Castillo-Olvera,&nbsp;José Sandoval-Cortes,&nbsp;Cristóbal Noe Aguilar","doi":"10.1016/j.nxsust.2025.100105","DOIUrl":"10.1016/j.nxsust.2025.100105","url":null,"abstract":"<div><div>Solid-State Fermentation (SSF) is a breakthrough approach in the sustainable bioprocessing of foods that applies bioengineering techniques to enhance the accumulation of bioactive compounds in functional foods. A review of bioengineering strategies that optimize microbial growth and metabolite production in SSF systems is presented in this chapter, including novel bioreactor designs and genetic engineering of microorganisms combined with metabolic engineering. The present document also describes some of the important developments in the extraction and purification of bioactive molecules from SSF processes, with special emphasis on their potential for using waste from the food industry to reduce the environmental burden. Combining SSF with state-of-the-art biotechnological tools aids in the efficient production of high value-added compounds, placing a strong basis for economic-ecological sustainability. The document further elaborates on the optimization techniques necessary for the maximum efficiency of SSF processes, trends, and challenges in the area in the future, and case studies that illustrate their application in real life. By providing an incisive review of the present status and future directions of SSF in food bioprocessing, this contribution highlights the importance of SSF in promoting sustainable food production systems.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100105"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Java and Bali land surface temperature decrease variation
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2024.100096
Munawar Munawar , Tofan Agung Eka Prasetya , Marzuki Marzuki , Muhamad Rifki Taufik , Teuku Fadhla
{"title":"Java and Bali land surface temperature decrease variation","authors":"Munawar Munawar ,&nbsp;Tofan Agung Eka Prasetya ,&nbsp;Marzuki Marzuki ,&nbsp;Muhamad Rifki Taufik ,&nbsp;Teuku Fadhla","doi":"10.1016/j.nxsust.2024.100096","DOIUrl":"10.1016/j.nxsust.2024.100096","url":null,"abstract":"<div><div>The world is facing global warming due to natural processes and human activities. From 1880–1980, the global average temperature increased by 1°C per century. Land Surface Temperature (LST) is a crucial climatic variable for analyzing the interaction between the Earth's surface and the atmosphere. Java Island has the highest population and is more urbanized than other islands in Indonesia. From January 2001 to January 2020, LST daytime data were downloaded from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) and Visible Infrared Imaging Radiometer Suite (VIIRS) Land Products Global Subsetting and Visualization Tool. This study aims to investigate the LST seasonal patterns and trends of Bali and Java islands. The appropriate distance between sub-regions was also observed, with 105 pixels and 52.5 pixels producing two and six super-regions, respectively. It was found that seasonal patterns could be represented with pixel distances of 105 and 52.5, using eight knots of cubic splines. From 2001–2020, the lowest LST was recorded in January, while the highest was in September. The highest average daily LST, 38.32 °C, was found in Cikande, Serang, and Banten, likely due to industrial activity. This study also analyzed LST fluctuations using seven knots of the cubic spline. It was found that the average daily LST decreased by −0.113 °C per decade in Java and Bali. The western super-regions of Java showed significant LST increases, while the eastern super-regions showed slight decreases. For the 52.5-pixel distance, there was no substantial variation in average LST, though Jakarta and Banten showed significant increases. The 105-pixel distance is useful for examining LST variations on small islands like Java, while the 52.5-pixel distance can detect deeper variations in smaller super-regions. This study also noted that monsoon season and precipitation impact LST decline, and suggested that further research is needed to validate these findings. Additional variables like NDVI, land elevation, and land cover should be considered for more accurate estimations, especially on larger islands or continents farther from the equator.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100096"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in carbon dioxide capture and conversion technologies: Industrial integration for sustainable chemical production
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100108
Okezie Emmanuel , Rozina , Thaddeus C. Ezeji
{"title":"Advances in carbon dioxide capture and conversion technologies: Industrial integration for sustainable chemical production","authors":"Okezie Emmanuel ,&nbsp;Rozina ,&nbsp;Thaddeus C. Ezeji","doi":"10.1016/j.nxsust.2025.100108","DOIUrl":"10.1016/j.nxsust.2025.100108","url":null,"abstract":"<div><div>Developing efficient strategies to capture carbon dioxide (CO<sub>2</sub>) is essential to addressing the escalating challenges of global warming. Despite being a major greenhouse gas, CO<sub>2</sub> holds significant potential as a sustainable feedstock for chemical production. It can serve as a solvent, a preservative, a raw material for producing fuels, carbonates, polymers, and chemicals, and as a recovery agent for processes such as enhanced coal bed methane and oil recovery. This review highlights significant progress made in CO<sub>2</sub> capture and its integration into various industrial applications. While technologies such as adsorption, absorption, membrane separation, and cryogenics have shown promise, challenges related to cost, scalability, and the efficiency of capture and utilization continue to pose significant barriers to widespread adoption. Innovative strategies, including integrated carbon capture and conversion (ICCC) and integrated carbon capture and utilization (ICCU), present promising pathways to reduce costs by combining capture and utilization processes within a single facility. Additionally, catalytic processes and biological systems, such as microalgae and microbial strains (e.g., acetogens), are paving the way for sustainable CO<sub>2</sub> conversion into high-value products. Successful large-scale deployment of these technologies will require sustained interdisciplinary collaboration, robust policy frameworks, and increased investment in research and development. Prioritizing sustainable energy development and management offers the potential to significantly reduce anthropogenic CO<sub>2</sub> emissions while creating useful products. Advancing these technologies will not only help in mitigating climate change but also promote the transition to a circular carbon economy, which aligns with global sustainability goals.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100108"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of glass fiber hybridization and radiation treatment to improve the performance of sustainable natural fiber-based hybrid (jute/glass) composites
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100104
S.H. Mahmud , S.C. Das , A. Saha , T. Islam , D. Paul , M.W. Akram , M.S. Jahan , M.Z.I. Mollah , M.A. Gafur , R.A. Khan
{"title":"Effect of glass fiber hybridization and radiation treatment to improve the performance of sustainable natural fiber-based hybrid (jute/glass) composites","authors":"S.H. Mahmud ,&nbsp;S.C. Das ,&nbsp;A. Saha ,&nbsp;T. Islam ,&nbsp;D. Paul ,&nbsp;M.W. Akram ,&nbsp;M.S. Jahan ,&nbsp;M.Z.I. Mollah ,&nbsp;M.A. Gafur ,&nbsp;R.A. Khan","doi":"10.1016/j.nxsust.2025.100104","DOIUrl":"10.1016/j.nxsust.2025.100104","url":null,"abstract":"<div><div>The current work aims to utilize sustainable natural fibers such as jute fiber in composite materials and a sustainable technology such as gamma (γ) irradiation to further treat the composites for their performance enrichment. First, synthetic glass fibers were hybridized to improve the performance of natural fiber composites (NFCs) with different stacking sequences. Jute fabrics were used as a natural fiber reinforcement and unsaturated polyester resin was employed as a thermoset polymer matrix. Composite laminates were manufactured by compression molding using a heat press machine. After hybridization, the mechanical properties and water resistance were improved compared to the neat NFCs (i.e., jute fiber composites, J0). The tensile strength, bending strength, tensile modulus, bending modulus, and impact strength were improved to 7–56, 5–53, 21–54, 27–69, and 199–387 %, respectively, than the J0. Further, gamma (γ) irradiation (5.0 kGy) was employed as a sustainable and chemical-free technology to treat the hybrid composite materials and improve the performance, and the optimum improvement was revealed for H3 (G<sub>2</sub>J<sub>4</sub>G<sub>2</sub>) hybrid composites. For H3, the enhancement of tensile, bending and impact strength was revealed at approximately 28, 65 and 27 %, respectively, while the tensile and bending modulus were exhibited at approximately 27 and 71 %, respectively, compared to their non-irradiated composite ones. Further characterization of the composites was studied by FTIR (Fourier Transform Infrared) spectroscopy and SEM (Scanning Electron Microscopy) experimentation.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100104"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143163066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient Phosphorus capture from treated sanitary wastewater using a waste-derived SiO2@FeOOH composite: Robustness, Ca2+ interactions, and recovery perspectives
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2024.100091
Renan S. Nunes , Gabriela T.M. Xavier , Alessandro L. Urzedo , Pedro S. Fadini , Marcio Romeiro , Wagner A. Carvalho
{"title":"Efficient Phosphorus capture from treated sanitary wastewater using a waste-derived SiO2@FeOOH composite: Robustness, Ca2+ interactions, and recovery perspectives","authors":"Renan S. Nunes ,&nbsp;Gabriela T.M. Xavier ,&nbsp;Alessandro L. Urzedo ,&nbsp;Pedro S. Fadini ,&nbsp;Marcio Romeiro ,&nbsp;Wagner A. Carvalho","doi":"10.1016/j.nxsust.2024.100091","DOIUrl":"10.1016/j.nxsust.2024.100091","url":null,"abstract":"<div><div>Phosphorus uptake and recovery from sanitary wastewater have been considered a promising approach to producing more sustainable fertilizers, in addition to reducing environmental damage caused by the discharge of this nutrient into water streams. In this study, the Phosphorus adsorption/desorption dynamics exhibited by a tailored SiO<sub>2</sub>@FeOOH adsorbent, produced using quartz sand waste and Fe derived from the acid dissolution of scrap iron, were examined. The adsorbent’s behavior, robustness, and interaction with Ca<sup>2+</sup> ions in simulated treated sanitary wastewater were systematically investigated. As a result, the behavior of the adsorbent under controlled conditions was successfully modeled, and relevant interactions between the material and Ca<sup>2+</sup> ions were identified under simulated conditions. The performance of the adsorbent was not affected by the presence of nitrate, carbonate, sulfate, ammonium, fluoride, and humic substances in the simulated media. Additionally, the composite can adsorb humic substances and Phosphorus simultaneously, without interfering with its Phosphorus adsorption capacity. In simulated treated wastewater, the adsorption of the nutrient was enhanced in the presence of Ca<sup>2+</sup>; however, the formation of insoluble Ca/P deposits on the adsorbent surface significantly changed the adsorption dynamics and disturbed the recovery of Phosphorus using the usual alkaline desorption method. The adsorbent exhibited a robust Phosphorus adsorption capacity as high as 40 mg P/g in simulated treated wastewater, showing clear potential for Phosphorus uptake in Wastewater Treatment Plants. Based on the experimental evidence, future perspectives on the final disposal of the spent adsorbent were also discussed within a circular economy framework.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"5 ","pages":"Article 100091"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143140690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical urea degradation and energy co-generation using palladium and iron-based catalysts
Next Sustainability Pub Date : 2025-01-01 DOI: 10.1016/j.nxsust.2025.100102
Nivaldo G. Pereira Filho, Victoria A. Maia, Rodrigo F.B. de Souza, Almir O. Neto
{"title":"Electrochemical urea degradation and energy co-generation using palladium and iron-based catalysts","authors":"Nivaldo G. Pereira Filho,&nbsp;Victoria A. Maia,&nbsp;Rodrigo F.B. de Souza,&nbsp;Almir O. Neto","doi":"10.1016/j.nxsust.2025.100102","DOIUrl":"10.1016/j.nxsust.2025.100102","url":null,"abstract":"<div><div>Cyclic voltammetry and in-situ ATR-FTIR spectroscopy experiments revealed that urea oxidation occurs through both faradaic direct and indirect mechanisms. The Pd/C electrocatalyst facilitated the formation of formate and NO<sub>x</sub> species, while Fe/C predominantly promoted formate formation via an indirect pathway, attributed to the high activity of iron in water activation. Polarization and power density curves indicated that both electrocatalysts degraded urea with simultaneous energy co-generation, showing comparable activity. Pd/C achieved a power density of 1.3 mW cm⁻², while Fe/C reached 1.1 mW cm⁻². Although Pd/C demonstrated advantages in reaction kinetics, the significantly lower cost of iron positions Fe/C as a promising alternative for practical applications, particularly in direct urea-fed fuel cell reactors. Additionally, Fe/C exhibited 50 % higher urea consumption near the open circuit potential compared to Pd/C, highlighting its potential for the development of more cost-effective and efficient fuel cell designs.</div></div>","PeriodicalId":100960,"journal":{"name":"Next Sustainability","volume":"6 ","pages":"Article 100102"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143162225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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