Interdisciplinary Materials最新文献_第9页

Fluorinated boron nitride nanosheet enhanced ultrathin and conductive polymer electrolyte for high-rate solid-state lithium metal batteries 氟化氮化硼纳米片增强超薄导电聚合物电解质用于高速率固态锂金属电池

Interdisciplinary Materials Pub Date : 2023-10-31 DOI: 10.1002/idm2.12121

Linjun Wang, Haodong Shi, Yingpeng Xie, Zhong-Shuai Wu

{"title":"Fluorinated boron nitride nanosheet enhanced ultrathin and conductive polymer electrolyte for high-rate solid-state lithium metal batteries","authors":"Linjun Wang, Haodong Shi, Yingpeng Xie, Zhong-Shuai Wu","doi":"10.1002/idm2.12121","DOIUrl":"https://doi.org/10.1002/idm2.12121","url":null,"abstract":"Polyethylene oxide (PEO)-based polymer solid electrolytes (PSE) have been pursued for the next-generation extremely safe and high-energy-density lithium metal batteries due to their exceptional flexibility, manufacturability, and lightweight nature. However, the practical application of PEO-PSE has been hindered by low ionic conductivity, limited lithium-ion transfer number (tLi+), and inferior stability with lithium metal. Herein, an ultrathin composite solid-state electrolyte (CSSE) film with a thickness of 20 μm, incorporating uniformly dispersed two-dimensional fluorinated boron nitride (F-BN) nanosheet fillers (F-BN CSSE) is fabricated via a solution-casting process. The integration of F-BN effectively reduces the crystallinity of the PEO polymer matrix, creating additional channels that facilitate lithium-ion transport. Moreover, the presence of F-BN promotes an inorganic phase-dominated electrolyte interface film dominated by LiF, Li2O, and Li3N on the lithium anode surface, greatly enhancing the stability of the electrode-electrolyte interface. Consequently, the F-BN CSSE exhibits a high ionic conductivity of 0.11 mS cm−1 at 30°C, high tLi+ of 0.56, and large electrochemical window of 4.78 V, and demonstrates stable lithium plating/striping behavior with a voltage of 20 mV for 640 h, effectively mitigating the formation of lithium dendrites. When coupled with LiFePO4, the as-assembled LiFePO4|F-BN CSSE|Li solid-state battery achieves a high capacity of 142 mAh g−1 with an impressive retention rate of 82.4% after 500 cycles at 5 C. Furthermore, even at an ultrahigh rate of 50 C, a capacity of 37 mAh g−1 is achieved. This study provides a novel and reliable strategy for the design of advanced solid-state electrolytes for high-rate and long-life lithium metal batteries.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"2 5","pages":"789-799"},"PeriodicalIF":0.0,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71924624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A tough injectable self-setting cement-based hydrogel for noninvasive bone augmentation 一种用于非侵入性骨增强的可注射自固化水泥基水凝胶

Interdisciplinary Materials Pub Date : 2023-10-18 DOI: 10.1002/idm2.12119

Peng Jin, Mingjie Xia, Masoud Hasany, Pan Feng, Jing Bai, Jian Gao, Wei Zhang, Mehdi Mehrali, Ruixing Wang

{"title":"A tough injectable self-setting cement-based hydrogel for noninvasive bone augmentation","authors":"Peng Jin, Mingjie Xia, Masoud Hasany, Pan Feng, Jing Bai, Jian Gao, Wei Zhang, Mehdi Mehrali, Ruixing Wang","doi":"10.1002/idm2.12119","DOIUrl":"https://doi.org/10.1002/idm2.12119","url":null,"abstract":"Composite hydrogels with excellent properties can open new opportunities to terminate the need for auto/allografts in bone augmentations. However, their clinical application has been limited by their insufficient mechanical strength and lack of osteoinductivity. Here we report a new strategy to design an injectable bioactive double network hydrogel reinforced by inorganic calcium/magnesium phosphate cement (CMPC) hydrates to meet the mechanical performance requirements for bone regeneration. The engineered CMPC hydration endows the composite hydrogel with an appropriate gelation time and temperature for injection, which shows no harm in the defect site. CMPC hydrates could also provide a lower swelling ratio and higher biodegradation rate fitting the in vivo bone regeneration needs. In vitro and in vivo experiments prove that the ions released from inorganic particles endow biocompatibility, cell migration, adhesion, differentiation, and significantly higher bone regeneration capacity. Taken together, the simple addition of CMPC particles imparts in-demand features that bring us closer to the clinical utilization of hydrogel-based materials for bone regeneration.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"2 5","pages":"771-788"},"PeriodicalIF":0.0,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71965656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in photocatalytic hydrogen evolution of AgIn5S8-based photocatalysts AgIn5S8基光催化剂光催化析氢研究进展

Interdisciplinary Materials Pub Date : 2023-10-12 DOI: 10.1002/idm2.12120

Xinlong Zheng, Yuqi Yang, Yiming Song, Zongxian Ma, Qizhi Gao, Yuhao Liu, Jing Li, Xiao Wu, Xingbo Wang, Weihua Mao, Weifeng Liu, Yijun Shen, Xinlong Tian

{"title":"Recent advances in photocatalytic hydrogen evolution of AgIn5S8-based photocatalysts","authors":"Xinlong Zheng, Yuqi Yang, Yiming Song, Zongxian Ma, Qizhi Gao, Yuhao Liu, Jing Li, Xiao Wu, Xingbo Wang, Weihua Mao, Weifeng Liu, Yijun Shen, Xinlong Tian","doi":"10.1002/idm2.12120","DOIUrl":"https://doi.org/10.1002/idm2.12120","url":null,"abstract":"The development of semiconductor photocatalysts is of great significance for the realization of efficient photocatalytic hydrogen evolution (PHE). AgIn5S8, as an emerging ternary metal sulfide photocatalyst, possesses the advantages of suitable bandgap (1.7–2.0 eV), environment-friendly elements, and strong photostability, which holds great potential to realize high-efficiency PHE. Although AgIn5S8-based photocatalysts have achieved promising research progresses, their PHE performances are still far below the level of commercial applications. In this review, the basic semiconductor properties of AgIn5S8 and PHE mechanism are first introduced in detail. Subsequently, the development process and PHE activities of AgIn5S8-based photocatalysts are systematically summarized, mainly including morphology control, Schottky junction formation through cocatalyst loading, and construction of different types of heterojunctions. Finally, the current issues and the possible solutions of AgIn5S8-based photocatalysts in future studies are presented.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"2 5","pages":"669-688"},"PeriodicalIF":0.0,"publicationDate":"2023-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71956438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Realizing high-energy density for practical lithium–sulfur batteries 实现实用锂硫电池的高能密度

Interdisciplinary Materials Pub Date : 2023-09-26 DOI: 10.1002/idm2.12118

Ruopian Fang, Ke Chen, Zhenhua Sun, Guangjian Hu, Da-Wei Wang, Feng Li

{"title":"Realizing high-energy density for practical lithium–sulfur batteries","authors":"Ruopian Fang, Ke Chen, Zhenhua Sun, Guangjian Hu, Da-Wei Wang, Feng Li","doi":"10.1002/idm2.12118","DOIUrl":"https://doi.org/10.1002/idm2.12118","url":null,"abstract":"Lithium–sulfur (Li–S) batteries has emerged as a promising post-lithium-ion battery technology due to their high potential energy density and low raw material cost. Recent years have witnessed substantial progress in research on Li–S batteries, yet no high-energy Li–S battery products have reached the market at scale. Achieving high-energy Li–S batteries necessitates a multidisciplinary approach involving advanced electrode material design, electrochemistry, and electrode and cell engineering. In this perspective, we offer a holistic view of pathways for realizing high-energy Li–S batteries under practical conditions. Starting with a market outlook for high-energy batteries, we present a comprehensive quantitative analysis of the critical parameters that dictate the cell-level energy density for a Li–S battery. Thereby we establish a protocol to expedite the integration of lab-scale Li–S research results into practical cell. Furthermore, we underscore several key considerations for promotion of commercial viability of high-energy Li–S batteries from the perspective of battery industrialization.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"2 5","pages":"761-770"},"PeriodicalIF":0.0,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71982467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Chiral supramolecular nanomaterials: From chirality transfer and amplification to regulation and applications 手性超分子纳米材料：从手性转移和扩增到调控和应用

Interdisciplinary Materials Pub Date : 2023-09-11 DOI: 10.1002/idm2.12117

Wenrui Chen, Boran Li, Guanbin Gao, Taolei Sun

引用次数: 0

Outside Front Cover: Volume 2 Issue 4 封面外：第2卷第4期

Interdisciplinary Materials Pub Date : 2023-07-31 DOI: 10.1002/idm2.12113

引用次数: 0

Inside Back Cover: Volume 2 Issue 4 封底：第2卷第4期

Interdisciplinary Materials Pub Date : 2023-07-31 DOI: 10.1002/idm2.12115

引用次数: 0

Evaluation of solid electrolytes: Development of conventional and interdisciplinary approaches 固体电解质的评估：传统和跨学科方法的发展

Interdisciplinary Materials Pub Date : 2023-07-31 DOI: 10.1002/idm2.12112

Muhammad Khurram Tufail, Pengbo Zhai, Waquar Khokar, Mengyang Jia, Ning Zhao, Xiangxin Guo

{"title":"Evaluation of solid electrolytes: Development of conventional and interdisciplinary approaches","authors":"Muhammad Khurram Tufail, Pengbo Zhai, Waquar Khokar, Mengyang Jia, Ning Zhao, Xiangxin Guo","doi":"10.1002/idm2.12112","DOIUrl":"https://doi.org/10.1002/idm2.12112","url":null,"abstract":"Solid-state lithium batteries (SSLBs) have received considerable attention due to their advantages in thermal stability, energy density, and safety. Solid electrolyte (SE) is a key component in developing high-performance SSLBs. An in-depth understanding of the intrinsic bulk and interfacial properties is imperative to achieve SEs with competitive performance. This review first introduces the traditional electrochemical approaches to evaluating the fundamental parameters of SEs, including the ionic and electronic conductivities, activation barrier, electrochemical stability, and diffusion coefficient. After that, the characterization techniques to evaluate the structural and chemical stability of SEs are reviewed. Further, emerging interdisciplinary visualization techniques for SEs and interfaces are highlighted, including synchrotron X-ray tomography, ultrasonic scanning imaging, time-of-flight secondary-ion mass spectrometry, and three-dimensional stress mapping, which improve the understanding of electrochemical performance and failure mechanisms. In addition, the application of machine learning to accelerate the screening and development of novel SEs is introduced. This review article aims to provide an overview of advanced characterization from a broad physical chemistry view, inspiring innovative and interdisciplinary studies in solid-state batteries.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"2 4","pages":"529-568"},"PeriodicalIF":0.0,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12112","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50156097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Outside Back Cover: Volume 2 Issue 4 外封底：第2卷第4期

Interdisciplinary Materials Pub Date : 2023-07-31 DOI: 10.1002/idm2.12116

引用次数: 0

Inside Front Cover: Volume 2 Issue 4 封面内页：第2卷第4期

Interdisciplinary Materials Pub Date : 2023-07-31 DOI: 10.1002/idm2.12114

引用次数: 0