Interdisciplinary Materials最新文献

{"title":"Outside Back Cover: Volume 4 Issue 4","authors":"","doi":"10.1002/idm2.70007","DOIUrl":"https://doi.org/10.1002/idm2.70007","url":null,"abstract":"<p><b>Outside Back Cover</b>: In the article of doi: 10.1002/idm2.12254, uniform Pt-modified mesoporous cerium oxide (Pt/mCeO₂) microspheres are designed for constructing hierarchically macro-/mesoporous sensing layer on MEMS chips. Thanks to the improved gas diffusion, enhanced gas-solid interaction interfaces and rich active metal/metal oxide sites, the as-fabricated gas sensor exhibits an excellent sensing performance.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":""},"PeriodicalIF":24.5,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.70007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Outside Front Cover: Volume 4 Issue 4","authors":"","doi":"10.1002/idm2.12189","DOIUrl":"https://doi.org/10.1002/idm2.12189","url":null,"abstract":"<p><b>Outside Front Cover</b>: For the article of doi: 10.1002/idm2.12255, the perovskite solar cell is protected by a transparent and robust “shield”. This “shield” can insulate perovskite solar cell from external environmental erosion such as rainwater and inhibit the lead leakage from the device.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":""},"PeriodicalIF":24.5,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12189","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Remolding Microenvironmental Homeostasis for Enhancing Regenerative Hypertrophic Scar Treatment Based on Functionalized Microneedles","authors":"Shengjie Jiang,&nbsp;Jialiang Zhou,&nbsp;Liyun Wang,&nbsp;Xin Liu,&nbsp;Jiaming Sun,&nbsp;Yu Zhuang,&nbsp;Li Yu,&nbsp;Haiyan Li,&nbsp;Dejian Li,&nbsp;Zhaoyong Zou,&nbsp;Zhen Gao,&nbsp;Kaili Lin","doi":"10.1002/idm2.70000","DOIUrl":"https://doi.org/10.1002/idm2.70000","url":null,"abstract":"<p>Hypertrophic scar (HS) is a common pathological fibrous hyperplasia with high incidence and recurrence rates. The limited understanding of the pathological characteristics of HS restricts the therapeutic efficacy of current strategies. In this study, we first identified the elevated mitophagy and suppressed apoptosis in hypertrophic scar fibroblasts (HSFs), which combined with excess inflammation to constitute the pathological microenvironment of HS, driving us to develop a functionalized microneedle (MN) patch for inhibiting mitophagy, promoting apoptosis and modulating inflammation to adapt HS treatment. The MNs integrate curcumin-loaded HSFs-derived extracellular vesicles (Cur@EV) and a decellularized extracellular matrix from umbilical cord-derived mesenchymal stem cells (UC-MSCs-dECM, UdECM). The homologous Cur@EV with enhanced cellular uptake significantly induced HSFs apoptosis via mitophagy inhibition, meanwhile reducing collagen deposition. Meanwhile, the UdECM exerted immunomodulation capacity by facilitating the M2 polarization of macrophages, aiding in the suppression of HSFs. Notably, the Cur@EV/UdECM-functionalized MN patches exhibited regenerative therapeutic outcomes on a rabbit HS model, with HS inhibition and new hair follicle formation. Overall, this study presents a synergistic strategy based on the regulation of “mitophagy-apoptosis-inflammation,” offering a novel, minimally invasive approach for HS management. The integration of homologous Cur@EV and UdECM into an MN patch represents an innovative, multifunctional approach that combines mitophagy inhibition, apoptosis induction, and immunomodulation. The regenerative outcomes observed in the rabbit HS model, including hair follicle formation, further underscore the translational potential of this strategy. Future research will focus on optimizing patch design for scalable production, assessing long-term safety and efficacy, and exploring its broader applicability.</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 5","pages":"728-744"},"PeriodicalIF":24.5,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.70000","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145196806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Materials-Algorithm Co-Optimization for Specific and Quantitative Gas Detection","authors":"Long Li,&nbsp;Lanpeng Guo,&nbsp;Binzhou Ying,&nbsp;Xinyi Chen,&nbsp;Wenjian Zhang,&nbsp;Kenan Liu,&nbsp;Shikang Xu,&nbsp;Licheng Zhou,&nbsp;Tiankun Li,&nbsp;Wei Luo,&nbsp;Bingbing Chen,&nbsp;Hua-Yao Li,&nbsp;Huan Liu","doi":"10.1002/idm2.70001","DOIUrl":"https://doi.org/10.1002/idm2.70001","url":null,"abstract":"<p>Rapid, reliable, and quantitative formaldehyde detection has become increasingly important in the processing industry and environmental protection. As an intelligent electronic instrument, the realization of electronic noses (e-noses) for quantitative gas detection relies on enhanced specificity. Here, we propose a materials-algorithm co-optimization (MACO) method that enables quantitative detection of formaldehyde in e-nose. This approach employs thermokinetic feature engineering to optimize data quality and algorithm selection, thereby reducing dependence on data scale and computing power resources. Specific thermokinetic activation patterns for formaldehyde can be generated through a single materials processing strategy. Through a combination of thermokinetic feature-driven machine learning, we demonstrated an e-nose—comprising only five Co₃O₄-based gas sensors—capable of discriminating formaldehyde from ethanol. The mathematical model reveals that the physicochemical mechanism of odor coding logic in our e-nose is dictated by the mass action law. A quantitative detection of formaldehyde in 0.1–20 ppm with a precision of 5% full-scale (F.S.) has been demonstrated. We also showcase the adaptability of e-nose for binary mixture analysis. The detection model of the MACO-driven e-nose is simple and interpretable, showing broad prospects to achieve quantitative gas detection rapidly and at a low cost.</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":"630-639"},"PeriodicalIF":24.5,"publicationDate":"2025-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.70001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Evidence of X-Ray Magnetic Circular Dichroism and Low-Field Microwave Absorption in Room-Temperature Organic Ferromagnetic Semiconductor","authors":"Jiaji Yang,&nbsp;Hanlin Gan,&nbsp;Xiandong He,&nbsp;Yanuo Zhu,&nbsp;Shaohua Tong,&nbsp;Wei Cui,&nbsp;Jiang Zhang,&nbsp;Qinglin Jiang,&nbsp;Yuguang Ma","doi":"10.1002/idm2.70002","DOIUrl":"https://doi.org/10.1002/idm2.70002","url":null,"abstract":"<p>Room-temperature organic ferromagnetic semiconductors represent a promising frontier in developing next-generation electronic and spintronic devices. However, the origin of magnetic moments in organic ferromagnets and the acquisition of critical evidence for magnetic ordering remain incompletely understood. This study presents compelling evidence for room-temperature ferromagnetism in <i>N</i>,<i>N′</i>-diamino perylene bisimide (2NH₂-PBI) radical aggregates through a comprehensive analysis utilizing X-ray magnetic circular dichroism (XMCD), low-field microwave absorption (LFMA) techniques and magnetic characterization. The 2NH₂-PBI samples, prepared via hydrothermal reduction, exhibit a significant saturation magnetization of 0.8 emu g⁻¹ (336.3 emu mol⁻¹) at 300 K, with a coercive field of 170 Oe. The XMCD measurements at the carbon K-edge exhibited a pronounced dichroic signal (~8.7%), confirming the origin of ferromagnetism in the π-conjugated electrons of the perylene core. Density functional theory calculations further support this finding by demonstrating that spin density is primarily delocalized on the π-conjugated skeleton, giving a microscopic explanation for the magnetic properties of 2NH₂-PBI radicals. Furthermore, LFMA studies provide additional evidence of ferromagnetic ordering, showcasing hysteretic behavior consistent with domain wall dynamics. Our work indicates that imide-based radical molecules with extended π-conjugated structures constitute a class of effective magnetic functional units.</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":"576-584"},"PeriodicalIF":24.5,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.70002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"On-Chip Construction of Hierarchically Macro-/Mesoporous Cerium Oxide/Pt Gas Sensitive Film for Ultrasensitive Detection of Trace Oxygen","authors":"Yu Deng,&nbsp;Keyu Chen,&nbsp;Wenhe Xie,&nbsp;Xin-Yu Huang,&nbsp;Fengluan Jiang,&nbsp;Lingxiao Xue,&nbsp;Ziling Zhang,&nbsp;Qin Yue,&nbsp;Limin Wu,&nbsp;Wei Luo,&nbsp;Yonghui Deng","doi":"10.1002/idm2.12254","DOIUrl":"https://doi.org/10.1002/idm2.12254","url":null,"abstract":"<p>Hierarchically porous structure is extremely favorable for many applications, including heterogeneous catalysis, chemical sensing, and energy conversion and storage. In these applications, controllable synthesis and assembly of transition metal oxide materials with tailored hierarchically porous structure and chemical microenvironments are highly desired but challenging. Herein, uniform mesoporous cerium oxide (mCeO₂) microspheres functionalized with Pt nanoparticles (NPs) were designed via efficient nanoemulsion approach and used to construct hierarchical macro-/mesoporous CeO₂/Pt film on micro-electromechanical system (MEMS) chips. The resultant functional chip-based devices have controllable porous structure and rich highly accessible active Pt–CeO₂ interfaces, and thus they exhibit outstanding performance as oxygen sensors with an unprecedented low limit of detection (LOD, 7.16 ppm), high sensitivity at a relatively low working temperature (250°C). Finite element analysis, density functional theory calculations, and in situ characterizations reveal that, such an excellent performance is mainly due to the favorable mass transfer and gas–solid interface interaction, the oxygen spillover effect enabled by the nanosized Pt, and the enhanced catalytic reaction causing the dramatic change of electronic resistance of the sensing layer in oxygen atmosphere. Finally, a smart gas sensing module capable of real-time precise detection of oxygen was fabricated, demonstrating the possibility for commercial application.</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":"585-598"},"PeriodicalIF":24.5,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12254","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient Inverted Perovskite Solar Cells Enabled by Sequential Passivation Using Two-Dimensional Perovskites","authors":"Bingcan Ke,&nbsp;Jing Li,&nbsp;Zewei Zhu,&nbsp;Siqi Zhang,&nbsp;Ruixuan Jiang,&nbsp;Chengkai Jin,&nbsp;Chang Hu,&nbsp;Qi Zhang,&nbsp;Jie Su,&nbsp;Sai Bai,&nbsp;Fuzhi Huang,&nbsp;Yi-Bing Cheng,&nbsp;Tongle Bu","doi":"10.1002/idm2.12256","DOIUrl":"https://doi.org/10.1002/idm2.12256","url":null,"abstract":"<p>Refining the process in which two-dimensional (2D) perovskites passivate three-dimensional (3D) perovskites is vital for improving the performance of perovskite solar cells (PSCs), yet is frequently overlooked. Herein, a novel sequential passivation process that initially employs phenethylamine iodide (PEAI) on the 3D perovskite surface, followed by treatment with 4-trifluoromethylphenylethylamine iodide (CF₃PEAI) is presented. A comprehensive comparison of the intrinsic molecular structures and their impact on the perovskites reveals that the small-sized, low-polarized PEA molecule induces minimal lattice strain and a negative shift of the vacuum energy level of perovskite surface, whereas the large-sized, high-polarized CF₃PEA molecule leads to larger lattice strain and a positive shift of the vacuum energy level. By leveraging the opposing properties of these molecules through our tailored sequential passivation strategy, optimal passivation effects and efficient interface charge transfer are obtained, outperforming the posttreatment with mixed ligands and greatly surpassing posttreatment with a single ligand. Consequently, a champion efficiency of 26.27% is achieved for the inverted PSCs, along with outstanding operational stability featuring a <i>T</i>₈₀ lifetime exceeding 1000 h under continuous light illumination at the maximum power point tracking.</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":"620-629"},"PeriodicalIF":24.5,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12256","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Manipulating Anti-Site Defects in α-MgAgSb for Thermoelectric Cooling Enhancement","authors":"Juan Li,&nbsp;Guijuan Li,&nbsp;Qiyong Chen,&nbsp;Jianghe Feng,&nbsp;Tao Feng,&nbsp;Lili Xi,&nbsp;Weishu Liu,&nbsp;Wenqing Zhang,&nbsp;Ruiheng Liu,&nbsp;Rong Sun","doi":"10.1002/idm2.12252","DOIUrl":"https://doi.org/10.1002/idm2.12252","url":null,"abstract":"<p><i>α</i>-MgAgSb is one of the few high-performance thermoelectric materials near room temperature, thanks to its inherently suppressed lattice thermal conductivity. However, conventional approaches to optimizing electrical properties often inadvertently degrade carrier mobility, adversely impacting thermoelectric performance at lower temperatures. In this study, we discovered in an experiment that Mg-Ag anti-site defects exist in the lattice and create staggered nanoscale anti-site zones in the matrix. This unique structure significantly scatters phonons while having a negligible influence on carrier transport due to the preservation of carrier transport channels. By fine-tuning the formation energy of Mg-Ag anti-sites through Zn doping, both carrier transport and phonon scattering were successfully bolstered. Consequently, a high figure of merit (<i>zT</i>) of ~0.45 at 200 K and an average <i>zT</i> of ~0.75 within the low-temperature range of 200–400 K can be achieved. Furthermore, a single-pair device constructed using the obtained <i>α</i>-MgAgSb and commercial Bi₂Te₃ legs exhibited a temperature difference of ~56 K at 325 K, showcasing promise for thermoelectric cooling applications. This demonstration underscores the efficiency of anti-site manipulation as a means to enhance the thermoelectric cooling performance of <i>α</i>-MgAgSb.</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 5","pages":"719-727"},"PeriodicalIF":24.5,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12252","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145196356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Creating Biomimetic Bouligand Architectures for Biomedical and Healthcare Applications","authors":"Hongye Yang,&nbsp;Xinyu Zhang,&nbsp;Shilei Wang,&nbsp;Yize Wang,&nbsp;Rui Xiong,&nbsp;Cui Huang","doi":"10.1002/idm2.12260","DOIUrl":"https://doi.org/10.1002/idm2.12260","url":null,"abstract":"<p>The hierarchical Bouligand structure, ubiquitous in organisms and endowing natural creatures with exceptional performance attributes, stands as a prime example of nature's evolutionary prowess. Following the example of nature, the construction of biomimetic Bouligand structures will significantly propel advancements and innovations within the domain of biomedical and healthcare applications. In this review, we summarize cutting-edge research progress of biomimetic Bouligand architectures. Firstly, the natural Bouligand structures in animals, plants, and humans are introduced. On this basis, the relationship between properties and Bouligand structure is briefly discussed, including toughening mechanism, optical characteristics, and biological properties. Subsequently, the review details the construction strategies of the biomimetic Bouligand architectures, covering a variety of methods such as self-assembly, biomimetic mineralization, shear brushing, electrostatic spinning, and 3D printing. Finally, the utilization of biomimetic Bouligand architectures in biomedical and healthcare fields, especially for bone regeneration, tooth repair, body protection, and biosensor transmission, is discussed in detail. Despite the significant theoretical advantages of Bouligand structure, its feasibility in biomedical and healthcare applications still remains in its infancy. We eagerly anticipate the future development of biomimetic Bouligand architectures with superior performance, tailored to clinical scenarios and health needs, thereby fulfilling the grand vision of “inspiration from nature and giving back to life.”</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":"539-567"},"PeriodicalIF":24.5,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12260","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultrathin Nanocomposite Membrane With Robust Anti-Wettability for Stable Membrane Distillation","authors":"Zhongao Chen,&nbsp;Yongxuan Wang,&nbsp;Xiao Chen,&nbsp;Cheng Huang,&nbsp;Shiqing Xu,&nbsp;Quanwei Xu,&nbsp;Shuaifei Zhao,&nbsp;Wojciech Kujawski,&nbsp;Pengchao Zhang","doi":"10.1002/idm2.12253","DOIUrl":"https://doi.org/10.1002/idm2.12253","url":null,"abstract":"<p>Hydrophobic porous membrane is the key to the desalination performance of membrane distillation (MD). However, traditional MD membranes suffer from poor hydrophobicity of pore surfaces, leading to pore wetting and causing the loss of desalination stability. In this study, we present an ultrathin polyvinylidene fluoride (PVDF) nanocomposite membrane with robust anti-wetting properties and high permeability for stable MD desalination. The improved anti-wetting properties are achieved by enhancing the hydrophobicity of membrane pore surfaces via introducing hydrophobic silica nanoparticles to build nanostructures on the pore surfaces. The hydrophobic nanostructured pore surfaces induce the formation of the nano-Cassie state upon contact with water, thereby enhancing the specific liquid entry pressure of water (LEP_w) with 788% compared to commercial PVDF membranes. The resulted porous structure and 10 μm membrane thickness (i.e., 20 times thinner than commercial PVDF membranes) enable the stable desalination flux of 20.30 kg m⁻² h⁻¹ and high salt rejection of &gt; 99.9% with 60°C seawater. Our ultrathin nanocomposite membranes provide a promising solution for long-term MD seawater desalination.</p>","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"4 4","pages":"610-619"},"PeriodicalIF":24.5,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12253","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144705327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}