Interdisciplinary Materials最新文献_第9页

SnS2 nanoparticles embedded in sulfurized polyacrylonitrile composite fibers for high-performance potassium-ion batteries 嵌入硫化聚丙烯腈复合纤维的 SnS2 纳米粒子用于高性能钾离子电池

Interdisciplinary Materials Pub Date : 2024-01-30 DOI: 10.1002/idm2.12135

Ruiling Li, Lijuan Tong, Yitong Jiang, Yaxin Wang, Jing Long, Xiaochuan Chen, Junxiong Wu, Xiaoyan Li, Yuming Chen

{"title":"SnS2 nanoparticles embedded in sulfurized polyacrylonitrile composite fibers for high-performance potassium-ion batteries","authors":"Ruiling Li, Lijuan Tong, Yitong Jiang, Yaxin Wang, Jing Long, Xiaochuan Chen, Junxiong Wu, Xiaoyan Li, Yuming Chen","doi":"10.1002/idm2.12135","DOIUrl":"https://doi.org/10.1002/idm2.12135","url":null,"abstract":"Potassium-ion batteries (PIBs) have garnered significant attention as a promising alternative to commercial lithium-ion batteries (LIBs) due to abundant and cost-efficient potassium reserves. However, the large size of potassium ions and the resulting sluggish reaction kinetics present major obstacles to the widespread use of PIBs. Herein, we present a simple method to ingeniously encapsulate SnS2 nanoparticles within sulfurized polyacrylonitrile (SPAN) fibers (SnS2@SPAN) for serving as a high-performance PIB anode. The large interlayer spacing of SnS2 provides a fast transport channel for potassium ions during charge–discharge cycles, while the one-dimensional SPAN skeleton offers massive binding sites and shortens the diffusion path for potassium ions, facilitating faster reaction kinetics. Additionally, the excellent ductility of SPAN can effectively accommodate the large volume changes that occur in SnS2 upon potassium-ion insertion, thereby enhancing the cyclic stability of SnS2. Benefiting from the above advantages, the SnS2@SPAN composites exhibit impressive cyclability over 500 cycles at 4 A g−1, with a capacity retention rate close to 100%. This study provides an effective approach for stabilizing high-capacity PIB anode materials with large volume variations.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 1","pages":"150-159"},"PeriodicalIF":0.0,"publicationDate":"2024-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12135","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139676802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metallosalen covalent organic frameworks for heterogeneous catalysis 用于异相催化的金属盐共价有机框架

Interdisciplinary Materials Pub Date : 2024-01-29 DOI: 10.1002/idm2.12140

Wei Zhou, Wei-Qiao Deng, Xing Lu

{"title":"Metallosalen covalent organic frameworks for heterogeneous catalysis","authors":"Wei Zhou, Wei-Qiao Deng, Xing Lu","doi":"10.1002/idm2.12140","DOIUrl":"https://doi.org/10.1002/idm2.12140","url":null,"abstract":"Metallosalen covalent organic frameworks (M(salen)-COFs) have garnered significant attention as promising candidates for advanced heterogeneous catalysis, including organocatalysis, electrocatalysis, and photocatalysis, due to their unique structural advantages (combining molecules catalysts and crystalline porous materials) and tunable topological network. It is essential to provide a comprehensive overview of emerging designs of M(salen)-COFs and corresponding advances in this field. Herein, this review first summarizes the reported metallolinkers and the synthesis methods of M(salen)-COFs. In addition, the review enumerates the excellent M(salen)-COF based heterogeneous catalysts and discusses the fundamental mechanisms behind the outstanding heterogeneous catalytic performance of M(salen)-COFs. These mechanisms include the pore enrichment effect (enhancing local concentration within porous materials to promote catalytic reactions), the three-in-one strategy (integrating enrichment, reduction, and oxidation sites in one system), and the incorporation of a built-in electric field (implanting a built-in electric field in heterometallic phthalocyanine covalent organic frameworks). Furthermore, this review discusses the challenges and prospects related to M(salen)-COFs in heterogeneous catalysis.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 1","pages":"87-112"},"PeriodicalIF":0.0,"publicationDate":"2024-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12140","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139676799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Single-atom materials: The application in energy conversion 单原子材料：在能量转换中的应用

Interdisciplinary Materials Pub Date : 2024-01-29 DOI: 10.1002/idm2.12141

Chenxi Zhu, Jiarui Yang, Jiangwei Zhang, Xinqiang Wang, Yong Gao, Dingsheng Wang, Hongge Pan

引用次数: 0

Bioinspired reflective display based on photonic crystals 基于光子晶体的生物启发反射显示器

Interdisciplinary Materials Pub Date : 2024-01-20 DOI: 10.1002/idm2.12138

Yifan Liu, Xiaoyu Hou, Yanlin Song, Mingzhu Li

引用次数: 0

A nonradiographic strategy to real-time monitor the position of three-dimensional-printed medical orthopedic implants by embedding superparamagnetic Fe3O4 particles 通过嵌入超顺磁性 Fe3O4 粒子实时监测三维打印医用骨科植入物位置的非放射策略

Interdisciplinary Materials Pub Date : 2024-01-13 DOI: 10.1002/idm2.12133

Yike Li, Peng Chen, Zhenhua Wu, Congcan Shi, Peng Chen, Yizhuo Xu, Xiaojun Chen, Manhui Chen, Yuxin Li, Chunze Yan, Yunsong Shi, Bin Su

{"title":"A nonradiographic strategy to real-time monitor the position of three-dimensional-printed medical orthopedic implants by embedding superparamagnetic Fe3O4 particles","authors":"Yike Li, Peng Chen, Zhenhua Wu, Congcan Shi, Peng Chen, Yizhuo Xu, Xiaojun Chen, Manhui Chen, Yuxin Li, Chunze Yan, Yunsong Shi, Bin Su","doi":"10.1002/idm2.12133","DOIUrl":"10.1002/idm2.12133","url":null,"abstract":"Monitoring the position of orthopedic implants in vivo is paramount for enhancing postoperative rehabilitation. Traditional radiographic methods, although effective, pose inconveniences to patients in terms of specialized equipment requirements and delays in rehabilitation adjustment. Here, a nonradiographic design concept for real-time and precisely monitoring the position of in vivo orthopedic implants is presented. The monitoring system encompasses an external magnetic field, a three-dimensional (3D)-printed superparamagnetic intervertebral body fusion cage (SIBFC), and a magnetometer. The SIBFC with a polyetheretherketone framework and a superparamagnetic Fe3O4 component was integrally fabricated by the high-temperature selective laser sintering technology. Owing to the superparamagnetic component, the minor migration of SIBFC within the spine would cause the distribution change of the magnetic induction intensities, which can be monitored in real-time by the magnetometer no matter in the static states or dynamic bending motions. Besides horizontal migration, occurrences of intervertebral subsidence in the vertical plane of the vertebrae can also be effectively distinguished based on the obtained characteristic variations of magnetic induction intensities. This strategy exemplifies the potential of superparamagnetic Fe3O4 particles in equipping 3D-printed orthopedic implants with wireless monitoring capabilities, holding promise for aiding patients' rehabilitation.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 1","pages":"133-149"},"PeriodicalIF":0.0,"publicationDate":"2024-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12133","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139531465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lattice dynamics and thermoelectric properties of diamondoid materials 金刚石材料的晶格动力学和热电特性

Interdisciplinary Materials Pub Date : 2024-01-10 DOI: 10.1002/idm2.12134

Hongyao Xie, Li-Dong Zhao, Mercouri G. Kanatzidis

{"title":"Lattice dynamics and thermoelectric properties of diamondoid materials","authors":"Hongyao Xie, Li-Dong Zhao, Mercouri G. Kanatzidis","doi":"10.1002/idm2.12134","DOIUrl":"10.1002/idm2.12134","url":null,"abstract":"The diamondoid compounds are a large family of important semiconductors, which possess various unique transport properties and had been widely investigated in the fields of photoelectricity and nonlinear optics. For a significantly long period of time, diamondoid materials were not given much attention in the field of thermoelectricity. However, this changed when a series of diamondoid compounds showed a thermoelectric figure of merit (ZT) greater than 1.0. This discovery sparked considerable interest in further exploring the thermoelectric properties of diamondoid materials. This review aims to provide a comprehensive view of our current understanding of thermal and electronic transport in diamondoid materials and stimulate their development in thermoelectric applications. We present a collection of recent discoveries concerning the lattice dynamics and electronic structure of diamondoid materials. We review the underlying physics responsible for their unique electrical and phonon transport behaviors. Moreover, we provide insights into the advancements made in the field of thermoelectricity for diamondoid materials and the corresponding strategies employed to optimize their performance. Lastly, we emphasize the challenges that lie ahead and outline potential avenues for future research in the domain of diamondoid thermoelectric materials.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 1","pages":"5-28"},"PeriodicalIF":0.0,"publicationDate":"2024-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12134","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139440380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Outside Back Cover: Volume 2 Issue 6

IF 24.5

Interdisciplinary Materials Pub Date : 2023-12-29 DOI: 10.1002/idm2.12137

引用次数: 0

Outside Front Cover: Volume 2 Issue 6

IF 24.5

Interdisciplinary Materials Pub Date : 2023-12-29 DOI: 10.1002/idm2.12136

引用次数: 0

Laser constructed bulk oxygen vacancy caused high P doping for boosting the sodium-storage capability

IF 24.5

Interdisciplinary Materials Pub Date : 2023-12-29 DOI: 10.1002/idm2.12132

Zhimeng Li, Man Huang, Bin Chang, Jinyu Ge, Di Xin, Di Jiang, Hong Liu, Weijia Zhou

{"title":"Laser constructed bulk oxygen vacancy caused high P doping for boosting the sodium-storage capability","authors":"Zhimeng Li, Man Huang, Bin Chang, Jinyu Ge, Di Xin, Di Jiang, Hong Liu, Weijia Zhou","doi":"10.1002/idm2.12132","DOIUrl":"https://doi.org/10.1002/idm2.12132","url":null,"abstract":"Defect-assisted heteroatom doping can effectively enhance the intrinsic transfer characteristics of carriers in the crystal structure, which advantages over fast and efficient charge storage. In this work, a three-dimensional self-supporting titanium dioxide nanoparticle rich in bulk vacancies (L-TiOx) on titanium substrate is synthesized by pulsed laser. Different from the surface vacancies, the bulk oxygen defects of L-TiOx cause a uniform and bulk phosphorus (P) doping with a high concentration of ~5.71 at %, which endows the elevated electronic conductivity, and accelerates the transport of Na+. The obtained P-doped L-TiOx (LP-TiOx) as an anode material in sodium-ion batteries (SIBs) provides a reversible capacity of 400 mAh g−1 at 200 mA g−1, outstanding rate capability of 196 mAh g−1 at 10,000 mA g−1, and maintains stable performance over 1000 cycles. In situ X-ray diffraction and ex situ high-resolution transmission electron microscopy show that LP-TiOx exhibits robust mechanical behavior with almost no lattice change under (de)sodiation. This work supplies a novel idea for high-concentration bulk heteroatoms doping to enhance the electrochemical performance of SIBs.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"2 6","pages":"876-887"},"PeriodicalIF":24.5,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12132","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143253744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Towards stable electrode–electrolyte interphases: Regulating solvation structures in electrolytes for rechargeable batteries

IF 24.5

Interdisciplinary Materials Pub Date : 2023-12-26 DOI: 10.1002/idm2.12131

Mengying Ma, Renzhi Huang, Min Ling, Yong-Sheng Hu, Huilin Pan

{"title":"Towards stable electrode–electrolyte interphases: Regulating solvation structures in electrolytes for rechargeable batteries","authors":"Mengying Ma, Renzhi Huang, Min Ling, Yong-Sheng Hu, Huilin Pan","doi":"10.1002/idm2.12131","DOIUrl":"https://doi.org/10.1002/idm2.12131","url":null,"abstract":"Rechargeable batteries are highly in demand to power various electronic devices and future smart electric grid energy storage. The electrode–electrolyte interphases play a crucial role in influencing the electrochemical performance of batteries, with the solvation chemistries of the electrolyte being particularly significant in regulating these interfacial reactions. However, the reaction mechanisms of electrolyte solvation and their specific functions in batteries are not yet fully understood. In this review, we embark on an exploration of the fundamental principles governing solvation and present a comprehensive overview of how solvation structures impact interfacial reactions at the electrode–electrolyte interface. We underscore the significance of interactions among cations, anions, and solvents in shaping electrolyte solvation structures. The primary strategies for controlling solvation structures are also discussed, including the optimization of salt concentrations, solvent interactions, and the introduction of functional cosolvents. Furthermore, we elucidate the oxidation/reduction reaction mechanisms of electrolyte components in different solvation structures and the new understanding of electrolyte additives in modulating interfacial chemistries in batteries. Additionally, we emphasize the importance of incorporating new characterization techniques and theoretical simulations to attain a deeper understanding of the intricate processes taking place within batteries. This review provides an in-depth understanding in solvations and interphasial properties and new ideas for designing advanced functional electrolytes for rechargeable batteries.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"2 6","pages":"833-854"},"PeriodicalIF":24.5,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12131","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143253158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0