Interdisciplinary Materials最新文献_第8页

Self-assembled monolayers (SAMs) in inverted perovskite solar cells and their tandem photovoltaics application 倒置过氧化物太阳能电池中的自组装单层 (SAM) 及其串联光伏应用

Interdisciplinary Materials Pub Date : 2024-02-23 DOI: 10.1002/idm2.12145

Zijun Yi, Xin Li, Yuchen Xiong, Guibin Shen, Wenguang Zhang, Yihuai Huang, Qinghui Jiang, Xin Ren Ng, Yubo Luo, Jianghui Zheng, Wei Lin Leong, Fan Fu, Tongle Bu, Junyou Yang

{"title":"Self-assembled monolayers (SAMs) in inverted perovskite solar cells and their tandem photovoltaics application","authors":"Zijun Yi, Xin Li, Yuchen Xiong, Guibin Shen, Wenguang Zhang, Yihuai Huang, Qinghui Jiang, Xin Ren Ng, Yubo Luo, Jianghui Zheng, Wei Lin Leong, Fan Fu, Tongle Bu, Junyou Yang","doi":"10.1002/idm2.12145","DOIUrl":"https://doi.org/10.1002/idm2.12145","url":null,"abstract":"Self-assembled monolayers (SAMs) employed in inverted perovskite solar cells (PSCs) have achieved groundbreaking progress in device efficiency and stability for both single-junction and tandem configurations, owing to their distinctive and versatile ability to manipulate chemical and physical interface properties. In this regard, we present a comprehensive review of recent research advancements concerning SAMs in inverted perovskite single-junction and tandem solar cells, where the prevailing challenges and future development prospects in the applications of SAMs are emphasized. We thoroughly examine the mechanistic roles of diverse SAMs in energy-level regulation, interface modification, defect passivation, and charge transportation. This is achieved by understanding how interfacial molecular interactions can be finely tuned to mitigate charge recombination losses in inverted PSCs. Through this comprehensive review, we aim to provide valuable insights and references for further investigation and utilization of SAMs in inverted perovskite single-junction and tandem solar cells.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 2","pages":"203-244"},"PeriodicalIF":0.0,"publicationDate":"2024-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12145","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140310370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In situ polymerization of water-induced 1,3-phenylene diisocyanate for enhanced efficiency and stability of inverted perovskite solar cells 原位聚合水诱导的 1,3-亚苯基二异氰酸酯，以提高倒置型过氧化物太阳能电池的效率和稳定性

Interdisciplinary Materials Pub Date : 2024-02-20 DOI: 10.1002/idm2.12147

Shiyao Jia, Jiabao Yang, Tong Wang, Xingyu Pu, Hui Chen, Xilai He, Guangpeng Feng, Xingyuan Chen, Yijun Bai, Qi Cao, Xuanhua Li

{"title":"In situ polymerization of water-induced 1,3-phenylene diisocyanate for enhanced efficiency and stability of inverted perovskite solar cells","authors":"Shiyao Jia, Jiabao Yang, Tong Wang, Xingyu Pu, Hui Chen, Xilai He, Guangpeng Feng, Xingyuan Chen, Yijun Bai, Qi Cao, Xuanhua Li","doi":"10.1002/idm2.12147","DOIUrl":"https://doi.org/10.1002/idm2.12147","url":null,"abstract":"In the realm of photovoltaics, organometallic hybridized perovskite solar cells (PSCs) stand out as promising contenders for achieving high-efficiency photoelectric conversion, owing to their remarkable performance attributes. Nevertheless, defects within the perovskite layer, especially at the perovskite grain boundaries and surface, have a substantial impact on both the overall photoelectric performance and long-term operational stability of PSCs. To mitigate this challenge, we propose a method for water-induced condensation polymerization of small molecules involving the incorporation of 1,3-phenylene diisocyanate (1,3-PDI) into the perovskite film using an antisolvent technique. Subsequent to this step, the introduction of water triggers the polymerization of [P(1,3-PDI)], thereby facilitating the in situ passivation of uncoordinated lead defects inherent in the perovskite film. This passivation process demonstrates a notable enhancement in both the efficiency and stability of PSCs. This approach has led to the attainment of a noteworthy power conversion efficiency (PCE) of 24.66% in inverted PSCs. Furthermore, based on the P(1,3-PDI) modification, these devices maintain 90.15% of their initial efficiency after 5000 h of storage under ambient conditions of 25°C and 50 ± 5% relative humidity. Additionally, even after maximum power point tracking for 1000 h, the PSCs modified with P(1,3-PDI) sustain 82.05% of the initial PCE. Small molecules can rationally manipulate water and turn harm into benefit, providing new directions and methods for improving the efficiency and stability of PSCs.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 2","pages":"316-325"},"PeriodicalIF":0.0,"publicationDate":"2024-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12147","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140310304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Expanding from materials to biology inspired by biomineralization 受生物矿化的启发，从材料扩展到生物学

Interdisciplinary Materials Pub Date : 2024-02-08 DOI: 10.1002/idm2.12144

Qi Wang, Lishan Hu, Xiaoyu Wang, Ruikang Tang

{"title":"Expanding from materials to biology inspired by biomineralization","authors":"Qi Wang, Lishan Hu, Xiaoyu Wang, Ruikang Tang","doi":"10.1002/idm2.12144","DOIUrl":"10.1002/idm2.12144","url":null,"abstract":"Biomineralization is the intricate process by which living organisms orchestrate the formation of organic–inorganic composites by regulating the nucleation, orientation, growth, and assembly of inorganic minerals. As our comprehension of biomineralization principles deepens, novel strategies for fabricating inorganic materials based on these principles have emerged. Researchers can also harness biomineralization strategies to tackle challenges in both materials' science and biomedical fields, demonstrating a thriving research field. This review begins by introducing the concept of biomineralization and subsequently shifts its focus to a recently discovered chemical concept: inorganic ionic oligomers and their cross-linking. As a novel approach for constructing inorganic materials, the inorganic ionic oligomer-based strategy finds applications in biomimetic regeneration and repair of hard tissues, such as teeth and bones. Aside from innovative methods for material fabrication, biomineralization has emerged as an alternative method for tackling biomedical challenges by integrating materials with biological organisms, facilitating advancements in biomedical fields. Emerging material-biological integrators play a critical role in areas like vaccine improvement, cancer therapy, universal blood transfusion, and arthritis treatment. This review highlights the profound impact of biomineralization in the development and design of high-performance materials that go beyond traditional disciplinary boundaries, potentially promoting breakthroughs in materials science, chemical biology, biomedical, and numerous other domains.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 2","pages":"165-188"},"PeriodicalIF":0.0,"publicationDate":"2024-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12144","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139851602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An ultrathin and crack-free metal-organic framework film for effective polysulfide inhibition in lithium–sulfur batteries 用于锂硫电池中有效抑制多硫化物的超薄无裂纹金属有机框架薄膜

Interdisciplinary Materials Pub Date : 2024-02-05 DOI: 10.1002/idm2.12143

Cheng Zhou, Chenxu Dong, Weixiao Wang, Yu Tian, Chunli Shen, Kaijian Yan, Liqiang Mai, Xu Xu

{"title":"An ultrathin and crack-free metal-organic framework film for effective polysulfide inhibition in lithium–sulfur batteries","authors":"Cheng Zhou, Chenxu Dong, Weixiao Wang, Yu Tian, Chunli Shen, Kaijian Yan, Liqiang Mai, Xu Xu","doi":"10.1002/idm2.12143","DOIUrl":"10.1002/idm2.12143","url":null,"abstract":"Due to their extensive microporous structure, metal-organic frameworks (MOFs) find widespread application in constructing modification layers, functioning as ion sieves. However, the modification layers prepared by existing methods feature gaps between MOFs that are noticeably larger than the inherent MOF pore dimensions. Polysulfides and lithium ions unavoidably permeate through these gaps, hindering the full exploitation of the structural advantages. Herein, an ultrathin (20 nm) and crack-free MOF film is formed on the separator by atomic layer deposition for the first time. Based on the separator, the mechanism of different MOF layers has been verified by phase field simulation and in situ Raman spectroscopy. The results accurately prove that the MOF particle layer can relieve the shuttle of polysulfides, but it does not have the effect of homogenizing lithium ions. Only the ultrathin and crack-free MOF film with proper pore size can act as the ion sieve for both polysulfides and lithium ions. As a result, under the test condition of 2 mA cm−2–2 mAh cm−2, the overpotential of the Li/Li symmetric battery is only 18 mV after 2500 h. The capacity retention rate of the lithium–sulfur battery is 95.6% after 500 cycles and 80% after 1000 cycles at 2 C.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 2","pages":"306-315"},"PeriodicalIF":0.0,"publicationDate":"2024-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12143","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139864210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Inside Back Cover: Volume 3 Issue 1 封底内页第 3 卷第 1 期

Interdisciplinary Materials Pub Date : 2024-01-31 DOI: 10.1002/idm2.12151

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Recent advances on monolithic perovskite-organic tandem solar cells 单片过氧化物有机串联太阳能电池的最新进展

Interdisciplinary Materials Pub Date : 2024-01-31 DOI: 10.1002/idm2.12142

Guanshui Xie, Huan Li, Longbin Qiu

{"title":"Recent advances on monolithic perovskite-organic tandem solar cells","authors":"Guanshui Xie, Huan Li, Longbin Qiu","doi":"10.1002/idm2.12142","DOIUrl":"https://doi.org/10.1002/idm2.12142","url":null,"abstract":"Perovskite-organic tandem solar cells (TSCs) have emerged as a groundbreaking technology in the realm of photovoltaics, showcasing remarkable enhancements in efficiency and significant potential for practical applications. Perovskite-organic TSCs also exhibit facile fabrication surpassing that of all-perovskite or all-organic TSCs, attributing to the advantageous utilization of orthogonal solvents enabling sequential solution process for each subcell. The perovskite-organic TSCs capitalize on the complementary light absorption characteristics of perovskite and organic materials. There is a promising prospect of achieving further enhanced power conversion efficiencies by covering a broad range of the solar spectrum with optimized perovskite absorber, organic semiconductors as well as the interconnecting layer's optical and electrical properties. This review comprehensively analyzes the recent advancements in perovskite-organic TSCs, highlighting the synergistic effects of combining perovskite with a low open-circuit voltage deficit, organic materials with broader light absorption, and interconnecting layers with reduced optical and electrical loss. Meanwhile, the underlying device architecture design, regulation strategies, and key challenges facing the high performance of the perovskite-organic TSCs are also discussed.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 1","pages":"113-132"},"PeriodicalIF":0.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12142","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139676745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Outside Back Cover: Volume 3 Issue 1 封底外页：第 3 卷第 1 期

Interdisciplinary Materials Pub Date : 2024-01-31 DOI: 10.1002/idm2.12150

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Inside Front Cover: Volume 3 Issue 1 封面内页：第 3 卷第 1 期

Interdisciplinary Materials Pub Date : 2024-01-31 DOI: 10.1002/idm2.12149

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Outside Front Cover: Volume 3 Issue 1 封面外页：第 3 卷第 1 期

Interdisciplinary Materials Pub Date : 2024-01-31 DOI: 10.1002/idm2.12148

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Regulatable interfacial adhesion between stamp and ink for transfer printing 用于转印的印章和油墨之间可调节的界面粘附力

Interdisciplinary Materials Pub Date : 2024-01-30 DOI: 10.1002/idm2.12139

Yiheng Li, Feilong Zhang, Shutao Wang

引用次数: 0