Interdisciplinary Materials最新文献_第7页

Chiral twisted molecular carbons: Synthesis, properties, and applications 手性扭曲分子碳：合成、性质和应用

IF 24.5

Interdisciplinary Materials Pub Date : 2024-05-11 DOI: 10.1002/idm2.12173

Yunqin Zhang, Junjie Guan, Leiquan Luo, Xiao Han, Jie Wang, Yongshen Zheng, Jialiang Xu

{"title":"Chiral twisted molecular carbons: Synthesis, properties, and applications","authors":"Yunqin Zhang, Junjie Guan, Leiquan Luo, Xiao Han, Jie Wang, Yongshen Zheng, Jialiang Xu","doi":"10.1002/idm2.12173","DOIUrl":"10.1002/idm2.12173","url":null,"abstract":"In recent years, the precisely controlled synthesis of chiral twisted molecular carbons has emerged as a forefront topic in the research of carbon materials. Molecular carbons refer to carbon nanomaterials synthesized with precision at the atomic level. Through rational design, rigid and stable chiral twisted structures can be synthesized. The exploration in the field of chiral twisted molecular carbons is key to fully understanding the various twisted configurations of carbon materials and delving into the relationship between structure design and functionality. This review explores chiral twisted configurations of carbon nanomaterials such as nanographene, carbon nanobelts, carbon nanosheets, graphdiyne, etc. It emphasizes the role of photocyclization, Scholl reaction, and Diels–Alder reactions in achieving precise chiral control and discusses a range of innovative design strategies. These strategies have led to the development of various twisted structures, such as helical, propeller, and Möbius strip configurations. The introduction of chirality, combined with the inherent exceptional optical properties of nanocarbon materials, has facilitated the creation of materials with superior chiroptical performances. This advancement is driving applications in fields such as optoelectronics and chiral optics.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 4","pages":"453-479"},"PeriodicalIF":24.5,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12173","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140988125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Single-element amorphous metals 单元素非晶金属

IF 24.5

Interdisciplinary Materials Pub Date : 2024-05-10 DOI: 10.1002/idm2.12171

Xiao Han, Geng Wu, Dong Sheng He, Xun Hong

引用次数: 0

Three-dimensional-printed Ni-based scaffold design accelerates bubble escape for ampere-level alkaline hydrogen evolution reaction 基于镍的三维打印支架设计可加速安培级碱性氢进化反应中的气泡逸出

IF 24.5

Interdisciplinary Materials Pub Date : 2024-04-29 DOI: 10.1002/idm2.12169

Jingxuan Chen, Gangwen Fu, Yu Tian, Xingchuan Li, Mengqi Luo, Xiaoyu Wei, Ting Zhang, Tian Gao, Cheng Chen, Somboon Chaemchuen, Xi Xu, Xing Sun, Tongle Bu, Francis Verpoort, John Wang, Zongkui Kou

{"title":"Three-dimensional-printed Ni-based scaffold design accelerates bubble escape for ampere-level alkaline hydrogen evolution reaction","authors":"Jingxuan Chen, Gangwen Fu, Yu Tian, Xingchuan Li, Mengqi Luo, Xiaoyu Wei, Ting Zhang, Tian Gao, Cheng Chen, Somboon Chaemchuen, Xi Xu, Xing Sun, Tongle Bu, Francis Verpoort, John Wang, Zongkui Kou","doi":"10.1002/idm2.12169","DOIUrl":"https://doi.org/10.1002/idm2.12169","url":null,"abstract":"Alkaline hydrogen evolution reaction (HER) for scalable hydrogen production largely hinges on addressing the sluggish bubble-involved kinetics on the traditional Ni-based electrode, especially for ampere-level current densities and beyond. Herein, 3D-printed Ni-based sulfide (3DPNS) electrodes with varying scaffolds are designed and fabricated. In situ observations at microscopic levels demonstrate that the bubble escape velocity increases with the number of hole sides (HS) in the scaffolds. Subsequently, we conduct multiphysics field simulations to illustrate that as the hole shapes transition from square, pentagon, and hexagon to circle, where a noticeable reduction in the bubble-attached HS length and the pressure balance time around the bubbles results in a decrease in bubble size and an acceleration in the rate of bubble escape. Ultimately, the 3DPNS electrode with circular hole configurations exhibits the most favorable HER performance with an overpotential of 297 mV at the current density of up to 1000 mA cm−2 for 120 h. The present study highlights a scalable and effective electrode scaffold design that promotes low-cost and low-energy green hydrogen production through the ampere-level alkaline HER.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 4","pages":"595-606"},"PeriodicalIF":24.5,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12169","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141730354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Manipulation of metavalent bonding to stabilize metastable phase: A strategy for enhancing zT in GeSe 操纵偏五价键以稳定蜕变相：提高 GeSe 锆钛酸锂热稳定性的策略

IF 24.5

Interdisciplinary Materials Pub Date : 2024-04-24 DOI: 10.1002/idm2.12170

Yilun Huang, Tu Lyu, Manting Zeng, Moran Wang, Yuan Yu, Chaohua Zhang, Fusheng Liu, Min Hong, Lipeng Hu

{"title":"Manipulation of metavalent bonding to stabilize metastable phase: A strategy for enhancing zT in GeSe","authors":"Yilun Huang, Tu Lyu, Manting Zeng, Moran Wang, Yuan Yu, Chaohua Zhang, Fusheng Liu, Min Hong, Lipeng Hu","doi":"10.1002/idm2.12170","DOIUrl":"10.1002/idm2.12170","url":null,"abstract":"Exploration of metastable phases holds profound implications for functional materials. Herein, we engineer the metastable phase to enhance the thermoelectric performance of germanium selenide (GeSe) through tailoring the chemical bonding mechanism. Initially, AgInTe2 alloying fosters a transition from stable orthorhombic to metastable rhombohedral phase in GeSe by substantially promoting p-state electron bonding to form metavalent bonding (MVB). Besides, extra Pb is employed to prevent a transition into a stable hexagonal phase at elevated temperatures by moderately enhancing the degree of MVB. The stabilization of the metastable rhombohedral phase generates an optimized bandgap, sharpened valence band edge, and stimulative band convergence compared to stable phases. This leads to decent carrier concentration, improved carrier mobility, and enhanced density-of-state effective mass, culminating in a superior power factor. Moreover, lattice thermal conductivity is suppressed by pronounced lattice anharmonicity, low sound velocity, and strong phonon scattering induced by multiple defects. Consequently, a maximum zT of 1.0 at 773 K is achieved in (Ge0.98Pb0.02Se)0.875(AgInTe2)0.125, resulting in a maximum energy conversion efficiency of 4.90% under the temperature difference of 500 K. This work underscores the significance of regulating MVB to stabilize metastable phases in chalcogenides.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 4","pages":"607-620"},"PeriodicalIF":24.5,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12170","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140663028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stable sodium metal anode enabled by interfacial room-temperature liquid metal engineering for high-performance sodium–sulfur batteries with carbonate-based electrolyte 通过界面室温液态金属工程实现稳定的金属钠阳极，用于使用碳酸盐基电解质的高性能钠硫电池

Interdisciplinary Materials Pub Date : 2024-04-22 DOI: 10.1002/idm2.12163

Kangdong Tian, Chuanliang Wei, Zhengran Wang, Yuan Li, Baojuan Xi, Shenglin Xiong, Jinkui Feng

{"title":"Stable sodium metal anode enabled by interfacial room-temperature liquid metal engineering for high-performance sodium–sulfur batteries with carbonate-based electrolyte","authors":"Kangdong Tian, Chuanliang Wei, Zhengran Wang, Yuan Li, Baojuan Xi, Shenglin Xiong, Jinkui Feng","doi":"10.1002/idm2.12163","DOIUrl":"10.1002/idm2.12163","url":null,"abstract":"Sodium (Na) metal is a competitive anode for next-generation energy storage applications in view of its low cost and high-energy density. However, the uncontrolled side reactions, unstable solid electrolyte interphase (SEI) and dendrite growth at the electrode/electrolyte interfaces impede the practical application of Na metal as anode. Herein, a heterogeneous Na-based alloys interfacial protective layer is constructed in situ on the surface of Na foil by self-diffusion of liquid metal at room temperature, named “HAIP Na.” The interfacial Na-based alloys layer with good electrolyte wettability and strong sodiophilicity, and assisted in the construction of NaF-rich SEI. By means of direct visualization and theoretical simulation, we verify that the interfacial Na-based alloys layer enabling uniform Na+ flux deposition and suppressing the dendrite growth. As a result, in the carbonate-based electrolyte, the HAIP Na||HAIP Na symmetric cells exhibit a remarkably enhanced cycling life for more than 650 h with a capacity of 1 mAh cm−2 at a current density of 1 mA cm−2. When the HAIP Na anode is paired with sulfurized polyacrylonitrile (SPAN) cathode, the SPAN||HAIP Na full cells demonstrate excellent rate performance and cycling stability.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 3","pages":"425-436"},"PeriodicalIF":0.0,"publicationDate":"2024-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12163","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140677109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Acid-etching induced metal cation competitive lattice occupancy of perovskite quantum dots for efficient pure-blue QLEDs 酸蚀诱导过氧化物量子点的金属阳离子竞争性晶格占位，实现高效纯蓝 QLED

Interdisciplinary Materials Pub Date : 2024-04-18 DOI: 10.1002/idm2.12164

Hanwen Zhu, Guoqing Tong, Junchun Li, Xuyong Tao, Yang Shen, Yuanyuan Sheng, Lin Shi, Fengming Xie, Jianxin Tang, Yang Jiang

{"title":"Acid-etching induced metal cation competitive lattice occupancy of perovskite quantum dots for efficient pure-blue QLEDs","authors":"Hanwen Zhu, Guoqing Tong, Junchun Li, Xuyong Tao, Yang Shen, Yuanyuan Sheng, Lin Shi, Fengming Xie, Jianxin Tang, Yang Jiang","doi":"10.1002/idm2.12164","DOIUrl":"10.1002/idm2.12164","url":null,"abstract":"Low efficiency and spectral instability caused by the surface defects have been considerable issues for the mixed-halogen blue emitting perovskite quantum dots light-emitting diodes (PeQLEDs). Here, an in situ surface passivation to perovskite quantum dots (PeQDs) is realized by introducing the metal cations competitive lattice occupancy assisted with acid-etching, in which the long-chain, insulating and weakly bond surface ligands are removed by addition of octanoic acid (OTAC). Meanwhile, the dissolved A-site cations (Na+) compete with the protonated oleyl amine and are subsequently anchored to the surface vacancies. The preadded lead bromide, acting as inorganic ligands, demonstrates strong bonding to the uncoordinated surface ions. The as-synthesized PeQDs show the boosted photoluminescence quantum yield (PLQY) and superior stability with longer lifetime. As a result, the PeQLEDs (470 nm) based on the OTAC-Na PeQDs exhibit an external quantum efficiency of 8.42% in the mixed halogen PeQDs (CsPb(BrxCl1−x)3). Moreover, the device exhibits superior spectra stability with negligible shift. Our competition mechanism in combination with in situ passivation strategy paves a new way for improving the performance of blue PeQLEDs.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 3","pages":"437-447"},"PeriodicalIF":0.0,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12164","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140689391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tailored wrinkles for tunable sensing performance by stereolithography 通过立体光刻技术定制可调传感性能的皱纹

Interdisciplinary Materials Pub Date : 2024-04-18 DOI: 10.1002/idm2.12161

Ruiyi Jiang, Jie Pu, Yuxuan Wang, Jipeng Chen, Gangwen Fu, Xue Chen, Jiayu Yang, Jianghua Shen, Xing Sun, Jun Ding, Xi Xu

{"title":"Tailored wrinkles for tunable sensing performance by stereolithography","authors":"Ruiyi Jiang, Jie Pu, Yuxuan Wang, Jipeng Chen, Gangwen Fu, Xue Chen, Jiayu Yang, Jianghua Shen, Xing Sun, Jun Ding, Xi Xu","doi":"10.1002/idm2.12161","DOIUrl":"10.1002/idm2.12161","url":null,"abstract":"Conducting polymer hydrogel can address the challenges of stricken biocompatibility and durability. Nevertheless, conventional conducting polymer hydrogels are often brittle and weak due to the intrinsic quality of the material, which exhibits viscoelasticity. This property may cause a delay in sensor response time due to hysteresis. To overcome these limitations, we have designed a wrinkle morphology three-dimensional (3D) substrate using digital light processing technology and then followed by in situ polymerization to form interpenetrating polymer network hydrogels. This novel design results in a wrinkle morphology conducting polymer hydrogel elastomer with high precision and geometric freedom, as the size of the wrinkles can be controlled by adjusting the treating time. The wrinkle morphology on the conducting polymer hydrogel effectively reduces its viscoelasticity, leading to samples with quick response time, low hysteresis, stable cyclic performance, and remarkable resistance change. Simultaneously, the 3D gradient structure augmented the sensor's sensitivity under minimal stress while exhibiting consistent sensing performance. These properties indicate the potential of the conducting polymer hydrogel as a flexible sensor.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 3","pages":"414-424"},"PeriodicalIF":0.0,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12161","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140687292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Moiré superlattice effects on interfacial mechanical behavior: A concise review 界面机械行为的摩尔超晶格效应：简明综述

Interdisciplinary Materials Pub Date : 2024-04-14 DOI: 10.1002/idm2.12162

Weidong Yan, Jiangtao Liu, Wengen Ouyang, Ze Liu

引用次数: 0

Unlocking photocatalytic NO removal potential in an S-type UiO-66-NH2/ZnS(en)0.5 heterostructure 挖掘 S 型 UiO-66-NH2/ZnS(en)0.5 异质结构中光催化去除 NO 的潜力

Interdisciplinary Materials Pub Date : 2024-04-06 DOI: 10.1002/idm2.12160

Wenrui Dai, Chenxiang Wang, Yi Wang, Jieting Sun, Hang Ruan, Yuhua Xue, Shuning Xiao

{"title":"Unlocking photocatalytic NO removal potential in an S-type UiO-66-NH2/ZnS(en)0.5 heterostructure","authors":"Wenrui Dai, Chenxiang Wang, Yi Wang, Jieting Sun, Hang Ruan, Yuhua Xue, Shuning Xiao","doi":"10.1002/idm2.12160","DOIUrl":"10.1002/idm2.12160","url":null,"abstract":"The contamination of nitric oxide presents a significant environmental challenge, necessitating the development of efficient photocatalysts for remediation. Conventional heterojunctions encounter obstacles such as large contact barriers, sluggish charge transport, and compromised redox capacity. Here, we introduce an innovative S-type heterostructure photocatalyst, UiO-66-NH2/ZnS(en)0.5, designed specifically to overcome these challenges. The synthesis, employing a unique microwave solvothermal method, strategically aligns the lowest unoccupied molecular orbital of UiO-66-NH2 with the highest occupied molecular orbital of ZnS(en)0.5, fostering the formation of a stepped heterojunction. The resulting intimate interface contact generates a built-in electric field, facilitating charge separation and migration, as evidenced by time-resolved photoluminescence spectroscopy and photoelectrochemical tests. The abundant active sites in the porous UiO-66-NH2 counterpart provide adsorption and activation sites for nitrogen monoxide (NO) oxidation. Performance evaluation reveals exceptional photocatalytic NO removal, achieving 70% efficiency and 99% selectivity toward nitrates under simulated solar illumination. Evidence from X-ray photoelectron spectroscopy and trapping experiments supports the effectiveness of the S-type heterostructure, showcasing refined reactive oxygen species, particularly superoxide. Thus, this study introduces a new perspective on advanced NO oxidation and unlocks the potential of S-scheme heterojunctions to refine reactive oxygen species for NO remediation.","PeriodicalId":100685,"journal":{"name":"Interdisciplinary Materials","volume":"3 3","pages":"400-413"},"PeriodicalIF":0.0,"publicationDate":"2024-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/idm2.12160","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140735100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Inside Front Cover: Volume 3 Issue 2 封面内页：第 3 卷第 2 期

Interdisciplinary Materials Pub Date : 2024-03-28 DOI: 10.1002/idm2.12166

引用次数: 0