Cleaner Chemical Engineering最新文献

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Pressurized torrefaction of waste biomass to improve bio coal quality: Synergistic effect between animal waste and wood chips 废弃生物质加压焙烧提高生物煤品质:动物粪便与木屑的协同效应
Cleaner Chemical Engineering Pub Date : 2025-04-19 DOI: 10.1016/j.clce.2025.100171
N.M. Tshuma , L.B. Moyo , G. Danha , T.A. Mamvura , G.S. Simate , C.D. Artur , G. Charis
{"title":"Pressurized torrefaction of waste biomass to improve bio coal quality: Synergistic effect between animal waste and wood chips","authors":"N.M. Tshuma ,&nbsp;L.B. Moyo ,&nbsp;G. Danha ,&nbsp;T.A. Mamvura ,&nbsp;G.S. Simate ,&nbsp;C.D. Artur ,&nbsp;G. Charis","doi":"10.1016/j.clce.2025.100171","DOIUrl":"10.1016/j.clce.2025.100171","url":null,"abstract":"<div><div>This study aims to investigate the effect blending waste material to improve its fuel properties using pressurized torrefaction. This research explored the benefits of blending animal waste with wood chips to produce a bio-coal with improved fuel properties. The process conditions investigated were temperature and pressure intervals of 200°C to 280°C and atmospheric pressure (AP) to 4MPa, respectively. The results showed that an increase in temperature and pressure improved the fixed carbon content of the blend almost threefold from 19.87 % to 66.93 % and the higher heating value (HHV) to 27.32MJ/kg from 13.90MJ/kg at mild torrefaction temperature of 280°C and gas pressure of 4MPa compared to atmospheric pressure conditions and the lowest temperature investigated. The HHV increased primarily due to a release of bound and unbound moisture and volatile matter. Wood chips had an HHV of 27.00MJ/kg at a torrefaction temperature of 280°C due to the decomposition of hemicellulose and cellulose which enhanced the thermal stability, fixed carbon content and calorific value. However, animal waste had the least incremental increase in HHV (16.45MJ/kg) due to a high initial content of volatile matter and moisture. The improved properties of the blend of materials indicated that pressurized torrefaction was effective in increasing fixed carbon content through secondary polymerization reactions. Moreover, it facilitated the decomposition of cellulose at a lower temperature than the typical range of 315-400°C if conducted at atmospheric pressure. This study elucidates the notable role of the synergistic effects of blending feed materials prior to torrefaction towards improving the properties and pyrolysis performance of biomass components.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100171"},"PeriodicalIF":0.0,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143874826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pristine metal–organic framework electrocatalysts for hydrogen production: Role of electrocatalyst properties in basic media 用于制氢的原始金属-有机框架电催化剂:电催化剂性能在碱性介质中的作用
Cleaner Chemical Engineering Pub Date : 2025-04-12 DOI: 10.1016/j.clce.2025.100170
Liberty L Mguni , Olga K Mmelesi , Emmanuel Kweinor Tetteh , Nombeko G Sijadu , Yali Yao , Sudesh Rathilal
{"title":"Pristine metal–organic framework electrocatalysts for hydrogen production: Role of electrocatalyst properties in basic media","authors":"Liberty L Mguni ,&nbsp;Olga K Mmelesi ,&nbsp;Emmanuel Kweinor Tetteh ,&nbsp;Nombeko G Sijadu ,&nbsp;Yali Yao ,&nbsp;Sudesh Rathilal","doi":"10.1016/j.clce.2025.100170","DOIUrl":"10.1016/j.clce.2025.100170","url":null,"abstract":"<div><div>The recent detrimental impacts of carbon-based fuels on the environment have necessitated the production of hydrogen as clean and renewable energy via an electrocatalytic process. However, a cathodic hydrogen evolution reaction (HER) with slow kinetics and water-splitting steps without a suitable catalyst limits its large-scale production. Herein, metal-organic frameworks (MOFs) due to the unique properties of high surface area, porosity and favourable tunability, offer significant advantages over conventional catalysts to provide greater flexibility and effective reactions in the energy sector. However, the use of MOFs as electrocatalysts faces challenges like electrode corrosion and poor electron mobility and conductivity due to the lack of an optimal fabrication approach. Additionally, there is limited information on the development of MOF materials for HER in basic medium electrolytes. Therefore, pristine MOF-based materials and applicability for HER in a basic environment were comprehensively reviewed. It was elucidated that pristine MOFs used in a basic medium are more advantageous than in an acidic medium. Furthermore, recent advancements in improving MOF electrocatalytic properties and activities were discussed. Also, the effect of pristine MOFs on rate-determining steps in HER was highlighted. In addition, the challenges and prospects of improving MOFs for HER and other field applications were examined in detail, providing a comprehensive view. It was found that solvent removal during MOF activation with metal ions and electron-donating groups on the ligand has a synergy impact on the available active sites for HER.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100170"},"PeriodicalIF":0.0,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143850253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MOSFSA-based CFBHSMC to enhance control accuracy and robustness of proton exchange membrane fuel cell> 基于mosfsa的CFBHSMC提高质子交换膜燃料电池>控制精度和鲁棒性
Cleaner Chemical Engineering Pub Date : 2025-04-08 DOI: 10.1016/j.clce.2025.100168
Ali Darvish Falehi
{"title":"MOSFSA-based CFBHSMC to enhance control accuracy and robustness of proton exchange membrane fuel cell>","authors":"Ali Darvish Falehi","doi":"10.1016/j.clce.2025.100168","DOIUrl":"10.1016/j.clce.2025.100168","url":null,"abstract":"<div><div>The Proton Exchange Membrane Fuel Cell (PEMFC) is one of the most important eco-friendly energy conversion systems which provides electrical energy from chemical energy as a consequence of electrochemical reaction. The performance, accuracy and durability of PEMFC-based power generation system are strongly dependent on its control strategy and design methodology, which may be a challenging and complex task owing to all-inclusive dynamic mechanism of air conditioning system. This paper aims to propose a new Chattering Free Binomial Hyperbolic Sliding Mode Controller (CFBHSMC) for DC-DC boost converter to augment the system performance and guarantee the system accuracy in presence of model uncertainties and external disturbances. Due to nonlinearity of PEMFC system and its high control sensitivity, the design control scheme has been formulated as multi-objective optimization problem using Multi-Objective Stochastic Fractal Search Algorithm (MOSFSA). The optimal CFBHSMC can significantly reduce the chattering effect, ensure the fast convergence and enhance the tracking accuracy. To validate the proposed controller's capabilities, the simulation results have been compared with fuzzy controller, classic SMC and super-twisting SMC. The simulation results have revealed that the oscillation ranges of PEMFC system for fuzzy controller, classic SMC, super-twisting SMC and CFBHSMC are respectively achieved 8 × 10<sup>–3</sup>, 9 × 10<sup>–3</sup>, 4 × 10<sup>–3</sup> and 2 × 10<sup>–4</sup>, and also the average deviations of these oscillations from the reference signal are respectively obtained as 14×10<sup>–3</sup>, 5 × 10<sup>–3</sup>, 2 × 10<sup>–3</sup> and 1 × 10<sup>–4</sup>.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100168"},"PeriodicalIF":0.0,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143842566","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing solar still performance using external condensers and floating fins: A comparative study 利用外聚光器和浮动翅片提高太阳能蒸馏器性能的比较研究
Cleaner Chemical Engineering Pub Date : 2025-04-06 DOI: 10.1016/j.clce.2025.100167
Tanvir Rahman , Lailatul Nehar , Yeamin Prodhan , Shahiduzzaman Shahed , Shahriar Al Hasib , M S Rahman , S.S. Tuly
{"title":"Enhancing solar still performance using external condensers and floating fins: A comparative study","authors":"Tanvir Rahman ,&nbsp;Lailatul Nehar ,&nbsp;Yeamin Prodhan ,&nbsp;Shahiduzzaman Shahed ,&nbsp;Shahriar Al Hasib ,&nbsp;M S Rahman ,&nbsp;S.S. Tuly","doi":"10.1016/j.clce.2025.100167","DOIUrl":"10.1016/j.clce.2025.100167","url":null,"abstract":"<div><div>Solar distillation is a sustainable and cost-effective method for producing potable water from brackish sources. However, its widespread adoption is limited because of low daily freshwater yield and inefficient solar energy utilization due to slow evaporation and condensation processes. This study presents a series of modifications to enhance these processes: floating aluminum fins (FAF) to improve evaporation and two types of external condensers (single rectangular/REC and multiple cylindrical/MCEC) to optimize condensation. Four configurations were tested: Case I (conventional solar still/CSS), Case II (CSS + FAF), Case III (CSS modified with FAF + REC), and Case IV (CSS modified with FAF + MCEC). Key results demonstrate that Case IV (FAF + MCEC) achieved the highest performance, with an average daily yield of 2725 ml/day (80.36 % higher than CSS), peak instantaneous efficiency of 39.7 %, and exergy efficiency improvements of 163 % over CSS. Environmental analysis revealed that Case IV mitigated 420 kg of CO₂ emissions over its lifetime, earning $135 in carbon credits, offsetting its higher embodied emissions (1450 kg CO₂) from manufacturing. The system's payback period of 273 days and modular design highlight its economic and scalability potential for water-scarce regions. These findings underscore the viability of floating fins and multi-condenser designs to simultaneously address water scarcity, energy efficiency, and environmental sustainability.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100167"},"PeriodicalIF":0.0,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green approach for obtaining bioactive compounds from Pterocaulon polystachyum through ultrasound-assisted deep eutectic solvent extraction 超声辅助深度共晶溶剂萃取法提取茯芩中生物活性化合物的绿色途径
Cleaner Chemical Engineering Pub Date : 2025-04-03 DOI: 10.1016/j.clce.2025.100166
Victor Hugo Silva Rodrigues , Jelena Vladic , Joana Pereira , Hugo Monteiro , Alexandre Paiva , Rubem Mário Figueiró Vargas , Eduardo Cassel , Ana Rita C. Duarte
{"title":"Green approach for obtaining bioactive compounds from Pterocaulon polystachyum through ultrasound-assisted deep eutectic solvent extraction","authors":"Victor Hugo Silva Rodrigues ,&nbsp;Jelena Vladic ,&nbsp;Joana Pereira ,&nbsp;Hugo Monteiro ,&nbsp;Alexandre Paiva ,&nbsp;Rubem Mário Figueiró Vargas ,&nbsp;Eduardo Cassel ,&nbsp;Ana Rita C. Duarte","doi":"10.1016/j.clce.2025.100166","DOIUrl":"10.1016/j.clce.2025.100166","url":null,"abstract":"<div><div>A green approach for the extraction of bioactive compounds from <em>Pterocaulon polystachyum</em> was studied. The extraction process was optimized regarding time, temperature, solid/liquid ratio and technique, either ultrasound-assisted extraction (UAE) or heating and stirring. Eleven deep eutectic solvents (DES) based on choline chloride, menthol and betaine were evaluated to identify the most effective solvent to extract bioactive compounds from <em>P. polystachyum</em>. The solvent was selected based on the total phenolic content (TPC) extracted. For all DES systems, their relative polarity, the water content, viscosity and density were determined. The results showed that the best extraction condition regarding extraction yield was 30 min, 40 °C, S/L ratio of 1:20 (m/m) and using UAE technique. The best DES for TPC extraction was Lac:Gly:Wat (3:1:3), with a TPC of 50.68 ± 2.87 (mg GAE/g <em>P. polystachyum</em>), and the Bet:Et (1:3) DES was the best extraction system without water and lactic acid in its composition, which are two components that can directly affect cell viability in cytotoxicity assays. Additionally, using the same extraction conditions, valorization of biomass wastes after steam distillation and supercritical fluid extraction was successfully achieved. In the cytotoxicity assays towards spontaneously immortalized human keratinocyte (HaCaT) cells, certain inconclusive results were obtained for the Lac:Gly:Wat (3:1:3) extracts, mainly because the color of the extract interfered with the absorbance measurement. For Bet:Et (1:3) extracts this interference was not observed and the half-maximal effective concentration value (EC<sub>50</sub>) was determined as 227 ± 64.29 mg/mL for Bet:Et (1:3) pure solvent, and between 114 ± 9.49 and 206.9 ± 15.61 mg/mL for Bet:Et (1:3) extracts. These results suggest that the <em>P. polystachyum</em> extracts obtained from the different plant materials are non-toxic to cells at concentrations typically used in cosmetic applications, highlighting the potential for creating new products using an environmental-friendly process.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100166"},"PeriodicalIF":0.0,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143800103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A critical review on textile dye-containing wastewater: Ecotoxicity, health risks, and remediation strategies for environmental safety 纺织染料废水的生态毒性、健康风险和环境安全修复策略综述
Cleaner Chemical Engineering Pub Date : 2025-03-29 DOI: 10.1016/j.clce.2025.100165
Md. Mynul Islam , Allah Rakha Aidid , Jamshed Nawaj Mohshin , Himel Mondal , Sumon Ganguli , Ashok Kumar Chakraborty
{"title":"A critical review on textile dye-containing wastewater: Ecotoxicity, health risks, and remediation strategies for environmental safety","authors":"Md. Mynul Islam ,&nbsp;Allah Rakha Aidid ,&nbsp;Jamshed Nawaj Mohshin ,&nbsp;Himel Mondal ,&nbsp;Sumon Ganguli ,&nbsp;Ashok Kumar Chakraborty","doi":"10.1016/j.clce.2025.100165","DOIUrl":"10.1016/j.clce.2025.100165","url":null,"abstract":"<div><div>Textile dyes are becoming major environmental pollutants worldwide. Generally, they are discharged from textile industries into aquatic systems, which serve as primary sources for entire ecosystems, ultimately affecting human health. Thus, it is crucial to know the potential adverse consequences of textile dye exposure on phytoplankton, fauna, terrestrial entities and humans in the environment. This study provides an assessment of the appropriate publications, from which it can be demonstrated that textile waste can affect the life cycle of living organisms by disrupting growth and reproduction. In particular, various aquatic bodies become targets of textile wastewater. The impact of these dyes and its intermediates on the development of diatoms and their behavior, and the oxidative approach. Humans consume textile dyes through their food web and the intake of contaminated water. The consumed dye is bio-converted into reactive intermediates and aromatic amines by enzymes of the cytochrome family in the human body. In sub-cellular moiety, textile dyes and their bio-converted products form DNA and protein adducts. These compounds act as catalysts to form free radicals and oncogene activation, and affect apoptotic cascades to produce lesions in multiple organs. Dyes and their bio-transformed products, have been shown to modulate epigenetic factors including DNA methylation, histone modifications, epigenetic enzymes leading to carcinogens. Various remediation processes including physical, physico-chemical, biological and some integrated systems are currently under investigation. However, further research is required to develop efficient, cost-effective, and eco-friendly techniques while identifying future directions to boost textile effluent treatment efficiency and address remaining challenges.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100165"},"PeriodicalIF":0.0,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143808067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifaceted applications of dye-saturated biochar: Agronomic amelioration, thermochemical valorization, and catalytic efficacy in advanced environmental remediation paradigms 染料饱和生物炭的多方面应用:农学改良、热化学增值和在先进环境修复范例中的催化效果
Cleaner Chemical Engineering Pub Date : 2025-03-17 DOI: 10.1016/j.clce.2025.100164
Sandra Ramachandran , Anshuman Gupta , Neelaambhigai Mayilswamy , Amrita Nighojkar , Balasubramanian Kandasubramanian
{"title":"Multifaceted applications of dye-saturated biochar: Agronomic amelioration, thermochemical valorization, and catalytic efficacy in advanced environmental remediation paradigms","authors":"Sandra Ramachandran ,&nbsp;Anshuman Gupta ,&nbsp;Neelaambhigai Mayilswamy ,&nbsp;Amrita Nighojkar ,&nbsp;Balasubramanian Kandasubramanian","doi":"10.1016/j.clce.2025.100164","DOIUrl":"10.1016/j.clce.2025.100164","url":null,"abstract":"<div><div>The intensifying challenge of dye-laden industrial wastewater necessitates innovative, sustainable remediation technologies to mitigate ecological and human health risks. Sewage sludge-derived biochar (SSB) has emerged as a cost-effective and versatile adsorbent, attributed to its high surface area, hierarchical porosity, and diverse surface functional groups, which facilitate superior dye adsorption under both batch and continuous flow systems. This review provides a critical evaluation of SSB's adsorption performance, elucidating mechanisms such as π-π interactions, electrostatic attraction, and surface complexation. Regeneration methods, including thermal treatment, chemical washing, and solvent desorption, are analyzed in terms of efficiency and scalability. Furthermore, the secondary applications of dye-saturated biochar, including its use as a soil amendment to enhance microbial activity and nutrient retention, its valorization as a high-calorific energy source, and its role as a catalyst in advanced oxidation processes, are systematically explored. The review identifies key limitations, such as feedstock variability, competing ions in wastewater, and energy-intensive production processes, and proposes strategies for optimizing biochar synthesis and functionalization. By bridging laboratory-scale studies with industrial applications, this work delineates the economic and environmental viability of SSB and advances the development of scalable, sustainable wastewater treatment solutions.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100164"},"PeriodicalIF":0.0,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143685521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption-photodegradation performance of Silver Titanate for Methylene blue removal: Kinetics, thermodynamics and isotherm studies 钛酸银去除亚甲基蓝的吸附-光降解性能:动力学、热力学和等温线研究
Cleaner Chemical Engineering Pub Date : 2025-03-10 DOI: 10.1016/j.clce.2025.100163
Nawrin Rahman Shefa , Most. Afroza Khatun , Ahmed Hasnain Jalal , M. Jasim Uddin , Md. Wasikur Rahman
{"title":"Adsorption-photodegradation performance of Silver Titanate for Methylene blue removal: Kinetics, thermodynamics and isotherm studies","authors":"Nawrin Rahman Shefa ,&nbsp;Most. Afroza Khatun ,&nbsp;Ahmed Hasnain Jalal ,&nbsp;M. Jasim Uddin ,&nbsp;Md. Wasikur Rahman","doi":"10.1016/j.clce.2025.100163","DOIUrl":"10.1016/j.clce.2025.100163","url":null,"abstract":"<div><div>Silver titanate (AgTO) was synthesized via an ion-exchange reaction between sodium titanate and silver nitrate. This study investigates the efficiency of AgTO in the combined adsorption-photodegradation process for removing Methylene Blue (MB). The synthesized material was characterized using FTIR, XRD, SEM, and EDX techniques. Batch adsorption experiments were conducted to assess the effects of AgTO dosage (0.1–1.0 g/L), initial MB concentration (5–20 mg/L), pH (3–11), and temperature (313–333 K). The highest MB removal efficiency (90 %) was achieved at 313 K, pH 3, and an initial MB concentration of 5 mg/L. The photocatalytic performance of AgTO was further evaluated under an 18-Watt UV light source, confirming its effectiveness in MB degradation. Adsorption followed pseudo-second-order (PSO) kinetics, while photodegradation adhered to first-order (FO) kinetics. Thermodynamic analysis indicated that both adsorption and photodegradation were endothermic processes. The Langmuir isotherm model, with a maximum adsorption capacity of 5.24 mg/g, provided the best fit for the adsorption data. Overall, as-prepared AgTO exhibited dual-functionality in a combined adsorption-photodegradation system for MB removal, revealing its high efficiency, kinetics, and thermodynamic feasibility, thereby establishing AgTO as a promising candidate for wastewater treatment.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100163"},"PeriodicalIF":0.0,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143619661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physical, thermal, chemical and biological approaches for plastics degradation–A review
Cleaner Chemical Engineering Pub Date : 2025-03-03 DOI: 10.1016/j.clce.2025.100162
Seetharam Pondala, Sathish Mohan Botsa
{"title":"Physical, thermal, chemical and biological approaches for plastics degradation–A review","authors":"Seetharam Pondala,&nbsp;Sathish Mohan Botsa","doi":"10.1016/j.clce.2025.100162","DOIUrl":"10.1016/j.clce.2025.100162","url":null,"abstract":"<div><div>Microplastics are pervasive pollutants in soil and water that break down slowly. Microplastics can adsorb other pollutants and have a high stability, long life time, and high fragmentation potential. The widespread presence of microplastics and their possible ecological effects make their removal from the environment a critical issue at the moment. This makes it necessary to find ways to eliminate micro plastics from the water and other media. Here, we go over numerous approaches have been put forth and examined in an effort to tackle this problem. Chemical, physical, and biological techniques are used in removal processes. The primary breakdown of microplastics by bacteria, fungi, algae, and macrophytes is the main function of biological methods. Physical methods include membrane technology, adsorption, centrifugation, sedimentation, and filtration techniques. Chemical techniques contain the plasma treatment, Fenton and photo-Fenton process and thermal degradation. Every technique has benefits and drawbacks, which emphasizes the requirement for integrated strategies catered to various environmental conditions and microplastic kinds. The main topics we covered were the mechanisms, effectiveness, benefits, and drawbacks of different removal techniques.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100162"},"PeriodicalIF":0.0,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143579864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable valorization of textile industry cotton waste through pyrolysis for biochar production 通过热解生产生物炭实现纺织业棉花废料的可持续增值
Cleaner Chemical Engineering Pub Date : 2025-03-02 DOI: 10.1016/j.clce.2025.100161
Fatema Tujjohra , Md. Ehsanul Haque , Md. Abdul Kader , Mohammed Mizanur Rahman
{"title":"Sustainable valorization of textile industry cotton waste through pyrolysis for biochar production","authors":"Fatema Tujjohra ,&nbsp;Md. Ehsanul Haque ,&nbsp;Md. Abdul Kader ,&nbsp;Mohammed Mizanur Rahman","doi":"10.1016/j.clce.2025.100161","DOIUrl":"10.1016/j.clce.2025.100161","url":null,"abstract":"<div><div>This study presents a novel and sustainable approach to the valorization of textile spinning industry waste cotton (WC) through direct pyrolysis, converting it into high-quality biochar with enhanced energy potential and structural stability. This research systematically examines the impact of pyrolysis temperature (300–500°C) on biochar yield, composition, and physicochemical properties to optimize conditions for maximum carbon retention and energy efficiency. The results indicate that biochar yield decreased from Biochar yield decreased from 50.5 % at 300°C to 26.7 % at 500°C, while fixed carbon content increased from 59.33 % to 68.65 %. Elemental analysis revealed a rise in carbon content (53.13 % to 73.62 %) and reductions in oxygen (46.7 % to 13.27 %) and hydrogen (6.06 % to 2.79 %), enhancing thermal stability. X-ray Diffraction (XRD) analysis demonstrated a transition from amorphous cellulose to condensed graphitic carbon at higher temperatures. Thermogravimetric Analysis (TGA) confirmed superior thermal resistance, with biochar retaining 14.7 % of its mass at 800°C. Differential Scanning Calorimetry (DSC) revealed key thermal transitions, with the endothermic peak shifting from 65.5°C in raw WC to 79.6°C at 500°C, indicating increased thermal stability. The calorific value peaked at 27.31 MJ/kg at 400°C, making it a promising solid biofuel. Additionally, Brunauer-Emmett-Teller (BET) analysis showed a substantial increase in porosity, with the highest specific surface area of 225.24 m<sup>2</sup>/g at 500°C, improving biochar's potential for adsorption, catalysis, and energy storage. These findings contribute to optimizing pyrolysis conditions for waste cotton valorization, supporting circular economy principles, reducing environmental pollution, and enhancing renewable energy applications. By integrating pyrolysis into textile waste management, this study offers a scalable and eco-friendly strategy for sustainable energy recovery and environmental remediation.</div></div>","PeriodicalId":100251,"journal":{"name":"Cleaner Chemical Engineering","volume":"11 ","pages":"Article 100161"},"PeriodicalIF":0.0,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143561892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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