Applied Organometallic Chemistry最新文献

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A Newly Constructed Cobalt-Organic Coordination Polymer and Its Two Carbon-Based Composites Demonstrating Electrochemical Sensing to NO2− and Cr (VI) 新型钴-有机配位聚合物及其对NO2−和Cr (VI)电化学敏感的两种碳基复合材料
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-09-02 DOI: 10.1002/aoc.70386
Si-Wei Zong, Ting Guo, Yuan-Wen Yang, Kou-Lin Zhang
{"title":"A Newly Constructed Cobalt-Organic Coordination Polymer and Its Two Carbon-Based Composites Demonstrating Electrochemical Sensing to NO2− and Cr (VI)","authors":"Si-Wei Zong,&nbsp;Ting Guo,&nbsp;Yuan-Wen Yang,&nbsp;Kou-Lin Zhang","doi":"10.1002/aoc.70386","DOIUrl":"https://doi.org/10.1002/aoc.70386","url":null,"abstract":"<div>\u0000 \u0000 <p>A novel cobalt-organic ionic coordination polymer, incorporating the multifunctional 2-iodo-4-sulfonatobenzoate anion (isba<sub>2</sub><sup>−</sup>) and the rigid nitrogen-containing ligand 4,4′-bipyridine (bipy) {[Co (bipy)(H<sub>2</sub>O)<sub>3</sub>(CH<sub>3</sub>CH<sub>2</sub>OH)]·isba·2H<sub>2</sub>O}<sub>n</sub> (Co-bipy), was synthesized via a straightforward solution evaporation method at room temperature. Two innovative carbon-based composite materials Co-bipy@MWCNTs and Co-bipy@GO were successfully fabricated through hybridization with multi-walled carbon nanotubes and graphene oxide, respectively. Experimental investigation indicates that the electrocatalytic ability of Co-bipy towards the NO<sub>2</sub><sup>−</sup> oxidation and Cr (VI) reduction can be enhanced by MWCNTs and GO. Among the three glassy carbon electrodes (GCE) modified with Co-bipy, Co-bipy@MWCNTs, and Co-bipy@GO, the Co-bipy@MWCNTs/GCE exhibits optimal performance for NO<sub>2</sub><sup>−</sup> oxidation sensing in 0.1 M PBS and Cr (VI) reduction sensing in 0.1 M H<sub>2</sub>SO<sub>4</sub>. The successful modification of Co-bipy@MWCNTs on the screen-printed electrode (SPE) further enhanced the electrocatalytic performance of Co-bipy@MWCNTs. The Co-bipy@MWCNTs/SPE shows the most efficient sensing to NO<sub>2</sub><sup>−</sup> and Cr (VI). The limits of detection (LOD) reach 0.13 μM for NO<sub>2</sub><sup>−</sup> and 0.25 μM for Cr (VI), respectively. Furthermore, the Co-bipy@MWCNTs/SPE was effectively employed for the accurate detection of NO<sub>2</sub><sup>−</sup> and Cr (VI) in the actual samples. The sensing mechanisms for NO<sub>2</sub><sup>−</sup> and Cr (VI) were illustrated with the aid of Hirshfeld surface analysis and density of states (DOS) calculations.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Transition Metal Complexes of PNP and PNN Ligands: Synthesis and Catalytic Applications in Hydrophosphination of Terminal Alkynes PNP和PNN配体的过渡金属配合物:合成及其在末端炔烃加氢磷酸化中的催化应用
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-09-02 DOI: 10.1002/aoc.70384
Khilesh C. Dwivedi, Gazal Sabharwal, Maravanji S. Balakrishna
{"title":"Transition Metal Complexes of PNP and PNN Ligands: Synthesis and Catalytic Applications in Hydrophosphination of Terminal Alkynes","authors":"Khilesh C. Dwivedi,&nbsp;Gazal Sabharwal,&nbsp;Maravanji S. Balakrishna","doi":"10.1002/aoc.70384","DOIUrl":"https://doi.org/10.1002/aoc.70384","url":null,"abstract":"<div>\u0000 \u0000 <p>In this study, we report the synthesis and structural characterization of a series of transition metal complexes derived from two pincer-type ligands: {(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O)NH(C<sub>9</sub>H<sub>6</sub>N)} (<b>1)</b> and {(<i>o</i>-Ph<sub>2</sub>PC<sub>6</sub>H<sub>4</sub>C(O)N(H)C<sub>6</sub>H<sub>4</sub>PPh<sub>2</sub>-<i>o</i>)} (<b>2</b>). Treatment of Ligand <b>1</b> with [Rh (acac)(CO)<sub>2</sub>] afforded rhodium pincer complex [Rh (CO){(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O)N(C<sub>9</sub>H<sub>6</sub>N)}κ<sup>3</sup>-<i>P</i>,<i>N</i>,<i>N</i>] (<b>3</b>). Ligand <b>1</b>, upon reaction with [Ru(H)(CO)(Cl)(PPh<sub>3</sub>)<sub>3</sub>] in THF, yielded the ruthenium complex [Ru (PPh<sub>3</sub>)(CO)(Cl){(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O)N(C<sub>9</sub>H<sub>6</sub>N)}κ<sup>3</sup>-<i>P</i>,<i>N</i>,<i>N</i>] (<b>4</b>), while its reaction with [Ru (Cl)<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>] in methanol afforded a Ru<sup>III</sup> complex, [Ru (CH<sub>3</sub>OH)(Cl)<sub>2</sub>{(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O) N(C<sub>9</sub>H<sub>6</sub>N)}κ<sup><i>3</i></sup>-P,N,N] <b>(5)</b>. Ligand <b>2</b>, when reacted with CuI in a 1:1 M ratio in a CH<sub>2</sub>Cl<sub>2</sub>/CH<sub>3</sub>CN (1:1 v/v) mixture, yielded the dimeric complex [CuI(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O) N(H)CH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>(<i>o</i>-PPh<sub>2</sub>)]<sub>2</sub> (<b>6</b>). Increasing the CuI to ligand ratio to 2:1 yielded the tetrameric complex [Cu<sub>4</sub>(<i>μ</i><sub>2</sub>-I)<sub>2</sub>(<i>μ</i><sub>3</sub>-I)<sub>2</sub>{(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O)NCH<sub>2</sub>C<sub>6</sub>H<sub>4</sub> (<i>o</i>-PPh<sub>2</sub>)}<sub>2</sub>-<i>P</i>,<i>P</i>] (<b>7</b>). The reaction of Ligand <b>2</b> with two equivalents of [AuCl (SMe<sub>2</sub>)] produced a binuclear gold complex, [AuCl{(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O)N(H)CH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>{(<i>o</i>-PPh<sub>2</sub>)}AuCl] (<b>8</b>). Furthermore, Ligand <b>2</b> underwent complexation with [Rh (acac)(CO)<sub>2</sub>] and [Mn<sub>2</sub>(CO)<sub>10</sub>] to afford PNP-type pincer complexes [RhCO{(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>C(O)NCH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>(<i>o</i>-PPh<sub>2</sub>)}κ<sup>3</sup>-<i>P</i>,<i>N</i>,<i>P</i>] (<b>9</b>) and [Mn (CO)<sub>3</sub>{(<i>o</i>-PPh<sub>2</sub>)C<sub>6</sub>H<sub>4</sub> C(O)NCH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>(<i>o</i>-PPh<sub>2</sub>)}κ<sup>3</sup>-<i>P</i>,<i>N</i>,<i>P</i>] (<b>10</b>) respectively. Notably, the rhodium PNN pincer Complex <b>3</b> was successfully employed as a catalyst in the additive-free hydrophosphination of phenylacetylenes, providing a more straightforward and operationally simple methodology for this transformation.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrospinning Polymethyl Methacrylate (PMMA)/UiO-66 for Hydrogen Generation via NaBH4 Hydrolysis 电纺丝聚甲基丙烯酸甲酯(PMMA)/UiO-66水解制氢研究
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-09-02 DOI: 10.1002/aoc.70382
Hani Nasser Abdelhamid
{"title":"Electrospinning Polymethyl Methacrylate (PMMA)/UiO-66 for Hydrogen Generation via NaBH4 Hydrolysis","authors":"Hani Nasser Abdelhamid","doi":"10.1002/aoc.70382","DOIUrl":"https://doi.org/10.1002/aoc.70382","url":null,"abstract":"<div>\u0000 \u0000 <p>Metal–organic framework (MOF) using UiO-66 as a model was fabricated into nanofibers via electrospinning with poly(methyl methacrylate) (PMMA), denoted as PUiO-66. The materials, containing different Ui-O66 loadings, were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), diffuse reflectance spectroscopy (DRS), and Tauc plots. Electrospun PUiO-66 exhibits a nanostructure with nanofiber diameters in the 150–400-nm range. UiO-66-derived polymer nanofibers (PUiO-66) were reported for hydrogen production via the photocatalytic hydrolysis of sodium borohydride (NaBH<sub>4</sub>). UiO-66 was integrated into electrospun PMMA fibers at varying loadings (0.2%, 0.5%, and 1.0%). The shape and homogeneity of the fibers were evaluated via SEM, while their optical properties were studied through DRS and Tauc plots, indicating a decrease in optical bandgap with high UiO-66 loading. The PUiO-66 (1%) demonstrated the maximum catalytic activity, attaining a hydrogen generating rate (HGR) of 500 mL/g<b>·</b>min, about five times higher than that of the PUiO-66 (0.2%). The photocatalytic activity significantly decreased the reaction time, demonstrating the effect of UV absorption of the PUiO-66 fibers on NaBH<sub>4</sub> hydrolysis. The influence of NaBH<sub>4</sub> concentration on hydrogen production was examined, revealing that increased reactant loading markedly enhanced the reaction rate and decreased time for the hydrolysis. The photocatalytic performance of the fibers can be recycled for five successive cycles without a significant drop in the material's performance. Our findings reveals the promising of PUiO-66 nanofibers for effective hydrogen production via photocatalytic hydrolysis of NaBH<sub>4</sub>.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Glucose-Modified Porphyrins With Superior Photostability for Enhanced Photodynamic Therapy 具有优越光稳定性的葡萄糖修饰卟啉增强光动力治疗
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-09-02 DOI: 10.1002/aoc.70357
Wen-Yuan Zhang, Bing-Jie Hou, Wen-Le Zhang, Bo Wang, Zi-Han Yang, Neng-Zhi Jin, Jia-Cheng Liu
{"title":"Glucose-Modified Porphyrins With Superior Photostability for Enhanced Photodynamic Therapy","authors":"Wen-Yuan Zhang,&nbsp;Bing-Jie Hou,&nbsp;Wen-Le Zhang,&nbsp;Bo Wang,&nbsp;Zi-Han Yang,&nbsp;Neng-Zhi Jin,&nbsp;Jia-Cheng Liu","doi":"10.1002/aoc.70357","DOIUrl":"https://doi.org/10.1002/aoc.70357","url":null,"abstract":"<div>\u0000 \u0000 <p>As one of the three major biomolecules, glucose and its modified derivatives exhibit strong cell specificity for cancer cells. Four glucose-modified porphyrin compounds (Glu-P, Glu-ZnP, Glu-InP, and Glu-CuP) were synthesized. Among these, Glu-P demonstrates excellent photostability, while Glu-ZnP exhibits the highest photophysical activity. In vitro anti-tumor experiments show that Glu-P has remarkable phototoxicity against cancer cells (HepG2, A549, and H-1975). Additionally, due to the specific targeting ability of porphyrin, it shows good biocompatibility with HS578Bst normal cells. Density functional theory (DFT) calculations indicate that Glu-InP also exhibits good photophysical activity. However, Glu-P outperforms it due to its superior photostability. With excellent photostability and a high singlet oxygen production rate, Glu-P presents a promising candidate for photodynamic therapy. These findings provide new insights for the development of effective metal-based anticancer photosensitizers for photodynamic therapy.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Addition of the Vulcanisation Accelerator Di(pentamethylene) thiuram Tetrasulfide (PMTT) to Low and High Valent Molybdenum Centres 在低价和高价钼中心添加硫化促进剂二(五亚甲基)硫脲四硫化(PMTT)
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-09-02 DOI: 10.1002/aoc.70381
Jagodish C. Sarker, David Pugh, Graeme Hogarth
{"title":"Addition of the Vulcanisation Accelerator Di(pentamethylene) thiuram Tetrasulfide (PMTT) to Low and High Valent Molybdenum Centres","authors":"Jagodish C. Sarker,&nbsp;David Pugh,&nbsp;Graeme Hogarth","doi":"10.1002/aoc.70381","DOIUrl":"https://doi.org/10.1002/aoc.70381","url":null,"abstract":"<div>\u0000 \u0000 <p>The reactivity of di(pentamethylene) thiuram tetrasulfide (PMTT) towards both low and high valent molybdenum centres has been investigated to compare with the well-studied reactivity of thiuram disulfides (TDS) and to generate potential new single source precursors (SSPs) to nanoscale MoS<sub>2</sub>. Heating two equivalents of PMTT and Mo(CO)<sub>6</sub> in acetone affords the Mo(V) complex [Mo(S<sub>2</sub>)(S<sub>2</sub>CNC<sub>5</sub>H<sub>10</sub>)<sub>3</sub>] (<b>1</b>) in moderate yields, crystallisation leading to partial oxidation of the S<sub>2</sub> moiety to give a mixture of <b>1</b> and [Mo(S<sub>2</sub>O)(S<sub>2</sub>CNC<sub>5</sub>H<sub>10</sub>)<sub>3</sub>] (<b>1</b>-O). Reaction of [NH<sub>4</sub>]<sub>2</sub>[MoS<sub>4</sub>] and two equivalents of PMTT occurs at room temperature to afford the Mo (VI) complex [MoS(S<sub>2</sub>)(S<sub>2</sub>CNC<sub>5</sub>H<sub>10</sub>)<sub>2</sub>] (<b>2</b>) in quantitative yields. While stable to O<sub>2</sub>, <b>2</b> is sensitive to water, slow hydrolysis yielding the corresponding oxide [MoO(S<sub>2</sub>)(S<sub>2</sub>CNC<sub>5</sub>H<sub>10</sub>)<sub>2</sub>] (<b>3</b>) which has been crystallographically characterised. Both of these reactions give different products to those formed from TDS under similar conditions, the molybdenum centre being more oxidised in reactions with PMTT. We speculate on possible mechanistic pathways to the observed products and suggest that the simple and high yielding formation of <b>2</b> makes it a potentially attractive SSP.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Surface Oxygen-Defective ZIF-8/Bi7O9I3 Nanocomposite for Effective Photocatalytic Degradation of Sulfonamide 表面氧缺陷ZIF-8/Bi7O9I3纳米复合材料有效光催化降解磺胺
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-09-01 DOI: 10.1002/aoc.70380
Ranjith Kumar Dharman, Tae Hwan Oh
{"title":"Surface Oxygen-Defective ZIF-8/Bi7O9I3 Nanocomposite for Effective Photocatalytic Degradation of Sulfonamide","authors":"Ranjith Kumar Dharman,&nbsp;Tae Hwan Oh","doi":"10.1002/aoc.70380","DOIUrl":"https://doi.org/10.1002/aoc.70380","url":null,"abstract":"<div>\u0000 \u0000 <p>Photocatalysts offer a promising solution to water pollution, with ongoing research focused on identifying suitable materials for removing dyes, pharmaceuticals, and heavy metals. Therefore, this study aims to synthesize a surface oxygen-defective ZIF-8/Bi<sub>7</sub>O<sub>9</sub>I<sub>3</sub> nanocomposite for sulfonamide degradation under visible light irradiation. Electron spin resonance and X-ray photoelectron spectroscopy analysis revealed the presence of oxygen defects in ZIF-8@Bi<sub>7</sub>O<sub>9</sub>I<sub>3</sub> photocatalysts. The optimum ZIF-8@Bi<sub>7</sub>O<sub>9</sub>I<sub>3</sub> nanocomposite achieved 96.12% degradation of sulfonamide after 180 min. The enhanced photocatalytic degradation performance was attributed to the presence of oxygen vacancies, which trap electrons and reduce recombination rates in the nanocomposites. Furthermore, the effects of the initial pollutant pH and catalyst dose on photodegradation performance were investigated and optimized. Recycling tests showed no decrease in degradation rate after five consecutive cycles. Electrochemical analysis revealed efficient charge transfer resistance and reduced recombination rate in the nanocomposite. Scavenger assays were employed to identify the main reactive species involved in photocatalytic degradation. The degradation system in this study was primarily driven by superoxide (.O<sub>2</sub><sup>−</sup>) and hydroxy radicals (.OH). These findings form the basis for a proposed photocatalytic degradation mechanism.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144927174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Immobilization of Zr(IV) and Ni(II) on the Surfaces of BN Codoped Carbon Nanospheres: An Efficient Catalyst for the Green Synthesis of Benzo[g]pyrimido[4,5-b]quinolinetetraon Derivatives 氮化硼共掺杂碳纳米球表面固定Zr(IV)和Ni(II):一种绿色合成苯并[g]嘧啶[4,5-b]喹啉四元衍生物的高效催化剂
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-09-01 DOI: 10.1002/aoc.70335
Leila Pirestani, Leila Moradi
{"title":"Immobilization of Zr(IV) and Ni(II) on the Surfaces of BN Codoped Carbon Nanospheres: An Efficient Catalyst for the Green Synthesis of Benzo[g]pyrimido[4,5-b]quinolinetetraon Derivatives","authors":"Leila Pirestani,&nbsp;Leila Moradi","doi":"10.1002/aoc.70335","DOIUrl":"https://doi.org/10.1002/aoc.70335","url":null,"abstract":"<div>\u0000 \u0000 <p>In this study, an effective route is presented for the preparation of boron–nitrogen (BN) codoped carbon nanospheres using the reaction of urea, boric acid, and glucose (as carbon, boron, and nitrogen sources), followed by the surface modification with ascorbic acid and immobilization of Zr(IV) and Ni(II) (BN-CNS/Zr(IV), Ni(II)) through mild conditions. In addition to B and N elements, which have catalytic roles, the immobilization of Zr(IV) and Ni(II) on the BN-CNS surfaces created the special bifunctional acid–base catalyst. The prepared catalyst was identified by various characterization techniques, and the efficiency of the catalyst for the synthesis of benzo[<i>g</i>]pyrimido[4,5-<i>b</i>]quinolinetetraon derivatives was explored in water media at 80°C. High to excellent yield of products, easy recovery of the catalyst, and green reaction conditions are some of the merits of the presented method.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144927175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Byproduct-Free, One-Pot Synthesis of Ortho Hydroxy Aryl Assimilated Dihydropyrimidones Over-Engineered Sulfonated Graphene Oxide at Room Temperature 室温下无副产物,一锅合成邻羟基芳基同化二氢嘧啶过度工程磺化氧化石墨烯
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-08-27 DOI: 10.1002/aoc.70372
Sushil R. Mathapati, Mantosh B. Swami, Vijaykumar S. More, Ashutosh Pandey, Suman Kusuma, Arvind H. Jadhav
{"title":"Byproduct-Free, One-Pot Synthesis of Ortho Hydroxy Aryl Assimilated Dihydropyrimidones Over-Engineered Sulfonated Graphene Oxide at Room Temperature","authors":"Sushil R. Mathapati,&nbsp;Mantosh B. Swami,&nbsp;Vijaykumar S. More,&nbsp;Ashutosh Pandey,&nbsp;Suman Kusuma,&nbsp;Arvind H. Jadhav","doi":"10.1002/aoc.70372","DOIUrl":"https://doi.org/10.1002/aoc.70372","url":null,"abstract":"<div>\u0000 \u0000 <p>Dihydropyrimidinones (DHPMs) are an important class of heterocyclic compounds that exhibit a wide range of biological activities. They serve as a key structural motif in pharmaceuticals and agrochemicals, making their efficient and sustainable synthesis highly desirable. The nucleophilic nature of hydroxy groups often alters the reaction pathway towards the formation of oxygen-bonded tetracyclic derivatives and lactonization by-products, which is a significant challenge for the synthesis of dihydropyrimidinone derivatives (DHPM) with ortho-hydroxy groups. In the present study, a highly promising and environmentally friendly protocol has been developed for the synthesis of DHPM derivatives using sulfonated graphene oxide (GO-HSO<sub>3</sub>) as a metal-free heterogeneous catalyst. The reaction proceeded in ethanol at room temperature, rendering a sustainable and greener approach. The catalytic system efficiently facilitated the Biginelli reactions between ethyl acetoacetate, urea, and azo salicylaldehyde or salicylaldehyde, leading to the selective transformation of DHPMs with excellent yields (84–94%) and minimal byproducts. The superior catalytic activity of GO-HSO<sub>3</sub> is attributed to its abundant –SO<sub>3</sub>H functional groups, which enhance the proton donation and reaction kinetics. This approach is a sustainable and practical method for DHPM synthesis due to its excellent yield, ease of execution, reusability of the catalyst, and adherence to green chemistry principles. Compared to conventional methods that yield an undesired side product, this approach ensures high selectivity and cleaner synthesis. The developed strategy not only aligns with the principle but also demonstrates the potential of sulfonated graphene oxides as a sustainable catalyst for organic transformations.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 9","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144905599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tri-Transition Metal-Substituted Lanthanum-Based Perovskite Formulation for Catalytic Application in AP 三过渡金属取代镧系钙钛矿配方在AP催化中的应用
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-08-26 DOI: 10.1002/aoc.70369
Taruna Likhariya, Pragnesh N. Dave
{"title":"Tri-Transition Metal-Substituted Lanthanum-Based Perovskite Formulation for Catalytic Application in AP","authors":"Taruna Likhariya,&nbsp;Pragnesh N. Dave","doi":"10.1002/aoc.70369","DOIUrl":"https://doi.org/10.1002/aoc.70369","url":null,"abstract":"<div>\u0000 \u0000 <p>Lanthanum-based tri-transition metal-based perovskite structure was synthesized LaMn<sub><i>x</i></sub>Co<sub><i>y</i></sub>Fe<sub><i>z</i></sub>O<sub>3</sub>(<i>x</i> + <i>y</i> + <i>z</i> = 1) in three different compositions. IR spectroscopy shows the existence of M-O bond peak. The XRD patterns of pure cubic phase show an average crystalline size of 11.7 nm. Raman study provides insights into the various modes of vibration within the perovskite structure. BET surface area of the calcined material was 15.5 m<sup>2</sup>/g. N<sub>2</sub> adsorption curve signifies the porous nature of the adsorbent material. Its catalytic behavior towards ammonium perchlorate (AP) was established by TGA analysis, which shows 84 °C, 81 °C, and 94 °C decrease in the DSC peak, DTG peak, and DTA peak decomposition temperature of AP. Artificial neural networks were applied to forecast the TG curves and activation energy values.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 9","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144897656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Ag/Vit B3-MOF: A Proficient and Sustainable Approach, Photocatalytic Activity, and Molecular Docking Validation as HIV Replication Inhibitor 新型Ag/Vit B3-MOF:一种高效和可持续的方法,光催化活性,以及作为HIV复制抑制剂的分子对接验证
IF 3.7 2区 化学
Applied Organometallic Chemistry Pub Date : 2025-08-26 DOI: 10.1002/aoc.70375
Mahmoud Tarek, Gehad E. Said, Abdulrahman A. Almehizia, Mohamed A. Al-Omar, Ahmed M. Naglah, Tamer K. Khatab
{"title":"Novel Ag/Vit B3-MOF: A Proficient and Sustainable Approach, Photocatalytic Activity, and Molecular Docking Validation as HIV Replication Inhibitor","authors":"Mahmoud Tarek,&nbsp;Gehad E. Said,&nbsp;Abdulrahman A. Almehizia,&nbsp;Mohamed A. Al-Omar,&nbsp;Ahmed M. Naglah,&nbsp;Tamer K. Khatab","doi":"10.1002/aoc.70375","DOIUrl":"https://doi.org/10.1002/aoc.70375","url":null,"abstract":"<div>\u0000 \u0000 <p>Ag-Vit B<sub>3</sub>/MOF, or porous silver-based organic framework, was synthesized in this study via a one-step solvothermal process. The produced photocatalyst was thoroughly characterized using a variety of analytical methods, including FT-IR, UV–Vis, XRD, SEM, EDX, TEM, XPS, and BET analysis, in order to assess its crystal structure and shape. Under xenon lamp irradiation, the produced catalyst's photocatalytic activity was tested using alizarine red S dye (ARS), an organic pollutant. Measurements of photocatalytic activity suggest that the photocatalyst may effectively destroy the organic ARS dye. Photocatalysis might degrade 99% of the dye in 90 min. Ag-Vit B<sub>3</sub>/MOF has a bandgap energy of 2.8 eV according to DFT and UV–vis spectrum studies. It has a conduction band (CB) potential of −4.69 eV and a valence band (VB) potential of −1.94 eV. Our findings demonstrate that the Ag-Vit B<sub>3</sub>/MOF photocatalyst is an effective and sustainable photocatalyst for the in situ degradation of ARS dye from industrial wastewater, with the maximum photostability lasting up to five cycles. The Ag-Vit B<sub>3</sub>/MOF complex was attached to the RNA at the HIV frameshift site and evaluated as a potential inhibitor of HIV replication. Compared to reference compounds such as dolutegravir and nevirapine, the Ag/Vit B<sub>3</sub>-MOF exhibited strong binding affinity (E-score greater than − 10 kcal/mol). Additionally, the Ag-MOF showed promising interactions with both reverse transcriptase and integrase enzymes, suggesting its potential as a potent inhibitor of HIV replication.</p>\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 9","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144897657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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