Arefeh Ahadi, Mojtaba Amini, Mahdieh Ghobadifard, Sajjad Mohebbi, Jan Janczak
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A Novel 3D Heteronuclear (Cu(II) and Mg(II)) Coordination Polymer: Synthesis, Crystal Structure, and Catalytic Activity in the Formation of 1,2,3-Triazoles
In the current study, the heteronuclear coordination polymer C12H18Cu2MgO12 was synthesized in crystalline form using the gradual evaporation method and utilized as a precursor for the synthesis of CuO/MgO mixed nano-oxide. The crystal structure and thermal stability of the polymer were confirmed. Following the calcination of the polymer compound at 500°C, CuO/MgO mixed nano-oxide were synthesized. The morphology and structure of the nanopowders were characterized through FE-SEM, EDX, XRD, FT-IR, VSM, XPS, ICP-OES, and TEM techniques. Ultimately, the nanopowders were employed as catalysts in the azide–alkyne cycloaddition reaction. With very low leaching of copper (2.40 ppm) and magnesium ions (0.52 ppm), CuO/MgO nanocatalyst recycling and reuse were achieved for up to five cycles.
期刊介绍：
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
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