Applied Organometallic Chemistry最新文献_第2页

Selective and Rapid Pb (II) Adsorption by Core–Shell Zinc-Glutamate-MOF @Bth-TFPOT-COF: Thermodynamic and Kinetic Insights

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-23 DOI: 10.1002/aoc.70092

Mahmoud Zare-Shahi, Mohsen Dehghani Ghanatghestani, Farid Moeinpour, Hossein Parvaresh

{"title":"Selective and Rapid Pb (II) Adsorption by Core–Shell Zinc-Glutamate-MOF @Bth-TFPOT-COF: Thermodynamic and Kinetic Insights","authors":"Mahmoud Zare-Shahi, Mohsen Dehghani Ghanatghestani, Farid Moeinpour, Hossein Parvaresh","doi":"10.1002/aoc.70092","DOIUrl":"https://doi.org/10.1002/aoc.70092","url":null,"abstract":"<div>\u0000 \u0000 Effectively reclaiming Pb (II) adsorbents is crucial for tackling environmental pollution. Metal–organic framework (MOF) and covalent organic framework (COF) composites, with their multiple functional groups, are anticipated to show outstanding Pb (II) adsorption capabilities. Nevertheless, creating and developing COF and MOF composite adsorbents for highly efficient Pb (II) removal remains a challenge. In this study, we synthesized a core–shell ZnGlu@Bth-TFPOT-COF (referred to as M@C) adsorbent via Schiff base reaction. Adsorbent demonstrated remarkable properties, including excellent durability, specificity, and straightforward solid–liquid separation. Under 298 K and pH 6.0 conditions, M@C effectively adsorbed Pb (II) and achieved 49.40 mg/g adsorption capacity within 15 min. Remarkably, it effectively eliminated Pb (II) from a solution containing multiple ions, demonstrating an adsorption efficiency of 99.80% and a Kd (partition coefficient) of 4.99 × 106 mL/g in the presence of 10 other ions. The adsorption process was controlled by the Freundlich isotherm model, and the pseudo-second-order kinetic model validated that multilayer chemisorption was the mechanism for removing Pb (II). A thermodynamic study showed that the removal process was both spontaneous and exothermic. M@C exhibited outstanding adsorption performance, achieving a capacity of 476.19 mg/g, and demonstrated exceptional selectivity. This makes it an excellent material for the efficient and selective removal of Pb (II).\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143689569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, Biological Evaluation, and Computational Insights of Organyltellurium(IV) Complexes With 5-Substituted Furan Ligand 含 5-取代呋喃配体的有机烷基碲（IV）配合物的合成、生物学评价和计算见解

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-20 DOI: 10.1002/aoc.70128

Nidhi Antil, Mahak Dalal, Binesh Kumar, Jai Devi, Anjaneyulu Bendi, Sapana Garg

{"title":"Synthesis, Biological Evaluation, and Computational Insights of Organyltellurium(IV) Complexes With 5-Substituted Furan Ligand","authors":"Nidhi Antil, Mahak Dalal, Binesh Kumar, Jai Devi, Anjaneyulu Bendi, Sapana Garg","doi":"10.1002/aoc.70128","DOIUrl":"https://doi.org/10.1002/aoc.70128","url":null,"abstract":"<div>\u0000 \u0000 Organyltellurium(IV) complexes have attracted significant attention due to their structural versatility and promising biological applications. In this study, a series of novel organyltellurium(IV) complexes with 5-substituted furan-based ligands were designed, synthesized, and evaluated for their antioxidant, antimicrobial, and anti-inflammatory properties. The synthesized compounds were characterized by ultraviolet–visible (UV–Vis), FT-IR, 1H-NMR, 13C-NMR, mass spectrometry, molar conductance, elemental analysis, powder X-ray diffraction and thermal analyses which states that the bidentate Schiff base ligand (MeF4AP) coordinated via oxygen and nitrogen atom with tellurium giving hexa-coordinated tellurium(IV) complexes. In silico studies, including molecular docking, density functional theory (DFT) calculations, MESP and ADME profiling provided insights into their stability, electronic properties, and pharmacokinetic potential. The DPPH and BSA assays revealed that complexes 3c (IC₅₀ = 4.95 ± 0.02 μM), 3b (IC₅₀ = 7.12 ± 0.07 μM and 3f (IC₅₀ = 4.14 ± 0.11 μM) exhibited the highest antioxidant and anti-inflammatory activity compared to the ligand. Notably, complex 3b exhibited MIC of 0.20 mg/mL against Candida albicans nearly twice as potent as the standard drug griseofulvin (MIC = 0.50 mg/mL). The FMO studies supports the more bioactivity of complexes as compared to Schiff base. MESP of the compounds displayed their most reactive regions. The strong correlation between computational predictions and in vitro results highlights the potential of these organyltellurium(IV) complexes as multifunctional therapeutic candidates and pave the way for further exploration of their biomedical applications.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143689423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparative Study of Conventional and Ultrasonic-Assisted Synthesis of Co(II)- and Cu(II)-Based MOFs for CO2 Adsorption

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-18 DOI: 10.1002/aoc.70083

Mohammad Reza Ahmadi, Effat Jamalizadeh, S. Yousef Ebrahimipour, Ghasem Sargazi

引用次数: 0

Study of Alternative Current Conduction Mechanisms on the α-LiFeO2-Based Cathode Materials

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-17 DOI: 10.1002/aoc.70088

Abdulaziz Abdulmohsen Alnafea, Narimen Chakchouk, Hala Siddiq, Saleh M. Altarifi, Mohamed Houcine Dhaou, Abdallah Ben Rhaiem

{"title":"Study of Alternative Current Conduction Mechanisms on the α-LiFeO2-Based Cathode Materials","authors":"Abdulaziz Abdulmohsen Alnafea, Narimen Chakchouk, Hala Siddiq, Saleh M. Altarifi, Mohamed Houcine Dhaou, Abdallah Ben Rhaiem","doi":"10.1002/aoc.70088","DOIUrl":"https://doi.org/10.1002/aoc.70088","url":null,"abstract":"<div>\u0000 \u0000 An improved solid-state synthesis method was used to create LiFeO2 layered oxides. The produced material adopts a cubic system (Fm-3m space group) with a refined cell parameter of a = 4.156(9) Å, as indicated by Rietveld refinement of the crystal structure. A morphological investigation revealed that the sample is composed of small primary particles with sizes ranging from 0.20 to 0.75 μm. IR spectroscopy vibrational analysis revealed the presence of FeO6 and LiO6 groups. The compound's semiconductor nature was confirmed when the band gap energy was generated and discovered to be 2 eV. There is a tighter dispersion of localized states within the band gap, as indicated by the obtained Urbach energy (0.39 eV), which presents just 20% from the band gap energy. The material's dielectric characteristics were assessed between 0.1 and 107 Hz in frequency and between 333 K and 523 K in temperature. The presence of both space charge and dipolar polarization is suggested by the real component of the dielectric permittivity, which indicates a high dielectric constant (between 100 and 350) at low frequency. The circuits are made up of constant phase elements (CPE) and bulk resistance R coupled in parallel. Jonscher's law was applied to interpret the frequency-dependent conductivity. The outcomes of the charge transport investigation on LiFeO2 imply that the layered oxide material possessed a large polaron tunneling (OLPT) paradigm with activation energy Ea of 0.26 eV. Comparing the polaron Rω (2 < Rω < 5 Å) optimal hopping length to the Li–O interatomic gap (2.077(9) Å), it is larger. We identified and examined a correlation between the ionic conductivity and the crystal structure.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, Characterization, and Application of MOF/COF Hybrid Composite as a Highly Active and Recyclable Catalyst for Multicomponent Synthesis of Chromeno[4,3-b]quinoline-6-ones

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-16 DOI: 10.1002/aoc.70039

Parvin Sanati-Tirgan, Hossein Eshghi

{"title":"Synthesis, Characterization, and Application of MOF/COF Hybrid Composite as a Highly Active and Recyclable Catalyst for Multicomponent Synthesis of Chromeno[4,3-b]quinoline-6-ones","authors":"Parvin Sanati-Tirgan, Hossein Eshghi","doi":"10.1002/aoc.70039","DOIUrl":"https://doi.org/10.1002/aoc.70039","url":null,"abstract":"<div>\u0000 \u0000 The conjugation of metal–organic frameworks (MOFs) with covalent organic frameworks (COF), as a catalytically active nanocomposite with integrated properties, is a smart strategy for developing efficient catalytic systems. Herein, we report the design and synthesis of NH2-Glu-MOF/MT-COF nanocomposite using the integration of glutamate MOF (NH2-Glu-MOF) and melamine-terephthaldehyde COF (MT-COF) via imine bond connection. The synthesized NH2-Glu-MOF/MT-COF nanocomposite has been fully characterized using FT-IR, XRD, BET, TEM, FE-SEM, EDX, EDX mapping, TGA, and ICP-OES techniques. Analyses demonstrate that NH2-Glu-MOF/MT-COF nanocomposite has ideal structural and compositional properties such as good specific surface area (241.631 m2 g−1), high pore volume, and high thermal stability (530°C). Because of such unbeatable structural and compositional features, NH2-Glu-MOF/MT-COF nanocomposite shows much better catalytic activity for the synthesis of a wide library chromeno[4,3-b]quinoline-6-one derivatives than parent materials (NH2-Glu-MOF or MT-COF). Additionally, NH2-Glu-MOF/MT-COF nanocomposite demonstrated supreme recyclability during five catalytic cycles.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of a New Bis-4-Cumyl Phenoxy Phthalocyaninato Silicon (IV) and Its Evaluation on Selectivity for Iron (III) Ions 一种新的双-4-异丙基苯氧基酞菁硅 (IV) 的合成及其对铁 (III) 离子选择性的评估

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-16 DOI: 10.1002/aoc.70120

Mehmet Salih Ağırtaş, Derya Güngördü Solğun

{"title":"Synthesis of a New Bis-4-Cumyl Phenoxy Phthalocyaninato Silicon (IV) and Its Evaluation on Selectivity for Iron (III) Ions","authors":"Mehmet Salih Ağırtaş, Derya Güngördü Solğun","doi":"10.1002/aoc.70120","DOIUrl":"https://doi.org/10.1002/aoc.70120","url":null,"abstract":"<div>\u0000 \u0000 Axial phthalocyanine compound carrying 4-cumyl phenoxy groups was obtained from the reaction of 4-cumyl phenol with silicon phthalocyanine dichloride (SiPcCl2). The compound was characterized by 1H NMR, UV–visible light, FTIR, and mass spectrum. Electronic properties and photochemical properties of the compound were investigated by UV–visible light spectra. Singlet oxygen production capacity for the compound was investigated, and the singlet oxygen production (Φ∆) value was found to be 0.14. The sensor potential of the compound was investigated by UV–visible light spectra against magnesium (II) ions (Mg2+), manganese (II) ions (Mn2+), sodium (I) ions (Na+), nickel (II) ions (Ni2+), zinc (II) ions (Zn2+), silver (I) ions (Ag+), barium (II) ions (Ba2+), cadmium (II) ions (Cd2+), copper (II) ions (Cu2+), cobalt (II) ions (Co2+), and iron (III) ions (Fe3+). The selective sensitivity of the phthalocyanine compound only to Fe3+ ions enables the practical analysis of Fe3+ ions in many environments. This study presents an alternative and practically applicable method for the sensitive determination of Fe3+ ions, which have widespread adverse effects on the environment, ecosystem and human health.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation, Chemical Characterization, and Determination of the Cytotoxicity and Anti-Thyroid Cancer Properties of Pomegranate Aqueous Extract Green-Synthesized Silver Nanoparticles Following the STAT3 and p53 Signaling Pathways

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-16 DOI: 10.1002/aoc.70112

Mengxuan Mao, Zhanbin Cui, Xiaofei Wei, Tengfei Liu, Mingqiang Han

{"title":"Preparation, Chemical Characterization, and Determination of the Cytotoxicity and Anti-Thyroid Cancer Properties of Pomegranate Aqueous Extract Green-Synthesized Silver Nanoparticles Following the STAT3 and p53 Signaling Pathways","authors":"Mengxuan Mao, Zhanbin Cui, Xiaofei Wei, Tengfei Liu, Mingqiang Han","doi":"10.1002/aoc.70112","DOIUrl":"https://doi.org/10.1002/aoc.70112","url":null,"abstract":"<div>\u0000 \u0000 The biogenic silver nanoparticles manufactured using pomegranate as a supporting material are described in this study. The plant's leaves effectively stabilized the produced silver nanoparticles (Ag NPs) and acted as a natural reducing agent. The physicochemical characteristics of the prepared NPs were examined using TEM, EDX, FE-SEM, and UV–Vis methods. According to the study's data, the antioxidant properties of nanoparticles may be related to how well they treat thyroid cancer in humans. The capacity of biologically produced nanoparticles to prevent thyroid cancer cells was assessed. As determined by the MTT assay, the silver nanoparticles had strong anti-thyroid cancer characteristics, effectively eliminating the BCPAP cancer cell in a way that depended on both concentration and time. Ag NPs decrease the anti-apoptotic marker Bcl-2 level while promoting cell death, which is associated with increased levels of pro-apoptotic indicators such as cleaved caspase-8 and Bax. Additionally, compared to the corresponding control group, silver nanoparticles show a reduction in colony development. The data of Ag NPs showed that p53 expression was much higher, and that the examined cell lines had lower levels of signal transducer and activator of transcription 3 (STAT3). This implies that the pomegranate extract-induced biological reactions in BCPAP human thyroid cancer cells depend critically on STAT3 and p53.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Triphenylamine-Based Dual Chemosensor for Cu2+ and Co2+ Ions and Volatile Acid Vapour Sensor, DFT Calculations 基于三苯胺的 Cu2+ 和 Co2+ 离子双重化学传感器和挥发性酸蒸汽传感器，DFT 计算

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-16 DOI: 10.1002/aoc.70105

Aravind R. Nesaragi, Jyoti Nagalik, Mounesh, Sharanakumar T. M., Halligudra Guddappa, Tahani Mazyad Almutairi, Sanjeev R. Inamdar, Anup Pandith

{"title":"Triphenylamine-Based Dual Chemosensor for Cu2+ and Co2+ Ions and Volatile Acid Vapour Sensor, DFT Calculations","authors":"Aravind R. Nesaragi, Jyoti Nagalik,  Mounesh, Sharanakumar T. M., Halligudra Guddappa, Tahani Mazyad Almutairi, Sanjeev R. Inamdar, Anup Pandith","doi":"10.1002/aoc.70105","DOIUrl":"https://doi.org/10.1002/aoc.70105","url":null,"abstract":"<div>\u0000 \u0000 In this work, a novel fluorescent chemosensor 3-(2-(2-(4-(diphenylamino)phenyl)-4,5-diphenyl-1H-imidazol-1-yl)thiazol-4-yl)-2H-chromen-2-one (TCCM) was effectively synthesized and characterized through NMR and Mass spectrum. An approach towards the recognition of Cu2+ and Co2+ ions using a turn-off fluorescence technique was developed. The chemosensor TCCM also exhibited colorimetric and fluorometric sensing behaviour with a visible colorimetric response to trifluoroacetic acid (TFA). Upon the addition of TFA to TCCM, a new peak formation at 500 nm in the absorption spectra along with the visible colour change from colourless to brown. In addition, it exhibits high selectivity towards Cu2+ and Co2+ ions with a limit of detection of 4.2 and 3.9 μM, respectively. It was discovered that the sensor was quite selective for Cu2+ and Co2+ ions that had a lot of competing ions. Further, the studies were supported by DFT analysis and NBO studies.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comprehensive Exploration of Water-Soluble Schiff Base Complexes of Ni (II), Cu (II), Mn (II), and Ce (III): Electrochemical, Computational, and Biological Studies

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-16 DOI: 10.1002/aoc.70122

Eida S. Al-Farraj, Mahdi A. Mohammed

{"title":"Comprehensive Exploration of Water-Soluble Schiff Base Complexes of Ni (II), Cu (II), Mn (II), and Ce (III): Electrochemical, Computational, and Biological Studies","authors":"Eida S. Al-Farraj, Mahdi A. Mohammed","doi":"10.1002/aoc.70122","DOIUrl":"https://doi.org/10.1002/aoc.70122","url":null,"abstract":"<div>\u0000 \u0000 Novel water-soluble Ni(II), Cu(II), Mn(II), and Ce(III) complexes of sodium 4-hydroxy-3-((2-picolinoylhydrazineylidene)methyl)benzenesulfonate ligand (NaH2PH) were synthesized and characterized by the different analytical methods and spectroscopic techniques as well as magnetic measurements. The chemical structures of the studied chelates were supported by computational studies using DFT calculation. The ligand acts as a mono-negative tridentate (ONN) ligand in the copper (II) complex by (C=N)py, (C=N)az, and the deprotonated enolic oxygen atom (C-O). In [Mn2(NaPH)Cl2(H2O)2] complex, NaH2PH ligand acts as a bi-negative tetradentate (ONNO) ligand via deprotonated (OH)phenolic and (C=N*) groups around the first Mn (II), the (HO)enolic, and (C=N)az groups coordinated to another Mn(II). As a mono-negative bidentate (ON) ligand, the NaH2PH ligand functions in the [Ni(NaHPH)Cl(H2O)]·3H2O complex. The ligand functions as a bi-negative tetradentate (ONNO) ligand in the [Ce(NaPH)Cl(H2O)]·3H2O complex. The isotropic shape of the ESR spectrum of [Cu(NaHPH)(H2O)2Cl].H2O complex confirmed the octahedral geometry around the copper(II) ion. The voltammogram of the Cu(II) and Mn(II) ions exhibited two oxidation and two reduction waves. The antiradical potencies discovered have good radical scavenging activities against ABTS and DPPH radicals. Antimicrobial activities of the isolated complexes have been assessed against selected microorganism. According to the molecular docking studies, the Mn(II) complex shows higher interaction against MCF-7 (PDB ID: 3W2S), which has a good agreement with experimental data.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Adsorptive Removal of Congo Red Dye From Aqueous Media Using Composite of Graphitic Carbon Nitride Nanosheet and the Biopolymer Alginate

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2025-03-16 DOI: 10.1002/aoc.70059

Mohammad Ali Shirani, Mohammad Dinari, Mohammad Hassan Maleki, Monir Fouladi

{"title":"Adsorptive Removal of Congo Red Dye From Aqueous Media Using Composite of Graphitic Carbon Nitride Nanosheet and the Biopolymer Alginate","authors":"Mohammad Ali Shirani, Mohammad Dinari, Mohammad Hassan Maleki, Monir Fouladi","doi":"10.1002/aoc.70059","DOIUrl":"https://doi.org/10.1002/aoc.70059","url":null,"abstract":"<div>\u0000 \u0000 The removal of dyes from wastewater using stable adsorbents is well documented in numerous scientific reports. Therefore, this study aimed to evaluate a composite of graphitic carbon nitride nanosheet (g-C3N4NS) and the biopolymer alginate for the removal of Congo red (CR) dye from aqueous media. To address the challenges associated with the independent use of calcium alginate and g-C3N4NS in water, particularly regarding recovery issues, silica-coated magnetic nanoparticles (SMNPs) were incorporated into the composite. To achieve this objective, an alginate-based bioadsorbent was synthesized by crosslinking sodium alginate with calcium chloride in the presence of g-C3N4NS and SMNPs using an in situ method. Structural characterization was conducted using BET, TGA, TEM, FE-SEM, and EDX-Mapping analyses. Subsequently, the bioadsorbent was utilized to remove CR dye. The influence of various parameters, including initial concentration, contact time, adsorbent dosage, and pH, was subsequently investigated. According to the isotherm models, the linear Langmuir model exhibited a good fit to the experimental data for CR, indicating a maximum adsorption capacity of 68.03 mg g−1 at pH 5 within 120 min. The synthesized composite has the potential to pave the way for novel applications in both organic and inorganic transformations, as well as in the physical or chemical remediation of diverse pollutants.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0