Applied Organometallic Chemistry最新文献_第2页

Engineering Zr-Metal Organic Framework-Based Binary Composite Using Facile In Situ Strategy for Photocatalytic Degradation of Multiple Dyes: Synergistic Effect and Mechanistic Insight 基于工程zr -金属有机框架的二元复合材料光催化降解多种染料：协同效应和机理研究

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-17 DOI: 10.1002/aoc.70556

Pranjit Borah, Md. Ahmaruzzaman

{"title":"Engineering Zr-Metal Organic Framework-Based Binary Composite Using Facile In Situ Strategy for Photocatalytic Degradation of Multiple Dyes: Synergistic Effect and Mechanistic Insight","authors":"Pranjit Borah, Md. Ahmaruzzaman","doi":"10.1002/aoc.70556","DOIUrl":"https://doi.org/10.1002/aoc.70556","url":null,"abstract":"<div>\u0000 \u0000 Although metal–organic frameworks (MOFs) have promising photocatalytic properties such as high surface area and customisable pore architectures, their practical applicability is frequently hampered by the rapid recombination of photogenerated charge carriers, which reduces degradation efficiency. To overcome this constraint, several approaches to integrating MOFs with light-responsive semiconductors have been investigated. This study used a Zr-based MOF with ZnCo2O4 to create a highly effective photocatalyst. The goal was to improve charge separation and photocatalytic performance. The resultant composite demonstrated exceptional degradation efficiencies of 82.27% for Bismarck Brown (BB) and 94.24% forRose Bengal (RB) under natural sunlight within 55 min, with optimal catalyst doses of 0.47 g/L. The composite's structural, morphological and optical properties were fully investigated utilising SEM–EDX, HRTEM, PXRD, FTIR, XPS, BET and UV-DRS techniques. The photodegradation process followed first-order kinetics, with rate constants of 0.0371 min−1 and 0.06544 min−1 for BB and RB, respectively. Photoluminescence (PL) spectroscopy, VB-XPS and scavenger quenching investigations provided mechanistic insights into successful charge separation and reactive species formation. The ZnCo2O4@UiO-66 composite is highly recyclable, with consistent XRD patterns confirming stable photocatalytic efficacy across five cycles. These findings emphasise the composite's potential as a strong and reusable MOF-based photocatalyst for efficiently removing dye contaminants in environmental remediation applications.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147566719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Two-Dimensional Coordination Polymers as Efficient Photoanodes Toward Solar-Driven Water Oxidation 二维配位聚合物作为太阳能驱动水氧化的高效光阳极

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-17 DOI: 10.1002/aoc.70558

Ting-Ting Wu, Bo-Bo Han, Yu-Jie Xie, Wen-Duo Zhu, Rui-Zi Xue, Sheng-Rui Zhang, Jiu-Fu Lu, Bo Liu

{"title":"Two-Dimensional Coordination Polymers as Efficient Photoanodes Toward Solar-Driven Water Oxidation","authors":"Ting-Ting Wu, Bo-Bo Han, Yu-Jie Xie, Wen-Duo Zhu, Rui-Zi Xue, Sheng-Rui Zhang, Jiu-Fu Lu, Bo Liu","doi":"10.1002/aoc.70558","DOIUrl":"https://doi.org/10.1002/aoc.70558","url":null,"abstract":"<div>\u0000 \u0000 Amid growing global energy demands and environmental concerns, hydrogen energy has emerged as a promising clean alternative. This study focuses on the development of efficient photoelectrocatalytic materials for the oxygen evolution reaction (OER). Three novel two-dimensional coordination polymers—SNUT-9-Cd, SNUT-9-Cd+Co, and SNUT-9-Co—were solvothermally synthesized using a tricarboxylic pyridazine-based ligand, H3(5-CMOIA). Thermogravimetric analysis (TGA) confirmed their high thermal stability, with SNUT-9-Co maintaining structural integrity up to 300°C. Mott–Schottky analysis confirmed the n-type semiconductor behavior of all three compounds. SNUT-9-Co stood out with its superior OER performance under simulated solar irradiation, displaying a low overpotential of 261 mV at 0.3 mA·cm−2, rapid charge transfer, and excellent stability, thereby highlighting its promise as a photoanode for solar-driven water splitting.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147566721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nickel(II) Complexes of Pentadentate Pyridylalkylamines as Bifunctional Electrocatalysts for Hydrogen Evolution and Water Oxidation 五齿酸吡啶烷基胺配合物镍（II）作为析氢和水氧化双功能电催化剂

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-16 DOI: 10.1002/aoc.70557

Xiao-Qing Sun, Hua-Xin Zhang, Jie Yu, Chao-Ran Zhang, Tai-Yang Guo, Fang-Bing Pang, Tian-Shun Wang

{"title":"Nickel(II) Complexes of Pentadentate Pyridylalkylamines as Bifunctional Electrocatalysts for Hydrogen Evolution and Water Oxidation","authors":"Xiao-Qing Sun, Hua-Xin Zhang, Jie Yu, Chao-Ran Zhang, Tai-Yang Guo, Fang-Bing Pang, Tian-Shun Wang","doi":"10.1002/aoc.70557","DOIUrl":"https://doi.org/10.1002/aoc.70557","url":null,"abstract":"<div>\u0000 \u0000 The development of catalysts based on nonnoble transition metals for hydrogen evolution reaction (HER) and water oxidation reaction (WOR) is conducive to the exploitation of sustainable green energy resources. Herein, two nickel(II) complexes of pentadentate pyridylalkylamines with the different alkyl chain lengths, namely, [Ni(tpmen)(CH3CN)](ClO4)2 (Ni-tpmen, tpmen = N,N,N′-tris(2-pyridylmethyl)-N′-methylethylenediamine) and [Ni(tpmpn)(CH3OH)](ClO4)2 (Ni-tpmpn, tpmpn = N,N,N′-tris(2-pyridylmethyl)-N′-methylpropane-1,3-diamine), were prepared and characterized. The electrochemical behaviors and the catalytic activities of two nickel(II) complexes for both HER and WOR were studied. The overpotentials of HER catalyzed by Ni-tpmen and Ni-tpmpn in CH3CN in the presence of AcOH were 587 and 500 mV, respectively, and the rate constants were 119.5 and 333.8 s−1, respectively. Meanwhile, Ni-tpmen and Ni-tpmpn displayed a catalytic activity for WOR in pH 8.0 0.1 M phosphate buffer solution with rate constants of 0.375 and 0.17 s−1, respectively, and the Faradaic efficiencies were 84% and 98%, respectively. Ni-tpmpn with a longer alkyl chain exhibited a better catalytic activity for HER than Ni-tpmen. In contrast, Ni-tpmen showed a better catalytic activity for WOR in terms of the overpotential and catalytic rate. This work showed that pyridylalkylamine metal complexes were promising candidates for bifunctional catalysts and that their catalytic performances were affected by the length of the alkyl chains in pyridylalkylamines.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147566478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nickel(II) Complexes of Pentadentate Pyridylalkylamines as Bifunctional Electrocatalysts for Hydrogen Evolution and Water Oxidation 五齿酸吡啶烷基胺配合物镍（II）作为析氢和水氧化双功能电催化剂

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-16 DOI: 10.1002/aoc.70557

Xiao-Qing Sun, Hua-Xin Zhang, Jie Yu, Chao-Ran Zhang, Tai-Yang Guo, Fang-Bing Pang, Tian-Shun Wang

{"title":"Nickel(II) Complexes of Pentadentate Pyridylalkylamines as Bifunctional Electrocatalysts for Hydrogen Evolution and Water Oxidation","authors":"Xiao-Qing Sun, Hua-Xin Zhang, Jie Yu, Chao-Ran Zhang, Tai-Yang Guo, Fang-Bing Pang, Tian-Shun Wang","doi":"10.1002/aoc.70557","DOIUrl":"https://doi.org/10.1002/aoc.70557","url":null,"abstract":"<div>\u0000 \u0000 The development of catalysts based on nonnoble transition metals for hydrogen evolution reaction (HER) and water oxidation reaction (WOR) is conducive to the exploitation of sustainable green energy resources. Herein, two nickel(II) complexes of pentadentate pyridylalkylamines with the different alkyl chain lengths, namely, [Ni(tpmen)(CH3CN)](ClO4)2 (Ni-tpmen, tpmen = N,N,N′-tris(2-pyridylmethyl)-N′-methylethylenediamine) and [Ni(tpmpn)(CH3OH)](ClO4)2 (Ni-tpmpn, tpmpn = N,N,N′-tris(2-pyridylmethyl)-N′-methylpropane-1,3-diamine), were prepared and characterized. The electrochemical behaviors and the catalytic activities of two nickel(II) complexes for both HER and WOR were studied. The overpotentials of HER catalyzed by Ni-tpmen and Ni-tpmpn in CH3CN in the presence of AcOH were 587 and 500 mV, respectively, and the rate constants were 119.5 and 333.8 s−1, respectively. Meanwhile, Ni-tpmen and Ni-tpmpn displayed a catalytic activity for WOR in pH 8.0 0.1 M phosphate buffer solution with rate constants of 0.375 and 0.17 s−1, respectively, and the Faradaic efficiencies were 84% and 98%, respectively. Ni-tpmpn with a longer alkyl chain exhibited a better catalytic activity for HER than Ni-tpmen. In contrast, Ni-tpmen showed a better catalytic activity for WOR in terms of the overpotential and catalytic rate. This work showed that pyridylalkylamine metal complexes were promising candidates for bifunctional catalysts and that their catalytic performances were affected by the length of the alkyl chains in pyridylalkylamines.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147566479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Indole- or Carbazole-Tethered β-Sulfonyl Fluorides Using Ethenesulfonyl Fluoride via Rh(III)-Catalyzed C–H Activation 乙烯磺酰氟经Rh（III）催化C-H活化合成吲哚或咔唑系结β-磺酰氟

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-14 DOI: 10.1002/aoc.70562

Hongwei Ren, Yiran Niu, Xiaomei Sun, Shuo Wen, Fangfei Xu, Xiangxiang Jiang, Maozhong Miao, Jinzhong Yao, Hongwei Zhou

引用次数: 0

Metalation Sequence Modulates CO2-To-Cyclic Carbonate Conversion With Porphyrin–Polyurea Covalent Organic Polymer Catalysts 金属化序列在卟啉-聚脲共价有机聚合物催化剂上调控二氧化碳到环碳酸盐的转化

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-14 DOI: 10.1002/aoc.70554

Wei Zhang, Ziheng Wen, Yu Tang, Yinying Jin, Linjun Shao, Xu Jiang, Faliang Gou

{"title":"Metalation Sequence Modulates CO2-To-Cyclic Carbonate Conversion With Porphyrin–Polyurea Covalent Organic Polymer Catalysts","authors":"Wei Zhang, Ziheng Wen, Yu Tang, Yinying Jin, Linjun Shao, Xu Jiang, Faliang Gou","doi":"10.1002/aoc.70554","DOIUrl":"https://doi.org/10.1002/aoc.70554","url":null,"abstract":"<div>\u0000 \u0000 A novel series of porphyrin–polyurea covalent organic polymers (COPs) was designed for CO2–epoxide cycloaddition to systematically investigate the influence of metalation sequence on structural ordering and catalytic behavior. Two cobalt–porphyrin-based COPs, PUa-CoDPP and PUa-DPPCo, were synthesized through pre-metalation and post-metalation strategies employing amine-isocyanate polycondensation and solution-phase metal coordination, respectively. Comprehensive characterization revealed that the pre-metalated system maintains high crystallinity, hierarchical porosity, and homogeneous dispersion of Co–N4 sites via controlled monomer assembly, whereas the post-metalated counterpart exhibits structural degradation and heterogeneous active sites due to coordination constraints within the preformed framework. In the solvent-free cycloaddition of CO2 and propylene oxide, PUa-CoDPP achieves a near-quantitative yield (> 99%) and exhibits superior recyclability, substantially outperforming PUa-DPPCo. This performance disparity is mechanistically attributed to three sequence-dependent factors: coordination completeness of active sites, framework-regulated metal accessibility, and pore architecture-mediated substrate diffusion. This study establishes the metalation sequence as a decisive design parameter for engineering high-performance metalloporphyrin polymers that reconcile catalytic efficiency with operational durability.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147565939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Copper-Bonded Polyoxovanadates-Based Hybrids as Efficient Catalysts for Azide−Alkyne Cycloaddition 铜键合多钒氧杂化物作为叠氮化物-炔环加成的高效催化剂

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-14 DOI: 10.1002/aoc.70559

Xiuyan Jiang, Yuekun Zhang, Chunxiao Zhang, Xinwang Song, Congcong Wang, Pengtu Zhang, Qiu Zhang

{"title":"Copper-Bonded Polyoxovanadates-Based Hybrids as Efficient Catalysts for Azide−Alkyne Cycloaddition","authors":"Xiuyan Jiang, Yuekun Zhang, Chunxiao Zhang, Xinwang Song, Congcong Wang, Pengtu Zhang, Qiu Zhang","doi":"10.1002/aoc.70559","DOIUrl":"https://doi.org/10.1002/aoc.70559","url":null,"abstract":"<div>\u0000 \u0000 Constructing structurally well-defined copper-based polyoxovanadates (POVs) catalysts for azide–alkyne cycloaddition is an attractive yet challenging research objective. Herein, three copper-based POVs hybrids, formulated, respectively, as [Cu(dpa)][V2O6] (1), [Cu(bipy)][V2O6] (2), [Cu(phen)(H2O)][V2O6] (3) (dpa = 2,2′-dipyridylamide, bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline) were successfully synthesized and fully characterized. Importantly, the three hybrids showed high efficiency for the azide–alkyne cycloaddition under mild conditions, and the yields were up to 99% because they integrate the catalytic ability of Cu sites with the multielectron-transfer ability of POVs. Moreover, the reusability of 3 was further investigated, and no significant decrease in catalytic activity was observed. These results indicate a sustainable molecular-level strategy to expand the application of POVs in the azide–alkyne cycloaddition for constructing triazole derivatives.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147565904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metalation Sequence Modulates CO2-To-Cyclic Carbonate Conversion With Porphyrin–Polyurea Covalent Organic Polymer Catalysts 金属化序列在卟啉-聚脲共价有机聚合物催化剂上调控二氧化碳到环碳酸盐的转化

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-14 DOI: 10.1002/aoc.70554

Wei Zhang, Ziheng Wen, Yu Tang, Yinying Jin, Linjun Shao, Xu Jiang, Faliang Gou

{"title":"Metalation Sequence Modulates CO2-To-Cyclic Carbonate Conversion With Porphyrin–Polyurea Covalent Organic Polymer Catalysts","authors":"Wei Zhang, Ziheng Wen, Yu Tang, Yinying Jin, Linjun Shao, Xu Jiang, Faliang Gou","doi":"10.1002/aoc.70554","DOIUrl":"https://doi.org/10.1002/aoc.70554","url":null,"abstract":"<div>\u0000 \u0000 A novel series of porphyrin–polyurea covalent organic polymers (COPs) was designed for CO2–epoxide cycloaddition to systematically investigate the influence of metalation sequence on structural ordering and catalytic behavior. Two cobalt–porphyrin-based COPs, PUa-CoDPP and PUa-DPPCo, were synthesized through pre-metalation and post-metalation strategies employing amine-isocyanate polycondensation and solution-phase metal coordination, respectively. Comprehensive characterization revealed that the pre-metalated system maintains high crystallinity, hierarchical porosity, and homogeneous dispersion of Co–N4 sites via controlled monomer assembly, whereas the post-metalated counterpart exhibits structural degradation and heterogeneous active sites due to coordination constraints within the preformed framework. In the solvent-free cycloaddition of CO2 and propylene oxide, PUa-CoDPP achieves a near-quantitative yield (> 99%) and exhibits superior recyclability, substantially outperforming PUa-DPPCo. This performance disparity is mechanistically attributed to three sequence-dependent factors: coordination completeness of active sites, framework-regulated metal accessibility, and pore architecture-mediated substrate diffusion. This study establishes the metalation sequence as a decisive design parameter for engineering high-performance metalloporphyrin polymers that reconcile catalytic efficiency with operational durability.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147565942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Indole- or Carbazole-Tethered β-Sulfonyl Fluorides Using Ethenesulfonyl Fluoride via Rh(III)-Catalyzed C–H Activation 乙烯磺酰氟经Rh（III）催化C-H活化合成吲哚或咔唑系结β-磺酰氟

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-14 DOI: 10.1002/aoc.70562

Hongwei Ren, Yiran Niu, Xiaomei Sun, Shuo Wen, Fangfei Xu, Xiangxiang Jiang, Maozhong Miao, Jinzhong Yao, Hongwei Zhou

引用次数: 0

Copper-Bonded Polyoxovanadates-Based Hybrids as Efficient Catalysts for Azide−Alkyne Cycloaddition 铜键合多钒氧杂化物作为叠氮化物-炔环加成的高效催化剂

IF 3.7 2区化学

Applied Organometallic Chemistry Pub Date : 2026-03-14 DOI: 10.1002/aoc.70559

Xiuyan Jiang, Yuekun Zhang, Chunxiao Zhang, Xinwang Song, Congcong Wang, Pengtu Zhang, Qiu Zhang

{"title":"Copper-Bonded Polyoxovanadates-Based Hybrids as Efficient Catalysts for Azide−Alkyne Cycloaddition","authors":"Xiuyan Jiang, Yuekun Zhang, Chunxiao Zhang, Xinwang Song, Congcong Wang, Pengtu Zhang, Qiu Zhang","doi":"10.1002/aoc.70559","DOIUrl":"https://doi.org/10.1002/aoc.70559","url":null,"abstract":"<div>\u0000 \u0000 Constructing structurally well-defined copper-based polyoxovanadates (POVs) catalysts for azide–alkyne cycloaddition is an attractive yet challenging research objective. Herein, three copper-based POVs hybrids, formulated, respectively, as [Cu(dpa)][V2O6] (1), [Cu(bipy)][V2O6] (2), [Cu(phen)(H2O)][V2O6] (3) (dpa = 2,2′-dipyridylamide, bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline) were successfully synthesized and fully characterized. Importantly, the three hybrids showed high efficiency for the azide–alkyne cycloaddition under mild conditions, and the yields were up to 99% because they integrate the catalytic ability of Cu sites with the multielectron-transfer ability of POVs. Moreover, the reusability of 3 was further investigated, and no significant decrease in catalytic activity was observed. These results indicate a sustainable molecular-level strategy to expand the application of POVs in the azide–alkyne cycloaddition for constructing triazole derivatives.\u0000 </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"40 4","pages":""},"PeriodicalIF":3.7,"publicationDate":"2026-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147565941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0