Siqi Li, Xiao Liang, Pengfei Shao, Songlin Chen, Zhenhua Li, Xujun Su, Tao Tao, Zili Xie, M. Ajmal Khan, Li Wang, T. T. Lin, Hideki Hirayama, Bin Liu, Dunjun Chen, Ke Wang, Rong Zhang
{"title":"Monolayer-scale AlN/GaN digital alloys grown by plasma-assisted molecular beam epitaxy","authors":"Siqi Li, Xiao Liang, Pengfei Shao, Songlin Chen, Zhenhua Li, Xujun Su, Tao Tao, Zili Xie, M. Ajmal Khan, Li Wang, T. T. Lin, Hideki Hirayama, Bin Liu, Dunjun Chen, Ke Wang, Rong Zhang","doi":"10.1063/5.0215886","DOIUrl":"https://doi.org/10.1063/5.0215886","url":null,"abstract":"The efficiency of usual AlGaN based deep ultraviolet light-emitting devices is still quite low. The difficulties are basically originated from the fundamental material properties of AlGaN. This work has adopted monolayer-scale (AlN)m/(GaN)n ordered digital alloys (DAs) as alternatives to AlGaN random alloys, m and n are the numbers of monolayers. X-ray diffraction scans have demonstrated clear satellite peaks, verifying good periodicity of AlN/GaN DAs grown by molecular beam epitaxy (MBE), and transmission electron microscopy results have revealed atomically sharp and smooth interfaces and quite precise m:n values agreeing well with designs. The electron densities of Si-doped (AlN)m/(GaN)n DAs with high equivalent Al compositions are significantly higher than those of conventional AlGaN:Si random alloys grown in the same MBE system. Si dopant ionization energies in DAs are only 2–5 meV, much lower than that for usual random alloys. The red shift of the light emission for DAs with thinner AlN barriers has suggested strong coupling between the GaN wells and thus formation of a miniband in a vertical direction. The results have demonstrated the potential of the (AlN)m/(GaN)n DAs as electronically functional alternatives for various device applications.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lin Li, Xiaohu Wu, Haotuo Liu, Zhimin Yang, Kun Yu
{"title":"Enhanced and tunable near-field thermophotovoltaics driven by hybrid polaritons","authors":"Lin Li, Xiaohu Wu, Haotuo Liu, Zhimin Yang, Kun Yu","doi":"10.1063/5.0220172","DOIUrl":"https://doi.org/10.1063/5.0220172","url":null,"abstract":"Near-field thermophotovoltaics (NF-TPV) offers the potential for achieving elevated power density and conversion efficiency by leveraging the amplification of thermal radiation within a nanoscale gap. Here, we propose an NF-TPV device with a sandwich emitter composed of calcite film and graphene layer. The results show that this sandwich configuration can significantly enhance output power, outperforming monolayer-graphene-covered heterostructures and the single calcite film. These are because the sandwich configuration can enhance hybrid polaritons, which are formed by the coupling between surface plasmon polaritons in graphene and hyperbolic phonon polaritons in calcite. In addition, the effects of graphene chemical potentials on the performance of NF-TPV devices are also studied. The tunable power density range of the sandwich structure can be up to 3.26 times that of other structures by altering the chemical potential of graphene. The findings presented here may unpack a promising path for enhancing and manipulating the performance of NF-TPV at the nano- and microscale.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Iltai Isaac Kim, Yang Lie, Hongkyu Yoon, Jeffrey A. Greathouse
{"title":"Transmission interference fringe (TIF) technique for the dynamic visualization of evaporating droplet","authors":"Iltai Isaac Kim, Yang Lie, Hongkyu Yoon, Jeffrey A. Greathouse","doi":"10.1063/5.0223571","DOIUrl":"https://doi.org/10.1063/5.0223571","url":null,"abstract":"The transmission interference fringe (TIF) technique was developed to visualize the dynamics of evaporating droplets based on the Reflection Interference Fringe (RIF) technique for micro-sized droplets. The geometric formulation was conducted to determine the contact angle (CA) and height of macro-sized droplets without the need for the prism used in RIF. The TIF characteristics were analyzed through experiments and simulations to demonstrate a wider range of contact angles from 0 to 90°, in contrast to RIF's limited range of 0–30°. TIF was utilized to visualize the dynamic evaporation of droplets in the constant contact radius (CCR) mode, observing the droplet profile change from convex-only to convex-concave at the end of dry-out from the interference fringe formation. The TIF also observed the contact angle increase from the fringe radius increase. This observation is uniquely reported as the interference fringe (IF) technique can detect the formation of interference fringe between the reflection from the center convex profile and the reflection from the edge concave profile on the far-field screen. Unlike general microscopy techniques, TIF can detect far-field interference fringes as it focuses beyond the droplet-substrate interface. The formation of the convex-concave profile during CCR evaporation is believed to be influenced by the non-uniform evaporative flux along the droplet surface.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiangwei Qu, Jingrui Ma, Depeng Li, Kai Wang, Xiao Wei Sun
{"title":"Space charge-induced capacitance recovery in blue quantum dot light-emitting diodes","authors":"Xiangwei Qu, Jingrui Ma, Depeng Li, Kai Wang, Xiao Wei Sun","doi":"10.1063/5.0226752","DOIUrl":"https://doi.org/10.1063/5.0226752","url":null,"abstract":"In this work, we report the capacitance recovery behavior in the blue quantum dot light-emitting diode (QLED) by capacitance–voltage (C–V) characterizations. A comprehensive study of the C–V, dC/dV–V, and current density–voltage characteristics of pristine and shelf-aged devices suggests that capacitance recovery is associated with space charge-induced charge accumulation. At lower temperatures, the capacitance recovery in the shelf-aged device is efficiently suppressed due to the difficulty in building up the space charge, which supports our argument. Moreover, the capacitance recovery behavior of QLED only happens at low frequencies (a few hundred hertz), which is related to the time constant for charge accumulation at the selected voltage. Our work shows the effect of space charge on device capacitance and enriches the comprehension of carrier processes in QLED under AC measurement.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Kinetics of monolayer MoS2-encapsulated nanobubbles on hexagonal boron nitride substrates","authors":"Zihan Liu, Yingchun Jiang, Dingli Wang, Junpeng Lai, Huimin Zhou, Jia Deng, Changhong Ke","doi":"10.1063/5.0224361","DOIUrl":"https://doi.org/10.1063/5.0224361","url":null,"abstract":"Understanding the kinetics of nanobubbles encapsulated by ultrathin two-dimensional (2D) layered van der Waals crystal membranes on atomically flat substrates is important to the applications of 2D materials and the pursuit of 2D nanobubble technologies. Here, we investigate the controlled motion of monolayer molybdenum disulfide (MoS2)-encapsulated nanobubbles on flat hexagonal boron nitride substrates using atomic force microscopy (AFM). Our study reveals a distinct transition from standstill bubble deformations to stable, stepwise bubble translations on flat substrates. The membrane tension-dominated 2D nanobubble behaves like an elastic soft body in its collision interaction with the AFM tip. This delicate motion-control technique enables neighboring 2D nanobubbles to move closer and eventually coalesce into larger nanobubbles. These findings pave the way for high-precision manipulation of nanobubbles and facilitate the exploration of their emerging applications.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Gallium nitride-based resonant tunneling diode oscillators","authors":"Masahiro Murayama, Hisayoshi Motobayashi, Yukio Hoshina, Miwako Shoji, Yoshiro Takiguchi, Hiroyuki Miyahara, Takahiro Koyama, Noriyuki Futagawa","doi":"10.1063/5.0225312","DOIUrl":"https://doi.org/10.1063/5.0225312","url":null,"abstract":"We demonstrated GaN-based resonant tunneling diode (RTD) oscillators employing monolithic microwave integrated circuits. The GaN-based RTDs with a GaN quantum well and AlN double barriers were grown on freestanding c-plane semi-insulating GaN substrates using metal–organic chemical vapor deposition. The circuit components, including an RTD, a coplanar waveguide, a metal–insulator–metal capacitor, and shunt resistors, were monolithically fabricated on the GaN substrate. The circuits oscillated at a fundamental frequency of 17 GHz, which closely matched an estimated frequency using a three-dimensional electromagnetic simulator and a circuit simulator. This study contributes to the advancement of semiconductor high-frequency devices for millimeter wave and terahertz applications.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuanyuan Zhang, Mengxin Chen, Ji Chen, Mingyi Zhang, Ping Xu
{"title":"A perspective on magnetic field-enhanced electrocatalytic water splitting","authors":"Yuanyuan Zhang, Mengxin Chen, Ji Chen, Mingyi Zhang, Ping Xu","doi":"10.1063/5.0229187","DOIUrl":"https://doi.org/10.1063/5.0229187","url":null,"abstract":"Magnetic field effects have received widespread attention due to their ability to enhance the process of water splitting at multiple scales. However, a systematic and comprehensive understanding of the source of the magnetic effect and the magnetic modulation of magnetic catalysts is lacking. This perspective focuses on recent advancements in harnessing external magnetic field to improve electrocatalytic water splitting and suggests future directions. First, the mechanism of several magnetic effects and their effects on water splitting are elaborated in detail, including the magnetohydrodynamic effect, magnetothermal effect, spin polarization effect, and magnetoresistance effect. Then, the classification and construction strategies of magnetic effect catalysts are summarized, primarily divided into single metal/alloy catalysts, metal oxide-based catalysts, and other magnetic catalysts. Finally, the challenges and potential perspective of magnetic field-enhanced water splitting are discussed, including mechanism study, in situ characterization, and multi-field synergy effects.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Miaoxin Di, Tenglong Miao, Zhenqi Song, Suhua Chen, Ying Bai
{"title":"FeS2/SnS2@C with mosaic-like heterointerface as robust sodium anode","authors":"Miaoxin Di, Tenglong Miao, Zhenqi Song, Suhua Chen, Ying Bai","doi":"10.1063/5.0226473","DOIUrl":"https://doi.org/10.1063/5.0226473","url":null,"abstract":"Sodium-ion batteries (SIBs) have been widely researched due to their abundant resource and inherent safety. However, the major challenge for further commercialization of SIBs is the absence of low-priced anode electrodes with high reversible capacity and durability. Herein, a hierarchical heterogeneous structure of FeS2/SnS2@C nanocubes with rich two-dimensional mosaic-like heterointerface and N/S co-doped carbon wrapping is constructed and synthesized, to achieve ultrahigh reversible capacity and long cycling stability as anode of SIBs. Combining x-ray photoelectron spectroscopy, ion diffusion kinetic analysis, and in situ x-ray diffraction, the exquisite hierarchical heterogeneous structure of FeS2/SnS2@C could promote charge/electrons transfer and accelerate ion diffusion kinetics. As expected, the FeS2/SnS2@C anode shows superior reversible capacity (867.5 mA h g−1 at 0.1 A g−1), good rate performance (718.9 mA h g−1 at 5.0 A g−1), and long cycle stability (738.0 mA h g−1 after 1200 cycles at 5.0 A g−1) with Na metal as counter electrode. This work proves that the effectiveness of heterojunction interfaces for promoting Na+ diffusion is highlighted by such capabilities.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effective control of magnetism and transport properties of monolayer WV2N4 with two magnetic atomic layers and its van der Waals heterostructure","authors":"Xiaoyan Guo, Xiaolin Zhang, Yu Zhu, Yuheng Liu, Xiufeng Han, Yu Yan","doi":"10.1063/5.0217334","DOIUrl":"https://doi.org/10.1063/5.0217334","url":null,"abstract":"The large magneto-resistance (MR) effect produced by electric control of the magnetic state for van der Waals (vdW) heterostructures composed of vdW intrinsic magnets holds great significance for low-dissipation spintronic devices. Our first-principles calculations reveal that the proposed monolayer WV2N4 is a ferromagnetic (FM) metal with two magnetic V atomic layers, and the interlayer magnetic coupling between two V atomic layers can be switched from FM to antiferromagnetic coupling by applying a small compressive strain. Interestingly, a large MR ratio of 253% is achieved in the proposed graphite/monolayer WV2N4/graphite vdW heterostructure using a −1.5% compressive strain. Combining the strain-induced change in magnetism of monolayer WV2N4 and the graphite/monolayer WV2N4/graphite vdW heterostructure with the inverse piezoelectricity of piezoelectric materials, a feasible strategy is proposed to achieve electric control of the interlayer magnetic coupling of monolayer WV2N4 in the graphite/monolayer WV2N4/graphite vdW heterostructure clamped by piezoelectric materials by utilizing the inverse piezoelectricity, thereby generating a large MR ratio in the graphite/monolayer WV2N4/graphite vdW heterostructure clamped by the piezoelectric material. Our work presents a promising avenue for developing energy-efficient spintronic devices.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiangpeng Zhang, Wei Li, Yang Li, Linze Jiang, Xixiang Zhu, Haomiao Yu, Jinpeng Li, Yumeng Shi, Ding Yi, Kai Wang
{"title":"Impact of orbital hybridization on spin-polarized electronic transport through Ni-MAPbI3 interfaces","authors":"Xiangpeng Zhang, Wei Li, Yang Li, Linze Jiang, Xixiang Zhu, Haomiao Yu, Jinpeng Li, Yumeng Shi, Ding Yi, Kai Wang","doi":"10.1063/5.0222322","DOIUrl":"https://doi.org/10.1063/5.0222322","url":null,"abstract":"The solution-processed methylammonium lead tri-iodine (MAPbI3), with long spin lifetimes and large spin diffusion lengths, has merit for developing stable perovskite spin valves (PeSV) with low saturation fields. By far, it remains challenging to avoid ill-defined ferromagnet-MAPbI3 interfaces during device fabrications using solution methods and to quantify the hybridized interfacial electronic and magnetic structures. Herein, an annealing-free method was developed for the fabrication of MAPbI3 based PeSV. In comparison to a thermally annealed device, an improved room temperature magnetoresistance (MR) was achieved. We found remarkable interfacial contributions to anisotropic magnetoresistance and MR. The first-principles calculation was further adopted to quantify the interfacial spin and orbital moments. Our results suggest that the orbital hybridization and the spin transfer are remarkable for the formation of the spin-dependent interfacial density of states. It consequently affects magnetic switching behaviors. This study holds an exceptionally important role for a deep understanding of the spin-polarized electronic transport through the Ni-MAPbI3 hybridized interface.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":null,"pages":null},"PeriodicalIF":4.0,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142166393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}