Helen C. Robinson,Daniil Danilin,Md. Shafiqul Islam Mollik,Darshana Wickramaratne,John L. Lyons,Vladimir Fedorov,Sergey Mirov,M. E. Zvanut
{"title":"Charge-state control of carbon-related optical absorption in AlN","authors":"Helen C. Robinson,Daniil Danilin,Md. Shafiqul Islam Mollik,Darshana Wickramaratne,John L. Lyons,Vladimir Fedorov,Sergey Mirov,M. E. Zvanut","doi":"10.1063/5.0347879","DOIUrl":"https://doi.org/10.1063/5.0347879","url":null,"abstract":"Sub-bandgap optical absorption (OA) in AlN between 2 and 4 eV is widely observed, but its microscopic origin remains contested. Using photo-induced electron paramagnetic resonance (photo-EPR) and OA spectroscopy on the same samples, we demonstrate a correlation between this absorption band and the neutral charge state of substitutional carbon on the nitrogen site (CN). Hybrid functional calculations of the OA spectra show that a transition involving CN and the valence band occurs near 3.3 eV, which agrees well with a peak identified within the measured OA between 2 and 4 eV. This conclusion requires the combined ability to manipulate the charge state of carbon using photo-EPR and to use first-principles calculations of the absorption line shape that account for the dispersion of the valence band and the energy dependence of the optical matrix elements.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"163 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148894158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fei Sun,Chao Chen,Deyang Chen,Minghui Qin,Xubing Lu,Xingsen Gao,Christopher T. Nelson,Jun-Ming Liu
{"title":"Reversibly strain engineering and electric-field control of crystal symmetry in multiferroic oxides","authors":"Fei Sun,Chao Chen,Deyang Chen,Minghui Qin,Xubing Lu,Xingsen Gao,Christopher T. Nelson,Jun-Ming Liu","doi":"10.1063/5.0257648","DOIUrl":"https://doi.org/10.1063/5.0257648","url":null,"abstract":"Multiferroic oxides, such as BiFeO3, have garnered significant attention due to their coupled ferroelectric, magnetic, and elastic properties, offering exciting opportunities for multifunctional device applications. Controlling phase transitions in these materials is critical for tuning their physical properties and achieving desired functionalities. While numerous studies have focused on ferroelectric–ferroelectric transitions at rhombohedral–tetragonal morphotropic phase boundaries, far less attention has been given to the ferroelectric–antiferroelectric phase boundaries. Such systems hold promise for discovering novel physical phenomena, such as reversible phase transitions, enhanced piezoelectricity, and magnetoelectric coupling. In this work, we report a reversible antiferroelectric-to-ferroelectric phase transition in La-doped BiFeO3 thin films. By modulating the residual strain via film thickness, an antiferroelectric orthorhombic (O) phase is stabilized within a ferroelectric rhombohedral (R) phase matrix. Under an external electric field, the phase transitions reversibly between these two states. This discovery not only enriches the understanding of O/R morphotropic phase boundaries but also provides a potential pathway for developing magnetoelectric devices with enhanced functionality.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"12 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148894024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carl Peterson,Chinmoy Nath Saha,Yizheng Liu,James S. Speck,Sriram Krishnamoorthy
{"title":"Evidence of micrometer-scale ion damage in (010), (110), and (011) β-Ga2O3 epitaxial layers","authors":"Carl Peterson,Chinmoy Nath Saha,Yizheng Liu,James S. Speck,Sriram Krishnamoorthy","doi":"10.1063/5.0340749","DOIUrl":"https://doi.org/10.1063/5.0340749","url":null,"abstract":"We report the experimental observation of charge depletion up to 11.5 μm deep in (010), (110), and (011) β-Ga2O3 epitaxial layers due to ion damage from sputtering and inductively coupled plasma (ICP) etching processes, whereas charge depletion in (001) β-Ga2O3 epitaxial layers was minimal. The orientation-dependent reduction in C–V-measured charge density was first observed in NiOx reactively sputtered heterojunction p–n diodes (HJDs). When compared to reference low-damage Schottky barrier diodes (SBDs), the sputtered HJDs showed a 9.4× increase in the specific on resistance (Ron,sp) and an 85% reduction in net donor concentration (ND − NA) at zero bias for sputter-damaged HJDs on (010) epitaxial layers, whereas HJDs on (001) remained unchanged. Similarly, sputtered SiO2 caused a reduction in ND − NA, extending 11.5 μm into the (010) material. Next, SBDs were fabricated on β-Ga2O3 surfaces previously etched via a BCl3 based ICP process and compared to SBDs on un-etched surfaces. The (010) SBDs on etched surfaces exhibited a 7.7× increase in Ron,sp and a 91% reduction in ND − NA at zero bias, whereas the (001) etched diodes exhibited little change. Additionally, (110) and (011) diodes fabricated on ICP damaged surfaces also showed an ∼82% reduction in ND − NA at zero bias, indicating that the (110) and (011) orientations are also susceptible to ion damage. Damage in the (010), (110), and (011) diodes is potentially caused by energetic ions that travel into the open channels present along the [010] direction and create compensating point defects, which could potentially diffuse further.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"56 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148894096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Runxing Hao,Xianghui Deng,Yanxia Wu,Yuanfei Jiang,Xiaomin Su,Mingxing Jin,Qingyi Li
{"title":"Enhanced interlayer coupling and slowed carrier relaxation in MXene (Ti3C2Tx) under hydrostatic pressure","authors":"Runxing Hao,Xianghui Deng,Yanxia Wu,Yuanfei Jiang,Xiaomin Su,Mingxing Jin,Qingyi Li","doi":"10.1063/5.0349753","DOIUrl":"https://doi.org/10.1063/5.0349753","url":null,"abstract":"MXene materials hold great promise for flexible pressure-sensing applications; however, the evolution of their carrier transport and energy relaxation processes under external pressure remains poorly understood. In this work, we systematically investigate the photoexcited ultrafast dynamics of the prototypical MXene Ti3C2Tx under hydrostatic pressures ranging from 0.7 to 6.4 kbar. Our results reveal that with increasing pressure, the relaxation of the excited-state absorption peak centered at ∼520 nm is significantly retarded, manifested by a monotonic increase in both the electron–electron scattering time (τ1) and the electron–phonon scattering time (τ2). The counterintuitive pressure-induced slowdown of carrier relaxation finds its origin in the synergistic effects of enhanced inter-flake charge hopping, reduced carrier densities, and weakened electron–phonon coupling. Furthermore, the accelerated relaxation of the plasmon bleach peak with increasing pressure provides direct evidence for improved lattice cooling efficiency due to weakened electron–phonon coupling and enhanced interlayer thermal diffusion. Collectively, our findings establish a microscopic physical picture of pressure-modulated interlayer coupling and ultrafast dynamics in MXenes, offering new experimental benchmarks and providing a microscopic foundation for the understanding of pressure-sensing mechanisms in MXene-based devices.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"10 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148894159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Denis Mamaluy,Md Rahatul Islam Udoy,Juan P. Mendez,Ben Feinberg,Wei Pan,Ahmedullah Aziz
{"title":"Predictive first-principles simulations for co-designing next-generation energy-efficient AI systems","authors":"Denis Mamaluy,Md Rahatul Islam Udoy,Juan P. Mendez,Ben Feinberg,Wei Pan,Ahmedullah Aziz","doi":"10.1063/5.0333458","DOIUrl":"https://doi.org/10.1063/5.0333458","url":null,"abstract":"In modern generative-AI workloads, matrix–vector/matrix–matrix multiplications (MatMul) dominate the compute and energy cost. Achieving dramatic reductions in energy per token therefore requires a novel, specialized hardware that is co-designed across materials, devices, interconnects, circuits, and architectures rather than optimized at any single layer in isolation. In this Perspectives article, we argue that predictive (first-principles, fitting-parameter-free) device and interconnect simulations can close the loop between nanoscale physics and workload-level metrics, enabling the identification of device/interconnect operating regimes that plausibly support orders-of-magnitude improvements in energy efficiency of AI accelerators.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"141 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148894160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fan Ye,Qian Gao,Qiao Tang,Yi-Zhu Xie,Ying Liu,Chun-Yan Yu,Fan Wang,Dong-Ping Zhang,Xing-Min Cai
{"title":"The recombination mechanism and defect energy levels of Ag-doped ZnSnN2/ZnSnN2 pn homojunction solar cells","authors":"Fan Ye,Qian Gao,Qiao Tang,Yi-Zhu Xie,Ying Liu,Chun-Yan Yu,Fan Wang,Dong-Ping Zhang,Xing-Min Cai","doi":"10.1063/5.0342923","DOIUrl":"https://doi.org/10.1063/5.0342923","url":null,"abstract":"The photovoltaic performance of ZnSnN2 homojunction has never been studied. Here, ZnSnN2 homojunction solar cells with Ag-doped ZnSnN2 as the p-type layer are fabricated with magnetron sputtering deposition, and the mechanism limiting the photovoltaic performance is revealed. The junction is abrupt. The current transport is dominated by thermionic emission below 320 K and generation-recombination (GR) in the space charge region in 330–380 K. Below 320 K, the short circuit current density and the open circuit voltage are limited by nonradiative interface recombination. The open circuit voltage loss also results from interfacial barrier height inhomogeneity, which obeys the Gaussian distribution model or the temperature fluctuation of interface barrier heights for holes. At higher temperatures, deep energy levels in the middle of the bandgap result in the GR in the space charge region. One shallow energy level at 0.13 eV and one interface energy level at 0.72 eV above the valence band maximum are observed. The former is likely induced by substitutional Ag-doping.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"47 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148894163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiahao Zhang,Jian Chu,Luhua Chen,Xiangzhe Zeng,Yang Zhang,Yi Wang,Jinhui Song
{"title":"Fast speed UV photodetector with high responsivity based on ZnO/MgZnO core–shell nanowires","authors":"Jiahao Zhang,Jian Chu,Luhua Chen,Xiangzhe Zeng,Yang Zhang,Yi Wang,Jinhui Song","doi":"10.1063/5.0335549","DOIUrl":"https://doi.org/10.1063/5.0335549","url":null,"abstract":"Ultraviolet (UV) photodetectors based on zinc oxide (ZnO) wide-bandgap semiconductors have been intensively explored for applications in environmental monitoring, optical communication, and biosensing. However, conventional ZnO-based photodetectors often suffer from limited responsivity and relatively slow photoresponse speeds, which severely restrict their practical applications. Herein, we report a highly sensitive and fast-responsive photodetector based on ZnO/MgZnO core–shell radial-heterostructured nanowires (NWs) through radial interface engineering. The introduction of a wider bandgap MgZnO shell onto ZnO NWs forms a radial ZnO/MgZnO heterojunction, which introduces a built-in electric field that effectively promotes the separation and collection of photogenerated carriers. The optimized device exhibits a fast response time of 0.41/2.30 s (rise/decay) and a high responsivity of 0.75 A/W at zero bias. Furthermore, this study reveals a nonlinear relationship between the MgZnO shell thickness and the photoresponsivity of the device, and identifies the optimal MgZnO shell thickness for optimizing device performance. These results demonstrate that core–shell heterointerface engineering is an effective strategy for balancing responsivity and response speed in ZnO-based UV photodetectors.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"80 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148895923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}