Oxidation of Metals最新文献_第7页

Oxidation Behavior of Additively Manufactured Ti-added FeCrAl Alloys 添加钛的铁铬铝合金的氧化行为

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-08-01 DOI: 10.1007/s11085-024-10276-5

Irina Fedorova, Mikael Kjellen, Saud Saleem, Dennis Karlsson, Fredrik Meurling, Roger Berglund

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Utilization of Alumina Scale Formation by Ni-Base Alloys for High-Temperature Oxidation and Corrosion Resistance in Harsh Environments 利用镍基合金形成的氧化铝鳞片实现恶劣环境中的高温氧化和耐腐蚀性能

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-30 DOI: 10.1007/s11085-024-10280-9

Bingtao Li, Lee M. Pike

{"title":"Utilization of Alumina Scale Formation by Ni-Base Alloys for High-Temperature Oxidation and Corrosion Resistance in Harsh Environments","authors":"Bingtao Li, Lee M. Pike","doi":"10.1007/s11085-024-10280-9","DOIUrl":"10.1007/s11085-024-10280-9","url":null,"abstract":"<div>High-temperature alloys rely on the formation of a protective oxide scale to resist high-temperature oxidation and corrosion attack, and chromia is the most common oxide to provide this function in commercial alloys. However, certain harsh environments require alloys that utilize the formation of even more protective oxide films to provide improved performance and longer lifetime. In these cases, an alumina scale becomes a viable solution to protect high-temperature alloys. This paper summarizes high-temperature oxidation and corrosion behaviors of several high-temperature Ni- and Co-base alloys tested under various high-temperature conditions, including short-term and long-term oxidation, cyclic oxidation, dynamic (burner rig) oxidation, water vapor oxidation, nitridation, and carburization at temperatures ranging from 871 to 1093 °C (1600–2000°F). The oxidation and corrosion behaviors are compared between the alumina-forming and chromia-forming alloys, and the results show that the alumina-forming alloys were significantly superior to the chromia-forming alloys for high-temperature oxidation and corrosion resistance in terms of oxidation and corrosion rate reduction, scale stability and adhesion, mass penetration suppression, etc. Based on the extensive tests, alumina scales were highly effective in resisting oxidation, nitridation, and carburization attacks, especially under severe oxidation and corrosion conditions. To further demonstrate the benefits of an alumina scale, an alumina-forming alloy with pre-oxidation heat-treatment was also studied in the nitridation test.</div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 6","pages":"1315 - 1330"},"PeriodicalIF":2.1,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141866553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Study of the Role of Nitrogen in the Oxidation of Titanium-Based Alloys by Changing the Reaction Gas 通过改变反应气体研究氮在钛基合金氧化过程中的作用

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-30 DOI: 10.1007/s11085-024-10275-6

Kevin Gautier, Daniel Monceau, Enrica Epifano, Damien Connétable, Thomas Gheno

{"title":"Study of the Role of Nitrogen in the Oxidation of Titanium-Based Alloys by Changing the Reaction Gas","authors":"Kevin Gautier, Daniel Monceau, Enrica Epifano, Damien Connétable, Thomas Gheno","doi":"10.1007/s11085-024-10275-6","DOIUrl":"10.1007/s11085-024-10275-6","url":null,"abstract":"<div>The role of nitrogen in the oxidation of Ti-2W, Ti-10Al-2W (at.%) and Ti6242S was investigated using experiments in air and in Ar-20%O2, and two-stage experiments where the reaction gas was switched from one mixture to the other. When switching from Ar-20%O2 to air, the oxidation rates first increased during a short period, then decreased. This surge of mass gain following the introduction of air was attributed to N pickup, forming a nitride layer and a N-enriched zone in the alloy, below the oxide layer. The subsequent decrease of oxidation rate was attributed to the formation of nitride and/or N-rich zone, which both act as diffusion barriers for oxygen. Switching from air to Ar-20%O2 caused an increase in the oxidation rate of the W-containing alloys, which was attributed to the consumption of this barrier. The gas change had no significant effect on the oxidation rate of Ti6242S, which formed a much thinner nitride layer in air. The faster the nitride layer grows, the faster it is consumed when removing N from the reaction gas, probably because of a higher diffusion rate of N in W-doped TiO2 compared to TiO2 formed on Ti6242S.</div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 5","pages":"861 - 872"},"PeriodicalIF":2.1,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-024-10275-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141866545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparison of Performance of NiCr2O4 and Cr2O3 Formed on the Ni-Based Superalloy RR1000 Under Corrosive Conditions 镍基超合金 RR1000 上形成的 NiCr2O4 和 Cr2O3 在腐蚀条件下的性能比较

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-30 DOI: 10.1007/s11085-024-10256-9

S. Gray, M. Mphahlele, D. M. Collins, C. Jackson, M. C. Hardy, M. P. Taylor

{"title":"Comparison of Performance of NiCr2O4 and Cr2O3 Formed on the Ni-Based Superalloy RR1000 Under Corrosive Conditions","authors":"S. Gray, M. Mphahlele, D. M. Collins, C. Jackson, M. C. Hardy, M. P. Taylor","doi":"10.1007/s11085-024-10256-9","DOIUrl":"10.1007/s11085-024-10256-9","url":null,"abstract":"<div>Samples of the Ni-based superalloy, RR1000, were exposed to 98% Na2SO4/2% NaCl salts at 700 °C with a flux of 1.5 µg cm−2 h−1 in flowing air + 300 ppm SO2 for a total of 250 h. Three pre-exposure conditions were studied: a bare reference alloy; fast heating to the test temperature followed by a 100 h hold; heating at a rate of 5 °C min−1 to the test temperature following by a 100 h hold. The surface oxide formed under the latter two conditions were Cr2O3 or NiCr2O4, respectively. The results show corrosion pit formation on the surface of the base, reference sample, and no pits present on the sample with the preformed Cr2O3. Some protection was found for the sample heated at 5 °C min−1 with a delay in the progression to accelerated corrosion attack. Additional testing under moisture containing air was also conducted. This showed no obvious difference in surface oxide morphology under the two tested heating rates for the short-term exposures examined but a difference was noted to be dependent on the moisture content of the air.</div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 5","pages":"1091 - 1102"},"PeriodicalIF":2.1,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-024-10256-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141866547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High Temperature Intergranular Oxidation of Nickel Based Superalloy Inconel 718 镍基超合金 Inconel 718 的高温晶间氧化作用

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-30 DOI: 10.1007/s11085-024-10260-z

Sudhanva Madhusudan, Enrica Epifano, Jérôme Favergeon, Tom Sanviemvongsak, David Maréchal, Daniel Monceau

{"title":"High Temperature Intergranular Oxidation of Nickel Based Superalloy Inconel 718","authors":"Sudhanva Madhusudan, Enrica Epifano, Jérôme Favergeon, Tom Sanviemvongsak, David Maréchal, Daniel Monceau","doi":"10.1007/s11085-024-10260-z","DOIUrl":"10.1007/s11085-024-10260-z","url":null,"abstract":"<div>Intergranular oxidation (IGO) of the Ni-based superalloy Inconel 718 was studied at 650 °C, 700 °C and 900 °C. The oxidized samples were characterized by X-ray diffraction and scanning electron microscopy. For all the studied temperatures, the external scale was mainly composed of Cr2O3, while the oxides along the grain boundaries were rich in Al and, to a minor extent, Ti. This was consistent with thermodynamic computations. The time evolution of the maximum depth of IGO was found to be parabolic with an apparent activation energy of 164 kJ/mol. The results of this study confirm with three temperatures that IGO kinetics can be described using an extension of the Wagner’s theory of internal oxidation, as recently suggested in the literature at 850 °C. According to this description, the mechanisms controlling the IGO kinetics of Inconel 718 are the aluminum diffusion in the alloy matrix and the oxygen diffusion along the interface between the alloy matrix and the oxidized grain boundary.</div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 5","pages":"873 - 884"},"PeriodicalIF":2.1,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-024-10260-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141866544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Decreased Metal Dusting Resistance of Ni-Cu Alloys by Fe and Mn Additions 添加铁和锰可降低镍铜合金的抗金属粉尘性能

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-29 DOI: 10.1007/s11085-024-10263-w

Anke S. Ulrich, Sergey Kasatikov, Till König, Andrea Fantin, Johannes T. Margraf, Mathias C. Galetz

{"title":"Decreased Metal Dusting Resistance of Ni-Cu Alloys by Fe and Mn Additions","authors":"Anke S. Ulrich, Sergey Kasatikov, Till König, Andrea Fantin, Johannes T. Margraf, Mathias C. Galetz","doi":"10.1007/s11085-024-10263-w","DOIUrl":"10.1007/s11085-024-10263-w","url":null,"abstract":"<div>Ni-Cu alloys are promising for application at temperatures between 400–900 °C and reducing atmospheres with high C-contents. Typically, under such conditions, metallic materials in contact with the C-rich atmosphere are degraded by a mechanism called metal dusting (MD). Ni-Cu-alloys do not form protective oxide scales, but their resistance is attributed to Cu, which catalytically inhibits the C-deposition on the surface. Adding other alloying elements, such as Mn or Fe, was found to enhance the MD attack of Ni-Cu alloys again. In this study, the effect of the Mn and Fe is divided into two affected areas: the surface and the bulk. The MD attack on binary Ni-Cu alloys, model alloys with Fe and Mn additions, and commercial Monel Alloy 400 is experimentally demonstrated. The surface electronic structure causing the adsorption and dissociation of C-containing molecules is investigated for model alloys. Analytical methods such as scanning electron microscopy combined with energy-dispersive X-ray spectroscopy, electron probe microanalysis combined with wavelength-dispersive X-ray spectroscopy, X-ray diffraction analysis, and near-edge X-ray absorption fine structure measurements were used. The results are correlated to CALPHAD calculations and atomistic simulations combining density functional theory calculations and machine learning. It is found that the Cu content plays a significant role in the surface reaction. The effect of Mn and Fe is mainly attributed to oxide formation. A mechanism explaining the enhanced attack by adding both Fe and Mn is proposed.</div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 6","pages":"1301 - 1314"},"PeriodicalIF":2.1,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-024-10263-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141866549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Growth of a Single MnCr2O4 Spinel on Ni–25Cr–1.5Mn Alloy by the Rhines Pack Method and Photoelectrochemical and Raman Signatures of MnCr2O4 Spinel 用莱茵包法在镍-25Cr-1.5Mn 合金上生长单一 MnCr2O4 尖晶石以及 MnCr2O4 尖晶石的光电化学和拉曼特征

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-29 DOI: 10.1007/s11085-024-10269-4

T. Perez, S. Mathieu, L. Latu-Romain, Y. Wouters, M. Vilasi

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Microstructure of Cr2O3 Scales Grown in Ar-5H2O-(5H2) at 850 °C 850 °C 时在 Ar-5H2O-(5H2) 中生长的 Cr2O3 鳞片的微观结构

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-29 DOI: 10.1007/s11085-024-10287-2

Thuan Dinh Nguyen, Jianqiang Zhang, David J. Young

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Low Cycle Fatigue/Corrosion Interactions at 950 °C of AM1 Single Crystal Nickel-Based Superalloy AM1 单晶镍基超级合金在 950 °C 下的低循环疲劳/腐蚀相互作用

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-28 DOI: 10.1007/s11085-024-10255-w

A. Martin, E. Drouelle, J. Rame, J. Cormier, F. Pedraza

{"title":"Low Cycle Fatigue/Corrosion Interactions at 950 °C of AM1 Single Crystal Nickel-Based Superalloy","authors":"A. Martin, E. Drouelle, J. Rame, J. Cormier, F. Pedraza","doi":"10.1007/s11085-024-10255-w","DOIUrl":"10.1007/s11085-024-10255-w","url":null,"abstract":"<div>Current nickel-based single crystal superalloys (SX) are mainly designed to increase significant mechanical loading at high temperatures. Therefore, the mechanical resistance is greatly dependant on the microstructure and on the potential metallurgical defects. Corrosion and oxidation at high temperatures may further induce a loss of load-bearing section and lower the overall mechanical performance of such single crystals. While the yet complex mechanical and corrosion mechanisms are relatively well established separately, little is known on their combined effects, let alone on as-cast (AC) versus fully heat-treated (FHT) microstructures. This paper shows that the low cycle fatigue (LCF) at 0.5 Hz, Rσ = 0.05 and 950 °C is lowered when the AM1 nickel-based single crystal superalloy is pre-corroded with 1 mg/cm2 Na2SO4 at 950 °C. The degradation increases with increasing pre-corrosion time due to the formation of a porous, brittle corrosion layer that favours the number of crack initiation sites, which are subsequently assisted by hot corrosion and oxidation. In addition, AM1 FHT shows better LCF fatigue resistance than AM1 AC, due to a better creep resistance of the FHT microstructure under these conditions.</div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 5","pages":"961 - 970"},"PeriodicalIF":2.1,"publicationDate":"2024-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141780858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Very Long Transient Oxidation of a Nickel-based Single-Crystal Superalloy at 900 °C and 850 °C 镍基单晶超级合金在 900 °C 和 850 °C 下的超长瞬态氧化

IF 2.1 3区材料科学

Oxidation of Metals Pub Date : 2024-07-27 DOI: 10.1007/s11085-024-10261-y

Martin Batiste, Thomas Perez, Tom Sanviemvongsak, Clara Desgranges, Daniel Monceau

{"title":"Very Long Transient Oxidation of a Nickel-based Single-Crystal Superalloy at 900 °C and 850 °C","authors":"Martin Batiste, Thomas Perez, Tom Sanviemvongsak, Clara Desgranges, Daniel Monceau","doi":"10.1007/s11085-024-10261-y","DOIUrl":"10.1007/s11085-024-10261-y","url":null,"abstract":"<div>The isothermal oxidation of Ni-base single-crystal superalloy AM1 was investigated for up to 3600 h at 850 °C and 900 °C. The aim of the study was to test an existing model of oxidation kinetics that considers transitory oxide growth. The samples were characterized at various intervals to correlate the microstructure of the oxide scale with the oxidation kinetics. Transition alumina (θ) was observed among other transition oxides such as spinel, rutile, and chromia, which helped in understanding the nature and kinetics of the transitory stage. After a sufficiently long duration, all samples formed a continuous α-alumina layer at the metal/oxide interface. The previously published model, based on three kinetic parameters, was validated in the temperature range of 800–1200 °C. The duration of the transient regime characterized in this study at 850 °C and 900 °C was consistent with the kinetics model, with a slight increase in the value of the model parameter describing the lateral growth kinetics of α-alumina. This modification resulted in a slight reduction in the duration of the transient regime at low temperatures.</div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 5","pages":"935 - 948"},"PeriodicalIF":2.1,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-024-10261-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141780856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0