Qingmei Xiao, Shiming Huang, Donghao Liang, Cheng Liu, Ruonan Zhang, Wenjin Li, Guangliang Gary Liu
{"title":"BaTiO3 Nanoparticle-Induced Interfacial Electric Field Optimization in Chloride Solid Electrolytes for 4.8 V All-Solid-State Lithium Batteries","authors":"Qingmei Xiao, Shiming Huang, Donghao Liang, Cheng Liu, Ruonan Zhang, Wenjin Li, Guangliang Gary Liu","doi":"10.1007/s40820-025-01901-2","DOIUrl":"10.1007/s40820-025-01901-2","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Time efficient ball milling achieves uniform BaTiO<sub>3</sub> ( coating without sacrificing\u0000ionic conductivity (1.06 mS cm<sup>−1</sup>).</p>\u0000 </li>\u0000 <li>\u0000 <p>Ferroelectric BTO coating suppresses Li<sub>2.5</sub>Y<sub>0.5</sub>Zr<sub>0.5</sub>Cl<sub>6</sub> (LYZC decomposition at 4.8 V\u0000via electric field modulation, enabling 76% capacity retention after 150 cycles.</p>\u0000 </li>\u0000 <li>\u0000 <p>BTO effectively minimizes the formation of interfacial ZrCl<sub>3</sub>O /YCl<sub>2</sub>O byproducts and\u0000mitigates the irreversible phase transition of single crystal NCM811 (SCNCM811), thereby improving the compatibility between LYZC and SCNCM811.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01901-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144923117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qin Ye, Yimou Huang, Baojian Yao, Zhuo Chen, Changming Shi, Brian W. Sheldon, Meijie Chen
{"title":"Radiative Coupled Evaporation Cooling Hydrogel for Above-Ambient Heat Dissipation and Flame Retardancy","authors":"Qin Ye, Yimou Huang, Baojian Yao, Zhuo Chen, Changming Shi, Brian W. Sheldon, Meijie Chen","doi":"10.1007/s40820-025-01903-0","DOIUrl":"10.1007/s40820-025-01903-0","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>An all-in-one photonic hydrogel was designed for above-ambient heat dissipation and flame retardancy by sky radiative cooling and evaporation cooling.</p>\u0000 </li>\u0000 <li>\u0000 <p>Radiative coupled with evaporation cooling can greatly improve the heat dissipation performance, indicating a 12.0 °C lower than the radiative cooling film under the same conditions.</p>\u0000 </li>\u0000 <li>\u0000 <p>Radiative cooling-assisted adsorption can improve atmospheric water harvesting to ensure evaporation under periodic workload and meteorological parameters.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01903-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144923119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yichuan Dou, Zhuang Liu, Lanling Zhao, Jian Zhang, Fanpeng Meng, Yao Liu, Zidong Zhang, Xingao Li, Zheng Shang, Lu Wang, Jun Wang
{"title":"Constructing Double Heterojunctions on 1T/2H-MoS2@Co3S4 Electrocatalysts for Regulating Li2O2 Formation in Lithium-Oxygen Batteries","authors":"Yichuan Dou, Zhuang Liu, Lanling Zhao, Jian Zhang, Fanpeng Meng, Yao Liu, Zidong Zhang, Xingao Li, Zheng Shang, Lu Wang, Jun Wang","doi":"10.1007/s40820-025-01895-x","DOIUrl":"10.1007/s40820-025-01895-x","url":null,"abstract":"<div><p>Co<sub>3</sub>S<sub>4</sub> electrocatalysts with mixed valences of Co ions and excellent structural stability possess favorable oxygen evolution reaction (OER) activity, yet challenges remain in fabricating rechargeable lithium-oxygen batteries (LOBs) due to their poor OER performance, resulting from poor electrical conductivity and overly strong intermediate adsorption. In this work, fancy double heterojunctions on 1T/2H-MoS<sub>2</sub>@Co<sub>3</sub>S<sub>4</sub> (1T/2H-MCS) were constructed derived from the charge donation from Co to Mo ions, thus inducing the phase transformation of MoS<sub>2</sub> from 2H to 1T. The unique features of these double heterojunctions endow the 1T/2H-MCS with complementary catalysis during charging and discharging processes. It is worth noting that 1T-MoS<sub>2</sub>@Co<sub>3</sub>S<sub>4</sub> could provide fast Co–S–Mo electron transport channels to promote ORR/OER kinetics, and 2H-MoS<sub>2</sub>@Co<sub>3</sub>S<sub>4</sub> contributed to enabling moderate e<sub>g</sub> orbital occupancy when adsorbed with oxygen-containing intermediates. On the basis, the Li<sub>2</sub>O<sub>2</sub> nucleation route was changed to solution and surface dual pathways, improving reversible deposition and decomposition kinetics. As a result, 1T/2H-MCS cathodes exhibit an improved electrocatalytic performance compared with those of Co<sub>3</sub>S<sub>4</sub> and MoS<sub>2</sub> cathodes. This innovative heterostructure design provides a reliable strategy to construct efficient transition metal sulfide catalysts by improving electrical conductivity and modulating adsorption toward oxygenated intermediates for LOBs.</p><img></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01895-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144923118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhixiang Gao, Xin Ju, Huabin Yu, Wei Chen, Xin Liu, Yuanmin Luo, Yang Kang, Dongyang Luo, JiKai Yao, Wengang Gu, Muhammad Hunain Memon, Yong Yan, Haiding Sun
{"title":"Ultrathin Gallium Nitride Quantum-Disk-in-Nanowire-Enabled Reconfigurable Bioinspired Sensor for High-Accuracy Human Action Recognition","authors":"Zhixiang Gao, Xin Ju, Huabin Yu, Wei Chen, Xin Liu, Yuanmin Luo, Yang Kang, Dongyang Luo, JiKai Yao, Wengang Gu, Muhammad Hunain Memon, Yong Yan, Haiding Sun","doi":"10.1007/s40820-025-01888-w","DOIUrl":"10.1007/s40820-025-01888-w","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>A novel GaN/AlN-based ultrathin quantum-disks-in-nanowires sensor was fabricated, demonstrating voltage bias tunable response characteristics to light stimuli.</p>\u0000 </li>\u0000 <li>\u0000 <p>Image enhancement functionality and a robust reservoir computing system were demonstrated based on the voltage tunable long-term and short-term persistent photocurrent respectively.</p>\u0000 </li>\u0000 <li>\u0000 <p>Furthermore, a high-performance artificial vision system with the two integrated functions was demonstrated, achieving a remarkable improvement in human action recognition.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01888-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144923102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Solar-Driven Redox Reactions with Metal Halide Perovskites Heterogeneous Structures","authors":"Qing Guo, Jin-Dan Zhang, Jian Li, Xiyuan Feng","doi":"10.1007/s40820-025-01886-y","DOIUrl":"10.1007/s40820-025-01886-y","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>This paper reviews the fundamentals and research progress of metal halide perovskites (MHPs)-based heterojunctions for solar-driven redox reactions.</p>\u0000 </li>\u0000 <li>\u0000 <p>A comprehensive summary is presented for the construction of various MHPs-based heterojunctions (e.g., Schottky-junction, type-I/II, Z-scheme, and S-scheme).</p>\u0000 </li>\u0000 <li>\u0000 <p>The versatile use of MHPs-based heterojunctions in key photocatalytic redox reactions are summarized, including H<sub>2</sub> evolution, CO<sub>2</sub> reduction, pollutant degradation, and organic synthesis.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01886-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144923120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Lithium-Ion Dynamic Interface Engineering of Nano-Charged Composite Polymer Electrolytes for Solid-State Lithium-Metal Batteries","authors":"Shanshan Lv, Jingwen Wang, Yuanming Zhai, Yu Chen, Jiarui Yang, Zhiwei Zhu, Rui Peng, Xuewei Fu, Wei Yang, Yu Wang","doi":"10.1007/s40820-025-01899-7","DOIUrl":"10.1007/s40820-025-01899-7","url":null,"abstract":"<div><p>Composite polymer electrolytes (CPEs) offer a promising solution for all-solid-state lithium-metal batteries (ASSLMBs). However, conventional nanofillers with Lewis-acid–base surfaces make limited contribution to improving the overall performance of CPEs due to their difficulty in achieving robust electrochemical and mechanical interfaces simultaneously. Here, by regulating the surface charge characteristics of halloysite nanotube (HNT), we propose a concept of lithium-ion dynamic interface (Li<sup>+</sup>-DI) engineering in nano-charged CPE (NCCPE). Results show that the surface charge characteristics of HNTs fundamentally change the Li<sup>+</sup>-DI, and thereof the mechanical and ion-conduction behaviors of the NCCPEs. Particularly, the HNTs with positively charged surface (HNTs<sup>+</sup>) lead to a higher Li<sup>+</sup> transference number (0.86) than that of HNTs<sup>−</sup> (0.73), but a lower toughness (102.13 MJ m<sup>−3</sup> for HNTs<sup>+</sup> and 159.69 MJ m<sup>−3</sup> for HNTs<sup>−</sup>). Meanwhile, a strong interface compatibilization effect by Li<sup>+</sup> is observed for especially the HNTs<sup>+</sup>-involved Li<sup>+</sup>-DI, which improves the toughness by 2000% compared with the control. Moreover, HNTs<sup>+</sup> are more effective to weaken the Li<sup>+</sup>-solvation strength and facilitate the formation of LiF-rich solid–electrolyte interphase of Li metal compared to HNTs<sup>−</sup>. The resultant Li|NCCPE|LiFePO<sub>4</sub> cell delivers a capacity of 144.9 mAh g<sup>−1</sup> after 400 cycles at 0.5 C and a capacity retention of 78.6%. This study provides deep insights into understanding the roles of surface charges of nanofillers in regulating the mechanical and electrochemical interfaces in ASSLMBs.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01899-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144914654","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Humaira Rafique, Ghulam Abbas, Manuel J. Mendes, Pedro Barquinha, Rodrigo Martins, Elvira Fortunato, Hugo Águas, Santanu Jana
{"title":"Recent Advancements and Perspectives of Low-Dimensional Halide Perovskites for Visual Perception and Optoelectronic Applications","authors":"Humaira Rafique, Ghulam Abbas, Manuel J. Mendes, Pedro Barquinha, Rodrigo Martins, Elvira Fortunato, Hugo Águas, Santanu Jana","doi":"10.1007/s40820-025-01823-z","DOIUrl":"10.1007/s40820-025-01823-z","url":null,"abstract":"<div><p>Low-dimensional (LD) halide perovskites have attracted considerable attention due to their distinctive structures and exceptional optoelectronic properties, including high absorption coefficients, extended charge carrier diffusion lengths, suppressed non-radiative recombination rates, and intense photoluminescence. A key advantage of LD perovskites is the tunability of their optical and electronic properties through the precise optimization of their structural arrangements and dimensionality. This review systematically examines recent progress in the synthesis and optoelectronic characterizations of LD perovskites, focusing on their structural, optical, and photophysical properties that underpin their versatility in diverse applications. The review further summarizes advancements in LD perovskite-based devices, including resistive memory, artificial synapses, photodetectors, light-emitting diodes, and solar cells. Finally, the challenges associated with stability, scalability, and integration, as well as future prospects, are discussed, emphasizing the potential of LD perovskites to drive breakthroughs in device efficiency and industrial applicability.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2025-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01823-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144897146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}