{"title":"Eco-Nanozymology: A Catalytic Paradigm Integrating Energy, Environment, and Ecology","authors":"Limin Shang, Ziqi Zhang, Hongyu Lin, Zichang Wang, Dehong Chen, Zhiling Zhu","doi":"10.1007/s40820-026-02269-7","DOIUrl":"10.1007/s40820-026-02269-7","url":null,"abstract":"<div><p>Eco-nanozymology, as an emerging interdisciplinary field, integrates nanotechnology with principles of enzymology to offer innovative strategies for energy conversion and environmental remediation. In contrast with conventional enzymology, eco-nanozymology enhances catalytic efficiency through the precise regulation of interfacial microstructures, electronic distributions, active site configurations, multienzyme cascade catalysis, and functionalized carrier engineering. By harnessing and amplifying natural ecological processes, eco-nanozymology enables effective modulation of energy flow and material cycling within ecosystems. This review focuses on recent advances in the application of eco-nanozymology across energy-related domains, including nitrogen fixation, carbon fixation, methane oxidation, hydrogen production, and energy conversion devices. It further provides an in-depth analysis of the recent progress in the efficient degradation of environmental pollutants and resource-oriented valorization of low-value biomass, such as lignin, agricultural residues, livestock manure, and microplastics. These studies highlight the pivotal role of eco-nanozymology in enhancing the efficiency of environmental management, accelerating the development of green energy technologies, and advancing carbon neutrality goals. The continued development of eco-nanozymology is expected to open new horizons for the deepening and expansion of nanozyme applications, offering green, environmentally friendly, and sustainable technological pathways to address global energy and environmental challenges.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02269-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148323819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Donghao Zhang, Xiaodan Wang, Na Pan, Wenxin Fan, Kunyan Sui
{"title":"Self-Oriented Gradient Ionic Skins for Dual-Function Electromagnetic Shielding and Self-Powered Sensing","authors":"Donghao Zhang, Xiaodan Wang, Na Pan, Wenxin Fan, Kunyan Sui","doi":"10.1007/s40820-026-02255-z","DOIUrl":"10.1007/s40820-026-02255-z","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>The diffusion-complexation strategy enabled the synchronous construction of both an in-plane oriented MXene network and a longitudinal charge gradient structure within the hydrogel.</p>\u0000 </li>\u0000 <li>\u0000 <p>An advanced ionic skin with an integrated architecture has been developed, which exhibits exceptional electromagnetic interference shielding performance along with outstanding self-powered sensing capability. </p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02255-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148323820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bang Yu, Hang Su, Zengyu Yan, Yun Su, Byoungwoo Kang, Xiaohui Rong, Liquan Chen, Yong-Sheng Hu
{"title":"Multiphysics Modeling and Analysis for Dendrite Problems in Solid-State Lithium/Sodium Metal Batteries","authors":"Bang Yu, Hang Su, Zengyu Yan, Yun Su, Byoungwoo Kang, Xiaohui Rong, Liquan Chen, Yong-Sheng Hu","doi":"10.1007/s40820-026-02200-0","DOIUrl":"10.1007/s40820-026-02200-0","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 \u0000<ul>\u0000 <li>\u0000 <p>Experimental observations of metal dendrites are systematically summarized across liquid and solid-state battery systems.</p>\u0000 </li>\u0000 <li>\u0000 <p>Dendrite evolution is elucidated from a multiphysics perspective, highlighting the coupling of electrochemical, thermal, and mechanical fields.</p>\u0000 </li>\u0000 <li>\u0000 <p>Mechanism-guided dendrite-suppression strategies are critically reviewed based on physical field regulation.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02200-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148313447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electron Redistribution by Fluorine-Induced Dual Defects in Cu3P Accelerated Charge Transfer Toward High-Performance Electrochemical Chloride Ion Removal","authors":"Ziqing Zhou, Yifan Ren, Fei Yu, Jie Ma","doi":"10.1007/s40820-026-02267-9","DOIUrl":"10.1007/s40820-026-02267-9","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Heteroatom doping-induced vacancy was achieved by molten salt treatment.</p>\u0000 </li>\u0000 <li>\u0000 <p>The dual defects led to marked electron redistribution, accelerating electron \u0000transfer and ion diffusion kinetics.</p>\u0000 </li>\u0000 <li>\u0000 <p>The electrodes with dual defects exhibited superior areal deionization capacity \u0000and rate.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02267-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shivaraju Guddehalli Chandrappa, Gerardo Morell, Ram S. Katiyar
{"title":"Halide-Based Solid Electrolytes for Advanced All-Solid-State Batteries: Design, Interfaces, and Electrochemical Performance","authors":"Shivaraju Guddehalli Chandrappa, Gerardo Morell, Ram S. Katiyar","doi":"10.1007/s40820-026-02251-3","DOIUrl":"10.1007/s40820-026-02251-3","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>General classification and methodology guidelines to halide-based solid electrolytes for high-voltage all-solid-state batteries.</p>\u0000 </li>\u0000 <li>\u0000 <p>A comprehensive evaluation of synthesis and interfacial modification methods that direct the enhancement of ionic conductivity and electrochemical stability.</p>\u0000 </li>\u0000 <li>\u0000 <p>Potential uses of halide-based solid electrolytes in full-cell configurations with cathodes based on high voltage in Li-ion batteries and beyond-Li-ion systems, such as Li–S, Li–O<sub>2</sub>, and Na-ion batteries.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02251-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148291233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Young-Han Lee, Je-Hyeon Han, Deok-Gyu Kim, Jung-Woon Yoo, Yoon-Cheol Ha, Jae-Hun Kim, Cheol-Min Park
{"title":"Multifunctional Conductive and Elastic Matrices-Engineered Si Nanocomposite Anodes for Liquid and Solid-State Lithium Batteries","authors":"Young-Han Lee, Je-Hyeon Han, Deok-Gyu Kim, Jung-Woon Yoo, Yoon-Cheol Ha, Jae-Hun Kim, Cheol-Min Park","doi":"10.1007/s40820-026-02258-w","DOIUrl":"10.1007/s40820-026-02258-w","url":null,"abstract":"<div><p>Silicon anodes have intrinsically low electronic conductivity and severe volume changes, leading to nonuniform reaction kinetics and progressive structural degradation in both lithium-ion batteries (LIBs) and all-solid-state lithium batteries (ASSLBs). To overcome these limitations, we develop a silicon nanocomposite anode via a scalable and facile synthesis route. The nanocomposite (Si/a-Sn/CoSi<sub>2</sub>/G/C) consists of ultrafine Si nanocrystallites integrated with a well-deformable, electronically conductive amorphous Sn; a mechanically robust and elastic CoSi<sub>2</sub> framework; a highly Li-reversible, electronically conductive, stress-mitigating graphite scaffold; and a highly elastic, electronically conductive PVC-pyrolyzed amorphous carbon shell. This hierarchical and synergistic architecture integrates uniform nanocrystalline Si dispersion, continuous electronic conduction, and mechanically rigid and elastically buffering matrices that accommodate volume expansion, thereby establishing a robust Si nanocomposite anode platform compatible with both LIBs and ASSLBs. The anode has a high reversible capacity, stable long-term cycling performance, high Coulombic efficiency, and improved rate capability. In LIB systems, a Si/a-Sn/CoSi<sub>2</sub>/G/C|NCM811 full-cell achieves an energy density of 434.4 Wh kg<sup>–1</sup> with durable cycling stability. In sulfide-based ASSLB systems employing Li<sub>6</sub>PS<sub>5</sub>Cl, the full-cell has an energy density exceeding 300 Wh kg<sup>–1</sup>, with structural and electrochemical stability. Thus, Si/a-Sn/CoSi<sub>2</sub>/G/C is a practical and scalable Si-based anode platform for next-generation LIBs and ASSLBs.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02258-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148291235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Stack of Bi2Se3/Carbon Films with Pyramid Interface for Dual-Mode Temperature–Pressure Sensing in Aquatic Environments","authors":"Yan Xu, Xuefei Zhang, Size Lou, Zhe Tang, Dongmei Xie, Chuanrui Zhang, Mengran Chen, Heng Liu, Chuan Sun, Yixiang Ou, Peng-an Zong","doi":"10.1007/s40820-026-02254-0","DOIUrl":"10.1007/s40820-026-02254-0","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>A pyramid-interface-structured Bi<sub>2</sub>Se<sub>3</sub> layer was electrochemically constructed on flexible carbon paper, exhibiting excellent hydrophobicity with a contact angle of 143.7°.</p>\u0000 </li>\u0000 <li>\u0000 <p>Dual-mode decoupling of temperature and pressure without cross-interference was achieved using a single material in both air and underwater environments.</p>\u0000 </li>\u0000 <li>\u0000 <p>The sensor maintains stable signal output under prolonged underwater operation, mechanical bending, electromagnetic interference exposure, and even direct flame contact, demonstrating exceptional environmental resilience.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02254-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148291229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ziqing Yao, Yulu Zou, Shuqi Zhang, Wei Xie, Yujie Li, Shuangke Liu, Xingyu Chen, Kun Zhang, Chunman Zheng, Weiwei Sun
{"title":"Engineering Dynamic Electrolyte Microenvironments via Double-Shell Hosts for Practical Lithium–Sulfur Batteries","authors":"Ziqing Yao, Yulu Zou, Shuqi Zhang, Wei Xie, Yujie Li, Shuangke Liu, Xingyu Chen, Kun Zhang, Chunman Zheng, Weiwei Sun","doi":"10.1007/s40820-026-02260-2","DOIUrl":"10.1007/s40820-026-02260-2","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>The efficient preparation of sulfur hosts derived from Prussian blue analogues with double-shell hollow structure was achieved through ion exchange with precisely controlled elemental ratios.</p>\u0000 </li>\u0000 <li>\u0000 <p>The double-shell structure alters the microenvironment of sulfur redox reaction through self-driven dynamic migration of electrolyte, preventing the local enrichment of lithium polysulfides around catalysts.</p>\u0000 </li>\u0000 <li>\u0000 <p>The double-shell sulfur cathode enhances the cycling stability and practical application of lithium–sulfur batteries, enabling an Ah-level pouch cell with an energy density of 454.7 Wh kg<sup>–1</sup>.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02260-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148291236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}