Nano-Micro Letters最新文献

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Triboelectric Wearable Sensors for Human-Centric Smart Electronics: From Self-Powered Sensing to Artificial Intelligence-Assisted Human–Machine Interface Systems 以人为中心的智能电子摩擦电可穿戴传感器:从自供电传感到人工智能辅助的人机界面系统。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-16 DOI: 10.1007/s40820-026-02263-z
Yoonsang Ra, Sumin Cho, Xinge Guo, Dongwhi Choi, Chengkuo Lee
{"title":"Triboelectric Wearable Sensors for Human-Centric Smart Electronics: From Self-Powered Sensing to Artificial Intelligence-Assisted Human–Machine Interface Systems","authors":"Yoonsang Ra,&nbsp;Sumin Cho,&nbsp;Xinge Guo,&nbsp;Dongwhi Choi,&nbsp;Chengkuo Lee","doi":"10.1007/s40820-026-02263-z","DOIUrl":"10.1007/s40820-026-02263-z","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>A wearable-centered review framework is presented for triboelectric sensors, covering self-powered sensing principles, material selection, device architectures, and fabrication strategies.</p>\u0000 </li>\u0000 <li>\u0000 <p>Artificial intelligence-assisted signal processing, triboelectric artificial synapses, and neuromorphic computing are identified as key bridges from self-powered sensing to adaptive human–machine interfaces.</p>\u0000 </li>\u0000 <li>\u0000 <p>Representative applications and future directions are organized toward human-centric smart electronics, including health care, gesture interaction, robotics, intelligent transportation, and next-generation embodied systems.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02263-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148256820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultra-Broadband Microwave Absorption and Programmable Multispectral Camouflage Enabled by Neural-Network-Driven Impedance-Gradient Metadevices 神经网络驱动的阻抗梯度元器件实现超宽带微波吸收和可编程多光谱伪装。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-16 DOI: 10.1007/s40820-026-02247-z
Chen Li, Leilei Liang, Baoshan Zhang, Yi Yang, Guangbin Ji
{"title":"Ultra-Broadband Microwave Absorption and Programmable Multispectral Camouflage Enabled by Neural-Network-Driven Impedance-Gradient Metadevices","authors":"Chen Li,&nbsp;Leilei Liang,&nbsp;Baoshan Zhang,&nbsp;Yi Yang,&nbsp;Guangbin Ji","doi":"10.1007/s40820-026-02247-z","DOIUrl":"10.1007/s40820-026-02247-z","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 \u0000<ul>\u0000 <li>\u0000 <p>An impedance-gradient metadevice for multispectral compatible camouflage was intelligently designed using the neural network.</p>\u0000 </li>\u0000 <li>\u0000 <p>The metadevice demonstrates excellent microwave ultra-broadband absorption (2–18 GHz), infrared thermal insulation (ΔT≈65 °C), low emissivity (0.38), and rapid visible color change (1–2 s).</p>\u0000 </li>\u0000 <li>\u0000 <p>The assembled device offers programmability and multimodality while also exhibiting impact resistance (~30,000 N) and environmental stability.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02247-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148256864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intelligent Breathing Electronic Skin Inspired by Nepenthes for Active Sweat Management, Multimodal Sensing and High-Fidelity Electromyographic Teleoperation Using Machine Learning 受Nepenthes启发的智能呼吸电子皮肤,用于主动汗液管理,多模态传感和使用机器学习的高保真肌电遥操作。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-12 DOI: 10.1007/s40820-026-02252-2
Yichen Li, Kai Zheng, Guangtian Zhang, Wentao Chen, Chengtan Liu, Seonho Shin, Bihai Yang, Ran Cai, Bin Hu
{"title":"Intelligent Breathing Electronic Skin Inspired by Nepenthes for Active Sweat Management, Multimodal Sensing and High-Fidelity Electromyographic Teleoperation Using Machine Learning","authors":"Yichen Li,&nbsp;Kai Zheng,&nbsp;Guangtian Zhang,&nbsp;Wentao Chen,&nbsp;Chengtan Liu,&nbsp;Seonho Shin,&nbsp;Bihai Yang,&nbsp;Ran Cai,&nbsp;Bin Hu","doi":"10.1007/s40820-026-02252-2","DOIUrl":"10.1007/s40820-026-02252-2","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>A <i>Nepenthes</i>-inspired Janus e-skin (SPTL) was developed to achieve active unidirectional sweat transport while maintaining high breathability, waterproofness, and biocompatibility for prolonged skin dryness.</p>\u0000 </li>\u0000 <li>\u0000 <p>The SPTL offers 627% stretchability and multimodal sensing (including Morse code and non-contact capacitive sensing) and enables high-fidelity acquisition of electroencephalogram, electromyogram, electrocardiogram, and electrooculogram\u0000signals.</p>\u0000 </li>\u0000 <li>\u0000 <p>By integrating machine learning, SPTL-based sensing allows for precise electromyogram control of a quadruped robot and letter recognition with &gt;95% accuracy.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02252-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148222413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking the Synergistic Promoter Role of Phosphorus in Evolving NiFe Phosphides for Enhanced Water Oxidation 揭示磷在进化NiFe磷化物中促进水氧化的协同促进作用。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-11 DOI: 10.1007/s40820-026-02238-0
Ningning Shi, Mingcheng Gao, M. Maneesha, C. S. Praveen, Panpan Liu, Shengnan Yue, Wangjing Xie, Dechao Chen, Yu Tang, Yuanqing Wang, Hua Fan, Xing Huang
{"title":"Unlocking the Synergistic Promoter Role of Phosphorus in Evolving NiFe Phosphides for Enhanced Water Oxidation","authors":"Ningning Shi,&nbsp;Mingcheng Gao,&nbsp;M. Maneesha,&nbsp;C. S. Praveen,&nbsp;Panpan Liu,&nbsp;Shengnan Yue,&nbsp;Wangjing Xie,&nbsp;Dechao Chen,&nbsp;Yu Tang,&nbsp;Yuanqing Wang,&nbsp;Hua Fan,&nbsp;Xing Huang","doi":"10.1007/s40820-026-02238-0","DOIUrl":"10.1007/s40820-026-02238-0","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Phosphorus drives NiFeP’s reconstruction into active NiFe (oxy)hydroxide, suppresses Fe dissolution, and modulates Ni’s electronic structure via residual PO<sub>4</sub><sup>3−</sup>.</p>\u0000 </li>\u0000 <li>\u0000 <p>PO<sub>4</sub><sup>3−</sup> and Fe synergistically act as a redox buffer, preventing Ni over-oxidation, narrowing the bandgap, and stabilizing key oxygen evolution reaction intermediates to lower the energy barrier.</p>\u0000 </li>\u0000 <li>\u0000 <p>The restructured catalyst achieves a low overpotential of 225 mV at 10 mA cm<sup>−2</sup> and maintains stable operation in alkaline media for over 100 h at current densities up to 500 mA cm<sup>−2</sup>.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02238-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148215923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioinspired Hierarchical Hydrogel Electrolyte for Ultralong-Life Flexible Zinc-Ion Batteries 用于超长寿命柔性锌离子电池的生物启发分层水凝胶电解质。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-10 DOI: 10.1007/s40820-026-02246-0
Ran Wang, Qian Gao, Runhai Wu, Yongqi Mi, Shaopei Yang, Hongxiao Wang, Ting Wan, Sehrish Gull, Kefeng Xie, Guankui Long, Pengcheng Du
{"title":"Bioinspired Hierarchical Hydrogel Electrolyte for Ultralong-Life Flexible Zinc-Ion Batteries","authors":"Ran Wang,&nbsp;Qian Gao,&nbsp;Runhai Wu,&nbsp;Yongqi Mi,&nbsp;Shaopei Yang,&nbsp;Hongxiao Wang,&nbsp;Ting Wan,&nbsp;Sehrish Gull,&nbsp;Kefeng Xie,&nbsp;Guankui Long,&nbsp;Pengcheng Du","doi":"10.1007/s40820-026-02246-0","DOIUrl":"10.1007/s40820-026-02246-0","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Drawing inspiration from the “adhesion-conduction” architecture of spider webs, a hierarchical hydrogel electrolyte (MTP) is developed with uniform 3D ion-conductive pathways.</p>\u0000 </li>\u0000 <li>\u0000 <p>Specific “sticky sites” on the MXene/tannic acid network facilitate superior electrochemical properties, including a high Zn<sup>2+</sup> transference number of 0.833 and ionic conductivity of 27.69 mS cm<sup>−1</sup>.</p>\u0000 </li>\u0000 <li>\u0000 <p>This strategy enables stable Zn anodes with an impressive lifespan of 4600 h (&gt;6 months) and empowers flexible full cells with outstanding cyclability over 10,000 cycles.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02246-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148209852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polymer-Based Flexible Wireless Sensors for Health Monitoring 基于聚合物的健康监测柔性无线传感器。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-08 DOI: 10.1007/s40820-026-02233-5
Heyuan Huang, Gang Xue, Jianning Zhan, Yu Yang, Ben Jia, Zhicheng Dong, Zexing Deng, Xin Zhao
{"title":"Polymer-Based Flexible Wireless Sensors for Health Monitoring","authors":"Heyuan Huang,&nbsp;Gang Xue,&nbsp;Jianning Zhan,&nbsp;Yu Yang,&nbsp;Ben Jia,&nbsp;Zhicheng Dong,&nbsp;Zexing Deng,&nbsp;Xin Zhao","doi":"10.1007/s40820-026-02233-5","DOIUrl":"10.1007/s40820-026-02233-5","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>A system-level review of polymer-based flexible wireless sensors for epidermal, subcutaneous, and short-term implantable health monitoring is presented, elucidating the coupling among materials, interfaces, and wireless links.</p>\u0000 </li>\u0000 <li>\u0000 <p>Materials design and application studies are systematically integrated to clarify how different material systems influence sensing performance, signal stability, and monitoring reliability.</p>\u0000 </li>\u0000 <li>\u0000 <p>Key challenges and future trends are summarized, with emphasis on mitigating material-level noise, high sensitivity, multifunctional integration, and clinical translation potential.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02233-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148196980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Beyond Isolated Optimization: A Holistic Review Across the Pre-Mid Post-Treatment Chain for Hard Carbon in Sodium-Ion Battery 超越孤立优化:钠离子电池中硬碳的前、中、后处理链的整体回顾。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-05 DOI: 10.1007/s40820-026-02248-y
Qingxuan Geng, Yonghui Zhang, Dongxu Xie, Chenhui Hao, Liping Guo, Jiwei Zhang, Paul K. Chu, Qingwei Li
{"title":"Beyond Isolated Optimization: A Holistic Review Across the Pre-Mid Post-Treatment Chain for Hard Carbon in Sodium-Ion Battery","authors":"Qingxuan Geng,&nbsp;Yonghui Zhang,&nbsp;Dongxu Xie,&nbsp;Chenhui Hao,&nbsp;Liping Guo,&nbsp;Jiwei Zhang,&nbsp;Paul K. Chu,&nbsp;Qingwei Li","doi":"10.1007/s40820-026-02248-y","DOIUrl":"10.1007/s40820-026-02248-y","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Proposes a holistic “Pre-Mid-Post” full-process engineering mode to go beyond fragmented single-point optimization of hard carbon anodes</p>\u0000 </li>\u0000 <li>\u0000 <p>Elucidates the synergistic and contradictory interplay among graphitic domains, nanopores, and defects in determining the Na⁺ storage properties</p>\u0000 </li>\u0000 <li>\u0000 <p>Future design necessitates cross-stage co-optimization and quantitative microstructure–performance relationships for rational HC engineering</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02248-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148161616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Triboelectric Nanogenerators in Military: Recent Progress and Critical Challenges 摩擦电纳米发电机在军事:最新进展和关键挑战。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-04 DOI: 10.1007/s40820-026-02221-9
Changcheng Bao, Xiaoxia Ma, Min He, Li Yang, Yingting Wang
{"title":"Triboelectric Nanogenerators in Military: Recent Progress and Critical Challenges","authors":"Changcheng Bao,&nbsp;Xiaoxia Ma,&nbsp;Min He,&nbsp;Li Yang,&nbsp;Yingting Wang","doi":"10.1007/s40820-026-02221-9","DOIUrl":"10.1007/s40820-026-02221-9","url":null,"abstract":"<div><p>The rapid evolution of modern warfare toward distributed, intelligent, and global stealth has posed severe energy supply and information perception bottlenecks for combat nodes. Traditional energy supply strategies are unable to meet the strategic needs of long-range stealth operations and extreme environmental survival. Triboelectric nanogenerators provide a disruptive path for constructing self-sustaining military microsystems with high-efficiency and zero-power-sensing characteristics. This review establishes a comprehensive framework that systematically evaluates recent technological advances across an escalating hierarchy, encompassing individual soldier combat platforms, unmanned combat systems, strategic aerospace equipment, and special tactical scenarios. Crucially, moving beyond generic laboratory demonstrations, this review adopts a rigorous defense engineering perspective by conducting an integrated failure mode analysis to evaluate device degradation under severe battlefield stressors. Furthermore, it critically analyzes the primary engineering bottlenecks currently hindering military adoption, such as inherent impedance mismatch and scalable manufacturing barriers, and proposes targeted mitigation strategies. To systematically validate these solutions, we explicitly propose a concise evaluation framework strictly aligned with established military testing protocols. Ultimately, this review outlines several forward-looking strategic priorities, thereby constructing a highly actionable roadmap to accelerate the practical deployment of self-driven intelligent technologies.</p><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02221-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148154791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anion Chemistry: Structure, Electrochemistry and Stability of NASICON Cathodes 阴离子化学:NASICON阴极的结构、电化学和稳定性。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-02 DOI: 10.1007/s40820-026-02241-5
Tingting Cai, Dongxu Yu, Xueyan Zhang, Shuangshuang Zhao, Liguang Wang
{"title":"Anion Chemistry: Structure, Electrochemistry and Stability of NASICON Cathodes","authors":"Tingting Cai,&nbsp;Dongxu Yu,&nbsp;Xueyan Zhang,&nbsp;Shuangshuang Zhao,&nbsp;Liguang Wang","doi":"10.1007/s40820-026-02241-5","DOIUrl":"10.1007/s40820-026-02241-5","url":null,"abstract":"<div><p>The development of high‐energy‐density sodium‐ion batteries places stringent requirements on cathode materials to simultaneously achieve high operating voltages, rapid Na<sup>+</sup> ions transport, and long‐term structural and interfacial stability. Polyanionic NASICON‐type frameworks have emerged as a compelling cathode platform due to their robust three‐dimensional Na<sup>+</sup> ions diffusion networks, strong inductive effects, and excellent thermal stability. Within this materials family, fluorophosphate NASICON cathodes offer elevated redox potentials, while targeted anion chemistry modulation provides an effective strategy to tune electronic structure, ion migration, and interfacial reactivity. Representative vanadium‐based fluorophosphate cathodes, Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>F<sub>3</sub> (NVPF) and Na<sub>3</sub>V<sub>2</sub>O<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>F (NVOPF), exhibit closely related crystal frameworks yet display distinct sodium storage behavior and degradation characteristics under high‐voltage operation. In NVOPF, partial substitution of F<sup>−</sup> by O<sup>2−</sup> enhances electronic conductivity and Na<sup>+</sup> ions transport kinetics, while NVPF maintains a higher redox potential associated with the V<sup>3+</sup>/V<sup>4+</sup> couple. This review critically compares NVPF‐ and NVOPF‐based cathodes in terms of crystal structure, sodium storage mechanism, synthesis and modification strategies, and high‐voltage cathode/electrolyte interfacial stability. By correlating structural chemistry with electrochemical and interfacial evolution, this work provides general insights and design guidelines for high‐voltage NASICON‐type cathodes in sodium‐ion batteries.</p><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02241-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148142366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High Polarity Doping of CoFe Layered Hydroxides: Bifunctional and Corrosion-Resistant Anion Exchange Membrane Seawater Electrolyzers 高极性掺杂的fe层状氢氧化物:双功能耐腐蚀阴离子交换膜海水电解槽。
IF 36.3 1区 材料科学
Nano-Micro Letters Pub Date : 2026-06-01 DOI: 10.1007/s40820-026-02230-8
Anandhan Ayyappan Saj, Sampath Prabhakaran, Mohsin Rasool, Kousik Bhunia, Dongho Lee, Hyunseok Ko, Tukaram D. Dongale, Muthukumar Perumalsamy, Arul Saravanan Raaju Sundhar, Do Hwan Kim, Sang Jae Kim
{"title":"High Polarity Doping of CoFe Layered Hydroxides: Bifunctional and Corrosion-Resistant Anion Exchange Membrane Seawater Electrolyzers","authors":"Anandhan Ayyappan Saj,&nbsp;Sampath Prabhakaran,&nbsp;Mohsin Rasool,&nbsp;Kousik Bhunia,&nbsp;Dongho Lee,&nbsp;Hyunseok Ko,&nbsp;Tukaram D. Dongale,&nbsp;Muthukumar Perumalsamy,&nbsp;Arul Saravanan Raaju Sundhar,&nbsp;Do Hwan Kim,&nbsp;Sang Jae Kim","doi":"10.1007/s40820-026-02230-8","DOIUrl":"10.1007/s40820-026-02230-8","url":null,"abstract":"<div><p>Green hydrogen production through seawater electrolysis is a promising strategy, although challenges such as sluggish oxygen evolution reaction (OER) kinetics and chlorine (Cl<sup>−</sup>) corrosion hinder its practical applicability. A novel fluorine (F)-doped cobalt (Co) and iron (Fe) layered metal hydroxide (F-CoFe LMH-8) is developed as a robust bifunctional catalyst achieving 81.23 and 265.5 mV at 10 mA cm<sup>−2</sup> for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), respectively. Theoretical and experimental studies demonstrate that the F-doping modulates the electronic structure, effectively tuning Fe sites toward a high-spin configuration that optimizes binding energies and induces a chlorophobic effect that repel corrosive (Cl<sup>−</sup>) ions. Notably, the F-CoFe LMH-8( +|| −) bifunctional catalyst integrated anion exchange membrane water electrolyzer (AEMWE) exhibited outstanding performance for continuous H<sub>2</sub> production, achieves a current density of 1.2 A cm<sup>−2</sup> in 1 M KOH, 1.02 A cm<sup>−2</sup> in 1 M KOH + 0.5 M NaCl, and 1 A cm<sup>−2</sup> in 1 M KOH in seawater at 2.3 V. Furthermore, a long short-term memory-based machine learning model was employed to forecast and predict the stability of F-CoFe LMH-8. This approach provides a comprehensive pathway for heuristic design of durable, chlorophobic, and advanced electrocatalyst for seawater-based AEMWE and large-scale hydrogen production.</p><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-026-02230-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148136368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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