BaTiO3 Nanoparticle-Induced Interfacial Electric Field Optimization in Chloride Solid Electrolytes for 4.8 V All-Solid-State Lithium Batteries

IF 36.3 1区材料科学 Q1 Engineering

Nano-Micro Letters Pub Date : 2025-09-01 DOI:10.1007/s40820-025-01901-2

Qingmei Xiao, Shiming Huang, Donghao Liang, Cheng Liu, Ruonan Zhang, Wenjin Li, Guangliang Gary Liu

{"title":"BaTiO3 Nanoparticle-Induced Interfacial Electric Field Optimization in Chloride Solid Electrolytes for 4.8 V All-Solid-State Lithium Batteries","authors":"Qingmei Xiao, Shiming Huang, Donghao Liang, Cheng Liu, Ruonan Zhang, Wenjin Li, Guangliang Gary Liu","doi":"10.1007/s40820-025-01901-2","DOIUrl":null,"url":null,"abstract":"<div><h2>Highlights</h2><div>\n \n <ul>\n <li>\n <p>Time efficient ball milling achieves uniform BaTiO<sub>3</sub> ( coating without sacrificing\nionic conductivity (1.06 mS cm<sup>−1</sup>).</p>\n </li>\n <li>\n <p>Ferroelectric BTO coating suppresses Li<sub>2.5</sub>Y<sub>0.5</sub>Zr<sub>0.5</sub>Cl<sub>6</sub> (LYZC decomposition at 4.8 V\nvia electric field modulation, enabling 76% capacity retention after 150 cycles.</p>\n </li>\n <li>\n <p>BTO effectively minimizes the formation of interfacial ZrCl<sub>3</sub>O /YCl<sub>2</sub>O byproducts and\nmitigates the irreversible phase transition of single crystal NCM811 (SCNCM811), thereby improving the compatibility between LYZC and SCNCM811.</p>\n </li>\n </ul>\n </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"18 1","pages":""},"PeriodicalIF":36.3000,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-025-01901-2.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano-Micro Letters","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s40820-025-01901-2","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Engineering","Score":null,"Total":0}

引用次数: 0

Abstract

Highlights

Time efficient ball milling achieves uniform BaTiO₃ ( coating without sacrificing ionic conductivity (1.06 mS cm⁻¹).
Ferroelectric BTO coating suppresses Li_2.5Y_0.5Zr_0.5Cl₆ (LYZC decomposition at 4.8 V via electric field modulation, enabling 76% capacity retention after 150 cycles.
BTO effectively minimizes the formation of interfacial ZrCl₃O /YCl₂O byproducts and mitigates the irreversible phase transition of single crystal NCM811 (SCNCM811), thereby improving the compatibility between LYZC and SCNCM811.

查看原文本刊更多论文

4.8 V全固态锂电池氯离子电解质中纳米BaTiO3诱导界面电场优化

高效球磨实现均匀的BaTiO3涂层，而不牺牲离子电导率（1.06 mS cm−1）。铁电BTO涂层通过电场调制抑制了Li2.5Y0.5Zr0.5Cl6 （LYZC）在4.8 vv下的分解，在150次循环后保持了76%的容量。BTO有效地减少了zrcl30 /YCl2O界面副产物的形成，减轻了单晶NCM811 （SCNCM811）的不可逆相变，从而提高了LYZC与SCNCM811之间的相容性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY

CiteScore

32.60

自引率

4.90%

发文量

981

审稿时长

1.1 months

期刊介绍： Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.