Acta Chimica Slovenica最新文献_第7页

Antimicrobial and anticancer evaluation of Juniperus chinensis seed oil with molecular docking of α-cedrol-AKT1. α-雪松- akt1分子对接评价刺柏籽油的抑菌和抗癌作用。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-04 DOI: 10.17344/acsi.2025.9517

Mürüvvet Kurt, Safiye Elif Korcan, Serap Yalçın Azarkan

引用次数: 0

Diazonium acid-dyes elimination via complexation with sulfonated calix[4]arene soluble in aqueous medium; on an experimental and theoretical study. 水溶性磺化杯芳烃络合去除重氮酸染料进行了实验和理论研究。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-23 DOI: 10.17344/acsi.2025.9558

Mojtaba Ghorbani, Saeed Taghvaei-Ganjali, Aliakbar Tarlani, Mandana Saber-Tehrani, Jacques Muzart

{"title":"Diazonium acid-dyes elimination via complexation with sulfonated calix[4]arene soluble in aqueous medium; on an experimental and theoretical study.","authors":"Mojtaba Ghorbani, Saeed Taghvaei-Ganjali, Aliakbar Tarlani, Mandana Saber-Tehrani, Jacques Muzart","doi":"10.17344/acsi.2025.9558","DOIUrl":"https://doi.org/10.17344/acsi.2025.9558","url":null,"abstract":"This research highlights the effectiveness in employing a sulfonated para-tert-butylcalix[4]arene derivative (SCX4) as an effective molecular host for adsorption of acidic azo dyes in aqueous environment. Due to its inherent stability and rigidity, this chemical may be suitable as a host for host-guest interactions. Therefore, the sulfonated calixarene was used to study its complexation properties with the dyes, namely Acid Red 88 (AR88) and Acid Orange 7 (AO7) as adsorbing guests. Calculated formation constants (Kf) for the SCX4/dyes complexes were estimated from comparison of the absorption intensities. The formation constants were 5.1∙104 M-1 and 5.2∙104 M-1, correspondingly. Calculated stoichiometric ratios of the complexes were evaluated via Benesi-Hildebrand diagrams, which gave a ratio of 1:1. The equilibrium adsorption data of Acid Orange 7 were evaluated via three adsorption isotherm models including Freundlich, Temkin and Langmuir. The adsorption isotherms showed compatibility with three different approaches. The findings suggest that the Freundlich model better covers this adsorption process. Using a DFT-based approximation revealed the preferred structure of SCX4 and its complex with Acid Orange 7.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"183-196"},"PeriodicalIF":1.3,"publicationDate":"2026-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of some novel sulfonamides with coumarin core. An unexpected product of the reaction. 以香豆素为核心的新型磺胺类化合物的合成。一个意想不到的反应产物。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-09 DOI: 10.17344/acsi.2025.9578

Rina R Krasniqi, Emil Popovski, Gašper Tavčar, Jan Jelen, Olaf Kunert, Ahmed Jashari

引用次数: 0

Determination of diuretics in the whey protein supplements: uncovering hidden contaminants in the sports nutrition market. 乳清蛋白补充剂中利尿剂的测定：揭露运动营养市场中隐藏的污染物。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-07 DOI: 10.17344/acsi.2025.9226

Siti Khadijah Ab Rahman, Nurhamizah Rahmat, Mohd Rizal Md Razali, Wee Kian Yeo

{"title":"Determination of diuretics in the whey protein supplements: uncovering hidden contaminants in the sports nutrition market.","authors":"Siti Khadijah Ab Rahman, Nurhamizah Rahmat, Mohd Rizal Md Razali, Wee Kian Yeo","doi":"10.17344/acsi.2025.9226","DOIUrl":"10.17344/acsi.2025.9226","url":null,"abstract":"The widespread use of whey protein supplements raises concerns about contamination with banned diuretics, posing health risks and the potential for inadvertent doping. In this study, a liquid-liquid extraction (LLE) procedure coupled with liquid chromatography-tandem mass spectrometry (LC-MS/MS) was developed and validated for the simultaneous detection of 23 diuretics in whey protein supplements. The method was assessed for selectivity, linearity, matrix effect, recovery, precision, and sensitivity. Statistical evaluation using the Shapiro-Wilk and Levene's tests confirmed that most calibration residuals exhibited a normal distribution and homogeneity of variance, ensuring the reliability of the regression model. The method demonstrated excellent linearity (R² = 0.980-0.999) and low method detection limits (MDLs, 0.39-2.73 ng/g). A total of 58 commercially available whey protein supplements were analysed, and bendroflumethiazide (D4) was detected in 12 samples, with concentrations ranging from 1.4 to 40.4 ng/g. These findings highlight the applicability of the validated method for routine monitoring and underscore the urgent need for stringent quality control and regulatory oversight in the sports supplement industry to protect consumer health and maintain fair competition.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"197-206"},"PeriodicalIF":1.2,"publicationDate":"2026-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Differential pulse anoding voltammetric determination of torasemide using carbon paste electrode. 碳糊电极差分脉冲阳极伏安法测定托拉塞胺。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-07 DOI: 10.17344/acsi.2025.9329

Sayed I M Zayed, Ibrahim H I Habib

引用次数: 0

Multi synthetic fuel products production from waste and flue gas using the carbon effect technique. 利用碳效应技术从废物和烟气中生产多种合成燃料产品。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-05 DOI: 10.17344/acsi.2025.9538

Anita Kovač Kralj, Tina Kegl

引用次数: 0

Design, synthesis, X-ray structure, Hirshfeld surface, and NLO behavior of 3-bromo-2-[(2E)-2-(2-oxonaphthalen-1(2H)-ylidene)hydrazinyl]benzoic acid. 3-溴-2-[(2E)-2-（2-氧萘-1(2H)-酰基）肼基]苯甲酸的设计、合成、x射线结构、Hirshfeld表面和NLO行为。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-05 DOI: 10.17344/acsi.2025.9398

Souheyla Chetioui, Mansour Azayez, Ouarda Brihi, Djebar Hadji, Zohra-Douaa Benyahlou, Youcef Megrouss, Abdelkader Chouaih, Mokhtaria Drissi, Jean-Pierre Djukic, Salem Yahiaoui

{"title":"Design, synthesis, X-ray structure, Hirshfeld surface, and NLO behavior of 3-bromo-2-[(2E)-2-(2-oxonaphthalen-1(2H)-ylidene)hydrazinyl]benzoic acid.","authors":"Souheyla Chetioui, Mansour Azayez, Ouarda Brihi, Djebar Hadji, Zohra-Douaa Benyahlou, Youcef Megrouss, Abdelkader Chouaih, Mokhtaria Drissi, Jean-Pierre Djukic, Salem Yahiaoui","doi":"10.17344/acsi.2025.9398","DOIUrl":"https://doi.org/10.17344/acsi.2025.9398","url":null,"abstract":"The crystalline form of the compound, 3-bromo-2-[(2E)-2-(2-oxonaphthalen-1(2H)-ylidene)hydrazinyl]benzoic acid (BOHB), has been synthesized in good yield by diazotization of 2-amino-3-bromobenzoic acid followed by a reaction with β-naphthol. The XRD-crystal measurements and DFT calculations confirmed that the hydrazone was the favored form. The structure of the synthetic product was also examined by IR and NMR spectroscopic methods. Using Hirshfeld surface analysis, interactions in the crystal have been highlighted, where many contributors are identified such as H···H (24.7%), O···H/H···O (20.6%), H···C/C···H (17.0%), and Br···H/H···Br (15.0%). Furthermore, the novel benzoic acid derivative was investigated for its nonlinear optical (NLO) properties. Computational results indicate that the compound shows enhanced first hyperpolarizability values relative to common reference systems. This suggests the benzoic acid derivative might offer a potential structural basis for exploring materials for selected NLO applications.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"140-153"},"PeriodicalIF":1.3,"publicationDate":"2026-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, characterization and antimicrobial activity of fluoro-containing aroylhydrazones. 含氟芳基腙的合成、表征及抗菌活性研究。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-02 DOI: 10.17344/acsi.2025.9574

Lei Shi, Xiaoniu Hong, Xinyue Zhang, Fu-Ming Wang, Feng Guo

引用次数: 0

Nickel(II) complex derived from 5-phenyl-1,3,4-oxadiazole-2-thiol and dppe ligands: synthesis, crystal structure, cytotoxicity and theoretical studies. 5-苯基-1,3,4-恶二唑-2-硫醇和dppe配体衍生的镍（II）配合物：合成、晶体结构、细胞毒性和理论研究。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-01-01 DOI: 10.17344/acsi.2025.9603

Beriwan Muhamad Hamad Ameen, Karwan Omer Ali, Rezan Ali Saleh

引用次数: 0

Examining the chemical reasoning of pre-service science teachers using a multiple-choice test based on the essential questions-perspectives framework. 运用基于基本问题-视角框架的多项选择测验来检验职前科学教师的化学推理能力。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2025-12-31 DOI: 10.17344/acsi.2025.9556

Gülen Önal Karakoyun

{"title":"Examining the chemical reasoning of pre-service science teachers using a multiple-choice test based on the essential questions-perspectives framework.","authors":"Gülen Önal Karakoyun","doi":"10.17344/acsi.2025.9556","DOIUrl":"https://doi.org/10.17344/acsi.2025.9556","url":null,"abstract":"The purpose of this study is to examine the chemical reasoning levels of pre-service science teachers. For this purpose, an inventory developed by the researcher in accordance with the Essential Questions-Perspectives Framework (EQ-P) was used as a data collection tool. The inventory consists of thirty-six questions related to three fundamental question types and twelve chemical perspectives. A total of 265 pre-service science teachers from six universities in Turkey participated in the study. A survey model was used in the study. Findings showed that pre-service science teachers performed better on questions related to identification and description. Success was moderate for questions requiring explanation and prediction. Success was lowest for questions requiring transformation and synthesis. When evaluated according to perspectives, high success was observed on questions related to physical properties, structure, composition, and reaction properties. Success was moderate for questions related to particles, interactions, kinetics, and thermodynamics. Success was low for questions related to target molecules, starting materials, addition-removal and process control. The results indicated that the chemical reasoning levels of pre-service science teachers varied significantly depending on the fundamental question types and perspectives. The findings reveal that synthesis and design-oriented thinking should be supported more in chemistry teaching.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"174-182"},"PeriodicalIF":1.3,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0