Acta Chimica Slovenica最新文献_第6页

Structural investigations of the XeF2-PtF5 system: crystal structures of [Xe2F3][PtF6]·XeF2, [Xe2F3][PtF6], and [XeF][PtF6]. XeF2- ptf5体系的结构研究：[Xe2F3][PtF6]·XeF2， [Xe2F3][PtF6]和[XeF][PtF6]的晶体结构。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-03-05 DOI: 10.17344/acsi.2026.9768

Klemen Motaln, Matic Lozinšek

引用次数: 0

Non-spherical atom refinement applied in structure determination of (N2H6)(H3F4)2 and crystal structure re-determination of N2H6F2. 非球面原子精细化用于（N2H6）（H3F4）2的结构测定和N2H6F2的晶体结构再测定。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-25 DOI: 10.17344/acsi.2025.9601

Evgeny Goreshnik

引用次数: 0

Review of coatings used for corrosion protection of aluminium alloys. 铝合金防腐涂料的研究进展。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-23 DOI: 10.17344/acsi.2025.9686

Ingrid Milošev, Ana Koblar

{"title":"Review of coatings used for corrosion protection of aluminium alloys.","authors":"Ingrid Milošev, Ana Koblar","doi":"10.17344/acsi.2025.9686","DOIUrl":"https://doi.org/10.17344/acsi.2025.9686","url":null,"abstract":"Aluminium and aluminium alloys are major technological metals, offering desirable mechanical properties, low density, thermal and electrical conductivity. Importantly, they exhibit high recyclability. While these materials are relatively stable and corrosion-resistant in most environments, they are often subjected to corrosion and wear in harsh environments. Coatings are the most common method of corrosion protection of aluminium and its alloys. Coatings can improve not only corrosion resistance but also wear resistance, and can add functional properties to the surface. In the present review, the coatings are summarised in five groups: (1) barrier aluminium oxide coatings, including anodised coatings, plasma electrolytic oxidised coatings, coatings deposited by atomic layer deposition, and by hydrothermal treatment, (2) conversion coatings including zirconium, titanium, trivalent chromium, and phosphate (3) metallic coatings comprising clad and electroplated metal coatings, (4) organic coatings comprising powder and liquids organic coatings, and sol-gel coatings, and (5) inhibition and wettability control coatings, comprising coatings incorporating inhibitors or nanoparticles and superhydrophobic coatings. The review focuses on production methodologies and the physical-chemical characteristics of coatings. Advantages and potential shortcomings of individual coatings are discussed in terms of their use and corrosion protection.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"11-30"},"PeriodicalIF":1.3,"publicationDate":"2026-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study of thermal decomposition of (Ba0.7Ca0.3)TiO3 and Ba(Zr0.2Ti0.8)O3 xerogels and thin films. （Ba0.7Ca0.3）TiO3和Ba(Zr0.2Ti0.8)O3干凝胶和薄膜的热分解研究。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-22 DOI: 10.17344/acsi.2025.9607

Sabi William Konsago, Dean Birmančević, Jena Cilenšek, Brigita Kmet, Katarina Žiberna, Barbara Malič

引用次数: 0

Discriminating cinnamon species and geographic origin using HPLC-UV and chemometrics. 用HPLC-UV和化学计量学鉴别肉桂种类和地理来源。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-22 DOI: 10.17344/acsi.2025.9540

Jernej Markelj, Katja Kastelec, Matjaž Grčman, Drago Kočar

{"title":"Discriminating cinnamon species and geographic origin using HPLC-UV and chemometrics.","authors":"Jernej Markelj, Katja Kastelec, Matjaž Grčman, Drago Kočar","doi":"10.17344/acsi.2025.9540","DOIUrl":"10.17344/acsi.2025.9540","url":null,"abstract":"The aim of this study was to evaluate biomarkers for the differentiation and classification of cinnamon species and geographical origin. A reverse phase high performance liquid chromatography method with UV-Vis detection was used to quantify the following biomarkers: coumarin, cinnamic acid, cinnamaldehyde and eugenol. A total of 23 cinnamon samples were analysed and processed using chemometric methods. Besides commonly used principal component analysis, uniform manifold approximation and projection was also used for exploratory analysis. Next, combination of dimensions reduction and classification algorithms were used for the development of 16 classification models. The models were validated using the bootstrapping resampling method. The best classification was achieved with the combination of principal component analysis - regularised discriminant analysis model with an overall accuracy of 84.0% and 89.2% in discriminating cinnamon species and their geographical origin, respectively. In addition, the samples were successfully classified according to their shape and whether the cinnamon samples were certified as \"bio\" organic.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"279-287"},"PeriodicalIF":1.2,"publicationDate":"2026-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Overexpression of the erythropoietin receptor is associated with upregulation of tubulin beta 6 and paclitaxel resistance in ovarian adenocarcinoma cells. 促红细胞生成素受体的过度表达与卵巢腺癌细胞微管蛋白β 6的上调和紫杉醇耐药性有关。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-16 DOI: 10.17344/acsi.2025.9420

Pavol Harvanik, Kristína Danková, Zuzana Solárová, Martina Šemeláková, Mangesh Bhide, Peter Solár

{"title":"Overexpression of the erythropoietin receptor is associated with upregulation of tubulin beta 6 and paclitaxel resistance in ovarian adenocarcinoma cells.","authors":"Pavol Harvanik, Kristína Danková, Zuzana Solárová, Martina Šemeláková, Mangesh Bhide, Peter Solár","doi":"10.17344/acsi.2025.9420","DOIUrl":"10.17344/acsi.2025.9420","url":null,"abstract":"The emergence of tumor cell resistance is one of the major issues in current oncology practice. It reduces the effectiveness of therapy and worsens cancer patients' prognoses. However, it confirms a wide range of molecular interactions as well as the complexity of the human organism. Our previous research confirmed the functionality of the erythropoietin receptor (EPOR) in ovarian and breast cancer cells, as well as its relationship to these cells' sensitivity to specific therapies. The current study demonstrates that EPOR overexpression in human ovarian adenocarcinoma cells A2780 is directly linked to paclitaxel resistance. Furthermore, EPOR overexpression results in morphological changes that vary according to the pattern of EPOR isotypes expressed. In this regard, the most interesting result appears to be the change in the shape of the T clone, which has a tendency to form spheroidal structures. In addition, functional enrichment analysis demonstrated that EPOR-associated differentially expressed genes are involved in several biological and cell processes. Indeed, a T clone with a single 68 kDa EPOR isotype demonstrates significant resistance to paclitaxel therapy and is associated with the upregulation of tubulin beta 6.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"258-266"},"PeriodicalIF":1.2,"publicationDate":"2026-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

RSM-optimized extraction of essential oils from Pistacia lentiscus sap, leaves, and berries: Comparative study of composition and activity against gastric bacteria. 黄连木树液、叶子和浆果精油的rsm优化提取：成分和抗胃细菌活性的比较研究。

IF 1.2 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-16 DOI: 10.17344/acsi.2025.9584

Nazim Chibane, Noura Hamour, Nabila Benamrouche, Saoussene Hamrouche, Koceila Touag, Sofiane Fatmi

{"title":"RSM-optimized extraction of essential oils from Pistacia lentiscus sap, leaves, and berries: Comparative study of composition and activity against gastric bacteria.","authors":"Nazim Chibane, Noura Hamour, Nabila Benamrouche, Saoussene Hamrouche, Koceila Touag, Sofiane Fatmi","doi":"10.17344/acsi.2025.9584","DOIUrl":"10.17344/acsi.2025.9584","url":null,"abstract":"Pistacia lentiscus essential oil is widely recognized for its gastroprotective and antimicrobial properties; however, there is no clear consensus on which plant part exhibits the strongest activity against Helicobacter pylori. The objective of this study was to compare essential oils extracted from leaves, berries, and sap in terms of extraction yield, chemical composition, and antibacterial activity. Essential oils were extracted, characterized by GC-MS, and evaluated for antibacterial activity against H. pylori strains J99 and F29, as well as Staphylococcus aureus, Escherichia coli, and Pseudomonas aeruginosa. The sap showed the highest yield (9.218%). GC-MS analysis revealed monoterpenes and sesquiterpenes as the main constituents, with α-pinene present in all samples. The leaf essential oil exhibited the strongest inhibition against H. pylori, exceeding the tested antibiotics against the F29 strain. These findings indicate that P. lentiscus leaves represent the most promising natural source for anti-H. pylori activity and suggest that the effect is due to synergistic interactions rather than α-pinene alone.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"267-278"},"PeriodicalIF":1.2,"publicationDate":"2026-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, characterization, crystal structures and catalytic property of copper(II) and dioxidomolybdenum(VI) complexes derived from N'-(3-bromo-5-chloro-2-hydroxybenzylidene)-4-methylbenzohydrazide. N'-（3-溴-5-氯-2-羟基苄基）-4-甲基苯并肼衍生物铜（II）和二氧化钼（VI）配合物的合成、表征、晶体结构和催化性能

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-07 DOI: 10.17344/acsi.2025.9696

Fen-Yan Wei, Wei Liu

引用次数: 0

Syntheses, characterization and crystal structures of Schiff base zinc(II) complexes with antimicrobial activity. 具有抗菌活性的席夫碱锌（II）配合物的合成、表征和晶体结构。

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-07 DOI: 10.17344/acsi.2025.9699

Yi-Xin Chen, Shu-Juan Liu, Xin-Ran Chen, Bin-Hao Ye, Xiao-Yang Qiu

{"title":"Syntheses, characterization and crystal structures of Schiff base zinc(II) complexes with antimicrobial activity.","authors":"Yi-Xin Chen, Shu-Juan Liu, Xin-Ran Chen, Bin-Hao Ye, Xiao-Yang Qiu","doi":"10.17344/acsi.2025.9699","DOIUrl":"https://doi.org/10.17344/acsi.2025.9699","url":null,"abstract":"Three new zinc(II) complexes, [ZnL1(CH3OH)] (1), [ZnBrL2] (2), and [ZnBr2(HL3)]·CH3OH (3·CH3OH), where L1 is the dianionic form of N,N'-bis(4-bromosalicylidene)cyclohexane-1,2-diamine (H2L1), L2 is the monoanionic form of 5-bromo-2-(((3-morpholinopropyl)imino)methyl)phenol (HL2), and HL3 is the zwitterionic form of 5-bromo-2-(((2-(pyrrolidin-1-yl)ethyl)imino)methyl)phenol (HL3), were facile prepared by reaction of 1:1 molar ratio of the Schiff bases with zinc bromide in methanol. The complexes were characterized by IR and UV-Vis spectroscopy. Detailed structures of the three complexes were confirmed by single crystal X-ray determination. The Zn(II) atom in complex 1 has a square pyramidal coordination, with the Schiff base ligand L1 coordinated to the Zn(II) atom through phenolate oxygen and imino nitrogen atoms. The Zn(II) atom in complex 2 has a tetrahedral coordination, with the Schiff base ligand L2 coordinated to the Zn(II) atom through phenolate oxygen, imino nitrogen and morpholine nitrogen atoms. The Zn(II) atom in complex 3·CH3OH has a tetrahedral coordination, with the Schiff base ligand L3H coordinated to the Zn(II) atom through phenolate oxygen and imino nitrogen atoms. The remaining sites are occupied by one methanol oxygen atom for 1, one Br ligand for 2, and two Br ligands for 3·CH3OH. The compounds show significant antimicrobial activities.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"243-250"},"PeriodicalIF":1.3,"publicationDate":"2026-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, crystal structure and performance study of cadmium(II) complex with 1,10-phenanthroline and 2-methyl-3-hydroxyquinoline-4-carboxylate anion. 1,10-菲罗啉- 2-甲基-3-羟基喹啉-4-羧酸阴离子镉配合物的合成、晶体结构和性能研究

IF 1.3 4区化学

Acta Chimica Slovenica Pub Date : 2026-02-06 DOI: 10.17344/acsi.2025.9682

Ting-Qun Qiu, Fo-Gen Chen, Zhi-Qiang Yi, Qing-Feng Peng, Xiu-Guang Yi, Xiong-Yuan Wang, Yu-Sheng Liao

{"title":"Synthesis, crystal structure and performance study of cadmium(II) complex with 1,10-phenanthroline and 2-methyl-3-hydroxyquinoline-4-carboxylate anion.","authors":"Ting-Qun Qiu, Fo-Gen Chen, Zhi-Qiang Yi, Qing-Feng Peng, Xiu-Guang Yi, Xiong-Yuan Wang, Yu-Sheng Liao","doi":"10.17344/acsi.2025.9682","DOIUrl":"https://doi.org/10.17344/acsi.2025.9682","url":null,"abstract":"The present work employs a hydrothermal method to synthesize a novel Cd(II) inorganic-organic hybrid luminescent complex [Cd(phen)2Cl(H2O)]L·3H2O (L = 2-methyl-3-hydroxyquinoline-4-carboxylate anion, phen = 1,10-phenanthroline). The crystallographic analysis indicates that Cd(II) center exhibits a distorted octahedral coordination geometry, where two phen ligands form a bidentate chelate, while the deprotonated 2-methyl-3-hydroxyquinoline-4-carboxylate anion (L⁻) acts as a charge-balancing lattice anion. The solid-state UV-Vis diffuse reflectance spectroscopy (DRS) reveals an optical band gap of 4.69 eV (wide-gap semiconductor). Upon excitation at 385 nm, the complex exhibits blue-green fluorescence with an emission peak at 456 nm (CIE: 0.2247, 0.2545), indicating its potential as a blue-green emitting material. Thermogravimetric analysis (TGA) shows a three-step decomposition process, suggesting good thermal stability. The work offers a new structural paradigm for Cd(II)-based blue-green emitters.","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"73 1","pages":"251-257"},"PeriodicalIF":1.3,"publicationDate":"2026-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147589382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0