Acta Chimica Slovenica最新文献

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Phytochemical analysis and evaluation of the antioxidant, anti-inflammatory, hemolytic, and antibacterial effects of Astragalus gombo (L.) leaves. 黄芪(L.)叶的植物化学分析及抗氧化、抗炎、溶血和抗菌效果评估
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-08-27 DOI: 10.17344/acsi.2024.8748
Mohammed Laid Tlili, Ibtissam Laib, Khadidja Salemi, Imane Chetehouna, Ines Ben Moussa
{"title":"Phytochemical analysis and evaluation of the antioxidant, anti-inflammatory, hemolytic, and antibacterial effects of Astragalus gombo (L.) leaves.","authors":"Mohammed Laid Tlili, Ibtissam Laib, Khadidja Salemi, Imane Chetehouna, Ines Ben Moussa","doi":"10.17344/acsi.2024.8748","DOIUrl":"10.17344/acsi.2024.8748","url":null,"abstract":"<p><p>The purpose of this study is to determine the phytochemical content and biological activities of the Astragalus gombo (endemic specie). While identification and quantification of individual secondary metabolites were performed by analysis HPLC. Antioxidant (DPPH and FRAP), anti-inflammatory, anti-hemolytic and antibacterial activities were evaluated. For analysis HPLC, we obtained 65 peaks and identified 6 major bioactive compounds. The total concentration in polyphenols, flavonoids and condensed tannins varied respectively from 66.306±0.88 mg GA eq/g, 34.312±1.4 mg Q eq/g and 5.343±2.74 mg Ca eq/g. In terms of antioxidant activity, we found that this extract had high inhibitory ratios equivalent to IC50=62.813±0.006 µg/mL for DPPH and IC50=19.375±0.041 µg/mL for FRAP.  A high anti-inflammatory activity was estimated at 1615.81µg/mL, and a weak anti-hemolytic activity, the other hand the antibacterial activity is somewhat moderate against the five strains studied. This study demonstrated that the aqueous extract of A. gombo from El Oued region has tremendous antioxidant, anti-inflammatory and antibacterial abilities.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 3","pages":"492-499"},"PeriodicalIF":1.2,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Validation of high-resolution continuum source flame atomic absorption spectrometry for determination of selected toxic and potential toxic metals in the decontamination process of wastewater discharged in natural receivers. 验证高分辨率连续源火焰原子吸收光谱法测定天然接收器中排放的废水净化过程中的特定有毒和潜在有毒金属。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-08-27 DOI: 10.17344/acsi.2023.8534
Bame Sanah Senna, Wellington Masamba, Veronica Obuseng, Tiberiu Frentiu, Bogdan Simion Angyus, Eniko Covaci
{"title":"Validation of high-resolution continuum source flame atomic absorption spectrometry for determination of selected toxic and potential toxic metals in the decontamination process of wastewater discharged in natural receivers.","authors":"Bame Sanah Senna, Wellington Masamba, Veronica Obuseng, Tiberiu Frentiu, Bogdan Simion Angyus, Eniko Covaci","doi":"10.17344/acsi.2023.8534","DOIUrl":"https://doi.org/10.17344/acsi.2023.8534","url":null,"abstract":"<p><p>A new method based on high-resolution continuum source flame atomic absorption spectrometry (HR-CS-FAAS) was validated for the determination of selected toxic and potentially toxic metals in wastewater resulting from mining activity. The results were compared with inductively coupled plasma optical emission spectrometry (ICP-OES). The HR-CS-FAAS method was characterized by detection limits in the range (µg L-1) 0.9(Mn)-33.6(Pb), better than ICP-OES for Cu, Fe, Ni, Co, Pb and Mn, and poorer for Cd, Zn and Cr. The Dunnett's and Tukey's statistical test showed that both methods were not affected by significant bias against certified value and between them. The recovery in HR-CS-FAAS method was in the range of 98-103% with relative extended uncertainty of 9-25%, and precision of 1.5-14.1%. The results indicated that the HR-CS-FAAS method is suitable for the determination of toxic and potentially toxic elements directly in filtered water samples without any chemical treatment.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 3","pages":"500-508"},"PeriodicalIF":1.2,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of eutectics of pioglitazone with citric acid and its effect on crystallite properties and dissolution. 吡格列酮与柠檬酸共晶的开发及其对结晶特性和溶解的影响
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-08-27 DOI: 10.17344/acsi.2024.8793
Mouli Das, Shibashis Panigrahy, Rasmita Dash, Rudra Narayan Sahoo, Rakesh Swain, Souvik Nandi, Sk Habibullah, Tanisha Das, Subrata Mallick
{"title":"Development of eutectics of pioglitazone with citric acid and its effect on crystallite properties and dissolution.","authors":"Mouli Das, Shibashis Panigrahy, Rasmita Dash, Rudra Narayan Sahoo, Rakesh Swain, Souvik Nandi, Sk Habibullah, Tanisha Das, Subrata Mallick","doi":"10.17344/acsi.2024.8793","DOIUrl":"https://doi.org/10.17344/acsi.2024.8793","url":null,"abstract":"<p><p>Eutectics of pioglitazone were developed using citric acid (CA) as the co-former, and the effect on crystallite properties and dissolution has correspondingly been studied. Pioglitazone-citric acid eutectics (PC1, PC2, PC3, and PC4) in different molar ratios (3:1, 3:2, 1:1, and 3:4 respectively) were prepared by simple solvent evaporation method. Difference in dislocation density and strain value of the eutectics were observed, and the maximum strain value of PC1 might be due to the highest deformation activity compared to PC2, PC3, and PC4. Carbonyl-thiazolidine or carboxyl-pyridine weak bond formation might be the reason of producing eutectics of PGZ-CA rather than cocrystal with a docking score of - 2.2 Kcal/M. Likewise, lowest particle size was found with PC1 rather than that of pure PGZ and other eutectics. PC1 demonstrated highest dissolution of drug (68 %) rather than other eutectics (54 to 61 %) and PGZ (44 %) after 360 min.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 3","pages":"482-491"},"PeriodicalIF":1.2,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterization and DFT study of Ti(IV) phthalocyanines with quinoline groups. 带有喹啉基团的 Ti(IV) 酞菁的合成、表征和 DFT 研究。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-08-21 DOI: 10.17344/acsi.2024.8813
Seyda Aydogdu, Oznur Dulger Kutlu, Ali Erdogmus, Arzu Hatipoglu
{"title":"Synthesis, characterization and DFT study of Ti(IV) phthalocyanines with quinoline groups.","authors":"Seyda Aydogdu, Oznur Dulger Kutlu, Ali Erdogmus, Arzu Hatipoglu","doi":"10.17344/acsi.2024.8813","DOIUrl":"https://doi.org/10.17344/acsi.2024.8813","url":null,"abstract":"<p><p>The synthesis, characterization, and electronic properties of 4-((7-methoxyquinolin-4-yl)oxy), 4-(quinolin-2-ylthio), and 4-((7-(trifluoromethyl)quinolin-4-yl)thio) peripherally substituted oxo-titanium phthalocyanines are described for the first time. The structures of the compounds were determined by UV-Vis, FTIR, 1H NMR, and MALDI-TOF mass spectrometry. Electronic spectra and molecular and electronic properties of compounds were calculated by Density Functional Theory (DFT) and Time-Dependent Density Functional Theory (TD-DFT) methods. Solvent effects on the electronic, geometric, and reactivity properties of the compounds were also investigated. Global and local reactivity indices and Molecular Electrostatic Potential surfaces of compounds were calculated. The reactivities and electronic structures of molecules vary depending on the solvent and substituents. It has been found that the synthesized compounds can be used for different purposes such as dye-sensitized solar cells and photodynamic therapy applications.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 3","pages":"437-450"},"PeriodicalIF":1.2,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring Teachers' Technological Pedagogical Content Knowledge as an Indicator for the Planning of In-service Teacher Training in Chemistry Education. 探索将教师的技术教学内容知识作为规划化学教育在职教师培训的指标。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-08-21 DOI: 10.17344/acsi.2024.8783
Mojca Orel, Cirila Peklaj, Vesna Ferk Savec
{"title":"Exploring Teachers' Technological Pedagogical Content Knowledge as an Indicator for the Planning of In-service Teacher Training in Chemistry Education.","authors":"Mojca Orel, Cirila Peklaj, Vesna Ferk Savec","doi":"10.17344/acsi.2024.8783","DOIUrl":"https://doi.org/10.17344/acsi.2024.8783","url":null,"abstract":"<p><p>This study examined how teachers teaching chemistry at different levels of education perceive their levels of technological pedagogical content knowledge (TPACK) and examined the relationship of TPACK with age, gender, teaching at different levels of education, time spent teaching chemistry, and frequency of information and communication technology (ICT) use. The study involved 261 teachers, 246 women and 15 men, from all over Slovenia, who have been teaching chemistry for an average of 18 years at different levels of education, with an average age of 45 years. The results showed that teachers teaching chemistry content perceive a high level of TPACK. There is a statistically significant correlation between age, time spent teaching chemistry, and frequency of ICT use with the perceived level of technological pedagogical content knowledge. Younger teachers, those with less professional experience and teachers who use ICT more frequently rated their TPACK higher. Based on the results of the survey, guidelines for planning the in-service teacher training that would support the development of TPACK of teachers teaching chemistry content were developed.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 3","pages":"451-461"},"PeriodicalIF":1.2,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of porous imidazole-based poly(ionic liquid) adsorbents and their toluene adsorption performance. 多孔咪唑基聚(离子液体)吸附剂的制备及其甲苯吸附性能。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-08-21 DOI: 10.17344/acsi.2024.8622
Fangwen Luo, Xujiao Tian, Xian Dong, Longchao Liang, Zhuo Chen
{"title":"Preparation of porous imidazole-based poly(ionic liquid) adsorbents and their toluene adsorption performance.","authors":"Fangwen Luo, Xujiao Tian, Xian Dong, Longchao Liang, Zhuo Chen","doi":"10.17344/acsi.2024.8622","DOIUrl":"https://doi.org/10.17344/acsi.2024.8622","url":null,"abstract":"<p><p>Efficient, economical, and durable adsorbents are required to remove volatile organic compounds (VOCs) from air. Cross-linked polyvinylic ionic liquids (PVIC) with porous structures were synthesized by quaternizing 1-vinylimidazole (1VI) with 1-bromobutane to obtain 3-butyl-1-vinylimidazolium bromide (VIC), which was then co-polymerized with divinylbenzene (DVB) radicals. 1H NMR, 13C NMR, scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, and N2 adsorption-desorption isotherms were applied in characterizing the composites. Through modification of the polymer structure by adjustment of DVB concentration(the ratio of DVB concentration to VIC concentration was x: 1 (x=0.4, 0.6, 0.8, 1.0) and the product was named PVIC-s (s=2, 3, 4, 5)), the optimal PVIC-4 pore structure was obtained, with a specific surface area and total pore volume of 192.5 m2 g-1 and 0.192 cm3 g-1, respectively. A toluene adsorption test verified the adsorption capacity. The adsorption behavior for VOCs, based on toluene, was investigated using adsorption breakthrough curves, adsorption kinetics, and isotherms. The adsorption process is well describing by the Bangham kinetic and Langmuir isotherm models. The dynamic adsorption of toluene followed the order PVIC-4 > PVIC-5 > PVIC-3 > PVIC-2. The optimum toluene adsorption by PVIC-4 was 264.4 mg g-1 as a result of its excellent pore structure. PVIC-4 also performed well in terms of recovery and has potential for the removal of VOCs from air.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 3","pages":"471-481"},"PeriodicalIF":1.2,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, crystal structures and antibacterial activity of nickel(II), cadmium(II) and zinc(II) complexes with hydrazone ligands. 含腙配体的镍(II)、镉(II)和锌(II)配合物的合成、晶体结构和抗菌活性。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-08-21 DOI: 10.17344/acsi.2024.8763
Wei-Guang Zhang
{"title":"Synthesis, crystal structures and antibacterial activity of nickel(II), cadmium(II) and zinc(II) complexes with hydrazone ligands.","authors":"Wei-Guang Zhang","doi":"10.17344/acsi.2024.8763","DOIUrl":"10.17344/acsi.2024.8763","url":null,"abstract":"<p><p>Three mononuclear nickel(II), cadmium(II) and zinc(II) complexes, [NiL2]·2CH3OH·H2O (1), [CdI2(HL)]·CH3OH (2) and [ZnL2] (3), have been synthesized from 3-hydroxy-4-methoxy-N'-[(Z)-(pyridin-2-yl)methylidene]benzohydrazide (HL) by microwave irradiation method. All complexes were characterized by CHN elemental analyses and infrared spectra. Structures of the complexes were further studied by single crystal X-ray determination, which reveals that the Ni and Zn atoms in complexes 1 and 3 are in octahedral coordination, and the Cd atom in complex 2 is in square pyramidal coordination. The biological activity of the complexes on the bacterial strains Bacillus subtilis, Staphylococcus aureus, Pseudomonas aeruginosa and Escherichia coli was evaluated. As a result, the zinc complex has interesting antibacterial activities.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 3","pages":"462-470"},"PeriodicalIF":1.2,"publicationDate":"2024-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142339080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
DRUŠTVENE VESTI IN DRUGE AKTIVNOSTI SOCIETY NEWS, ANNOUNCEMENTS, ACTIVITIES. društvene vesti in druge aktivnosti 社会新闻、公告和活动。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-06-20
{"title":"DRUŠTVENE VESTI IN DRUGE AKTIVNOSTI SOCIETY NEWS, ANNOUNCEMENTS, ACTIVITIES.","authors":"","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 2","pages":"S49-S74"},"PeriodicalIF":1.2,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141449335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The reusage of different wastes by using the multiple's effect technique for sustainable gasoline production. 利用多重效应技术重新利用不同废物,实现汽油的可持续生产。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-06-13 DOI: 10.17344/acsi.2024.8714
Anita Kovač Kralj
{"title":"The reusage of different wastes by using the multiple's effect technique for sustainable gasoline production.","authors":"Anita Kovač Kralj","doi":"10.17344/acsi.2024.8714","DOIUrl":"https://doi.org/10.17344/acsi.2024.8714","url":null,"abstract":"<p><p>The unused garbage which is accumulating the landfills, such as raw materials, could be reused for synthetic gasoline production. This study presents the multiple's effect technique, which is based on the reusage of different non, party and sorted municipal solid wastes (MSW), or biogas for syngas, converted into synthetic gasoline. The novelties of this technique include a basic multiple's effect parameter (MUW), which present a level of waste sorting, an effect of oxygen inhibition into different wastes, a simplified mathematical model and simulation with an Aspen Plus® simulator using the retrofitted methanol plan converted into the synthetic gasoline production. This technique includes a circular economy by using a circulated purified flue gas as raw material, co-products of hydrogen and water. This technique was tested on an existing methanol process, replacing natural gas with different alternatives of wastes or biogas for the synthetic gasoline production. The best alternative was the sorted MSW, which could generate an additional profit of 4.8 MEUR/a, including the garbage and CO2 emission reductions of 0.106·106 t/a and of 0.084 ·106 t/a.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 2","pages":"388-397"},"PeriodicalIF":1.2,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141449295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation, Structures, Photoluminescence and Semiconductive Properties of Two Novel Lanthanide Mercury Materials with a 3-D Framework Structure. 两种具有三维框架结构的新型镧系汞材料的制备、结构、光致发光和半导体特性。
IF 1.2 4区 化学
Acta Chimica Slovenica Pub Date : 2024-06-11 DOI: 10.17344/acsi.2024.8661
Wen-Tong Chen, Hao-Dong Liu, Xi-Yu Shao, Yu-Yue Xu, Cheng Liu, Sheng-Ping Dai, Chang-Wang Pan
{"title":"Preparation, Structures, Photoluminescence and Semiconductive Properties of Two Novel Lanthanide Mercury Materials with a 3-D Framework Structure.","authors":"Wen-Tong Chen, Hao-Dong Liu, Xi-Yu Shao, Yu-Yue Xu, Cheng Liu, Sheng-Ping Dai, Chang-Wang Pan","doi":"10.17344/acsi.2024.8661","DOIUrl":"https://doi.org/10.17344/acsi.2024.8661","url":null,"abstract":"<p><p>Two novel lanthanide mercury materials, [Gd(IA)3(H3O)2Hg3Br6]n·2nCl (1) and [La(IA)3(H3O)2Hg3Br6]n·2nCl (2) (IA = isonicotinic anion), have been prepared under solvothermal conditions and characterized by single-crystal X-ray diffraction techniques. They are isomorphic and characterized by a three-dimensional (3-D) framework structure. The lanthanide ions are bound by eight oxygen atoms to exhibit a square antiprismatic geometry. The solid-state photoluminescence experiment discovers that compound 1 shows a strong emission in the red region. Compound 1 possesses CIE (Commission Internationale de I'Éclairage) chromaticity coordinates of 0.7347 and 0.2653. Its CCT (correlated color temperature) is 6514 K. Compound 2 displays yellow photoluminescence and it has CIE chromaticity coordinates of 0.4411 and 0.5151. The CCT of compound 2 is 3633 K. Solid-state UV/Vis diffuse reflectance spectra revealed that their semiconductor band gaps are 2.16 eV and 2.85 eV, respectively.</p>","PeriodicalId":7122,"journal":{"name":"Acta Chimica Slovenica","volume":"71 2","pages":"380-387"},"PeriodicalIF":1.2,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141449262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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