Journal of the Australian Ceramic Society最新文献

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High thermal stability of the dielectric properties of the La2Ti2O7—La4Ti9O24 composites under temperature variation La2Ti2O7-La4Ti9O24复合材料的介电性能在温度变化下具有较高的热稳定性
IF 2.1 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-26 DOI: 10.1007/s41779-024-01106-7
Francisco Enilton Alves Nogueira, José Wagner de Oliveira Bezerra, Daniel Barros de Freitas, João Paulo Costa do Nascimento, Tallison Oliveira Abreu, Francisco Alekson Chaves Nobrega, Roterdan Fernandes Abreu, Marcos José Pereira Alves, Paulo Maria de Oliveira Silva, Ronaldo Glauber Maia de Oliveira, Felipe Felix do Carmo, Marcelo Antonio Santos da Silva, Ronaldo Santos da Silva, Antonio Sergio Bezerra Sombra
{"title":"High thermal stability of the dielectric properties of the La2Ti2O7—La4Ti9O24 composites under temperature variation","authors":"Francisco Enilton Alves Nogueira,&nbsp;José Wagner de Oliveira Bezerra,&nbsp;Daniel Barros de Freitas,&nbsp;João Paulo Costa do Nascimento,&nbsp;Tallison Oliveira Abreu,&nbsp;Francisco Alekson Chaves Nobrega,&nbsp;Roterdan Fernandes Abreu,&nbsp;Marcos José Pereira Alves,&nbsp;Paulo Maria de Oliveira Silva,&nbsp;Ronaldo Glauber Maia de Oliveira,&nbsp;Felipe Felix do Carmo,&nbsp;Marcelo Antonio Santos da Silva,&nbsp;Ronaldo Santos da Silva,&nbsp;Antonio Sergio Bezerra Sombra","doi":"10.1007/s41779-024-01106-7","DOIUrl":"10.1007/s41779-024-01106-7","url":null,"abstract":"<div><p>In this work, an experimental and numerical investigation of the dielectric properties in the radio frequency (RF) and microwave (MW) regions of the La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>—La<sub>4</sub>Ti<sub>9</sub>O<sub>24</sub> composites was conducted. X-ray diffraction demonstrated that there was a reaction between La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> (LTO) and TiO<sub>2</sub>, resulting in the formation of La<sub>4</sub>Ti<sub>9</sub>O<sub>24</sub>. Electrical studies in the RF region demonstrated that the composites presented a thermally activated process with activation energy values between 1.50 and 2.30 eV, indicating that the addition provided an increase in activation energy (E<sub>a</sub>). In the MW region, an increase in the permittivity (ε'<sub>r</sub>) and dielectric loss (tan δ) was observed with the increased presence of La<sub>4</sub>Ti<sub>9</sub>O<sub>24</sub>, as well as a change in the temperature coefficient (τ<sub>f</sub>). The materials were tested as dielectric resonator antennas (DRA), showing reflection coefficients below –10 dB, realised gain between 4.18 and 4.97 dBi, bandwidth varying from 73 to 207 MHz, and radiation efficiency above 75%. These results show that La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>—La<sub>4</sub>Ti<sub>9</sub>O<sub>24</sub> composites are promising candidates for use in electronic circuits in the radiofrequency and microwave regions.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 3","pages":"887 - 895"},"PeriodicalIF":2.1,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145170174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of peanut husk derived heat-treated Si3N4 on load bearing properties of basalt fibre-reinforced polyester composite 花生壳衍生热处理氮化硅对玄武岩纤维增强聚酯复合材料承载性能的影响
IF 2.1 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-25 DOI: 10.1007/s41779-024-01104-9
S. Jeevanantham, Seeniappan Kaliappan, L. Natrayan, M. Muthukannan
{"title":"Influence of peanut husk derived heat-treated Si3N4 on load bearing properties of basalt fibre-reinforced polyester composite","authors":"S. Jeevanantham,&nbsp;Seeniappan Kaliappan,&nbsp;L. Natrayan,&nbsp;M. Muthukannan","doi":"10.1007/s41779-024-01104-9","DOIUrl":"10.1007/s41779-024-01104-9","url":null,"abstract":"<div><p>This study looks into how heat-treated bio-ceramic (Si3N4) affects the mechanical, wear, thermal, flammability, and microstructure characteristics of polyester composites reinforced with basalt fibers. Peanut husks were used to prepare the Si3N4, which was then heat-treated at 1200oC to remove any remaining tensions. The hand layup method was used to create the composites, and they were post-cured. The results show that the RBS2 (3 vol% Si3N4) composite has better mechanical properties than the other composites, R, RB, RBS1, RBS2, and RBS3 (5 vol% Si3N4). Its improved tensile strength is 61 MPa, and its flexural strength is 113 MPa. It is also shown that a composite constructed with 3% volume percent of heat-treated Si3N4 particle has an increased Izod impact strength of 4.21 J. Furthermore, under varying stress levels, the composite RBS2 exhibits longer fatigue life cycles. Conversely, the composite RBS3 shows better wear resistance, with a 0.32 coefficient of friction and a specific wear rate of 0.0098 mm<sup>3</sup>/Nm. With a glass transition (TG) temperature of 90 °C and an initial breakdown temperature of 381 °C, the RBS3 composite also showed enhanced thermal stability. In line with the flammability findings, every composite obtained a UL-94 rating of V-0, indicating exceptional fire resistance. Finally, the enhanced filler dispersion and interfacial bonding with resin are verified by scanning electron microscopy (SEM) examination. These results highlight these composites’ potential for uses requiring high levels of wear resistance, fire resistance, thermal stability, and mechanical strength.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 3","pages":"855 - 867"},"PeriodicalIF":2.1,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145169049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tobacco stem extract-mediated green synthesis of Fe-doped ZnO nanoparticles towards enhanced photocatalytic degradation of methylene blue and solar cell efficiency 烟草茎提取物介导的绿色合成fe掺杂ZnO纳米颗粒对提高光催化降解亚甲基蓝和太阳能电池效率的作用
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-24 DOI: 10.1007/s41779-024-01101-y
Orhan Baytar, Arzu Ekinci, Sinan Kutluay, Gurbet Canpolat, Ömer Şahin, Sabit Horoz
{"title":"Tobacco stem extract-mediated green synthesis of Fe-doped ZnO nanoparticles towards enhanced photocatalytic degradation of methylene blue and solar cell efficiency","authors":"Orhan Baytar,&nbsp;Arzu Ekinci,&nbsp;Sinan Kutluay,&nbsp;Gurbet Canpolat,&nbsp;Ömer Şahin,&nbsp;Sabit Horoz","doi":"10.1007/s41779-024-01101-y","DOIUrl":"10.1007/s41779-024-01101-y","url":null,"abstract":"<div><p>This study presents an innovative method for the synthesis of zinc oxide (ZnO) and iron-doped zinc oxide (Fe-doped ZnO) nanoparticles (NPs), employing extracts derived from tobacco stems. The environmentally friendly green synthesis process here represents the novelty of production and applications. Various analytical techniques including FT-IR, XRD, EDX, SEM and TEM were used to characterise ZnO and Fe-doped ZnO NPs. The study reveals that 1% Fe-doped ZnO NPs demonstrate markedly improved photocatalytic performance, attributed to a narrower band gap and enhanced charge separation. These NPs effectively promote the photocatalytic degradation of methylene blue, a promising approach for wastewater treatment and pollution control. Furthermore, the investigation of Fe-doped ZnO NPs in solar cells demonstrates their potential to substantially improve solar energy conversion efficiency. This novel approach paves the way for sustainable and eco-friendly advancements in both photocatalysis and photovoltaic technologies.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 5","pages":"1697 - 1708"},"PeriodicalIF":1.8,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142778547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effectiveness of Zeolite [LTA] amendment in improving the growth of cherry tomato (Solanum lycopersicum) and its physicochemical properties of soil 沸石[LTA]改良剂对樱桃番茄生长及土壤理化性质的影响
IF 2.1 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-24 DOI: 10.1007/s41779-024-01105-8
Norsuhailizah Sazali, Zawati Harun, Norazlianie Sazali
{"title":"Effectiveness of Zeolite [LTA] amendment in improving the growth of cherry tomato (Solanum lycopersicum) and its physicochemical properties of soil","authors":"Norsuhailizah Sazali,&nbsp;Zawati Harun,&nbsp;Norazlianie Sazali","doi":"10.1007/s41779-024-01105-8","DOIUrl":"10.1007/s41779-024-01105-8","url":null,"abstract":"<div><p>In the agriculture sector, optimizing the yield becomes the main purpose in this industry which can be achieved by introducing zeolite which acts as a soil amendment in the plant. To achieve this purpose, the study analyzed the effectiveness of the synthesis of zeolite LTA amended in the soil to increase the growth characteristics of cherry tomatoes and the physicochemical properties of the soil. Zeolite LTA is a synthetic zeolite characterized by a unique crystalline structure, possessing a high cation exchange capacity that enhances nutrient retention, moisture retention, and soil structure improvement. For the method of study, seven different treatments including three control treatments with no zeolite added and four treatments with zeolite added per plant in 1000 g of soil were analyzed to determine the optimum ratio of soil and fertilizer. The implementation of the Least Significant Difference (LSD) post-hoc test (<i>P</i> ≤ 0.05) enables the effectiveness of measurement of all plant treatments towards the plant growth and physicochemical analysis of soil. The plant growth results, including plant height, number of leaves, and stem width diameter, at harvest 1, 2, and 3 revealed that the 6gZ amended in soil has a higher significant difference towards the other treatments. Regarding cherry tomato weight, 6gz exhibits 18.31% heavier compared to the control height, 12.9% heavier compared to the control low, and 18.51% heavier compared to 4gZ. Additionally, 6gZ has the greatest disparity in plant height percentages when compared to the control standard, with a difference of 26.17%. For physical analysis of soil (water content capacity, soil moisture, soil organic content) and chemical analysis (total available nutrient), 6gZ also gives a higher significant effect than other treatments. In conclusion, analysis from all results performance experiments indicates that 6gZ was capable of increasing the yield of plants.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 3","pages":"869 - 886"},"PeriodicalIF":2.1,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145169520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis of cellulose nanocrystals from bio-renewable resources and their potential biological applications: A critical review 利用生物可再生资源绿色合成纤维素纳米晶体及其潜在的生物学应用综述
IF 2.1 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-19 DOI: 10.1007/s41779-024-01099-3
Elahe Kamelnia, Reyhane Kamelnia, Majid Darroudi
{"title":"Green synthesis of cellulose nanocrystals from bio-renewable resources and their potential biological applications: A critical review","authors":"Elahe Kamelnia,&nbsp;Reyhane Kamelnia,&nbsp;Majid Darroudi","doi":"10.1007/s41779-024-01099-3","DOIUrl":"10.1007/s41779-024-01099-3","url":null,"abstract":"<div><p>Nanocellulose refers to free nano-sized crystallites and fibrils isolated from cellulose-based biomass called cellulose nanocrystals (CNC). Cellulose is famous for its unending abundance on earth as a renewable and environmentally friendly biopolymer. The extending investment in nanocellulose is due to its diverse applications throughout the fields of material science and biomedical engineering, which is facilitated by its sustainable creation, anisotropic anatomy, unique mechanical features, satisfying biocompatibility, and adaptable surfaced chemistry. The crucial functionality of its physicochemical properties, including size, mass status in liquid, and surface charge, in the ultimate interactions of nanoparticles with target subjects, is undeniable. The four fundamental sources of nanocellulose are bacteria (<i>Gluconacetobacter</i>), plants (trees, shrubs, and herbs), algae (<i>Cladophora</i>), and animals (<i>Tunicata</i>). This review provides an extensive survey of cellulose and its structural and biomedical properties. Furthermore, it attempted to gather data on this emerging nanomaterial and particularly focused on the extraction processes, technological progress, and exertion of CNC-based materials. The following sections discuss on the impact of these products on decreasing the rate of cytotoxicity in biological surroundings. Lastly, we presented an overview of the development of CNC-based materials implementation to gather data on the imaginable and futuristic uses of CNC-based functional nanomaterials and their future aspects in biomedical engineering applications.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 section","pages":"77 - 99"},"PeriodicalIF":2.1,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reviewing and exploring boron oxide’s role in bioactive glasses: a synthesis of modeling and applications 氧化硼在生物活性玻璃中的作用综述与探索:建模与应用综述
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-17 DOI: 10.1007/s41779-024-01103-w
Takwa E. Ellakwa, Ayman Ellakwa, Ahmad S. Abu-Khadra, Hosam M. Gomaa, Fakiha El-Taib Heakal, Doha El-Sayed Ellakwa
{"title":"Reviewing and exploring boron oxide’s role in bioactive glasses: a synthesis of modeling and applications","authors":"Takwa E. Ellakwa,&nbsp;Ayman Ellakwa,&nbsp;Ahmad S. Abu-Khadra,&nbsp;Hosam M. Gomaa,&nbsp;Fakiha El-Taib Heakal,&nbsp;Doha El-Sayed Ellakwa","doi":"10.1007/s41779-024-01103-w","DOIUrl":"10.1007/s41779-024-01103-w","url":null,"abstract":"<div><p>Bioactive glasses, especially those based on borate, are characterized by their unique structural and mechanical properties, which are significantly influenced by boron content. Optimal boron levels enhance the thermal stability and bioactivity of these glasses, while excessive boron can degrade mechanical strength due to weaker -B-O-Si bonds. These materials are utilized in a range of applications, including bone regeneration, wound healing, and dental treatments. Advances in production methods, such as sol-gel techniques and melt-quenching, have led to improvements in their performance. Recent developments have produced bioglasses with enhanced antibacterial properties for blood-contact applications and those suitable for vascular tissue engineering. Comparatively, borate glasses convert to hydroxyapatite more rapidly than silicate glasses, providing advantages in medical applications. The bioactive potential of these materials is further enhanced by innovations like ion exchange and the creation of composite structures. Research continues to focus on optimizing these glasses to improve their bioactivity, mechanical properties, and adaptability to specific medical needs. The evolving field of bioactive glasses demonstrates significant promise for advancing tissue engineering and regenerative medicine, addressing both functional and biological requirements in various clinical settings.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 2","pages":"719 - 732"},"PeriodicalIF":1.8,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of contemporary polishing systems on hardness and roughness of one-shaded dental composites 现代抛光系统对单面牙复合材料硬度和粗糙度的影响
IF 2.1 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-16 DOI: 10.1007/s41779-024-01100-z
Kivanc Dulger, Gencaga Purcek
{"title":"Effect of contemporary polishing systems on hardness and roughness of one-shaded dental composites","authors":"Kivanc Dulger,&nbsp;Gencaga Purcek","doi":"10.1007/s41779-024-01100-z","DOIUrl":"10.1007/s41779-024-01100-z","url":null,"abstract":"<div><p>One-shaded dental composites have gained importance in dental practices because they can match a tooth’s color in a short period of time. Polishing is an important step in dental treatments. Therefore, the aim of the present study is to evaluate the effects of contemporary polishing systems on the hardness and roughness of one-shaded dental composites. Three one-shaded dental composites (Omnichroma (OMN), Charisma Diamond One (CDO), and Vittra Unique APS (VUA)) were used to prepare composite specimens (<i>n</i> = 120). For each group besides the control one (<i>n</i> = 10), the specimens were randomly divided into three polishing systems: Sof-Lex Discs (SLD), Clearfil Twist Dia (CTD), and Optionestep (OSP). Microhardness measurements were performed using Vickers hardness. Surface roughness values were determined using a contact profilometer. The data were analyzed using two-way ANOVA and two-way robust ANOVA tests at a significance level of 0.05 for both results. One representative sample from each group was examined with scanning electron microscopy (SEM) and SEM- Energy Dispersive X-Ray Spectroscopy <b>(</b>EDX). The control group of VUA had the lowest hardness value, while the CDO polished with SLD had the highest hardness value. The control group of CDO had the highest roughness value, while the OMN polished by SLD had the lowest roughness value. All the polishing systems caused some micro-stratches or micro-grooves on the surface of one-shaded dental composites owing to the effect of abrasive particles in the polishing systems. Polishing systems were found to have an important effect on the hardness of the one-shaded dental composites. Two-step polishing may be used instead of four-step polishing systems to shorten dental treatments on one-shaded composites.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 3","pages":"841 - 854"},"PeriodicalIF":2.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145165546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dielectric and magnetic properties of Fe-doped CdTiO3 ilmenite ceramics 掺铁CdTiO3钛铁矿陶瓷的介电和磁性能
IF 2.1 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-04 DOI: 10.1007/s41779-024-01095-7
R. Belfkih, M. Joghlaf, N. Gouitaa, M. Ahabboud, T. Lamcharfi
{"title":"Dielectric and magnetic properties of Fe-doped CdTiO3 ilmenite ceramics","authors":"R. Belfkih,&nbsp;M. Joghlaf,&nbsp;N. Gouitaa,&nbsp;M. Ahabboud,&nbsp;T. Lamcharfi","doi":"10.1007/s41779-024-01095-7","DOIUrl":"10.1007/s41779-024-01095-7","url":null,"abstract":"<div><p>Fe-doped CdTiO<sub>3</sub> powders were synthesized using the sol–gel method with new precursors and titanium tetraisopropoxide. The samples were characterized by X-ray diffraction (XRD), which confirmed that all samples exhibited the ilmenite structure, along with secondary traces of TiO<sub>2</sub> and CdO phases. The ratios of these secondary phases varied with different Fe concentrations. The effects of iron substitution on the ferroelectric properties of Fe-doped CdTiO<sub>3</sub> ilmenite samples were studied through dielectric and magnetic measurements. Vibrating sample magnetometer (VSM) measurements indicated significant changes in the magnetic properties of Fe-doped CdTiO<sub>3</sub> ilmenite, revealing that both the coercive field (HC) and remanent magnetization (MR) decreased with increasing Fe concentration.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 section","pages":"221 - 234"},"PeriodicalIF":2.1,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145121501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing micromechanical property characterization in ceramic multilayer coatings via hierarchical machine learning 基于分层机器学习的陶瓷多层涂层微力学性能表征
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-10-01 DOI: 10.1007/s41779-024-01098-4
Hachem Chaib, Shavan Askar, Harikumar Pallathadka, Sultan K. Salamah, M. K. Sharma, Marwan Kheimi
{"title":"Advancing micromechanical property characterization in ceramic multilayer coatings via hierarchical machine learning","authors":"Hachem Chaib,&nbsp;Shavan Askar,&nbsp;Harikumar Pallathadka,&nbsp;Sultan K. Salamah,&nbsp;M. K. Sharma,&nbsp;Marwan Kheimi","doi":"10.1007/s41779-024-01098-4","DOIUrl":"10.1007/s41779-024-01098-4","url":null,"abstract":"<div><p>This study focuses on a numerical data-driven machine learning (ML) approach applied to predict critical parameters, including hardness, Von Mises stress, and equivalent plastic strain in various ceramic multilayer coatings on a Ti alloy substrate, such as Ti/TiN, Ti/TiVN, Ti/TiZrN, Cr/CrN, Cr/CrAlN, and Ta/Ti-Zr-Ta, through the nanoindentation process. The regression analysis demonstrated the model’s effectiveness in predicting these parameters, with heightened accuracy in hardness and stress compared to plastic strain. The remarkable efficiency of the proposed hierarchical ML model derives from its ability to unravel complex interdependencies within the dataset, revealing subtle relationships that traditional models often overlook. The outcomes also revealed a direct correlation between increases in output targets, such as hardness and average Von Mises stress, and the amplification of weight factors associated with processing parameters. Conversely, heightened values of equivalent plastic strain demonstrated a proportional increase in weight factors associated with material properties. This observation underscores the individual contributions of processing parameters and material characteristics in modeling the mechanical behavior of multilayer coatings. Moreover, the ML model significantly enhanced the predictive performance for multilayer coatings by providing a detailed relevance score for the material properties of the layers. These properties included factors such as elastic modulus, hardness, Poisson ratio, and yield strength.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 2","pages":"553 - 568"},"PeriodicalIF":1.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eggshell powder-derived calcium sodium borosilicate-based glass coating production: characterization and coating performance 蛋壳粉衍生硼硅酸钙钠基玻璃涂层的生产:表征及涂层性能
IF 2.1 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-09-30 DOI: 10.1007/s41779-024-01093-9
Kumru Karaman-Ünlütürk, Yasin Bozkurt Yilmaz, Tamer Cengiz, Buğra Çiçek
{"title":"Eggshell powder-derived calcium sodium borosilicate-based glass coating production: characterization and coating performance","authors":"Kumru Karaman-Ünlütürk,&nbsp;Yasin Bozkurt Yilmaz,&nbsp;Tamer Cengiz,&nbsp;Buğra Çiçek","doi":"10.1007/s41779-024-01093-9","DOIUrl":"10.1007/s41779-024-01093-9","url":null,"abstract":"<div><p>Eggshells (ES) have economic importance due to organic (3–4%wt.) and inorganic (96–97%wt.) such as Calcite (CaCO<sub>3</sub>) content, leading to alternative calcium oxide (CaO) sources for the glass and ceramic industry. Experiments began with the grinding and calcination of eggshells. After obtaining eggshell powders (ESP), two precursor glasses (PGs) were prepared from different CaO sources; CaCO<sub>3</sub> which is an industrial CaO source, and calcined eggshell powder (C-ESP). The batches were melted at 1200 °C for 1 h. The PGs were applied on low-carbon steel plates by the wet spray method and fired at 760 °C for 4 min. The samples were characterized for their chemical composition, phase formation, thermal features, and microstructure by XRF, XRD, TG-DSC, and SEM-EDS analysis. The color and brightness values, surface roughness, and morphology of the coatings were examined. Finally, phase formation was examined in the controlled crystallization of the precursor glasses, and calcium fluoride (CaF<sub>2</sub>) phase formation was observed in both types of glass. The chemical and thermal properties of the precursor glasses and the final properties of the coated products from the two sources showed consistent results. It was shown that utilizing calcined ESP as a CaO source is appropriate for producing industrial glass-ceramic coatings.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 section","pages":"207 - 220"},"PeriodicalIF":2.1,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145122580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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