Journal of Solid State Electrochemistry最新文献

筛选
英文 中文
Electrochemical characteristics of composites based on novel asymmetric pillar[5]arene with carbon materials and their potential electrochemical applications 新型不对称柱[5]芳烃与碳材料复合材料的电化学特性及其潜在的电化学应用
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-27 DOI: 10.1007/s10008-024-06147-3
Rezeda Shamagsumova, Karina Gayazova, Dmitriy Shurpik, Vladimir Evtugyn, Daniil Stoikov, Ivan Stoikov, Gennady Evtugyn
{"title":"Electrochemical characteristics of composites based on novel asymmetric pillar[5]arene with carbon materials and their potential electrochemical applications","authors":"Rezeda Shamagsumova,&nbsp;Karina Gayazova,&nbsp;Dmitriy Shurpik,&nbsp;Vladimir Evtugyn,&nbsp;Daniil Stoikov,&nbsp;Ivan Stoikov,&nbsp;Gennady Evtugyn","doi":"10.1007/s10008-024-06147-3","DOIUrl":"10.1007/s10008-024-06147-3","url":null,"abstract":"<p>Electrochemical behavior of asymmetric pillar[5]arene (P5A) with one unsubstituted hydroquinone moiety and four ones with eight substituents bearing terminal amino groups was investigated for the first time on the surface of glassy carbon electrode (GCE) modified with various carbon nanomaterials (functionalized multi-walled carbon nanotubes (fMWCNTs), carbon black (CB), electrochemically reduced graphene oxide (ERGO)) by cyclic voltammetry. Quasi-reversible peak pair on voltammograms was attributed to the redox conversion of the hydroquinone moiety. P5A adsorbed at the modified GCE retained its ability to supramolecular interaction and demonstrated redox mediator properties. This effect was proved by the determination of L-tyrosine after its accumulation on the surface of GCE/CB/P5A sensor. The interaction between P5A and silver nitrate salt resulted in the formation of Ag nanoparticles. Morphology of P5A-Ag layers was assessed by transmission electron microscopy (TEM). Nanocomposite consisting of CB/P5A-Ag was also tested in nitrite-anion oxidation and demonstrated a reduction of the redox potential by up to 300 mV. Besides, a voltammetric GCE/CB/P5A-Ag sensor was used for chloride-anion determination in a concentration range from 50 µM to 0.1 mM.</p>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 5","pages":"1929 - 1943"},"PeriodicalIF":2.6,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143821728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical investigation of thermo-electro-mechanical behavior in solid oxide fuel cells with novel traps design interconnects for enhanced mass transfer 采用新型陷阱设计互连增强传质的固体氧化物燃料电池热-电-机械行为的数值研究
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-22 DOI: 10.1007/s10008-024-06144-6
Aimen Abdellah Bouaiss, Mohamed Souri Mimoune, Djafar Chabane, Nadhir Lebaal, Oussama Bouaiss, Lotfi Alloui
{"title":"Numerical investigation of thermo-electro-mechanical behavior in solid oxide fuel cells with novel traps design interconnects for enhanced mass transfer","authors":"Aimen Abdellah Bouaiss,&nbsp;Mohamed Souri Mimoune,&nbsp;Djafar Chabane,&nbsp;Nadhir Lebaal,&nbsp;Oussama Bouaiss,&nbsp;Lotfi Alloui","doi":"10.1007/s10008-024-06144-6","DOIUrl":"10.1007/s10008-024-06144-6","url":null,"abstract":"<div><p>Recent efforts in solid oxide fuel cell (SOFC) research have prioritized performance optimization by addressing reported issues and improving fundamental mechanisms. This paper opens the doors to the enhancement of SOFC performance through traps-designed interconnects, aimed at enhancing mass transfer and electrochemical conversion efficiency. A numerical investigation is conducted to analyze the effects of traps, including their number and three-dimensional size (length, width, and height), on SOFC behavior. Results show that the traps design effectively addresses the widely reported issue of poor reactants’ distribution in the under-rib areas. Additionally, increasing traps’ size enhances SOFC performance, with traps length identified as the primary contributor to improvement. However, variations in traps width exhibited inconsistencies in its impact. As a result, these parameters were carefully optimized for the optimal performance. The optimal configuration for a three-traps design is determined to be 12 mm in length, 0.3 mm in width, and 1 mm in height, resulting in a 14% increase in power output compared to conventional design. A thermo-mechanical analysis is also conducted, revealing that the electrical performance comes as a compromise with the mechanical stability of the cell. Specifically, an increase in thermal stresses around traps corners is observed, resulting in a significant rise in the probability of electrolyte failure probability. The authors suggest incorporating support layers or further optimizing trap shapes with mechanical stresses as a study constraint to enhance SOFC durability in response to these findings.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 5","pages":"1907 - 1927"},"PeriodicalIF":2.6,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143822046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of uncompensated resistance on Hads-terminated Pt electrodeposition 未补偿电阻对hads端接Pt电沉积的影响
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-22 DOI: 10.1007/s10008-024-06130-y
Y. Liu, M. Lafouresse, U. Bertocci, J. Bonevich, J. A. Dura, L. J. Richter, G. R. Stafford, T. P. Moffat
{"title":"Impact of uncompensated resistance on Hads-terminated Pt electrodeposition","authors":"Y. Liu,&nbsp;M. Lafouresse,&nbsp;U. Bertocci,&nbsp;J. Bonevich,&nbsp;J. A. Dura,&nbsp;L. J. Richter,&nbsp;G. R. Stafford,&nbsp;T. P. Moffat","doi":"10.1007/s10008-024-06130-y","DOIUrl":"10.1007/s10008-024-06130-y","url":null,"abstract":"<div><p>Self-terminated Pt electrodeposition on Au occurs at large negative overpotentials where hydrogen adsorption H<sub>ads</sub> inhibits the coordination of PtCl<sub>4</sub><sup>2−</sup> and/or PtCl<sub>3</sub>(H<sub>2</sub>O)<sup>−</sup> to the electrode surface in chloride-supported electrolytes. Potential control can be used to toggle the H<sub>ads</sub> coverage to enable multicycle Pt deposition. Specifically, the applied potential is stepped between + 0.4 V<sub>SSCE</sub> and − 0.8 V<sub>SSCE</sub>, transiting the regime of overpotential activated Pt electrodeposition. The amount of metal deposited depends on capacitive charging delays associated with the double layer and competitive Cl<sup>−</sup>, H, and PtCl<sub>4-x</sub>(H<sub>2</sub>O)<sub>x</sub><sup>−2+x</sup> adsorption. In addition, significant potential deviations arise from ohmic losses that are a function of the supporting electrolyte, cell geometry, and PtCl<sub>4-x</sub>(H<sub>2</sub>O)<sub>x</sub><sup>−2+x</sup> concentration. Taken in combination, the delay in reaching the growth termination potential leads to additional metal deposition and roughening per pulse cycle. Experiments with a parallel plate cell enable the resistive component of the ohmic losses to be specified by the separation between the working and reference electrodes. During multicycle deposition, the H<sub>upd</sub> pseudo-capacitance associated with Pt surface sites leads to further RC time constant delays and roughening. The transition to three-dimensional growth leads to low-density films as clearly evidenced after 50 deposition cycles. The difficulties with the pulsed potential scheme can be circumvented, or at least minimized, by using electrolyte exchange to introduce the PtCl<sub>4-x</sub>(H<sub>2</sub>O)<sub>x</sub><sup>−2+x</sup> reactant at a fixed potential, i.e., − 0.8 V<sub>SSCE</sub> into the weakly acidic electrolyte. The resulting fractional Pt coverage per cycle is a monotonic function of K<sub>2</sub>PtCl<sub>4</sub> concentration and ranged from 0.2 to almost a complete monolayer reflecting the competition between PtCl<sub>4-x</sub>(H<sub>2</sub>O)<sub>x</sub><sup>−2+x</sup> reduction and adsorption of the blocking H<sub>ads</sub> layer.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 4","pages":"1401 - 1421"},"PeriodicalIF":2.6,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Decentralized and cost-effective colorimetry analysis by smartphone-based method digital image for monitoring electrochemical elimination of dye from water matrices 分散和成本效益比色分析基于智能手机的方法数字图像监测电化学消除染料从水基质
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-22 DOI: 10.1007/s10008-024-06146-4
Jussara C. Cardozo, Inalmar D. Barbosa Segundo, Maria Eduarda de Medeiros Leandro, Amanda D. Gondim, Livia N. Cavalcanti, Elisama V. dos Santos, Carlos A. Martínez-Huitle
{"title":"Decentralized and cost-effective colorimetry analysis by smartphone-based method digital image for monitoring electrochemical elimination of dye from water matrices","authors":"Jussara C. Cardozo,&nbsp;Inalmar D. Barbosa Segundo,&nbsp;Maria Eduarda de Medeiros Leandro,&nbsp;Amanda D. Gondim,&nbsp;Livia N. Cavalcanti,&nbsp;Elisama V. dos Santos,&nbsp;Carlos A. Martínez-Huitle","doi":"10.1007/s10008-024-06146-4","DOIUrl":"10.1007/s10008-024-06146-4","url":null,"abstract":"<div><p>The present research provides a newly developed method that aims at versatile, rapid, portable, and low-cost instrumental protocol for colorimetric analysis of waters, polluted by dyes, through the use of a smartphone and app that detects and represents the RGB (red, green, and blue) color model. The calibration of the method is based on RGB values obtained by capturing images of colored solutions with known concentrations. The method was spectrophotometrically validated by analyzing the same samples, reaching more than 95% of accuracy. The utilization of this smartphone-based method for colorimetric analysis was proposed to follow, for the first time, the electrochemical treatment of different water matrices (400 mL of synthetic and real) with substantial organic and salts content (50 mg L<sup>−1</sup> of methylene blue in 0.1 mol L<sup>−1</sup> Na<sub>2</sub>SO<sub>4</sub>) using boron-doped diamond (BDD) anode by applying current densities (<i>j</i>) of 15, 30, and 60 mA cm<sup>−2</sup>. Discoloration results (which were achieved with this novel smart water security solution) clearly showed that significant removal efficiencies were achieved in 2 h, depending on the <i>j</i>, when synthetic and real effluents were used. A key role was played by the sulfates in solution which were electroconverted to persulfates via reaction with <sup>•</sup>OH produced at BDD surface, enhancing the oxidation power of the electrochemical treatment. Then, the procedure presented here obtained a high level of confidence representing great support for scientific laboratories as an alternative that can replace the use of expensive spectrophotometers.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 3","pages":"873 - 885"},"PeriodicalIF":2.6,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical simulation of direct methanol solid oxide fuel cells 直接甲醇固体氧化物燃料电池的电化学模拟
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-20 DOI: 10.1007/s10008-024-06135-7
Yongkun Zhu, Zhipeng Ma, Yan Li, Yuting Zhang
{"title":"Electrochemical simulation of direct methanol solid oxide fuel cells","authors":"Yongkun Zhu,&nbsp;Zhipeng Ma,&nbsp;Yan Li,&nbsp;Yuting Zhang","doi":"10.1007/s10008-024-06135-7","DOIUrl":"10.1007/s10008-024-06135-7","url":null,"abstract":"<div><p>Solid oxide fuel cells (SOFCs), efficient and clean energy converters, typically use hydrogen, which has low energy density and transport challenges. Methanol (CH<sub>3</sub>OH), with its high energy density and ease of storage, is an ideal alternative. This study uses a 3D multiphysics model in COMSOL to simulate methanol decomposition and the water-gas shift reaction, verifying model accuracy. The effects of temperature, porosity, and operating voltage on methanol SOFC performance were investigated. Results showed output current density increased from 13.60 kA·m<sup>−2</sup> to 14.05 kA·m<sup>−2</sup> as porosity rose from 0.2 to 0.7. As temperature increased from 873 K to 1273 K, current density rose from 72.54 kA·m<sup>−2</sup> to 37.89 kA·m<sup>−2</sup>. Increasing anode thickness from 0.1 to 0.8 mm raised current density from 13.17 kA·m<sup>−2 </sup>to 15.64 kA·m<sup>−2</sup>. These findings provide theoretical foundations and data for optimizing methanol SOFC design and operation.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 5","pages":"1893 - 1906"},"PeriodicalIF":2.6,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143822032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimizing laser-induced graphene oxide electrodes for electroanalytical applications using response surface methodology 利用响应面方法优化电分析应用的激光诱导氧化石墨烯电极
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-19 DOI: 10.1007/s10008-024-06141-9
Ângelo Rafael Machado, Thaís Machado Lima, Rafael Mendes Coelho, Geycson Figueiredo Dias, Priscila Izabela Soares, Helen Rodrigues Martins, Diego Leoni Franco, Arnaldo César Pereira, Lucas Franco Ferreira
{"title":"Optimizing laser-induced graphene oxide electrodes for electroanalytical applications using response surface methodology","authors":"Ângelo Rafael Machado,&nbsp;Thaís Machado Lima,&nbsp;Rafael Mendes Coelho,&nbsp;Geycson Figueiredo Dias,&nbsp;Priscila Izabela Soares,&nbsp;Helen Rodrigues Martins,&nbsp;Diego Leoni Franco,&nbsp;Arnaldo César Pereira,&nbsp;Lucas Franco Ferreira","doi":"10.1007/s10008-024-06141-9","DOIUrl":"10.1007/s10008-024-06141-9","url":null,"abstract":"<div><p>Laser-induced graphene (LIG) electrodes have shown promise for electroanalytical applications because of their unique properties, precise thickness, and morphology control. This study optimized the fabrication parameters of LIG electrodes on the thinnest commercial polyimide tapes by employing response surface methodology (RSM) combined with a randomized Box-Behnken experimental design (BBD). Kapton polyimide (PI) tapes were laser-engraved to create a three-electrode electrochemical system. Laser power, engraving speed, and laser distance were evaluated using the heterogeneous kinetic constant (<i>k</i>°) as the response variable. Optimal conditions were identified as 1.925 W power, 2729 mm/min speed, and 7.6 mm focal distance, yielding peak differences of 93 mV, electric double-layer capacitance of 1.95 µF, anodic peak current of 60.1 µA, and <i>k</i>° of 0.0074 cm/s. Raman spectroscopy of the LIG showed peaks at ~ 1350 cm<sup>−1</sup> (D band), ~ 1580 cm<sup>−1</sup> (G band), and ~ 2700 cm<sup>−1</sup> (2D band), indicating disordered and ordered graphitic structures. XRD analysis confirmed the presence of amorphous adhesive material and partial restoration of the graphene structure, with peaks corresponding to reduced graphene oxide (rGO) and graphitic planes. Reproducibility and repeatability studies via cyclic voltammetry (CV) in Fe(CN)<sub>6</sub><sup>3−</sup>/<sup>4−</sup> solution showed minor variations in peak currents and potentials, with RSD values of 2.64% for anodic and 2.26% for cathodic currents. Stability over 120 cycles showed an RSD of 1.57% for potentials and 3.53% for currents, with long-term tests over 20 days revealing a 14.5% and 15.9% decrease in anodic and cathodic peak currents, respectively. Optimized LIG electrodes were used to determine catechol (CC) and ascorbic acid (AA) using differential pulse voltammetry (DPV). CC determination yielded a linear range of 2 to 400 µM with a limit of detection (LOD) of 0.37 µM and a limit of quantification (LOQ) of 1.25 µM. AA determination resulted in a linear range of 20–4000 µM with an LOD of 4.26 µM and an LOQ of 14.21 µM. These results highlight the excellent performance of the optimized LIG electrodes in electroanalytical applications.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 3","pages":"855 - 872"},"PeriodicalIF":2.6,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ion conductivity and the stability of the interface between Na metal and Na3OCl 离子电导率及金属Na与Na3OCl界面的稳定性
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-18 DOI: 10.1007/s10008-024-06142-8
Kana Ishigami, Reona Miyazaki, Takehiko Hihara
{"title":"Ion conductivity and the stability of the interface between Na metal and Na3OCl","authors":"Kana Ishigami,&nbsp;Reona Miyazaki,&nbsp;Takehiko Hihara","doi":"10.1007/s10008-024-06142-8","DOIUrl":"10.1007/s10008-024-06142-8","url":null,"abstract":"<div><p>Solid-state Li<sup>+</sup>/Na<sup>+</sup> conductors are used as electrolytes in all-solid-state Li/Na batteries. The ion conductivity and electrode stability of solid electrolytes directly determine battery performances. In addition to the solid electrolyte layer, Na<sup>+</sup> conductors are also used as additives in electrode composites to enhance the charge–discharge properties. In this study, the ion conductivity and Na metal stability of the Na-rich anti-perovskite Na<sub>3</sub>OCl were investigated. Na<sub>3</sub>OCl was prepared by controlling the Cl<sup>−</sup>/O<sup>2−</sup> ratio. Dense pellets of Na<sub>3</sub>OCl were prepared by sintering. The conductivities of stoichiometric and Cl-excess Na<sub>3</sub>OCl are 9.7 × 10<sup>−6</sup> and 3.0 × 10<sup>−5</sup> S/cm at 240 °C, respectively. The Na<sup>+</sup> vacancies, which were introduced as the charge compensation of Cl<sup>−</sup>/O<sup>2−</sup> substitution, are considered to be the origin of the conductivity improvement. Off-stoichiometry of Cl<sup>−</sup>/O<sup>2−</sup> can also be effective when Na<sub>3</sub>OCl is used as the anode composite. The decomposition of Na<sub>3</sub>OCl at the Na metal interphase was suggested, indicating that Na<sub>3</sub>OCl is unstable with Na. These results contradict the current knowledge on the charge–discharge performance of Na<sub>3</sub>OCl anode composites. The present results indicate that the Na<sup>+</sup> conduction properties and stability in Na<sub>3</sub>OCl with high crystallinity are different from the in situ-formed Na<sub>3</sub>OCl in previously reported anode composites. In conjunction with its low conductivity, decomposition at the Na metal interphase indicates that the direct use of Na<sub>3</sub>OCl as a solid electrolyte is challenging.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 5","pages":"1875 - 1882"},"PeriodicalIF":2.6,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143822027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mn2+-doped (NH4)2V4O9 cathode materials for highly stable aqueous zinc-ion batteries 高稳定水性锌离子电池用掺杂Mn2+ (NH4)2V4O9正极材料
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-18 DOI: 10.1007/s10008-024-06139-3
Baohe Yuan, Pengfei Zhao, Tianbao Liu, Zheng An, Mingliang Shi, Yinzhe Zhao, Mingyang Li, Chenjun Zhang, Lulu Chen, Shijun Luo, Yangchun Liao
{"title":"Mn2+-doped (NH4)2V4O9 cathode materials for highly stable aqueous zinc-ion batteries","authors":"Baohe Yuan,&nbsp;Pengfei Zhao,&nbsp;Tianbao Liu,&nbsp;Zheng An,&nbsp;Mingliang Shi,&nbsp;Yinzhe Zhao,&nbsp;Mingyang Li,&nbsp;Chenjun Zhang,&nbsp;Lulu Chen,&nbsp;Shijun Luo,&nbsp;Yangchun Liao","doi":"10.1007/s10008-024-06139-3","DOIUrl":"10.1007/s10008-024-06139-3","url":null,"abstract":"<div><p>Due to their high specific capacity, ammonium vanadate salts are commonly utilized as cathode materials for aqueous zinc-ion batteries (AZIBs). However, their inferior efficiency and rate performance have hindered widespread adoption. In order to address these issues, we developed evenly distributed hybrid nanosheets (NVM) of (NH<sub>4</sub>)<sub>2</sub>V<sub>4</sub>O<sub>9</sub> and MnV<sub>2</sub>O<sub>6</sub> by introducing manganese ions into (NH<sub>4</sub>)<sub>2</sub>V<sub>4</sub>O<sub>9</sub> through the hydrothermal technique. The results show that AZIB exhibits outstanding rate performance, stable cycle performance, and good efficiency characteristics when NVM as electrode materials. The AZIB has a high specific capacity of 500 mAh g<sup>−1</sup> at a current density of 0.1 A·g<sup>−1</sup>. And it maintains a specific capacity of 350 mAh g<sup>−1</sup> after 100 cycles at 1 A·g<sup>−1</sup>. It exhibits good stable cycle performance, the specific capacity is 140 mAh g<sup>−1</sup> after 1000 cycles at 5 A·g<sup>−1</sup>, retaining 98% of its initial capacity. The addition of manganese ions can reduce the electrode’s diffusion impedance and increase its diffusion coefficient, resulting in a lower voltage window of 0.13 V. The large capacity and high energy efficiency of NVM materials make the battery more widely used in practical applications.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 5","pages":"1883 - 1892"},"PeriodicalIF":2.6,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143822000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing oxygen reduction reaction in acidic medium: A novel electrocatalyst of Pt–Co embedded in nitrogen-rich carbon nanosheets derived from polypyrrole-g-C3N4 在酸性介质中增强氧还原反应:由聚吡咯-g- c3n4衍生的富氮碳纳米片包埋Pt-Co的新型电催化剂
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-16 DOI: 10.1007/s10008-024-06140-w
Balamurali Ravichandran, Naresh Narayanan, Sabarinathan Ravichandran, Huiyuan Liu, Weiqi Zhang, Narayanamoorthy Bhuvanendran, Huaneng Su
{"title":"Enhancing oxygen reduction reaction in acidic medium: A novel electrocatalyst of Pt–Co embedded in nitrogen-rich carbon nanosheets derived from polypyrrole-g-C3N4","authors":"Balamurali Ravichandran,&nbsp;Naresh Narayanan,&nbsp;Sabarinathan Ravichandran,&nbsp;Huiyuan Liu,&nbsp;Weiqi Zhang,&nbsp;Narayanamoorthy Bhuvanendran,&nbsp;Huaneng Su","doi":"10.1007/s10008-024-06140-w","DOIUrl":"10.1007/s10008-024-06140-w","url":null,"abstract":"<div><p>In this study, PtCo alloy nanoparticles (NPs) were successfully synthesized and deposited on nitrogen-rich carbon nanosheets derived from Polypyrrole-g-C<sub>3</sub>N<sub>4</sub> using a chemical reduction method. This electrocatalyst not only offers enhanced catalytic efficiency but also significantly improves the stability for the oxygen reduction reaction (ORR) in in acidic medium. In terms of electrocatalytic performance, the PtCo/CN@PPY-g-C<sub>3</sub>N<sub>4</sub> catalyst demonstrated a mass activity of 0.378 mA µg<sub>Pt</sub><sup>−1</sup> at 0.85 V, 0.131 mA µg<sub>Pt</sub><sup>−1</sup> at 0.9 V and a specific activity of 2.900 mA cm<sub>Pt</sub><sup>−2</sup> at 0.85 V, 1.004 mA cm<sub>Pt</sub><sup>−2</sup> at 0.9 V which are respectively 2.3, 2.8 and 10, 12 times higher than those of a commercial 20% Pt/C catalyst (0.166 mA µg<sub>Pt</sub><sup>−1</sup> at 0.85 V, 0.046 mA µg<sub>Pt</sub><sup>−1</sup> at 0.9 V and 0.285 mA cm<sub>Pt</sub><sup>−2</sup> at 0.85 V, 0.079 mA cm<sub>Pt</sub><sup>−2</sup> at 0.9 V). This indicates superior catalytic activity. Furthermore, after 5000 cycles, the PtCo/CN@PPY-g-C<sub>3</sub>N<sub>4</sub> retained approximately 77% at 0.85 V and 83% at 0.9 V of its initial mass activity, with only a 14 mV decrease in the half-wave potential, whereas commercial 20% Pt/C catalyst retained only 40% at0.85 V and 30% at 0.9 V of its initial mass activity. These enhancements can be attributed to the synergistic effects and strong interactions between the Pt–Co alloy nanoparticles and the carbon nitride support. The findings of this study underscore the potential of PtCo/CN@PPY-g-C<sub>3</sub>N<sub>4</sub> as a viable and efficient alternative to traditional catalysts in electrochemical applications.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 5","pages":"1863 - 1874"},"PeriodicalIF":2.6,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143822004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrodeposition of palladium nanoparticles onto indium tin oxide glass electrode. A kinetical and morphological study and effect of the potential in the particle size 钯纳米粒子在氧化铟锡玻璃电极上的电沉积。动力学和形态学的研究和影响的电势在粒度
IF 2.6 4区 化学
Journal of Solid State Electrochemistry Pub Date : 2024-11-15 DOI: 10.1007/s10008-024-06134-8
Luis Humberto Mendoza-Huizar
{"title":"Electrodeposition of palladium nanoparticles onto indium tin oxide glass electrode. A kinetical and morphological study and effect of the potential in the particle size","authors":"Luis Humberto Mendoza-Huizar","doi":"10.1007/s10008-024-06134-8","DOIUrl":"10.1007/s10008-024-06134-8","url":null,"abstract":"<div><p>In the present work, it was conducted an electrochemical, kinetic, and morphological investigation of the electrodeposition of palladium (Pd) nanoparticles onto an Indium Tin Oxide (ITO) glass electrode. The electrodeposition was performed using a plating bath containing 0.001 M PdCl₂ and 1 M NH₄Cl at a pH of 6. The results indicate that Pd can be electrodeposited without the influence of hydrogen adsorption/desorption processes by selecting an applied potential range between 1.00 and − 0.6 V. The electrodeposition of Pd is diffusion-controlled, as evidenced by the linear relationship between the peak current (<i>j</i><sub>p</sub>) and the square root of the scan rate (<i>ν</i>¹<sup>/</sup>²). The kinetic study reveals a progressive nucleation process, leading to the formation of Pd particles of varying sizes. Morphological analysis using optical microscopy and Atomic Force Microscopy (AFM) demonstrates that particle size decreases as the applied potential to the ITO substrate becomes more negative. AFM images indicate that the average heights of the Pd clusters are 149.5 nm, 91.6 nm, and 79.2 nm at -0.150 V, -0.200 V, and − 0.250 V, respectively; while the diameters of the particles ranged from 120 to 735 nm at -0.150 V, from 80 to 550 nm at -0.200 V, and from 60 to 360 nm at -0.250 V. At -0.300 V, agglomeration of Pd nanoparticles was observed due to the high nucleation rate.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 5","pages":"1849 - 1861"},"PeriodicalIF":2.6,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143822001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信