Journal of Solid State Electrochemistry最新文献_第5页

Enantiomeric covalent organic polymers-based electrodes for selective electrochemical recognition of cysteine enantiomers and detection of L-Cysteine 基于对映体共价有机聚合物的半胱氨酸对映体选择性电化学识别和l -半胱氨酸检测电极

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-19 DOI: 10.1007/s10008-026-06633-w

Ying Nie, Hui Zhang, Jianwei Zhao, Zhili Fang

{"title":"Enantiomeric covalent organic polymers-based electrodes for selective electrochemical recognition of cysteine enantiomers and detection of L-Cysteine","authors":"Ying Nie, Hui Zhang, Jianwei Zhao, Zhili Fang","doi":"10.1007/s10008-026-06633-w","DOIUrl":"10.1007/s10008-026-06633-w","url":null,"abstract":"<div><p>In this work two novel chiral sensing platforms were constructed from enantiomeric covalent organic polymers (R-CCOP and S-CCOP) prepared via a one-step solvothermal method, for the enantioselective recognition of L- and D-cysteine (Cys). The prepared materials were characterized using scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), nitrogen adsorption-desorption (BET), and X-ray diffraction (XRD). By integrating the chiral characteristics of R-(+)-1,1-bisnaphthyl-2,2-diamine/S-(-)-1,1-bisnaphthyl-2,2-diamine building blocks with the electrochemical behavior of large π-conjugated systems formed after polymerization, two types of electrochemical chiral sensing interfaces were constructed using glassy carbon electrodes (GCE) modified with R-CCOP and S-CCOP. These interfaces were employed for the electrochemical chiral recognition of Cys enantiomers. The results showed that R-CCOP/GCE exhibited the highest chiral recognition efficiency, with an enantioselectivity coefficient (<i>I</i><sub>L</sub>/<i>I</i><sub>D</sub>) of 2.86, while S-CCOP/GCE had a chiral recognition efficiency of 1.37. Density functional theory (DFT) calculations confirmed that both R-CCOP and S-CCOP demonstrated stronger recognition capabilities for L-Cys, with hydrogen bonding being the key factor in recognition. Additionally, the R-CCOP/GCE sensing interface exhibited a linear response within a concentration range of 5 µM to 500 µM for L-Cys, with a detection limit of 0.50 µM (S/<i>N</i> = 3) for L-Cys, along with good stability and reproducibility, making it an effective chiral sensing interface for the recognition of Cys enantiomers.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 9","pages":"3153 - 3168"},"PeriodicalIF":3.1,"publicationDate":"2026-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148710386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Silicon-carbon composite anodes for high-energy lithium-ion batteries: challenges, design strategies, and recent advances 高能锂离子电池用硅碳复合阳极：挑战、设计策略和最新进展

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-19 DOI: 10.1007/s10008-026-06627-8

Kishore V.S, R. Praveen Surya, J. Vinoth Kumar, Munusamy Settu, Prabu S, Nithish Kumar M, Tamilselvi Arumugam

引用次数: 0

Kinetic and morphological study of copper electrodeposits onto glassy carbon electrodes from an electrolytic bath containing perchlorate ions 含高氯酸盐离子的电解液中铜在玻碳电极上沉积的动力学和形态学研究

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-19 DOI: 10.1007/s10008-026-06632-x

Yilmair Rodríguez-Santillán, Luis H. Mendoza-Huizar, Clara H. Rios-Reyes, Uriel Caudillo-Flores, Daniel O. González-Ábrego

{"title":"Kinetic and morphological study of copper electrodeposits onto glassy carbon electrodes from an electrolytic bath containing perchlorate ions","authors":"Yilmair Rodríguez-Santillán, Luis H. Mendoza-Huizar, Clara H. Rios-Reyes, Uriel Caudillo-Flores, Daniel O. González-Ábrego","doi":"10.1007/s10008-026-06632-x","DOIUrl":"10.1007/s10008-026-06632-x","url":null,"abstract":"<div><p>A kinetic and morphological study of copper electrodeposition onto glassy carbon electrodes (GCE) was performed using cyclic voltammetry and chronoamperometry in an aqueous 0.001 M Cu(ClO<sub>4</sub>)<sub>2</sub>·6H<sub>2</sub>O solution with 0.1 M NaClO<sub>4</sub> as supporting electrolyte at pH 5.5. Electrochemical results indicate that copper deposition is diffusion-controlled and proceeds via a progressive nucleation mechanism. Cyclic voltammograms display a well-defined cathodic peak corresponding to the Cu<sup>2</sup>⁺/Cu⁰ redox couple, preceded by a distinct cathodic pre-peak at more positive potentials, associated with the initial stages of nucleation. A kinetic analysis based on potentiostatic transients allowed the determination of key parameters, including the nucleation rate constant (<i>A</i>), the number of active nucleation sites (<i>N</i><sub>0</sub>), and the diffusion coefficient (<i>D</i>). Morphological characterization by scanning electron microscopy (SEM) shows that at low overpotentials (0.020 and 0.0 V), copper deposits consist of well-defined cubic and prismatic nanocrystals with sizes ranging from 100 to 200 nm, exhibiting faceted morphologies dominated by {100} planes. The presence of these faceted structures indicates crystallographically controlled growth during the early stages of deposition. As the applied overpotential becomes more negative, a transition to a high-density nucleation regime is observed, leading to the formation of a larger number of smaller nuclei and a progressive loss of faceting. This morphological evolution is accompanied by a systematic decrease in particle size, reaching values between 15 and 25 nm at − 0.100 V, consistent with a shift from growth-dominated to nucleation-dominated deposition. Energy-dispersive X-ray spectroscopy (EDS) confirms that the observed nanostructures are composed exclusively of copper.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 9","pages":"3183 - 3195"},"PeriodicalIF":3.1,"publicationDate":"2026-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148710339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrochemical biosensor for β-hydroxybutyrate based on NADH oxidase-like mimics of Pt NPs@MWCNTs 基于NADH氧化酶样Pt模拟物的β-羟基丁酸酯电化学生物传感器NPs@MWCNTs

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-17 DOI: 10.1007/s10008-026-06630-z

Jianzhen Pan, Xinting Liu, Minghui Yang

引用次数: 0

Disposable 3D-printed electrochemical sensor as a potential tool for on-site analysis of metal-based paint materials in cultural heritage studies 一次性3d打印电化学传感器作为文化遗产研究中金属基涂料材料现场分析的潜在工具

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-15 DOI: 10.1007/s10008-026-06623-y

Lucas Puhl dos Santos, Edson Roberto Santana, João Paulo Winiarski, Eduardo Constante Martins, Juliana Priscila Dreyer, Thiago Guimarães Costa, Almir Spinelli, Iolanda Cruz Vieira

{"title":"Disposable 3D-printed electrochemical sensor as a potential tool for on-site analysis of metal-based paint materials in cultural heritage studies","authors":"Lucas Puhl dos Santos, Edson Roberto Santana, João Paulo Winiarski, Eduardo Constante Martins, Juliana Priscila Dreyer, Thiago Guimarães Costa, Almir Spinelli, Iolanda Cruz Vieira","doi":"10.1007/s10008-026-06623-y","DOIUrl":"10.1007/s10008-026-06623-y","url":null,"abstract":"<div><p>A miniaturized and disposable 3D-printed electrochemical sensor was developed for the qualitative analysis of metal-containing paint test specimens relevant to cultural heritage studies. The device was fabricated using a conductive carbon black-poly(lactic acid) (CB-PLA) filament printed onto an acrylonitrile-butadiene-styrene (ABS) substrate. After printing, the sensor surface was electrochemically activated in 1.0 mol L<sup>−1</sup> NaOH by applying a constant potential of +1.2 V for 30 min. Model paint test specimens composed of copper-based pigments (azurite, malachite, and verdigris), dispersed in four different binders (linseed oil, alkyd resin, acrylic resin, and rabbit glue), were subjected to an accelerated aging protocol corresponding to 161 years at 25 °C. The specimens were subsequently analyzed by voltammetry of immobilized microparticles (VIMP), in which a small amount of the pigment-binder material was mechanically transferred to the electrode surface. The electrochemical response was markedly influenced by the nature of the binder, revealing distinct behaviors among the pigment-binder systems and underscoring the role of the organic matrix in modulating copper electroactivity. Despite these matrix effects, copper was successfully detected in all paint test specimens investigated. Owing to its high sensitivity, miniaturized and disposable configuration, low-cost fabrication, and compatibility with scalable 3D printing, the proposed sensor platform shows strong potential for on-site electrochemical analysis of paint materials in cultural heritage artefacts.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 9","pages":"3131 - 3143"},"PeriodicalIF":3.1,"publicationDate":"2026-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10008-026-06623-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148710385","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rapid assessment of stainless steels corrosion by bipolar electrochemistry 双极电化学快速评价不锈钢腐蚀

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-13 DOI: 10.1007/s10008-026-06626-9

Rahul Shrivastava, Rita Maurya, Prvan Kumar Katiyar

{"title":"Rapid assessment of stainless steels corrosion by bipolar electrochemistry","authors":"Rahul Shrivastava, Rita Maurya, Prvan Kumar Katiyar","doi":"10.1007/s10008-026-06626-9","DOIUrl":"10.1007/s10008-026-06626-9","url":null,"abstract":"<div><p>This study investigates the influence of applied constant current (0.5–2 A) on the localized corrosion behaviour of 304 and 316 austenitic stainless steels (ASSs), 2205 duplex stainless steel (DSS), and 32750 super duplex stainless steel (SDSS) using bipolar electrochemical (BPE) testing in freely aerated 3.5% NaCl, where each experiment was conducted for a duration of 2 h. The BPE technique induces spatial anodic-cathodic polarization without direct electrical contact, enabling realistic simulation of crevice and pitting corrosion. Among the investigated grades, 304 ASS exhibited the lowest corrosion resistance, showing the highest weight loss (~ 0.069 g/cm<sup>2</sup>), severe pit coalescence, and deep crevice penetration (~ 610 μm) at 2 A. The addition of Mo in 316 ASS improved performance, reducing weight loss to 0.055 g/cm² and crevice depth to ~ 505 μm. In contrast, 2205 DSS demonstrated significantly enhanced resistance, with weight loss limited to ~ 0.007 g/cm<sup>2</sup> at 2 A, along with shallow crevices (~ 224 μm) and pitting mainly localized at ferrite-austenite interfaces. The highest resistance was observed in 32750 SDSS, which maintained minimal weight loss (0.004 g/cm<sup>2</sup>), very shallow crevices (< 100 μm at 2 A), negligible pitting, and the lowest corrosion volume-to-area ratios. Optical profilometry confirmed extensive penetration in 304 ASS and markedly shallower attack in duplex grades. Raman analysis identified α-FeOOH and γ-FeOOH in austenitic steels, indicating sustained active corrosion, whereas γ-Fe<sub>2</sub>O<sub>3</sub> dominated in 2205 DSS and 32750 SDSS, reflecting more stable corrosion products and improved localized corrosion resistance.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 9","pages":"3107 - 3130"},"PeriodicalIF":3.1,"publicationDate":"2026-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148710331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A study on low-frequency pulse charging strategies for silicon-based all-solid-state batteries based on the single-ion conducting electrolyte model 基于单离子导电电解质模型的硅基全固态电池低频脉冲充电策略研究

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-11 DOI: 10.1007/s10008-026-06619-8

Yigang Feng, Qingfeng Zhang, Shaoyang Wang, Wenxuan Xia, Jianqiu Zhou

{"title":"A study on low-frequency pulse charging strategies for silicon-based all-solid-state batteries based on the single-ion conducting electrolyte model","authors":"Yigang Feng, Qingfeng Zhang, Shaoyang Wang, Wenxuan Xia, Jianqiu Zhou","doi":"10.1007/s10008-026-06619-8","DOIUrl":"10.1007/s10008-026-06619-8","url":null,"abstract":"<div><p>All-solid-state batteries (ASSBs) are a leading candidate for next-generation energy storage, owing to their exceptional safety and high energy density. However, silicon anodes undergo significant volume changes during the lithium-intercalation and deintercalation processes, leading to interface degradation and structural failure. This is due to severe electro-mechanical coupling stresses generated during these processes. To address this critical issue, this work has developed a multi-physics (electrochemical-thermal-mechanical) coupling model for silicon-based all-solid-state batteries based on single-ion conducting electrolyte (SCE) theory. Based on this model, a low-frequency pulse charging strategy was introduced to investigate the effects of temperature and mechanical constraints on battery performance. The results indicate that temperature is a key factor determining lithium-ion distribution and stress evolution: at temperatures below 268 K, lithium-ion concentration polarization and stress accumulation increase; in the temperature range of 298–313 K, the battery achieves an optimal balance between electrochemical performance and mechanical stability; and at temperatures above 313 K, performance declines but remains superior to that under low-temperature conditions. Mechanical constraints exert an asymmetric regulation on electrode stress: external loads (0-100 MPa) reduce cathode stress but increase anode stress, and their effects on lithium-ion concentration and temperature are negligible. This study provides a theoretical framework for the structural design and thermal management of batteries (ASSBs).</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 9","pages":"3089 - 3106"},"PeriodicalIF":3.1,"publicationDate":"2026-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148710343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication of ZnO–polysulfone solid-state composite membrane for water purification applications 水净化用zno -聚砜固体复合膜的制备

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-11 DOI: 10.1007/s10008-026-06609-w

Mohd Arsalan, Aiman Khan, Shaikh Aliya Aijaz, Md Oayes Midda, Fahad Alam, Afzal Hussain, Mohamed F. Alajmi, Suhaib Alam, Mohammad Ehtisham Khan

{"title":"Fabrication of ZnO–polysulfone solid-state composite membrane for water purification applications","authors":"Mohd Arsalan, Aiman Khan, Shaikh Aliya Aijaz, Md Oayes Midda, Fahad Alam, Afzal Hussain, Mohamed F. Alajmi, Suhaib Alam, Mohammad Ehtisham Khan","doi":"10.1007/s10008-026-06609-w","DOIUrl":"10.1007/s10008-026-06609-w","url":null,"abstract":"<div><p>The increasing exploitation of water resources and the growing scarcity of clean water have pushed the trajectory of research to clean water generation techniques. In the given study, a novel Polysulfone and Zinc Oxide (PSf@ZnO) thin film composite membrane is presented for the removal of heavy metal ions from wastewater. The membrane was fabricated using the phase inversion technique and subsequently surface-modified with ZnO nanoparticles to enhance its chemical stability and filtration performance. FESEM, FTIR, XRD, and TGA were the characterization techniques employed to examine the membrane’s morphology, chemical structure, crystallinity, and thermal degradation. The concentrations of heavy metal ions Pb<sup>2</sup>⁺, Cu<sup>2</sup>⁺, Cd<sup>2</sup>⁺, Cr<sup>6+</sup>, and Ni<sup>2</sup>⁺ using atomic absorption apectroscopy (AAS) were analyzed. The results show that ZnO nanoparticles spread evenly throughout the polysulfone matrix. The ZnO modification improves surface hydrophilicity and surface wettability, leading to enhanced filtration efficiency by reducing pore blockage and promoting more uniform surface transport behavior. Thermal tests (TGA/DTA) show the membrane stands up better to heat and resists breaking down. When it comes to removing heavy metal ions, the membrane works remarkably well across the tested range, as long as conditions are suitable. Additionally, ZnO brings strong antibacterial properties, which helps the membrane fight off fouling and keeps it running longer. In conclusion, these findings point to the PSf@ZnO composite membrane as a cost-effective and sustainable option for water purification. The ZnO nanoparticles push its performance, making it an apt choice for both environmental and industrial uses.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 10","pages":"3469 - 3484"},"PeriodicalIF":3.1,"publicationDate":"2026-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148986419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ti1.3Nb1.76O7 porous microspheres: a low-niobium niobate for Li+-storage anodes Ti1.3Nb1.76O7多孔微球：用于Li+存储阳极的低铌酸盐

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-11 DOI: 10.1007/s10008-026-06621-0

Yanxin Zhang, Zhenying Sun, Xuehua Liu, Chuan Zhang, Zhongzhu Liu, Chunfu Lin

{"title":"Ti1.3Nb1.76O7 porous microspheres: a low-niobium niobate for Li+-storage anodes","authors":"Yanxin Zhang, Zhenying Sun, Xuehua Liu, Chuan Zhang, Zhongzhu Liu, Chunfu Lin","doi":"10.1007/s10008-026-06621-0","DOIUrl":"10.1007/s10008-026-06621-0","url":null,"abstract":"<div><p>Niobate Li<sup>+</sup>-storage anode materials, especially TiNb<sub>2</sub>O<sub>7</sub> (TNO), have garnered significant attention for their intrinsically safe characteristics and substantial capacities as well as fast and stable electrochemical kinetics. However, several limitations hinder the application of TNO in lithium-ion battery anodes, chief among them being its high niobium content. Herein, by adjusting the ratio of Ti and Nb elements in TNO, a novel low-niobium Ti<sub>1.3</sub>Nb<sub>1.76</sub>O<sub>7</sub> (LN-TNO) anode material with a micro-sized porous spherical morphology and oxygen-vacancy proportion of 2.8% has been exploited. The oxygen vacancies provide more active sites for electrochemical reactions, enabling impressive rate capability with a 5 C to 0.1 C capacity retention of 70.4%. LN-TNO demonstrates stable cycling performance with 86.5% capacity retention after 250 cycles at 5 C. Even at − 10 °C, it delivers a super high-rate behavior with 46.7% capacity retention from 5 C to 0.1 C, along with stable cycling performance retaining 90.0% of its capacity upon 500 cycles at 5 C. Owing to the outstanding properties mentioned above, LN-TNO demonstrates promising potential for practical applications in high-performance Li<sup>+</sup> storage.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 8","pages":"2995 - 3003"},"PeriodicalIF":3.1,"publicationDate":"2026-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148433745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In-situ construction of a crystalline LiAlO2 ion-conducting layer via residual lithium conversion for ultra-stable Ni-Rich NCM811 cathodes 超稳定富镍NCM811阴极残锂转化原位构建LiAlO2离子导电层

IF 3.1 4区化学

Journal of Solid State Electrochemistry Pub Date : 2026-06-10 DOI: 10.1007/s10008-026-06620-1

Rui Fan, Saijing Wang, Xuan Yang, Wenjun Lu, Zhenni Wang, Maolin Zhang, Xiaofei Sun, Shengnan He

{"title":"In-situ construction of a crystalline LiAlO2 ion-conducting layer via residual lithium conversion for ultra-stable Ni-Rich NCM811 cathodes","authors":"Rui Fan, Saijing Wang, Xuan Yang, Wenjun Lu, Zhenni Wang, Maolin Zhang, Xiaofei Sun, Shengnan He","doi":"10.1007/s10008-026-06620-1","DOIUrl":"10.1007/s10008-026-06620-1","url":null,"abstract":"<div><p>The commercialization of Ni-rich layered oxide cathodes is critically impeded by interfacial instability, primarily caused by spontaneous reactions with ambient moisture/CO<sub>2</sub> that generate electrochemically inert residual lithium species (Li<sub>2</sub>CO<sub>3</sub>/LiOH). These residues not only impede Li⁺ transport, but also trigger electrolyte decomposition, accelerating capacity fade. While converting these residues into protective coatings is an attractive mitigation strategy, the resulting layers are often amorphous, lacking the structural integrity and ionic conductivity required for long-term cycling stability. Herein, we transform this inherent drawback into an advantage by in situ synthesizing a crystalline LiAlO<sub>2</sub> coating (5–10 nm) from the residual lithium. Advanced electron microscopy confirms its near-epitaxial growth on NCM811 primary particles, which is facilitated by a minimal lattice mismatch. This coherent interface consumes electrochemically harmful residual lithium and reduces interface resistance. It can also act as a physical barrier to ion conduction, inhibit parasitic reactions, and mitigate the structural failure during cycle process. Crystal LiAlO<sub>2</sub> is a rapid Li<sup>+</sup> conductor with a 3D diffusion path, thereby enhancing reaction kinetics. The modified cathode delivers ultra-stable cycling (95.9% capacity retention after 100 cycles at 1 C) and superior rate performance (124.0 mAhg<sup>− 1</sup> at 10 C). This study provides a modified strategy for constructing crystalline LiAlO<sub>2</sub> coating on the surface of LiNi<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>O<sub>2</sub> cathode, fundamentally highlighting the critical role of coating crystallinity in governing interfacial ion transport and structural integrity.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 8","pages":"2983 - 2993"},"PeriodicalIF":3.1,"publicationDate":"2026-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148433699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0