Journal of Solid State Electrochemistry最新文献_第5页

A one-pot synthesis of ZnS-NiS-NiS2 composite and its synergistic effect on different electrolytes for supercapacitor applications 一锅法合成ZnS-NiS-NiS2复合材料及其对不同电解液的增效作用

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-25 DOI: 10.1007/s10008-025-06288-z

Ponnusamy Paunkumar, Sundaram Ganesh Babu

{"title":"A one-pot synthesis of ZnS-NiS-NiS2 composite and its synergistic effect on different electrolytes for supercapacitor applications","authors":"Ponnusamy Paunkumar, Sundaram Ganesh Babu","doi":"10.1007/s10008-025-06288-z","DOIUrl":"10.1007/s10008-025-06288-z","url":null,"abstract":"<div><p>To date, owing to high molar conductivity and capacitance, metal sulfide–based electrodes have been constructed for supercapacitor applications. Supercapacitors (SCs) are known for their rapid charge–discharge rate and long-cycle durability. For the first time, a composite including zinc sulfide, nickel sulfide, and nickel disulfide (ZnS-NiS-NiS<sub>2</sub>) was successfully produced using a one-pot solvothermal technique for supercapacitor applications in diverse electrolytes. XRD and FT-IR measurements revealed the construction of the prepared composite. SEM and HR-TEM investigations demonstrate that the produced material is possessed spherical. The ZnS-NiS-NiS<sub>2</sub> composite was studied for its specific capacitance in the presence of dissimilar electrolytes. In comparison to Na<sub>2</sub>SO<sub>4</sub> (1 M) electrolyte and a blend of KOH (0.5 M)/Na<sub>2</sub>SO<sub>4</sub> (1 M) electrolytes, the KOH (0.5 M) electrolyte achieves an exceptional specific capacitance of 179 F g⁻<sup>1</sup> at a current density of 1 A g⁻<sup>1</sup>. The ZnS-NiS-NiS<sub>2</sub> electrode preserves 91% of its capacitance across 3000 cycles at 5 A g⁻<sup>1</sup> when using KOH (0.5 M) as an electrolyte. The synthesized ZnS-NiS-NiS<sub>2</sub> electrode can be employed in the future development of energy preservation.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 9","pages":"3967 - 3976"},"PeriodicalIF":2.6,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Numerical simulation of lead-acid battery (I): the impact of plate size and discharge rate on its performance 铅酸蓄电池的数值模拟（一）：极板尺寸和放电速率对其性能的影响

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-25 DOI: 10.1007/s10008-025-06265-6

Yifan Zhang, Tian Jiang, Zhiliang Guo, Yujie Hou, Yuli Zhang, Xinyi Wan, Qian Lu, Ran Chen, Lixu Lei

{"title":"Numerical simulation of lead-acid battery (I): the impact of plate size and discharge rate on its performance","authors":"Yifan Zhang, Tian Jiang, Zhiliang Guo, Yujie Hou, Yuli Zhang, Xinyi Wan, Qian Lu, Ran Chen, Lixu Lei","doi":"10.1007/s10008-025-06265-6","DOIUrl":"10.1007/s10008-025-06265-6","url":null,"abstract":"<div><p>Lead acid batteries (LABs) could solve all the problems in renewable energy storage of ultra-large scale (up to GW/TWh) due to their cost-efficiency, reliability and recyclability. The ultra-large scale storage demands large-capacity LABs with enhanced performance. To investigate the impact of plate size and discharge rate on discharge performance of LABs, we have constructed three-dimensional models considering the conductivities of grid and active materials, electrochemical reactions, and mass transfer to simulate galvanostatic discharge processes. The simulations show that inherent electrical resistance causes inhomogeneous distributions of potential and overpotential, which result in uneven reaction rate across the plates that causes even more inhomogeneous distribution of current density, sulfuric acid concentration and depth of discharge. During high-rate discharge of large electrode, the increased ohmic voltage drop, coupled with slow mass transfer of sulfuric acid, causes lower utilization of active materials located at the positions further away from the lug and sulfuric acid stratification. These simulations provide insights for optimizing the design of LABs.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 9","pages":"3951 - 3965"},"PeriodicalIF":2.6,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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The density of states in electrolyte solutions 电解质溶液中状态的密度

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-25 DOI: 10.1007/s10008-025-06287-0

Stephen Fletcher

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Development of an azo-based organic electrode material for aqueous rechargeable lithium batteries 用于水可充电锂电池的偶氮基有机电极材料的研制

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-23 DOI: 10.1007/s10008-025-06282-5

M. Chaithra, G. S. Suresh

{"title":"Development of an azo-based organic electrode material for aqueous rechargeable lithium batteries","authors":"M. Chaithra, G. S. Suresh","doi":"10.1007/s10008-025-06282-5","DOIUrl":"10.1007/s10008-025-06282-5","url":null,"abstract":"<div><p>Employment of environmentally friendly, potentially stable, and low-cost organic electrode material is assumed to be a very promising electrode material for next-generation rechargeable lithium batteries (RLBs). Herein for the first time, we fabricated a Bismarck Brown Y (BBY) as electrode material for aqueous rechargeable lithium batteries. BBY is a prototypical aromatic azo compound with two azo bonds (-N = N-) in their molecular structure with an IUPAC name, 4,4′-[benzene-1,3-diyldi(<i>E</i>)diazene-2,1-diyl]dibenzene-1,3-diamine. It reversibly reacts with lithium-ion via redox reaction of the azo group. To improve the electrochemical behaviour and stability of electrode material, carbon nanotubes are incorporated in BBY through solution-processing method. The resulting composite (BBY@CNTs) in three-electrode system showed a discharge capacity of 226.56 mA h g<sup>−1</sup> which proved that N = N bond can act as an active site for reversible redox process. BBY/C│aq. Saturated Li<sub>2</sub>SO<sub>4</sub>│LiMn<sub>2</sub>O<sub>4</sub> full cell showed the charge–discharge capacity at 118.43 mA h g<sup>−1</sup> and 107.24 mA h g<sup>−1</sup>, respectively. This agreeable result mark ably suits this material as an anode in aqueous rechargeable lithium batteries for present and future high energy demands.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 9","pages":"3939 - 3949"},"PeriodicalIF":2.6,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Temperature-aided multi-faced electrochemistry of copper (II) ions set inside self-assembled 2D homocysteine films attached onto the gold surface 附在金表面的自组装2D同型半胱氨酸膜内的铜（II）离子的温度辅助多层电化学

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-22 DOI: 10.1007/s10008-025-06263-8

Nikoloz Nioradze, Tinatin Dolidze, Lela Kvinikadze, David Vashakidze, Dimitri E. Khoshtaryia

{"title":"Temperature-aided multi-faced electrochemistry of copper (II) ions set inside self-assembled 2D homocysteine films attached onto the gold surface","authors":"Nikoloz Nioradze, Tinatin Dolidze, Lela Kvinikadze, David Vashakidze, Dimitri E. Khoshtaryia","doi":"10.1007/s10008-025-06263-8","DOIUrl":"10.1007/s10008-025-06263-8","url":null,"abstract":"<div><p>Transformation of the “ordinary,” (originally appearing) electrochemical cyclic voltammetry (CV) signal of Au/homocysteine/Cu(II) two-dimensional (2D) composite to the amplified sharp voltammetric response was studied in electrolyte solutions by means of the fast-scan cyclic voltammetry. The composite was constructed via building self-assembled (SAM) monolayer of L-homocysteine (L-Hcy) or DL-homocysteine (DL-Hcy) on a gold electrode surface with subsequent anchoring copper(II) on it. The change of nature of electrochemical response of the system was triggered by the moderate elevation of temperature of the cell (containing phosphate buffer or sodium chloride serving as electrolyte solutions). Solutions at the first stage of the overall procedure of SAM preparation contained L-Hcy or DL-Hcy components, and the copper chloride, at the second stage, aiming anchoring Cu ions onto SAM. This work is another outstanding case reporting about the remarkable specific CV signal transformation for emerging hybrid 2D bioinspired redox-active 2D systems presumably capable of collective charge-carrier exchange transformations.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 9","pages":"3931 - 3938"},"PeriodicalIF":2.6,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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The effect of turbostratic stacking and interlayer disorder on the birnessite recharging 涡层堆积和层间无序对硼钛矿再充注的影响

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-22 DOI: 10.1007/s10008-025-06274-5

Sergey Ya. Istomin, Leonid V. Pugolovkin, Kirill A. Dosaev, Ivan V. Mikheev, Dmitrii A. Strebkov, Aleksandra I. Zybina, Galina A. Tsirlina

{"title":"The effect of turbostratic stacking and interlayer disorder on the birnessite recharging","authors":"Sergey Ya. Istomin, Leonid V. Pugolovkin, Kirill A. Dosaev, Ivan V. Mikheev, Dmitrii A. Strebkov, Aleksandra I. Zybina, Galina A. Tsirlina","doi":"10.1007/s10008-025-06274-5","DOIUrl":"10.1007/s10008-025-06274-5","url":null,"abstract":"<div><p>Three chemically synthesized sodium birnessites with essentially different structural features are studied in respect to the analysis of various contributions to recharging in neutral and alkaline solutions in a wide potential interval. The comparison of voltammetric data in Na<sub>2</sub>SO<sub>4</sub> and NaOH solutions confirms that an apparent extension of the overall recharging interval observed in the former case is a general feature of various birnessites, which can be reliably explained by participation of protons in intercalation and, correspondingly, by local pH increase. This results in the shift of potential scale referred to reversible hydrogen electrode. The effect of lattice disorder induced by the increase of the average oxidation state of manganese, as well as the effect of interlayer space extension, is addressed on the basis of coulometric analysis of scan rate dependence. Rather weak effect of birnessite turbostratic distortions/Mn oxidation state on intercalation contribution to recharging is found. However, this distortion and the extension of the interlayer space favor higher intercalation reversibility at not too high scan rates. The increase of interfacial contribution to recharging by means of birnessite dispersion seems to be the most efficient way to increase the reversible recharging capacity, as this strategy can be applied to any potential interval, when the alternative strategy focused on the increase of intercalation contribution requires too low cathodic potentials, i.e., induces the risk of reductive birnessite degradation.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 2024","pages":"2265 - 2280"},"PeriodicalIF":2.6,"publicationDate":"2025-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144125731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Oxford chemistry primers. Electrode potentials. 2nd Edition 牛津化学底漆。电极电位。第二版

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-21 DOI: 10.1007/s10008-025-06281-6

Galina Tsirlina

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Impact of switching potential and time on the optical performance of Nickel/Tungsten oxide-based electrochromic devices 开关电位和时间对镍/钨基电致变色器件光学性能的影响

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-20 DOI: 10.1007/s10008-025-06256-7

Jarinya Yosthisud, Piyapong Asanithi, Pattana Rakkwamsuk, Chumphon Luangchaisri

{"title":"Impact of switching potential and time on the optical performance of Nickel/Tungsten oxide-based electrochromic devices","authors":"Jarinya Yosthisud, Piyapong Asanithi, Pattana Rakkwamsuk, Chumphon Luangchaisri","doi":"10.1007/s10008-025-06256-7","DOIUrl":"10.1007/s10008-025-06256-7","url":null,"abstract":"<div><p>This study investigates the effects of switching potential and switching time on the optical performance of electrochromic devices (ECDs). Full-cell ECDs were assembled into sandwich-type cells, with nickel hydroxide (NiO<sub>x</sub>H<sub>y</sub>) as the anodic and tungsten oxide (WO₃) as the cathodic layers. A conductive layer of 0.5 M lithium perchlorate in propylene carbonate was used, with all layers positioned between fluorine-doped tin oxide-coated glass. NiO<sub>x</sub>H<sub>y</sub> and WO₃ thin films were deposited via reactive direct current magnetron sputtering under optimized conditions. The optical performance was evaluated under switching potentials (± 0.5 to ± 2.5 V) and switching times (5 to 35 s). Optimal switching conditions were achieved at ± 2.0 V and 30 s, yielding a visible transmittance change (Δ%T<sub>vis</sub>) of 63.2%, a transmittance change at 550 nm (Δ%T<sub>550</sub>) of 65.6%, a contrast ratio of 7.02, and an optical density change of 0.85. Under these conditions, either or both NiO<sub>x</sub>H<sub>y</sub> and WO₃ layers approached saturation, with nearly all sites occupied by the injected Li⁺ ions. They also exhibited excellent optical memory, with %T<sub>550</sub> increasing by only 2.9% over 6,200 s. Stable performance was observed at ± 1.5 V and 20 s, with Δ%T<sub>550</sub> maintained between 44 and 49% for over 12,600 s. These findings highlight the importance of optimizing switching potential and time for enhanced ECD performance. The results are particularly relevant for smart windows, energy-efficient buildings, and automotive glass. Fast switching reduces glare in windshields, improving driving safety, while moderate switching in buildings enhances energy efficiency and occupant comfort.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 9","pages":"3911 - 3929"},"PeriodicalIF":2.6,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Study on the thermal characteristics of layered NMC cathodes in lithium-ion batteries 锂离子电池层状NMC阴极热特性研究

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-20 DOI: 10.1007/s10008-025-06206-3

Milad Nourizadeh, Younes Bakhshan, Jamshid Khorshidi, Saeed Niazi

{"title":"Study on the thermal characteristics of layered NMC cathodes in lithium-ion batteries","authors":"Milad Nourizadeh, Younes Bakhshan, Jamshid Khorshidi, Saeed Niazi","doi":"10.1007/s10008-025-06206-3","DOIUrl":"10.1007/s10008-025-06206-3","url":null,"abstract":"<div><p>Lithium-ion batteries (LIBs) are the primary energy storage solution for electric vehicles due to their excellent energy efficiency, lack of memory effect, prolonged cycle life, high energy density, and enhanced power density. High-capacity nickel manganese cobalt oxide (NMC) pouch cells, increasingly used in automotive applications for their superior energy storage capabilities, are the focus of the model design presented in this study. The researchers developed a P2D electrochemical model and a three-dimensional thermal energy balance for a 37-Ah pouch cell to predict thermal behavior under various operational conditions. The model identifies and characterizes heat sources under different discharge rates and thermal boundary conditions. It also delineates the relationships between electrochemical processes and heat generation within the cell. At the onset of the discharge cycle, the cell’s temperature rises rapidly due to the elevated C-rate, which increases the rate of electrochemical reactions. After the initial temperature rises, the thermal profile stabilizes, and the peak temperature shifts from the tabs to the central regions. An investigation of thermal sources within the cell revealed that the heat of mixing and reversible heat in the positive electrode, along with reaction heat and reversible heat in the negative electrode, are the primary contributors to heat generation. This research examines the behavior of each heat source during the cell discharge process and its underlying mechanisms.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"29 9","pages":"3897 - 3910"},"PeriodicalIF":2.6,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Spectroelectrochemical properties of 8-aminoquinoline: voltammetric and computational studies 8-氨基喹啉的光谱电化学性质：伏安法和计算研究

IF 2.6 4区化学

Journal of Solid State Electrochemistry Pub Date : 2025-03-19 DOI: 10.1007/s10008-025-06267-4

M. Z. Wiloch, D. G. Piekarski, N. Baran, A. Kubas, M. Jönsson-Niedziółka

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