The density of states in electrolyte solutions
IF 2.6
4区 化学
Q3 ELECTROCHEMISTRY
引用次数: 0
Abstract
The goal of this paper is to develop a physical model of energy fluctuations inside electrolyte solutions. The methods used are essentially those of statistical thermodynamics. The key result is an explicit formula for the density of acceptor state energies involved in electron transfer. It is a chi-squared density with one degree-of-freedom. This discovery provides an important correction to the Marcus-Hush-Chidsey theory of electron transfer, which wrongly assumes that the density of energy states in an electrolyte solution is Gaussian.
电解质溶液中状态的密度
本文的目的是建立电解质溶液内部能量波动的物理模型。所用的方法基本上是统计热力学的方法。关键的结果是一个明确的公式的密度受体状态能量参与电子转移。它是一个自由度的卡方密度。这一发现对Marcus-Hush-Chidsey电子转移理论提供了重要的修正，该理论错误地假设电解质溶液中的能态密度是高斯分布的。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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来源期刊
CiteScore
4.80
自引率
4.00%
发文量
227
审稿时长
4.1 months
期刊介绍：
The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry.
The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces.
The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis.
The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.
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