{"title":"Application of Tectona grandis Leaf Extract for Efficient and Stabilized Coloration of Mulberry Silk Fabric","authors":"Shristirupa Borah, Rinku Moni Kalita, Priyanga Manjuri Bhuyan, Barnali Sarma, Swapnali Hazarika, Parikshit Gogoi","doi":"10.1007/s12221-024-00752-9","DOIUrl":"10.1007/s12221-024-00752-9","url":null,"abstract":"<div><p>Plant-based dyes are swiftly supplanting synthetic dyes due to their safe, eco-friendly nature, health benefits, and versatile applications. In this study, an attempt was made to explore the dyeing and functional finishing of mulberry silk using extracts from teak (<i>Tectona grandis</i>) leaves utilizing metal mordants. This method enhances the fastness properties, color strength, antibacterial activity, and UV protection ability of the silk fabric. Based on total polyphenols, flavonoids, and antioxidant activity, methanol/water/HCl was considered as the optimized solvent system for functional component extraction from teak leaves. The highest color yield was found to be in the methanol/water solvent system using HCl at pH 2.5 (<i>K/S</i> = 48.338) and temperature at 80 °C (<i>K/S</i> = 28.009) for a dyeing time of 45 min. The dyed silk with alum mordant exhibited good fastness properties (rating 4–5) and the UPF values were highest with silk dyed using a methanol/water/HCl solvent system (UPF = 56.10). The silk fabric showed good antimicrobial activity against <i>Staphylococcus epidermis</i> MTCC435 dyed with methanol/water and methanol/water/HCl solvent extracts using alum mordant. The bonding interactions were demonstrated by X-ray photoelectron spectroscopy (XPS). The study demonstrated that teak extracts are safe, abundant, and sustainable coloring agents appropriate for dyeing mulberry silk on an industrial scale.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 12","pages":"4755 - 4770"},"PeriodicalIF":2.2,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142778175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Stearyl Alcohol/Polyethylene Glycol Hybrids as Water-Repellent Finishes for Cotton/Polyester Blended Fabric","authors":"H. M. Fahmy, A. Amr","doi":"10.1007/s12221-024-00696-0","DOIUrl":"10.1007/s12221-024-00696-0","url":null,"abstract":"<div><p>Nowadays, developing and innovation of new finishing agents that are cost effective, efficient, durable, and safe for the consumer as well as the environment are greatly required by the textile manufactures. In that concern, new stearyl alcohol/polyethylene glycol (SA/PEG) hybrids were synthesized, characterized, and applied as textile finishes to impart cotton/polyester fabric with water repellency. Such hybrids were synthesized by reaction of SA with PEG of molecular weight 1000 or 4000 Da in the presence of ammonium persulfate (APS) as initiator. The optimum conditions of the synthesis reaction are: APS/PEG, 20%; PEG/SA, 15%; reaction temperature, 80 °C and reaction time, 45 min. The synthesized hybrids are self-water dispersible that form oil-in-water stable emulsions. The results indicated that treating cotton/polyester fabric with easy-care finishing formulation containing 60 g/L of dimethyloldihydroxyethylene urea as a cross-linker, and 60 g/L of any of such hybrids emulsions imparts the treated fabric with water repellency, softness, and stiffness properties. Moreover, increasing the PEG molecular weight from 1000 to 4000 Da leads to a reduction in extents of softness and contact angle along with an enhancement in stiffness of treated fabric. Furthermore, the prepared hybrids emulsions-treated fabric samples are durable up to five washing cycles. The FTIR analysis confirmed the chemical structure of the synthesized SA/PEG1000 hybrid. The transmission electron microscope (TEM) revealed that the particles size of SA/PEG4000 hybrid emulsion is in the range of 34–70 nm and reaches to 185 nm in case of the SA/PEG4000 hybrid emulsion. The surface of SA/PEG1000 hybrid emulsion-treated fabric was characterized via scanning electron microscope (SEM).</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 12","pages":"4641 - 4650"},"PeriodicalIF":2.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12221-024-00696-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142778089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation into the Role of Z-Fiber Orientation in Low-Velocity Impact Behavior of Sandwich-Structured Composite: Numerical and Experimental Analysis","authors":"Fatemeh Hasanalizadeh, Hadi Dabiryan","doi":"10.1007/s12221-024-00732-z","DOIUrl":"10.1007/s12221-024-00732-z","url":null,"abstract":"<div><p>Sandwich composites reinforced with weft-knitted spacer fabrics (WKSF) have a high potential for use in low-velocity impact applications due to the presence of Z-fibers. The present research fabricated sandwich composites using C-glass weft-knitted spacer fabrics and epoxy resin. Three different architectures, i.e., 1 × 1-Rib gaiting, 3 × 3-Rib gaiting, and 5 × 5-Rib, were used to achieve different orientations of Z-fibers. Low-velocity impact test was carried out on the prepared samples. Also, the impact behavior of the sandwich composite was simulated using ABAQUS standard/explicit. The experimental and numerical results show that Z-fibers affect the low-velocity impact behavior of sandwich composites. Based on experiments, the lower maximum reduced acceleration of the impactor and higher contact duration in 3 × 3 Rib-gating means that this specimen has more impact resistance. The indentation percentages of 1 × 1-Rib gaiting, 3 × 3-Rib gaiting, and 5 × 5-Rib gaiting samples were 37%, 34%, and 91%, respectively. In addition, considering the thickness of composites, the experimental indentation of 3 × 3 Rib-gating is lower than other samples which is confirmed by the numerical displacement of the impactor. Numerical analysis showed that the elastic modulus of Z-fibers, its position, and boundary conditions affected stress distribution. The discontinuity among Z-fibers prevents the transfer of stress from the impact area to the outside of this area. Generally, composites reinforced with 3 × 3-Rib gaiting structures show the highest resistance to impact stiffness.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 12","pages":"4807 - 4822"},"PeriodicalIF":2.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142778091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"One-Step Polyester Dyeing and Antibacterial Treatment Using Innovative Thiazole Azo Dyes in Supercritical Carbon Dioxide","authors":"Mamdouh Sofan, Hanan Elsisi, Fathy El-Taweel, Khaled El-nagar, Mohamed Yuesf, Elham Negm","doi":"10.1007/s12221-024-00744-9","DOIUrl":"10.1007/s12221-024-00744-9","url":null,"abstract":"<div><p>A novel approach in the field, a range of new azothiazole dyes substituted with different hydrophobic groups, was utilized as colorants for dyeing polyester fabrics in a supercritical carbon dioxide environment. The innovative dyes were analyzed using standard spectroscopy techniques and elemental analysis. The dyeing process was assessed for its dyeing ability, color strength, and color fastness for twelve different dyes. The polyester fabrics dyed with these dyes appeared in various shades, between red and magenta. Using the AATCC method, the antibacterial assessment revealed that some dyes exhibited significant antibacterial properties against both positive and negative bacteria. All 12 dyes showed outstanding resistance to washing, rubbing, and light, with staining and color change ratings of 4–5. The results indicate that the synthesized dyes could be employed for large-scale, energy-efficient, and environmentally friendly polyester fabric dyeing utilizing supercritical carbon dioxide.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 12","pages":"4713 - 4725"},"PeriodicalIF":2.2,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12221-024-00744-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142778092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gyu Dong Lee, Song Jun Doh, Yoonjin Kim, Jung Nam Im
{"title":"Novel Degradable Superabsorbent Polymers Based on Carboxymethyl Cellulose","authors":"Gyu Dong Lee, Song Jun Doh, Yoonjin Kim, Jung Nam Im","doi":"10.1007/s12221-024-00740-z","DOIUrl":"10.1007/s12221-024-00740-z","url":null,"abstract":"<div><p>In this study, biocompatible and biodegradable superabsorbent polymers (SAPs) were prepared from carboxymethyl cellulose (CMC) using citric acid as a crosslinking agent, utilizing a high-concentration CMC paste and a short annealing process. The effects of CMC molecular weight, annealing temperature and time, and crosslinker concentration on the absorption properties in saline solution were evaluated. In addition, the effects of mixing CMC SAPs with different molecular weights were explored to optimize performance. The results showed that CMC molecular weight significantly affected absorption properties, with medium molecular weight (395 kDa) exhibiting the best overall performance. The content of the crosslinking agent and annealing conditions were also critical—higher crosslinking improved absorption under load but reduced free swell absorption and retention. In addition, the absorption properties could be optimized by appropriately mixing the CMC SAPs with different molecular weights, indicating complementary interactions that enhance performance beyond the individual contributions of each SAPs. These findings can contribute to the development of environmentally friendly, high-performance superabsorbent materials for personal care products as a sustainable alternative to conventional petroleum-derived SAPs.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4185 - 4198"},"PeriodicalIF":2.2,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yi Li, Haopeng Wang, Hongda Cheng, Ye Zhang, Huan Wang, Changyu Han
{"title":"Poly(l-lactide)/poly(d-lactide)/bamboo fiber (BF) bio-composites with enhanced heat resistance, mechanical and rheological performance","authors":"Yi Li, Haopeng Wang, Hongda Cheng, Ye Zhang, Huan Wang, Changyu Han","doi":"10.1007/s12221-024-00753-8","DOIUrl":"10.1007/s12221-024-00753-8","url":null,"abstract":"<div><p>Natural-fiber-reinforced poly(lactic acid) (PLA) is a simple and effective method to improve properties with retaining the fully biodegradability and eco-friendliness. Herein, we prepared the poly(<span>l</span>-lactic acid) (PLLA)/poly(<span>d</span>-lactic acid) (PDLA)/bamboo fiber (BF) bio-composites through melt compounding. The stereocomplex PLA (SC-PLA) was formed during the melt blending. The SC-PLA crystals combined with BFs in the PLLA/PDLA/BF bio-composites had synergistic effects that could enhance crystallization rate, rheological and mechanical properties, and heat resistance. The results showed that the SC-PLA crystals drastically increased the nucleation density and accelerated the crystallization process of the bio-composites. The rheological properties of the bio-composites were obviously enhanced by the incorporation of BFs and PDLA. Mechanical properties of the bio-composites were increased compared to neat PLLA. The bio-composite with 10 wt% PDLA showed tensile strength of 72.4 MPa, and Young’s modulus of 2855 MPa, which were 9.4% and 18% higher than those of neat PLLA, respectively. Moreover, Vicat softening temperature (VST) of the bio-composites was about 90 °C higher than that of neat PLLA. Overall, this work provides an interesting strategy of fabrication of the BFs reinforced PLA composites with controllable properties.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4453 - 4467"},"PeriodicalIF":2.2,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and Characterization of Carboxymethyl Chitosan/Polyvinyl Alcohol Containing Zinc Oxide Nanoparticles as Hydrogel Wound Dressing","authors":"Kimia Bakhtiari, Soheila Kashanian, Rezvan Mohamadinooripoor, Khodabakhsh Rashidi, Soraya Sajadimajd, Kobra Omidfar","doi":"10.1007/s12221-024-00748-5","DOIUrl":"10.1007/s12221-024-00748-5","url":null,"abstract":"<div><p>In the biomedical field, hydrogels are extensively utilized due to their ability to provide mechanical support and create a moist environment for wounds. In this study, nanocomposite hydrogels containing carboxymethyl chitosan (CsMe), polyvinyl alcohol (PVA), and zinc oxide nanoparticles (ZnO-NPs) in different weight ratios (0, 0.5, 0.8, and 1.2%) were prepared for wound healing. The prepared hydrogels were analyzed using Fourier transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FE-SEM), and X-ray diffraction (XRD). Additionally, the mechanical properties, swelling ratio, MTT assay, antibacterial efficacy, and in vivo wound healing were assessed. MTT assays indicated no toxicity after incorporating ZnO-NPs into the hydrogel, and the maximum antibacterial efficiencies of CsMe/PVA/ZnO-NPs (0.5%) hydrogels against <i>E. coli</i> and <i>S. aureus</i> were 91.85 ± 1.2% and 52.7 ± 0.84%, respectively. In vivo studies demonstrated that the hydrogel containing 0.5% ZnO-NPs significantly accelerated wound healing, with 96 ± 2.41% wound closure after 14 days, compared to 83.5 ± 6.76% for the group treated with commercial ZnO ointment. The results suggest that ZnO-NPs in hydrogels enhance antibacterial activity and promote better wound healing than traditional ZnO ointments, offering a promising material for advanced wound care applications.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4199 - 4213"},"PeriodicalIF":2.2,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sylvia Owusua Donkor, Danmei Sun, David Bucknall, Jim Buckman
{"title":"Surface Activation of Cotton Fabric with Low-Temperature Air Plasma Treatment for Metallic Printing","authors":"Sylvia Owusua Donkor, Danmei Sun, David Bucknall, Jim Buckman","doi":"10.1007/s12221-024-00738-7","DOIUrl":"10.1007/s12221-024-00738-7","url":null,"abstract":"<div><p>In this investigation, air plasma treatment was utilised to activate the surfaces of 100% grey and bleached cotton fabrics in preparation for metallic pigment printing. The study delved into the surface morphology, wettability, and surface chemistry properties. Scanning electron microscopy (SEM) revealed roughness and grooves in the treated samples. The contact angle witnessed a 29% and 41% increase for grey and bleached fabrics, respectively, compared to their untreated counterparts. Surface chemistry analysis using FTIR and XPS provided crucial insights into the functional polar groups, such as OH and C=O, along with significantly elevated O1 peaks in both plasma-treated grey and bleached cotton fabrics. These findings contributed to the enhanced surface free energy of the fabrics, preparing them for the subsequent pigment printing process. The study explores the impact of plasma treatment on the colour fastness of grey and bleached cotton fabrics printed with gold and silver metallic pigments. Untreated fabrics exhibited poor durability, with low colour change and staining-resistance ratings, particularly for gold pigments. Plasma treatment significantly improved colour retention, adhesion, and resistance to staining for both metallic pigments, with silver outperforming gold. Rubbing fastness tests revealed that plasma treatment moderately enhanced durability, though gold remained susceptible to friction damage. Light fastness was excellent for both pigments, and plasma treatment further improved performance. Perspiration tests showed that plasma treatment bolstered resistance, particularly for gold. These findings suggest that plasma treatment enhances the stability of metallic pigments, offering potential applications in the textile industry for improved product quality and durability.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4321 - 4332"},"PeriodicalIF":2.2,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12221-024-00738-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mahmoud M. Awd Allah, Mohamed A. Abbas, Ali Saeed Almuflih, Samy F. Mahmoud, Marwa A. Abd El-baky
{"title":"On the Influence of Different Infill Pattern Structures on the Crashworthiness Performance of 3D Printed Tubes Subjected to Lateral Loading Condition","authors":"Mahmoud M. Awd Allah, Mohamed A. Abbas, Ali Saeed Almuflih, Samy F. Mahmoud, Marwa A. Abd El-baky","doi":"10.1007/s12221-024-00756-5","DOIUrl":"10.1007/s12221-024-00756-5","url":null,"abstract":"<div><p>The objective of this research is to investigate the effect of different infill pattern structures on the deformation behavior and crashworthiness performance of 3D-printed tubes under quasi-static lateral compression loading. Subsequently, polylactic-acid (PLA) was utilized in the 3D printing process to create the proposed tubes. Five distinct infill pattern structures were fabricated: circular, square, triangular, zig-zag, and cross patterns, each designed with a consistent infill density of 50%. Following that, quasi-static lateral compression loading was applied to the printed structure. The failure histories were tracked, and the crashing load and energy absorbed versus displacement responses were provided for the tested tubes. Several indications were measured to conduct the crashworthiness examination, i.e., the initial peak load (<span>({F}_{text{ip}})</span>), total absorbed energy (AE), and specific energy absorption (SEA). Furthermore, the complex proportional assessment (COPRAS) method, was employed to identify the optimal infill pattern for maximizing crashworthiness performance. The analysis showed that the zig-zag infill pattern with 2.13 kN, 62.52 J, and 2.90 J/g, respectively, for <span>({F}_{text{ip}})</span>, AE, and SEA, showed the maximum performance in energy absorption among the investigated patterns, according to the COPRAS analysis.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4437 - 4451"},"PeriodicalIF":2.2,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaodong Tan, Qingyan Peng, Zbigniew Stempień, Jana Saskova, Mohanapriya Venkataraman, Jakub Wiener, Jiri Militky
{"title":"Development of Supercapacitor Electrodes with High Strength via Inkjet Printing of Reduced Graphene Oxide/Aramid Nanofibers Membranes","authors":"Xiaodong Tan, Qingyan Peng, Zbigniew Stempień, Jana Saskova, Mohanapriya Venkataraman, Jakub Wiener, Jiri Militky","doi":"10.1007/s12221-024-00754-7","DOIUrl":"10.1007/s12221-024-00754-7","url":null,"abstract":"<div><p>Supercapacitors (SCs), as emerging electrochemical energy storage devices, have garnered widespread attention due to their rapid charge–discharge characteristics and high power density. With the growing demand for electronic devices and the diversification of applications in daily life scenarios, SCs with outstanding flexibility, mechanical and electrochemical performance are becoming increasingly important. In this study, an in situ reduction method was employed, utilizing inkjet printing technology to deposit reduced graphene oxide (rGO) onto the prepared aramid nanofibrous (ANFs)/PVDF/PVA composite film for the fabrication of solid-state SCs. The optimized ANFs/PVDF/PVA composite film exhibited a tensile strength and Young's modulus of 185 N and 760 MPa, respectively. Even in a bent state, the cyclic voltammetry (CV) curves remained essentially unchanged. At a current density of 0.1 A/g, the specific capacitance and energy density reached 120.9 F/g and 10.8 Wh/kg, respectively, while at a current density of 0.5 A/g, the power density reached 3201 W/kg. After 5000 charge–discharge cycles, the efficiency maintained above 90%. Such exceptional electrochemical and mechanical performance provides more options for the manufacturing of next-generation portable and wearable electronic devices.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4215 - 4226"},"PeriodicalIF":2.2,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}