Fibers and Polymers最新文献

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Surface Modification of Plain-Woven Ramie Fabrics Using Bridged Bis (3-Trimethoxysilylpropyl) Amine Silane for Improved Hydrophobicity 使用桥式双(3-三甲氧基硅丙基)胺硅烷对平织苎麻织物进行表面改性以提高疏水性
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-23 DOI: 10.1007/s12221-024-00737-8
Bewuket Teshome Wagaye, Jiansheng Guo, Buguang Zhou, Can Gao, Luc The Nguyen
{"title":"Surface Modification of Plain-Woven Ramie Fabrics Using Bridged Bis (3-Trimethoxysilylpropyl) Amine Silane for Improved Hydrophobicity","authors":"Bewuket Teshome Wagaye,&nbsp;Jiansheng Guo,&nbsp;Buguang Zhou,&nbsp;Can Gao,&nbsp;Luc The Nguyen","doi":"10.1007/s12221-024-00737-8","DOIUrl":"10.1007/s12221-024-00737-8","url":null,"abstract":"<div><p>Conventional silane treatment can increase the hydrophobicity of natural cellulosic fibers. This report employs a combination of alkali and dipodal silane treatments. Bridged bis (3-trimethoxysilylpropyl) amine (BAS), a dipodal silane, was used instead of regular ones to enhance the hydrophobicity of ramie plain-woven fabrics. Before silane application, alkali treatment conditions’ impact on mechanical properties was optimized using response surface methodology (RSM). The desirability function approach and graphical optimization techniques were employed to find out the optimum condition. The RSM demonstrated that a concentration of 6.11% alkali, a duration of 30 min, and a temperature of 39.10 °C yielded the optimal conditions, resulting in a breaking force of 518.27 N and an elongation of 23.36%. After optimization of parameter, alkali treatment of the fabric was carried out. These alkali-treated fabrics were then bulk-treated with BAS. The Taguchi L9 orthogonal array experimental design was applied to identify a variable that has the highest impact on the hydrophobicity. Furthermore, BAS’s impact on water contact angle (WCA), surface morphology, and thermal properties was investigated. Alkali-treated ramie fabrics absorb water due to hemicellulose and lignin removal. However, BAS treatment resulted in a hydrophobic ramie fabric surface, as the combined alkali and BAS-treated fabrics exhibit a WCA greater than 94°, reaching 113.85°. According to thermo-gravimetric analysis, combined alkali and silane treatment improved the degradation temperature of fabrics to 403.25 °C. This improvement is attributed to the formation of six, rather than three, Si–O bonds on the ramie fabric surface.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4307 - 4320"},"PeriodicalIF":2.2,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of an All-Natural Seaweed Functionalized Lyocell Fiber: A Scalable Approach from Nature to Fabrics 制备全天然海藻功能化 Lyocell 纤维:从自然到织物的可扩展方法
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-23 DOI: 10.1007/s12221-024-00730-1
Jiayu Zhang, Ting Li, TianYin Liu, Chenxi Zhang, Xiaojun Li, Chunxiao Yu, Zhongkai Xu, Genli Wang, Chunzu Cheng, Jigang Xu
{"title":"Preparation of an All-Natural Seaweed Functionalized Lyocell Fiber: A Scalable Approach from Nature to Fabrics","authors":"Jiayu Zhang,&nbsp;Ting Li,&nbsp;TianYin Liu,&nbsp;Chenxi Zhang,&nbsp;Xiaojun Li,&nbsp;Chunxiao Yu,&nbsp;Zhongkai Xu,&nbsp;Genli Wang,&nbsp;Chunzu Cheng,&nbsp;Jigang Xu","doi":"10.1007/s12221-024-00730-1","DOIUrl":"10.1007/s12221-024-00730-1","url":null,"abstract":"<div><p>Based on the green and environmentally friendly production process of lyocell fiber, an innovative lyocell fiber was prepared by online-adding seaweed micron particles using a new dispersion procedure. Considering the fiber diameter range of 10–15 μm. To improve the incorporation rate of seaweed powders, the particle size distribution and compatibility of seaweed powders in NMMO were first studied. On comparing the powder size distribution of seaweed particle in different disperse liquid, it was found that seaweed powders are partially soluble in NMMO and weaken the inherent alkaline environment, while the remaining powders swell more significantly with increasing NMMO concentration. Following this protocol, an integrated dispersion process was successfully developed with high seaweed loading in low-concentration NMMO solution. The resultant functionalized seaweed modified lyocell fibers (abbreviated as “SL Fiber”) demonstrated effective loading of seaweed particles, comparable mechanical properties, improved heat resistance and antibacterial properties. Thus, the fibers meet the major requirements for hometextiles, packaging materials, filtration, and other fields. The antibacterial rates of fibers against <i>Escherichia coli</i>, Staphylococcus aureus, and <i>Candida albicans</i> all reached the requirements, inhibiting harmful bacteria growth and preventing mold and odor. To demonstrate the multi-functionality in textile applications, the novel SL fibers were scale produced on production line. The article demonstrated a facile and scalable approach from fiber preparation and yarn spinning to textile weaving applications. These novel materials are natural, recyclable and renewable, which is more in line with the development strategy of green manufacturing and the green cycle of the industrial chain.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4257 - 4269"},"PeriodicalIF":2.2,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of Impact, Shear and Wear Performance of Glass Fiber/Epoxy Composites by Inclusion of Polycarbonate Sheets 通过加入聚碳酸酯板增强玻璃纤维/环氧树脂复合材料的冲击、剪切和磨损性能
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-23 DOI: 10.1007/s12221-024-00757-4
Amr Seif, Samy F. Mahmoud, M. Megahed
{"title":"Enhancement of Impact, Shear and Wear Performance of Glass Fiber/Epoxy Composites by Inclusion of Polycarbonate Sheets","authors":"Amr Seif,&nbsp;Samy F. Mahmoud,&nbsp;M. Megahed","doi":"10.1007/s12221-024-00757-4","DOIUrl":"10.1007/s12221-024-00757-4","url":null,"abstract":"<div><p>The key objective of this study is to fabricate an unconventional composite structure with outstanding impact performance, low weight, low cost, and better wear resistance. Utilizing a hand lay-up procedure, epoxy composites reinforced with glass fibers (G) and polycarbonate (PC) sheets were fabricated. Neat glass (NG) and three distinct hybrid PC composites were produced by altering the position of the PC sheets. The flat and edgewise impact, in-plane shear strength, and wear behavior of hybrid composites were studied to assess their performance and compatibility for various industrial applications. Morphological investigations of the fractured surfaces were conducted with a digital microscope. The results showed that hybrid PC specimens enhanced flat and edge-wise impact performance by an average of 100.9%. Impact strength values are significantly affected by the arrangement pattern. The presence of PC in the outer and core composite laminates improved shear strength by 15.09% and 14.85%, respectively. The hybrid composites produced smooth and free-of-damage worn surfaces, resulting in a significant reduction in the specific wear rate of 40.4%.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4421 - 4436"},"PeriodicalIF":2.2,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improvement of Moisture Transmission Properties of Acrylic–Cotton Blended Fabric Using Calcium Chloride-Based Desiccants: A Novel Approach 使用氯化钙基干燥剂改善腈纶-棉混纺织物的透湿性能:一种新方法
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-22 DOI: 10.1007/s12221-024-00739-6
Rijon Saha, Md. Abdul Hannan, Umera Islam, Anamul Hoque Bhuiyan
{"title":"Improvement of Moisture Transmission Properties of Acrylic–Cotton Blended Fabric Using Calcium Chloride-Based Desiccants: A Novel Approach","authors":"Rijon Saha,&nbsp;Md. Abdul Hannan,&nbsp;Umera Islam,&nbsp;Anamul Hoque Bhuiyan","doi":"10.1007/s12221-024-00739-6","DOIUrl":"10.1007/s12221-024-00739-6","url":null,"abstract":"<div><p>This research reports the results of a work intended to increase the attributes regarding moisture management of acrylic–cotton-blended single jersey fabrics. In a single-step exhaust method, the blended fabric is treated with 60% calcium chloride-based desiccant at 60 °C for 1 h. The multidirectional liquid transport behavior of treated fabric through properties such as time for wetting, rate of absorbing moisture, maximum radius of wetted area, speed of spreading the test liquid, moisture transport index, and total moisture management capacity is analyzed. The experimental results exhibit improvement in the moisture management property of the treated fabrics from 0 to 0.75. The wettability of the fabric is also enhanced as the water contact angle has reduced from 108.37° to 66.45° after the treatment. Treated samples transport the test liquid across the fabric much more quickly than untreated samples due to fabric–desiccant interaction through a strong hydrogen bond. This is characterized by an FTIR peak at 2341 cm<sup>−1</sup> which gets reduced after treatment. The impact of desiccant treatment on physical properties such as color strength, fabric thickness and weight was also analyzed. The desiccant treatment shows durability up to five wash cycles equivalent to 25 home laundering cycles, dictating a great prospect of applying this method in the moisture management of cotton–acrylic-blended textiles. Moreover, the presence of randomly deposited desiccant particles on the blended fabric surface confirmed by SEM is achieved in a single step, emphasizing the versatility of this method.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4291 - 4306"},"PeriodicalIF":2.2,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Activated Carbon/Polyaniline Composite for Azo Dye Adsorption: Kinetics, Equilibrium, Thermodynamics, and Statistical Physics Interpretations 用于偶氮染料吸附的活性炭/聚苯胺复合材料:动力学、平衡、热力学和统计物理学解释
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-21 DOI: 10.1007/s12221-024-00750-x
Hind Hajjaoui, Amal Soufi, Mohamed Abdennouri, Aicha Machrouhi, Abdelhakim Elmouwahidi, Maymounah N. Alharthi, Noureddine Barka
{"title":"Activated Carbon/Polyaniline Composite for Azo Dye Adsorption: Kinetics, Equilibrium, Thermodynamics, and Statistical Physics Interpretations","authors":"Hind Hajjaoui,&nbsp;Amal Soufi,&nbsp;Mohamed Abdennouri,&nbsp;Aicha Machrouhi,&nbsp;Abdelhakim Elmouwahidi,&nbsp;Maymounah N. Alharthi,&nbsp;Noureddine Barka","doi":"10.1007/s12221-024-00750-x","DOIUrl":"10.1007/s12221-024-00750-x","url":null,"abstract":"<div><p>Activated carbon (Ac) prepared from <i>Thapsia transtagana</i> was combined with a different ratio of aniline to synthesize Ac/PAni composites. Various characterization techniques, such as XRD, FESEM-EDX, TEM, and ATR-FTIR, were conducted to confirm the structure, surface morphology, and chemical characteristics of the composites. The materials were tested for eriochrome black T (EBT) adsorption. Batch results exposed that the Ac/PAni6 with the highest ratio of aniline displays the highest EBT removal efficiency. The kinetics of EBT adsorption over the Ac/PAni6 composite followed the Elovich model, and the equilibrium data suited the Redlich–Peterson and Toth isotherm models. The adsorption was spontaneous, feasible, and endothermic. The statistical physics equations have also been investigated. Four models have been proposed as one layer and two layers with one and two energies. The adsorption of EBT on the Ac/PAni6 composite correlated to the one layer two energies model. The statistical physical parameters, including the number of adsorbed molecules per site (<span>({n}_{1})</span>, <span>({n}_{2})</span>), the receptor sites density (<span>({N}_{1M})</span>, <span>({N}_{2M})</span>), the adsorption capacity at saturation (<span>({Q}_{1})</span>, <span>({Q}_{2})</span>), and the energy of adsorption (<span>({E}_{1})</span>, <span>({E}_{2})</span>) have all been considered. The total capacity at saturation is enhanced with temperature, which approves the endothermic nature of the process. The interpretation of the calculated energies <span>({E}_{1})</span> and <span>({E}_{2})</span> (&lt; 40 kJ/mol) suggested that the EBT interaction with the Ac/PAni6 surface was mainly a physisorption process.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4333 - 4348"},"PeriodicalIF":2.2,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilization of Waste Cotton Fibers by Extracting Nanocellulose Crystals: A Study on Phosphoric Acid Method Compared with Sulfuric Acid Method and TEMPO Oxidation Method 通过提取纳米纤维素晶体利用废棉纤维:磷酸法与硫酸法和 TEMPO 氧化法的比较研究
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-20 DOI: 10.1007/s12221-024-00733-y
Mohan Hou, Lifang Wang, Qiuyu Xu, Xuepeng Zhang, Xue Yang, Lei Zhang, Yun Bai, Yanyun Li, Lifang Liu
{"title":"Utilization of Waste Cotton Fibers by Extracting Nanocellulose Crystals: A Study on Phosphoric Acid Method Compared with Sulfuric Acid Method and TEMPO Oxidation Method","authors":"Mohan Hou,&nbsp;Lifang Wang,&nbsp;Qiuyu Xu,&nbsp;Xuepeng Zhang,&nbsp;Xue Yang,&nbsp;Lei Zhang,&nbsp;Yun Bai,&nbsp;Yanyun Li,&nbsp;Lifang Liu","doi":"10.1007/s12221-024-00733-y","DOIUrl":"10.1007/s12221-024-00733-y","url":null,"abstract":"<div><p>Waste cotton fibers are an ideal raw material for extracting nanocellulose crystals (CNCs), benefitting from  their high cellulose content. In this study, the waste cotton fibers from the calendering finishing process were used to extract CNCs by sulfuric acid, TEMPO oxidation, and phosphoric acid methods, aiming to create a new way to reutilize the waste cotton fiber and also to verify the practicability that the phosphoric acid method can replace sulfuric acid and TEMPO oxidation methods. The CNCs obtained from the three methods are all in cellulose I state with an average length of 200-500nm and diameter of 15-20nm, indicating that the waste cotton fiber can extract CNCs. However, the CNCs from the phosphoric acid method showed the highest thermostability but the lowest crystallinity, while the ones from the sulfuric acid and TEMPO oxidation methods had higher crystallinity but lower thermal stability. Overall, the three methods are all acceptable for preparing CNCs, but the phosphoric acid method has more significant potential due to its low cost, environmental friendliness, and safety.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4271 - 4281"},"PeriodicalIF":2.2,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical Performance of Intralayer Hybrid 3D Woven Honeycomb Core for Lightweight Structural Composites 用于轻质结构复合材料的层内混合三维编织蜂窝芯材的力学性能
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-18 DOI: 10.1007/s12221-024-00743-w
Omender Singh, B. K. Behera
{"title":"Mechanical Performance of Intralayer Hybrid 3D Woven Honeycomb Core for Lightweight Structural Composites","authors":"Omender Singh,&nbsp;B. K. Behera","doi":"10.1007/s12221-024-00743-w","DOIUrl":"10.1007/s12221-024-00743-w","url":null,"abstract":"<div><p>In weight-sensitive applications, the widespread use of honeycomb composites underscores the significance of enhancing their specific strength and energy absorption capacity. In this pursuit, various hybrid honeycomb structures have been developed, with a particular focus on their cell wall buckling behaviour. This study involved testing six different specimen types, incorporating intralayer hybridization with materials namely, Kevlar, Glass, Dyneema, Sisal, Hemp, and Jute. The incorporation of the intralayer hybrid technique examined various aspects of honeycomb structures, leading to improvements in mechanical performance. In addition, the effects of specific energy absorption and crush force efficiency on the compressive and flexural strength were investigated. Among all the samples, the honeycomb core with a height of 15 mm demonstrated the highest compressive strength and specific energy absorption values. This enhancement is attributed to the synergistic effects of intralayer hybridization, emphasizing the potential for utilizing natural alternatives such as sisal, hemp, and jute, which may offer pronounced advantages in impact stress propagation within hybrid composites.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4401 - 4419"},"PeriodicalIF":2.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling the Static Puncture (CBR) Properties of Non-woven Geotextiles Based on Neural Network and Multi-optimization 基于神经网络和多重优化的无纺土工织物静态穿刺(CBR)性能建模
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-18 DOI: 10.1007/s12221-024-00746-7
Morteza Vadood, Mohammad Saleh Ahmadi, Hasan Mashroteh, Mohammad Javad Abghary, Zahra Hajhosaini
{"title":"Modeling the Static Puncture (CBR) Properties of Non-woven Geotextiles Based on Neural Network and Multi-optimization","authors":"Morteza Vadood,&nbsp;Mohammad Saleh Ahmadi,&nbsp;Hasan Mashroteh,&nbsp;Mohammad Javad Abghary,&nbsp;Zahra Hajhosaini","doi":"10.1007/s12221-024-00746-7","DOIUrl":"10.1007/s12221-024-00746-7","url":null,"abstract":"<div><p>The optimization of geotextile mechanical properties is crucial for enhancing their performance in civil engineering applications such as soil reinforcement and stabilization. This study focuses on the influence of manufacturing parameters on the static puncture (CBR) properties of polyester geotextiles. Polyester geotextile samples were manufactured using various parameters, including needle-punching density, penetration depth, calendering temperature, and speed. The mechanical properties of the samples, specifically strength and elongation, were evaluated using the CBR test according to EN ISO 12236. The data were analyzed using multivariate analysis of variance, followed by statistical analysis to determine the influence of the manufacturing parameters on the mechanical properties. Furthermore, the relationship between these parameters and the mechanical properties was modeled using artificial neural networks (ANN) and regression analysis. The results indicated that all manufacturing parameters significantly impacted the strength and elongation of the geotextiles. The ANN models, employing two hidden layers, predicted the strength and elongation with errors of 1.43% and 1.26%, respectively.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4495 - 4502"},"PeriodicalIF":2.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Radial Distribution of Functional Groups in Polyacrylonitrile Pre-oxidized Fibers 聚丙烯腈预氧化纤维中官能团的径向分布
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-18 DOI: 10.1007/s12221-024-00751-w
Panpan Xu, Junxin Tang, Yutao Liu, Ke Zhang, Changqing Li
{"title":"Radial Distribution of Functional Groups in Polyacrylonitrile Pre-oxidized Fibers","authors":"Panpan Xu,&nbsp;Junxin Tang,&nbsp;Yutao Liu,&nbsp;Ke Zhang,&nbsp;Changqing Li","doi":"10.1007/s12221-024-00751-w","DOIUrl":"10.1007/s12221-024-00751-w","url":null,"abstract":"<div><p>The functional group distribution and skin–core structure of polyacrylonitrile (PAN) pre-oxidized fibers have been evaluated by solid-state <sup>13</sup>C-NMR, electron probe micro-analysis, element analysis, nano-infrared spectroscopy atomic force microscopy, and optical microscopy. The pre-oxidized fibers exhibited a skin–core structure with high optical density (OD) values in the skin and low OD values in the core. As the heat treatment temperature was increased, the OD of the pre-oxidized fibers increased, which is because of the formation of C = O, C = N, C = C, and their conjugated structures of C = N with C = C. The difference in the OD values between the pre-oxidized fiber skin and core became increasingly apparent as the heat treatment temperature increased, with the OD difference increasing from 0.045 at 220 °C to 0.085 at 260 °C. The OD difference is closely related to the oxygen element and C = O functional groups in the fiber. The contents of the oxygen element and C = O in the pre-oxidized fiber skin were higher than those in the pre-oxidized fiber core. At a heat treatment temperature of 260 °C, the relative content of C = O in the skin was 0.454, whereas that in the core was 0.313, which was consistent with the trend of the OD value change. In comparison, C = C and C = N formed during pre-oxidation were not substantially distributed in the radial direction of the fibers. The radial inhomogeneity of the pre-oxidized fiber was mainly affected by the radial difference of the carbonyl content.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"25 11","pages":"4283 - 4290"},"PeriodicalIF":2.2,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142579536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of infrared-, ultrasonic-, and microwave-assisted mordanting methods for the natural dyeing properties of hemp fabrics 比较红外线、超声波和微波辅助媒染法对麻织物天然染色性能的影响
IF 2.2 4区 工程技术
Fibers and Polymers Pub Date : 2024-10-15 DOI: 10.1007/s12221-024-00724-z
Seranee Srisuk, Thipparat Intarat, Natchaporn Damkham, Penwisa Pisitsak
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