Fibers and Polymers最新文献

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Enhancing the Dyeing and Color Fastness Properties of Cotton Fabric Dyed with Curcumin: A Sustainable Double Mordanting Approach Using Waste-Derived Biomordants 提高姜黄素染色棉织物的染色和色牢度:利用废物来源的生物染发剂可持续的双重染发剂方法
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-11 DOI: 10.1007/s12221-025-01059-z
Md Morshedur Rahman, Sanghyun Yoon, Seunga Choi, Soohyun Kim, Youngdae Kim, Ingi Hong, Nazrul Hsan, Nahyun Oh, Santosh Kumar, Joonseok Koh
{"title":"Enhancing the Dyeing and Color Fastness Properties of Cotton Fabric Dyed with Curcumin: A Sustainable Double Mordanting Approach Using Waste-Derived Biomordants","authors":"Md Morshedur Rahman,&nbsp;Sanghyun Yoon,&nbsp;Seunga Choi,&nbsp;Soohyun Kim,&nbsp;Youngdae Kim,&nbsp;Ingi Hong,&nbsp;Nazrul Hsan,&nbsp;Nahyun Oh,&nbsp;Santosh Kumar,&nbsp;Joonseok Koh","doi":"10.1007/s12221-025-01059-z","DOIUrl":"10.1007/s12221-025-01059-z","url":null,"abstract":"<div><p>Natural dyes are increasingly favored for their eco-friendly, sustainable, and non-toxic properties. However, their application in textiles is often hindered by limitations such as low color yield and poor fastness, which necessitate the use of mordants. This study investigates the effectiveness of a double mordanting technique to enhance the color strength and fastness of curcumin, a natural yellow dye derived from turmeric, on cotton fabrics. The double mordanting process involved the sequential application of waste-derived biomaterials (pomegranate rind, onion peel, and chitosan) and metallic mordants, followed by dyeing with curcumin. The dyed fabrics were comprehensively evaluated based on color parameters, color strength, levelness, and fastness. Results showed that double mordanting led to a significant improvement in both color strength—up to 69.68% higher—and wash fastness—up to 1.5 grades better—compared to traditional single mordanting. Additionally, the process reduced the residual metal content in the mordant bath by up to 27.00%, promoting a more sustainable dyeing method. Various combinations of biomordants and metal mordants were found to produce fabrics with diverse hues and shades. Notably, the combination of pomegranate rind and iron(II) sulfate yielded a rich, deep black shade on cotton. These findings underscore the potential of using waste-derived biomordants in a double mordanting process as an eco-conscious and effective strategy to enhance the performance of curcumin-dyed cotton while minimizing environmental impact.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"3963 - 3979"},"PeriodicalIF":2.3,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrospun Polycarbonate-Thermoplastic Polyurethane Nanocomposite Membranes Incorporating Copper Oxide Nanoparticles for Efficient Water Treatment: Anti-fouling Performance Against Organic Pollutant 含有氧化铜纳米粒子的电纺聚碳酸酯-热塑性聚氨酯纳米复合膜用于高效水处理:对有机污染物的防污性能
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-10 DOI: 10.1007/s12221-025-01073-1
Javad Yekrang, Habib Etemadi, Seyed Mehdi Sajjadi
{"title":"Electrospun Polycarbonate-Thermoplastic Polyurethane Nanocomposite Membranes Incorporating Copper Oxide Nanoparticles for Efficient Water Treatment: Anti-fouling Performance Against Organic Pollutant","authors":"Javad Yekrang,&nbsp;Habib Etemadi,&nbsp;Seyed Mehdi Sajjadi","doi":"10.1007/s12221-025-01073-1","DOIUrl":"10.1007/s12221-025-01073-1","url":null,"abstract":"<div><p>Electrospun nanocomposite membranes (ENCMs) offer promising advancements for water microfiltration (MF) applications. In this study, polycarbonate/thermoplastic polyurethane (PC/TPU) nanocomposite membranes were electrospun and incorporated with 1, 3, and 5 wt.% copper oxide nanoparticles (CuO NPs). The resulting membranes were evaluated in terms of their morphological features, chemical composition, hydrophilicity, tensile strength, water flux performance, and anti-fouling capabilities. Morphological analysis revealed that the average diameter of the electrospun nanofibers ranged between 67 and 90 nm. Energy dispersive X-ray spectroscopy (EDS) indicated a tendency for CuO NPs migration and agglomeration at the highest loading of 5 wt.%. Fourier transform infrared spectroscopy (FTIR) confirmed the presence of all characteristic functional groups from the constituent materials in the final nanocomposite membranes. Water contact angle (WCA) measurements demonstrated a significant improvement in membrane hydrophilicity with CuO NP incorporation. Specifically, WCA decreased from 114° for the neat membrane to 63° when the CuO NP content was increased to 3 wt.%. Water flux experiments were carried out using a submerged filtration module with humic acid (HA) as a model organic pollutant. The membrane containing 3 wt.% CuO NPs exhibited a pure water flux of 907 L.m<sup>−2</sup>.h<sup>−1</sup> and a HA solution flux of 446 L.m<sup>−2</sup>.h<sup>−1</sup>. Furthermore, NFM-Cu3 displayed superior anti-fouling performance with an irreversible fouling ratio (IFR) of only 5.8% and high HA rejection efficiency of about 99%. These findings suggest that ENCMs containing CuO NPs has the potential to serve as an effective alternative to conventional thin-film polymer membranes in water filtration systems, offering improved permeability, selectivity, and fouling resistance.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"3871 - 3888"},"PeriodicalIF":2.3,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of Prussian Blue Dye/SiO2 Composite Microspheres and Their Structurally Coloration on White Fabrics 普鲁士蓝染料/二氧化硅复合微球的制备及其在白色织物上的结构着色
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-10 DOI: 10.1007/s12221-025-01044-6
Yijian Lu, Weihong Gao, Xiaoyan Zhao, Xinyi Yang, Yijiao Sun, Shu Yang, Binjie Xin
{"title":"Fabrication of Prussian Blue Dye/SiO2 Composite Microspheres and Their Structurally Coloration on White Fabrics","authors":"Yijian Lu,&nbsp;Weihong Gao,&nbsp;Xiaoyan Zhao,&nbsp;Xinyi Yang,&nbsp;Yijiao Sun,&nbsp;Shu Yang,&nbsp;Binjie Xin","doi":"10.1007/s12221-025-01044-6","DOIUrl":"10.1007/s12221-025-01044-6","url":null,"abstract":"<div><p>Structural coloration is renowned for its vibrant hues and environmental compatibility; however, it frequently exhibits unsatisfactory chromatic performance on white substrates. To enhance the color saturation of structural colors on white textiles, this study engineered composite structural units by electrostatically adsorbing Prussian blue (PB) dye onto silica (SiO₂) microspheres, forming core–shell architectures with outer dye coatings. Two fabrication approaches—spray coating and gravity sedimentation—were employed to construct structural colors on white polyester fabrics. The results demonstrated that Prussian blue dye/SiO<sub>2</sub> composite microspheres (SiO<sub>2</sub>@PB) enabled vivid structural coloration on white textiles. Notably, the spray-coating method promoted a more ordered and regular arrangement of SiO₂@Prussian blue microspheres across fabric surfaces compared to gravity sedimentation, thereby yielding superior structural color performance. This methodology effectively circumvents the conventional requirement for black substrates, achieving high-contrast structural coloration directly on white textile matrices, while streamlining the textile coloration process. The proposed strategy establishes a viable pathway for improving structural color quality in white textiles, with potential implications for sustainable pigment-free manufacturing.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"3941 - 3950"},"PeriodicalIF":2.3,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Roll-to-Roll Oxidative Chemical Vapor Deposition of Highly Conductive and Uniform Thin Films on Large-Scale Textile Substrates 高导电性和均匀性薄膜在大规模纺织基材上的卷对卷氧化化学气相沉积
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-10 DOI: 10.1007/s12221-025-01078-w
Kurtuluş Yılmaz, Mustafa Karaman
{"title":"Roll-to-Roll Oxidative Chemical Vapor Deposition of Highly Conductive and Uniform Thin Films on Large-Scale Textile Substrates","authors":"Kurtuluş Yılmaz,&nbsp;Mustafa Karaman","doi":"10.1007/s12221-025-01078-w","DOIUrl":"10.1007/s12221-025-01078-w","url":null,"abstract":"<div><p>A continuous vapor deposition process is demonstrated for organic conductive surface modification of large-area textile substrates. Transparent and conductive poly(3,4-ethylenedioxythiophene) (PEDOT) films were deposited by oxidative chemical vapor deposition (oCVD) technique on polyethylene terephthalate (PET) fabrics in a roll-to-roll fashion, in which as-deposited PEDOT films had excellent thickness and structural uniformity across very large areas (2 × 250 cm). We designed a continuous vacuum deposition system, in which the feeding and wrapping units of the system were in the open air, thanks to the specially designed fabric feedthroughs in and out of the vacuum system. The pristine fabric was fed into the oCVD vacuum reactor by unreeling from the outside atmosphere, where it was pretreated with oxidant iron(III) chloride (FeCl<sub>3</sub>) solution. The effect of rolling speed of the fabric on the structure, morphology, uniformity, and electrical conductivities of the as-deposited PEDOT films were studied. FTIR and SEM analyses were carried out to verify the structure and morphology of as-deposited PEDOT films. Uniform and conformal PEDOT films with measurable conductivity were observed independent of the rolling speed. The highest conductivity value of 803.5 S/cm was observed for the films deposited at a rolling speed of 8 cm/min and doped with Cl<sup>–</sup> ions from a 3.5 wt.% HCI solution.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"3919 - 3926"},"PeriodicalIF":2.3,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Comprehensive Experimental and Numerical Analysis on Free Vibration and Axial Buckling Behavior of Hybrid Composites 混杂复合材料自由振动和轴向屈曲行为的综合实验与数值分析
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-10 DOI: 10.1007/s12221-025-01071-3
Muhammet Raci Aydin
{"title":"A Comprehensive Experimental and Numerical Analysis on Free Vibration and Axial Buckling Behavior of Hybrid Composites","authors":"Muhammet Raci Aydin","doi":"10.1007/s12221-025-01071-3","DOIUrl":"10.1007/s12221-025-01071-3","url":null,"abstract":"<div><p>In parallel with technological advancements, studies on the hybridization of fiber-reinforced laminate composites have continued to increase. In this study, the effects of axial buckling and free vibration on interply and intraply hybridization are analyzed experimentally and numerically to enhance the stability and dynamic behavior of composite structures. Three different types of fabric were used: aramid (A), glass (G), and aramid/glass (GA) hybrid fabric, all having the same areal density and woven structure. Composite plates with five different configurations, including aramid and glass reference groups, two different interply hybrid composite groups [interply_1 (G/A/A/G) and interply_2 (A/G/G/A)], and one intraply (GA/AG/AG/GA) hybrid composite group, were manufactured by The Vacuum-Assisted Resin Transfer Molding (VARTM) method. Comparative analyses were conducted on natural frequency, damping ratio, axial buckling load, and axial buckling stress by preparing specimens according to the relevant ASTM standard. The results showed that the interply_2 hybrid configuration, which features aramid on the outer surface and glass layers on the inner layers, has a natural frequency value that is 19% higher than those of the other two hybrid structures. In comparison to the glass composites, this hybridization achieved frequency values that were 70% higher. Regarding axial buckling, the interply_2 specimens obtained 26% higher values compared to the interply_1 specimens and 123% higher values compared to glass. The intraply hybrid structures demonstrated superior damping performance compared to other hybrids.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"4069 - 4086"},"PeriodicalIF":2.3,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814304","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of Aging and UV Radiation on Antibacterial Properties of Knitted Fabrics Dyed with Achillea millefolium L. Extract 老化和紫外线辐射对千年木犀提取物染色针织物抗菌性能的影响
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-09 DOI: 10.1007/s12221-025-01057-1
Dragana Grujić, Aleksandar Savić, Ljiljana Topalić-Trivunović, Blanka Škipina, Branka Ružičić, Jovana Milanović, Milena Milošević, Milena Ivanović, Mitja Kolar
{"title":"Influence of Aging and UV Radiation on Antibacterial Properties of Knitted Fabrics Dyed with Achillea millefolium L. Extract","authors":"Dragana Grujić,&nbsp;Aleksandar Savić,&nbsp;Ljiljana Topalić-Trivunović,&nbsp;Blanka Škipina,&nbsp;Branka Ružičić,&nbsp;Jovana Milanović,&nbsp;Milena Milošević,&nbsp;Milena Ivanović,&nbsp;Mitja Kolar","doi":"10.1007/s12221-025-01057-1","DOIUrl":"10.1007/s12221-025-01057-1","url":null,"abstract":"&lt;div&gt;&lt;p&gt;In recent years, there has been increasing public concern about ultraviolet radiation (UVR), and clothing is considered to provide the most effective protection against it. In this study, the influence of aging and UVR on the antibacterial properties and degree of coloration of knitted fabrics was investigated. Knitted fabrics of different raw materials compositions in single weaves made of three types of yarn: cotton (CO), bamboo (BAM), and polyester (PES), were used. Samples were treated with methanol extract of &lt;i&gt;Achillea millefolium&lt;/i&gt; L. conc. 100 mg/mL, to which citric acid and tannic acid were added, using ultrasonic atomization. Using an ultrasonic atomizer increased the speed of dyeing, shortened the processing time and allowed the use of a smaller amount of extract compared to conventional dyeing. The antibacterial properties of knitted fabrics obtained against &lt;i&gt;Staphylococcus aureus&lt;/i&gt; and &lt;i&gt;Escherichia coli&lt;/i&gt; were evaluated. The tests of antibacterial properties and color strenght (&lt;i&gt;K/S&lt;/i&gt;) of knitted fabrics were done after dyeing, after aging (30 months), and after exposure to UV light with a wavelength of 254 nm and 365 nm. The antibacterial effect of knitted fabrics dyed with &lt;i&gt;A. millefolium&lt;/i&gt; L. extract on &lt;i&gt;S. aureus&lt;/i&gt; after natural aging and treatment with UV wavelength of 254 nm results in a reduction of the zone of inhibition (&lt;span&gt;({Z}_{i})&lt;/span&gt;) from 23% (BAM) to 57% (CO), compared to &lt;span&gt;({Z}_{i})&lt;/span&gt; after dyeing. Treatment of the samples with UV light with a wavelength of 365 nm increased the &lt;span&gt;({Z}_{i})&lt;/span&gt; against &lt;i&gt;S. aureus&lt;/i&gt;, in PES knitted fabric was even higher than after dyeing, while there were no significant changes &lt;i&gt;in E. coli&lt;/i&gt;. In CO and BAM knitted fabrics, after aging and exposure to UV radiation, high protection factors (UPF) were found, the values of which ranged from 31.38 to 51.68. Aging and exposure to UV light affect the degree of dyeing and color fastness, which are more pronounced in knitted fabrics made of cotton and bamboo fibers compared to polyester. In addition to the research of the impact of UVA radiation (365 nm), it was important to emphasize that research on UVC radiation (254 nm) was conducted to determine how the disinfection process affects the antibacterial properties of knitted fabric treated with &lt;i&gt;A. millefolium&lt;/i&gt; extract.The results obtained from research into the stability of antibacterial treatment to aging and UV radiation represent a significant contribution to the research in the field of medical textiles and textiles intended for the production of clothing for allergic dermatitis.&lt;/p&gt;&lt;p&gt;These findings highlight the importance of studying the effects of UV radiation and aging processes on the color fastness and antimicrobial properties of textile materials treated with herbal extracts. The developed materials can be used to protect people from UV radiation. In addition, to create sustainable textiles, future research should i","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"3801 - 3815"},"PeriodicalIF":2.3,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of Mechanical, Physiochemical and Water Resistance Properties of TiO2-Coated Jute Fibers: Effects of Gamma Irradiation, Chemical Treatments and Crystallinity 增强二氧化钛涂层黄麻纤维的机械、物理化学和耐水性:γ辐射、化学处理和结晶度的影响
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-09 DOI: 10.1007/s12221-025-01062-4
Md. Monirul Islam, Mohammad Asaduzzaman Chowdhury, Anik Talukder, Nayem Hossain, Md. Masud Rana, Shuva Chandra Das, Minhaz Hossain, Md. Rifat Khandaker, Md. Ahadul Islam Patwary, Ruhul Amin Khan
{"title":"Enhancement of Mechanical, Physiochemical and Water Resistance Properties of TiO2-Coated Jute Fibers: Effects of Gamma Irradiation, Chemical Treatments and Crystallinity","authors":"Md. Monirul Islam,&nbsp;Mohammad Asaduzzaman Chowdhury,&nbsp;Anik Talukder,&nbsp;Nayem Hossain,&nbsp;Md. Masud Rana,&nbsp;Shuva Chandra Das,&nbsp;Minhaz Hossain,&nbsp;Md. Rifat Khandaker,&nbsp;Md. Ahadul Islam Patwary,&nbsp;Ruhul Amin Khan","doi":"10.1007/s12221-025-01062-4","DOIUrl":"10.1007/s12221-025-01062-4","url":null,"abstract":"<div><p>This study introduces a novel, synergistic surface modification approach combining peracetic acid (PAA) treatment, TiO<sub>2</sub> nanoparticle coating, and gamma irradiation to significantly enhance jute fibers' mechanical strength, surface morphology, crystallinity, and water resistance. Integrating these three unique methods enables profound structural alteration and surface functionalization, resulting in a more hydrophobic, durable, and mechanically robust fiber. The strategic sequence of treatments promotes adequate TiO<sub>2</sub> adhesion, fiber densification, and improved fiber matrix compatibility. This approach addresses critical limitations in raw jute fiber performance and offers a scalable path forward for bio-based composite development in packaging, textiles, and other industrial applications. Raw jute fibers exhibited low breaking force and high water absorption. TiO<sub>2</sub> coating improved these properties, with further enhancements observed upon gamma irradiation at 3 kGy. The most significant improvements were the chemical treatment to remove lignin and hemicellulose (cellulose JF) and per-acetic acid (PAA) treatment, combined with TiO<sub>2</sub> coating and gamma irradiation. PAA-treated fibers showed the highest breaking force (492.23 N, a 112% increase compared to raw fibers), tensile strength (169.85% increase), elastic modulus (237.26% increase), and toughness (116% increase). These fibers also exhibited the lowest moisture content (3.86%, a 67.54% reduction), moisture regain (4.01%, a 70.24% reduction), and water absorption (102.26%, a 52.92% reduction), along with the highest water contact angle (86.25°, a 117.51% increase). SEM analysis revealed that PAA treatment resulted in a more compact and uniform fiber structure, promoting better TiO<sub>2</sub> adhesion and mitigating some micro-cracking induced by gamma radiation. FTIR spectroscopy confirmed the presence of TiO<sub>2</sub> and indicated significant structural changes, especially with PAA treatment. Crystallinity also increased with each treatment step, reaching a maximum of 83.53% for the PAA-treated fibers. These findings demonstrate the synergistic effects of TiO<sub>2</sub> coating, gamma irradiation, and chemical treatments in enhancing the properties of jute fibers for high-performance applications.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"4033 - 4054"},"PeriodicalIF":2.3,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bio-based Terpolymers: Synthesis, Characterization, Wet-Spinning, and Evaluation as Geotextile 生物基三元共聚物:合成、表征、湿纺及作为土工布的评价
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-09 DOI: 10.1007/s12221-025-01035-7
Daniel Alcalá-Sánchez, Juan-Carlos Tapia-Picazo, Julieta A. Rodríguez-Romero, Gabriel Luna-Bárcenas, Adrián Bonilla-Petriciolet
{"title":"Bio-based Terpolymers: Synthesis, Characterization, Wet-Spinning, and Evaluation as Geotextile","authors":"Daniel Alcalá-Sánchez,&nbsp;Juan-Carlos Tapia-Picazo,&nbsp;Julieta A. Rodríguez-Romero,&nbsp;Gabriel Luna-Bárcenas,&nbsp;Adrián Bonilla-Petriciolet","doi":"10.1007/s12221-025-01035-7","DOIUrl":"10.1007/s12221-025-01035-7","url":null,"abstract":"<div><p>Microplastics (MPs) are a priority environmental pollution issue worldwide due to their poor biodegradability and persistent contamination. Nowadays, there is a growing interest in the design of biopolymers as an alternative for the total or partial substitution of plastic materials that generate MPs. In this paper, new biodegradable terpolymers (BPAN) with starch (ST), chitosan (CS), acrylonitrile (AN), 2-hydroxy ethyl methacrylate (HEMA), and vinyl acetate (VA) have been synthesized with different chemical properties using suspension polymerization initiated by sodium bisulfite/ammonium persulfate. The effect of polymerization conditions, concentration, and types of monomers on the characteristics of BPAN was analyzed. Cultured fungal and Burial test were used to test the biodegradability of a selected BPAN. Biodegradable fiber (BioF) from a BPAN was obtained by wet-spinning and used for the fabrication of geotextiles. The effective use of the geotextiles, on radish plant growth and soil moisture retention, was examined. The results showed that the polymerization system AN-HEMA-ST base provides good polymer conversion rate, high molecular weight, high moisture retention, and high grafting efficiency. The biodegradation of a film from a selected BPAN was observed by changes in coloration and fragmentation of small particles after 150 days of Burial test. Functional group changes from FTIR analysis confirmed the degradation. Fungal growth after 13 days of observation on sprayed BPAN also confirmed biodegradability. In addition, biocompatibility was observed by root growth on the surface of the BPAN film. With the AN-HEMA-ST based BPAN, a fiber with a linear density of 10.7 denier, tensile strength of 2.88 MPa, 10.71% elongation, and 88% moisture retention could be obtained. The use of geotextile from BioF increased soil moisture retention by about 100%. Biometric analysis of radish plants showed that in pots with geotextile, there was an increase of 62.12% in leaf length, 39.78% in leaf width, and 81.73% in leaf stem thickness, concerning the control experiments. The technical orientation for the synthesis, processing, and application of bio-based materials are the basis for the generation of new and better alternatives for sustainable engineering, environmental care, and regeneration of soils affected by PMs.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"3729 - 3750"},"PeriodicalIF":2.3,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of Microfiber Bundles via Melt Electrospinning Technique 熔体静电纺丝技术制备超细纤维束
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-09 DOI: 10.1007/s12221-025-01069-x
Chunming Wang, Qi Xia, Bowen Yang, Minghang Li, Wenwen Han, Hongbo Chen
{"title":"Fabrication of Microfiber Bundles via Melt Electrospinning Technique","authors":"Chunming Wang,&nbsp;Qi Xia,&nbsp;Bowen Yang,&nbsp;Minghang Li,&nbsp;Wenwen Han,&nbsp;Hongbo Chen","doi":"10.1007/s12221-025-01069-x","DOIUrl":"10.1007/s12221-025-01069-x","url":null,"abstract":"<div><p>Polypropylene (PP) yarn has the advantages of low density, excellent mechanical properties and good abrasion resistance. Its fiber preparation process is low cost and environmentally friendly. The process of preparing PP yarns involves forming stable fibers, aggregating the fibers into bundles, and twisting the bundles to form yarns. However, in the melt electrostatic spinning process, the poor uniformity of the melt reaching the nozzle position leads to an unstable fiber generation process during spinning, which increases the difficulty of directly and continuously collecting the fibers and forming fiber tows. In this paper, a melt-differential electrostatic spinning method using unilateral airflow assistance is proposed for the preparation of PP fiber tows. In this method, the melt at the nozzle is stretched and cooled to form fibers under the action of an electric field. Assisted by a unilateral airflow, these fibers can be further stretched and cooled before contacting the electrode plate, and are finally collected on a rotating roll to form fiber bundles. In this paper, the effects of voltage, airflow rate, and collection roller speed on the morphology and mechanical properties of fibers and their assemblies are investigated. The experimental results show that the addition of auxiliary airflow significantly improves the collection efficiency of fibers when the speed of unilateral auxiliary airflow is controlled within 2.5 m/s compared with the experimental results without auxiliary airflow, and the number of fibers in each fiber bundle increases under the condition of auxiliary airflow. In addition, the auxiliary airflow helps to refine the fiber diameter to 10–20 μm and significantly improves the overall fiber mechanical efficiency. This technology opens up new avenues for the application of PP fibers in a wider range of applications and shows good prospects for development.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"3843 - 3853"},"PeriodicalIF":2.3,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selection of Hydrogen Peroxide-Treated Coir Geotextile for Road Pavement using Grey Relational Analysis 应用灰色关联分析选择路面用过氧化氢处理的椰壳土工布
IF 2.3 4区 工程技术
Fibers and Polymers Pub Date : 2025-07-08 DOI: 10.1007/s12221-025-01060-6
Dinesh Bhatia,  Kavita, Kapil Dev, Rishav Sharma
{"title":"Selection of Hydrogen Peroxide-Treated Coir Geotextile for Road Pavement using Grey Relational Analysis","authors":"Dinesh Bhatia,&nbsp; Kavita,&nbsp;Kapil Dev,&nbsp;Rishav Sharma","doi":"10.1007/s12221-025-01060-6","DOIUrl":"10.1007/s12221-025-01060-6","url":null,"abstract":"<div><p>The primary purpose of this study is to select hydrogen peroxide-treated coir geotextiles for the road pavement applications, utilizing the Triangular Fuzzy Analytical Hierarchy Process and Grey Relational Analysis (GRA) methods. 15 different samples of hydrogen peroxide-treated coir geotextiles were prepared by using the Box–Behnken design by varying the concentrations, temperatures, and treatment durations. The triangular fuzzy AHP method was employed to ascertain the weights of different properties by constructing a pairwise matrix based on an absolute number of priority levels for various road pavement characteristics. The various treated geotextiles with hydrogen peroxide were subsequently evaluated to find the optimum rank was done by using Grey Relational Analysis (GRA). The optimum rank was achieved for coir geotextile subjected to treatment at 35 °C for three hours with 20% concentration of hydrogen peroxide. The results of the best selected treated geotextile with hydrogen peroxide show a reduction in permeability and water absorption by 9.27% and 11.86%, respectively, 31.40% enhancement in adhesion, 39.09% higher CBR, 35.24% higher interface friction angle, and 13% and 15.01% higher tensile strength in warp and weft direction, respectively, in comparison to untreated geotextile. FTIR and SEM analyses show that the treated coir geotextiles had noticeable changes on their surface, which improved their mechanical and physical properties.</p></div>","PeriodicalId":557,"journal":{"name":"Fibers and Polymers","volume":"26 9","pages":"4021 - 4031"},"PeriodicalIF":2.3,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144814261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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