{"title":"Firefighting aqueous film forming foam composition, properties and toxicity: a review","authors":"Pragya Malik, Durgesh Nandini, Bijay P. Tripathi","doi":"10.1007/s10311-024-01739-x","DOIUrl":"10.1007/s10311-024-01739-x","url":null,"abstract":"<div><p>Global warming and urbanization are likely to increase fires in natural and urbanized areas, requiring advanced fire management techniques such as the use of aqueous film forming foams. However, these foams contains in particular toxic fluorinated compounds that belongs to the class of the so-called ‘forever chemicals’. Here we review aqueous film forming foams with focus on classification, film forming, composition, toxicity, and standards. Foams are classified into aqueous film forming foams, alcohol-resistant foams, and fluoroprotein foams. Foams contain hydrocarbon surfactants, fluorosurfactants, organic solvents, and additives such as pH buffers, stabilizers, salts, corrosion inhibitors, and anti-freeze agents. Firefighting foams are aggregates of small bubbles that efficiently combat liquid fuel fires by forming a vapor-suppressing blanket over the fuel surface. Aqueous film forming foams contain 2–15% of stable perfluorinated molecules. Concerning toxicity, perfluorooctanoic acid has a half-life of more than five years in adult humans. Alternative compounds such as perfluorobutane sulfonate has a shorter half-life of 45 days in adult humans, yet its impact on soil and aquatic ecosystems is not fully understood. The proprietary nature of the aqueous film forming foam formulations is a challenge in developing sustainable firefighting foams.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"2013 - 2033"},"PeriodicalIF":15.0,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140846218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chook Kiong Teo, Poh Wai Chia, Nurhamizah Nordin, Su-Yin Kan, Noor Maizura Ismail, Zainal Zakaria, Rock Keey Liew, Lei Wu, Fu Siong Julius Yong
{"title":"Calcium oxide waste-based catalysts for biodiesel production and depollution: a review","authors":"Chook Kiong Teo, Poh Wai Chia, Nurhamizah Nordin, Su-Yin Kan, Noor Maizura Ismail, Zainal Zakaria, Rock Keey Liew, Lei Wu, Fu Siong Julius Yong","doi":"10.1007/s10311-024-01740-4","DOIUrl":"10.1007/s10311-024-01740-4","url":null,"abstract":"<div><p>Pollution, climate change and waste accumulation are critical societal issues calling for advanced methods to recycle matter and clean polluted ecosystems. Here, we review the use of calcium oxide waste-based catalysts for industrial and environmental applications such as biodiesel production, and pollutant degradation and removal. Catalysts can be produced from mud clam shell, eggshell, spent coffee ground, fish bones waste, marble waste, face mask waste, and snail shell. The preparation of composite catalysts, adsorbents, nanoparticles, and photocatalysts is presented.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"1741 - 1758"},"PeriodicalIF":15.0,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140846118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rahul Navik, Eryu Wang, Xiao Ding, KaiXuan Qiu, Jia Li
{"title":"Atmospheric carbon dioxide capture by adsorption on amine-functionalized silica composites: a review","authors":"Rahul Navik, Eryu Wang, Xiao Ding, KaiXuan Qiu, Jia Li","doi":"10.1007/s10311-024-01737-z","DOIUrl":"10.1007/s10311-024-01737-z","url":null,"abstract":"<div><p>The rising negative effects of climate change are caused mainly by the increase of atmospheric carbon dioxide concentrations, calling for advanced technologies to extract carbon dioxide from atmospheric air. Here we review carbon dioxide capture from atmospheric air by amine-functionalized silica composites with emphasis on development principles, mechanisms, absorbent criteria, performance determination, and preparation techniques. Amine-silica absorbent preparation for carbon dioxide capture is done by impregnation, chemical graphting, hybrid functionalization, and in situ polymerization. High costs, poor performance, and scalability are actually posing challenges for large-scale deployment.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"1791 - 1830"},"PeriodicalIF":15.0,"publicationDate":"2024-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140881544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Michele Costanzo, Maria Anna Rachele De Giglio, Melinda Gilhen-Baker, Giovanni Nicola Roviello
{"title":"The chemical basis of seawater therapies: a review","authors":"Michele Costanzo, Maria Anna Rachele De Giglio, Melinda Gilhen-Baker, Giovanni Nicola Roviello","doi":"10.1007/s10311-024-01720-8","DOIUrl":"10.1007/s10311-024-01720-8","url":null,"abstract":"<div><p>The rising number of diseases and deaths caused by pollution and modern lifestyle habits is a growing societal concern. Marine ecosystems are both victim to this human behaviour as a recipient of human pollution as well as being a source of medicinal chemicals which can cure a variety of diseases. In this paper, we review the chemical basis of water-based treatments and their effects on human health, while focusing on the threats to marine ecosystems and the potential benefits of balneotherapy, thalassotherapy, and bioactive chemical species. We found that seawater has potential benefits for skin health, demonstrating emollient properties, protection against skin barrier disruption, and inhibition of atopic dermatitis-like skin lesions. We present the putative mechanisms by which minerals, salts, and marine organic matter can slow down disease progression, through their numerous activities, such as anti-inflammatory, antioxidant, and wound healing properties. Water-living organisms also have an impact on such mechanisms by producing biologically active compounds with beneficial effects on human health.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"2133 - 2149"},"PeriodicalIF":15.0,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01720-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140881620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dwi Hantoko, Wasim Ullah Khan, Ahmed I. Osman, Mahmoud Nasr, Ahmed K. Rashwan, Yahya Gambo, Ahmed Al Shoaibi, Srinivasakannan Chandrasekar, Mohammad M. Hossain
{"title":"Carbon–neutral hydrogen production by catalytic methane decomposition: a review","authors":"Dwi Hantoko, Wasim Ullah Khan, Ahmed I. Osman, Mahmoud Nasr, Ahmed K. Rashwan, Yahya Gambo, Ahmed Al Shoaibi, Srinivasakannan Chandrasekar, Mohammad M. Hossain","doi":"10.1007/s10311-024-01732-4","DOIUrl":"10.1007/s10311-024-01732-4","url":null,"abstract":"<div><p>The global hydrogen demand is projected to increase from 70 million tons in 2019 to more than 200 million tons in 2030. Methane decomposition is a promising reaction for H<sub>2</sub> production, coupled with the synthesis of valuable carbon nanomaterials applicable in fuel cell technology, transportation fuels, and chemical synthesis. Here, we review catalytic methane decomposition, with focus on catalyst development, deactivation, reactivation, regeneration, and on economics. Catalysts include mono-, bi-, and trimetallic compounds and carbon-based compounds. Catalyst deactivation is induced by coke deposition. Despite remarkable strides in research, industrialization remains at an early stage.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"1623 - 1663"},"PeriodicalIF":15.0,"publicationDate":"2024-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01732-4.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140622815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Materials for sustainable metallic iron-based water filters: a review","authors":"Minhui Xiao, Rui Hu, Willis Gwenzi, Ran Tao, Xuesong Cui, Huichen Yang, Chicgoua Noubactep","doi":"10.1007/s10311-024-01736-0","DOIUrl":"10.1007/s10311-024-01736-0","url":null,"abstract":"<div><p>Water pollution is calling for a sustainable remediation method such as the use of metallic iron (Fe<sup>0</sup>) to reduce and filter some pollutants, yet the reactivity and hydraulic conductivity of iron filters decline over time under field conditions. Here we review iron filters with focus on metallic corrosion in porous media, flaws in designing iron filters, next-generation filters and perspectives such as safe drinking water supply, iron for anaemia control and coping with a reactive material. We argue that assumptions sustaining the design of current Fe<sup>0</sup> filters are not valid because proposed solutions address the issues of declining iron reactivity and hydraulic conductivity separately. Alternatively, a recent approach suggest that each individual Fe<sup>0</sup> atom corroding within a filter contributes to both reactivity and permeability loss. This approach applies well to alternative iron materials such as bimetallics, composites, hybrid aggregates, e.g. Fe<sup>0</sup>/sand, and nano-Fe<sup>0</sup>. Characterizing the intrinsic reactivity of individual Fe<sup>0</sup> materials is a prerequisite to designing sustainable filters. Indeed, Fe<sup>0</sup> ratio, Fe<sup>0</sup> type, Fe<sup>0</sup> shape, initial porosity, e.g. pore size and pore size distribution, and nature and size of admixing aggregates, e.g. pumice, pyrite and sand, are interrelated parameters which all influence the generation and accumulation of iron corrosion products. Fe<sup>0</sup> should be characterized in long-term experiments, e.g. 12 months or longer, for Fe dissolution, H<sub>2</sub> generation and removal of contaminants in three media, i.e., tap water, spring water and saline water, to allow reactivity comparison and designing field-scale filters.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"2113 - 2131"},"PeriodicalIF":15.0,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01736-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140607665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Methods to treat industrial salted waste: a review","authors":"Xiuxiu Ruan, Min Song, Zhihao Fang, Hao Wang, Chaoyang Zhang, Weidong Chen","doi":"10.1007/s10311-024-01721-7","DOIUrl":"10.1007/s10311-024-01721-7","url":null,"abstract":"<div><p>The rising production of industrial salted waste induces issues of disposal and pollution, calling for advanced methods to treat, purify and recycle the raw salt in the context of the circular economy. The main components of salted waste are organic and mineral fractions. Here we review the methods used to treat salted waste with focus on sources of salted waste, properties and removal of organic matter, and separation of minerals. Organic matter can be removed by pyrolysis carbonization, high-temperature melting, elution, and oxidation. Salt can be separated by evaporative crystallization, salt washing, and nanofiltration.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"2035 - 2053"},"PeriodicalIF":15.0,"publicationDate":"2024-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140604083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sahil Sahil, Rickwinder Singh, Shyam K. Masakapalli, Nidhi Pareek, Andrey A. Kovalev, Yuriy V. Litti, Sonil Nanda, Vivekanand Vivekanand
{"title":"Biomass pretreatment, bioprocessing and reactor design for biohydrogen production: a review","authors":"Sahil Sahil, Rickwinder Singh, Shyam K. Masakapalli, Nidhi Pareek, Andrey A. Kovalev, Yuriy V. Litti, Sonil Nanda, Vivekanand Vivekanand","doi":"10.1007/s10311-024-01722-6","DOIUrl":"10.1007/s10311-024-01722-6","url":null,"abstract":"<div><p>The negative effects of the accelerating climate change due partly to fossil fuel consumption is calling for the rapid development of sustainable energies such as biohydrogen, which is produced using microorganisms. Here we review biohydrogen production from biomass, with focus on biomass pretreatment, fermentative production, factors affecting production, bioreactors, kinetics and modeling, and improved production with nanoparticles. Pretreatments include chemical, physical and biological methods. Hydrogen production is done by photo-fermentation or dark fermentation. Influencing factors comprise pH, temperature, hydraulic retention time, and the presence of fermentation inhibitors. Continuous stirred tank-, anaerobic fluidized bed-, anaerobic sequencing batch-, up-flow anaerobic sludge blanket- and dynamic membrane reactors are used. Additives include cobalt, nickel and iron nanoparticles. Compared to thermochemical, photochemical and electrochemical processes, biohydrogen production needs more time but is easy to operate, cost-effective and environmentally friendly.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"1665 - 1702"},"PeriodicalIF":15.0,"publicationDate":"2024-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140541334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Food chain microplastics contamination and impact on human health: a review","authors":"Chukwuebuka Gabriel Eze, Chidiebele Emmanuel Nwankwo, Satarupa Dey, Suresh Sundaramurthy, Emmanuel Sunday Okeke","doi":"10.1007/s10311-024-01734-2","DOIUrl":"10.1007/s10311-024-01734-2","url":null,"abstract":"<div><p>Microplastics have been recently detected in many environmental media and living organisms, yet their transfer and toxicity to humans are poorly known. Here, we review microplastic transfer in the food chain with focus on microplastic pollution sources, methods to analyze microplastics in food, health impact of food-related microplastic exposure, and remediation of microplastic pollution. Microplastic pollution sources include seafood, food additives, packaging materials, and agricultural and industrial products. Remediation techniques comprise the use of microbial enzymes and biofilms. Microplastic detection methods in food rely on separation and quantification by optical detection, scanning electron micrography, and Fourier-transform infrared spectroscopy. Human health impact following microplastic ingestion include cancers, organ and respiration damage, and reproductive impairments. Overall, microplastic toxicity is mainly due to their ability to enter the metabolism, adsorption into the circulatory system for translocation, and difficulty, if not impossibility, of excretion.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"1889 - 1927"},"PeriodicalIF":15.0,"publicationDate":"2024-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140538485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization and environmental applications of soil biofilms: a review","authors":"Guoliang Wang, Tian Li, Qixing Zhou, Xiaoling Zhang, Ruixiang Li, Jinning Wang","doi":"10.1007/s10311-024-01735-1","DOIUrl":"10.1007/s10311-024-01735-1","url":null,"abstract":"<div><p>Despite the major influence of soils on climate change, carbon sequestration, pollution remediation, and food security, soil remains a largely unexplored media with an extreme complexity of microbes, minerals, and dead organic matter, most of them being actually poorly known. In particular, soil biofilms have recently attracted attention because they strongly influence biogeochemical reactions and processes. Here we review biofilms with focus on their behavior, proliferation, distribution, characterization methods, and applications. Characterization methods include optical, electron, scanning probe, and X-ray microscopy; metagenomics, metatranscriptomics, metaproteomics, metabolomics; and tracking approaches. Applications comprise pollution remediation by metal immobilization or organics degradation; and methane oxidation, carbon dioxide reduction, and carbon sequestration. Advanced methods such as DNA-stable isotope probing and meta-omics have uncovered the multiple functions of soil biofilms and their underlying molecular mechanisms. Investigations have improved our understanding of inter- and intra-kingdom interactions, and of gene transfer. Extracellular materials such as polysaccharides enhance the transport of substances and electrons flow among microorganisms.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"1989 - 2011"},"PeriodicalIF":15.0,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140534537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}