Chem Catalysis最新文献_第2页

Stabilization of highly active Ru sites toward acidic water oxidation by dual-atom doping 双原子掺杂稳定高活性钌位对酸性水氧化的影响

IF 9.4

Chem Catalysis Pub Date : 2025-07-03 DOI: 10.1016/j.checat.2025.101441

Jialin Tang, Qisheng Zeng, Qiu Jiang, Haoyuan Wang, Sunpei Hu, Yuan Ji, Hongliang Zeng, Chunxiao Liu, Hong-Jie Peng, Xu Li, Tingting Zheng, Chih-Wen Pao, Xinyan Liu, Chuan Xia

引用次数: 0

Surface reconstruction of versatile perovskites via in situ nanoparticle engineering for solid oxide cells 固体氧化物电池中多用途钙钛矿的原位纳米工程表面重建

IF 9.4

Chem Catalysis Pub Date : 2025-07-01 DOI: 10.1016/j.checat.2025.101432

Boshen Xu, Jiufeng Ruan, Pengxi Zhu, Sidong Lei, Hanping Ding, Pei Dong

{"title":"Surface reconstruction of versatile perovskites via in situ nanoparticle engineering for solid oxide cells","authors":"Boshen Xu, Jiufeng Ruan, Pengxi Zhu, Sidong Lei, Hanping Ding, Pei Dong","doi":"10.1016/j.checat.2025.101432","DOIUrl":"https://doi.org/10.1016/j.checat.2025.101432","url":null,"abstract":"Renewable energy conversion is pivotal for decarbonization via a carbon-neutral energy cycle. Solid oxide cells (SOCs) offer efficient energy conversion for power generation, hydrogen production, and CO2 electrolysis. These devices benefit from favorable thermodynamic and catalytic mechanisms enabled by high-temperature operation. Perovskite oxides are key SOC catalysts due to their tunable lattice structures, which influence electronic properties, defect chemistry, and catalytic activity. Perovskite surface reconstruction attracts much attention as a critical strategy to enhance reaction kinetics by tailoring surface properties and improving electrode performance. This review explores the unique adaptability of perovskite oxides for surface modification, along with the relationships between lattice structures, surface characteristics, and catalytic performance. It highlights methods for atomic-level reconstruction and summarizes recent experimental and theoretical progress, offering insights for designing next-generation SOC catalysts and advancing the application of perovskite oxides in renewable energy.","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":"19 1","pages":""},"PeriodicalIF":9.4,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144521329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Modeling electron storage at the interface between Au and anatase-TiO2 under ambient conditions 模拟环境条件下Au和锐钛矿- tio2界面上的电子存储

IF 9.4

Chem Catalysis Pub Date : 2025-06-30 DOI: 10.1016/j.checat.2025.101430

Yichen Li, Dongfang Cheng, Giyeong Son, Anna V. Shneidman, Kang Rui Garrick Lim, Joanna Aizenberg, Philippe Sautet

{"title":"Modeling electron storage at the interface between Au and anatase-TiO2 under ambient conditions","authors":"Yichen Li, Dongfang Cheng, Giyeong Son, Anna V. Shneidman, Kang Rui Garrick Lim, Joanna Aizenberg, Philippe Sautet","doi":"10.1016/j.checat.2025.101430","DOIUrl":"https://doi.org/10.1016/j.checat.2025.101430","url":null,"abstract":"Au supported on TiO2 is a promising photocatalyst due to its ability to catalyze reactions under illumination and store electrons for sustained reactivity in the dark. Using density functional theory (DFT), we investigate the structural evolution and reactivity of the Au/anatase-TiO2(001) interface under realistic conditions. Phase diagrams and charge analysis reveal that the Au nanoparticles supported on TiO₂ (Au/TiO2) interface can reversibly store electrons by transitioning between different charge states and structures via oxidation and reduction. This electron storage and the associated reducing potential, along with the atomic arrangement, promote key photoelectrochemical reactions, such as the oxygen reduction reaction (ORR) and the CO2 reduction reaction (CO2RR). Lattice titanium and oxygen vacancies act as active sites, with the two-electron (2e)-ORR pathway (H2O2 formation) kinetically favored due to a lower proton-coupled electron transfer barrier. The interface also facilitates CO2 activation, which is challenging on bare Au. These findings provide a foundation for optimizing Au/TiO2 composites for energy storage and conversion.","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":"29 1","pages":""},"PeriodicalIF":9.4,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144516251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design of highly efficient catalysts guided by redox of individual carbon supports 由单个碳载体氧化还原引导的高效催化剂的设计

IF 9.4

Chem Catalysis Pub Date : 2025-06-27 DOI: 10.1016/j.checat.2025.101436

Dezheng Zhang, Jing Cao, Xuanhao Mei, Huimin Zhang, Shaoqing Zhang, Yaheng Gu, Ce Han, Ping Song, Weilin Xu

{"title":"Design of highly efficient catalysts guided by redox of individual carbon supports","authors":"Dezheng Zhang, Jing Cao, Xuanhao Mei, Huimin Zhang, Shaoqing Zhang, Yaheng Gu, Ce Han, Ping Song, Weilin Xu","doi":"10.1016/j.checat.2025.101436","DOIUrl":"https://doi.org/10.1016/j.checat.2025.101436","url":null,"abstract":"The precise design of highly efficient nanocatalysts with traditional ensemble methodologies faces a challenge. Here, we demonstrate the first precise guidance of basic research on carbon supports at the single-particle level for designing Pt/C nanoelectrocatalysts. With single-molecule fluorescence microscopy to measure redox electron transfer (ET) rates on individual graphene sheets (GSs), we reveal that the reductive ET rate increases with the thickness decrease of GSs, while the oxidative ET increases with the thickness decrease first and reaches a constant on thinner GSs. Notably, O=C-OH accelerates reductive ET while slowing oxidative ET. All these insights are further confirmed on carbon nanospheres. Guided by these unprecedented insights, two high-efficiency Pt/C nanoelectrocatalysts for the hydrogen evolution reaction and hydrogen oxidation reaction are designed. Compared to traditional ensemble methods, our single-particle-level research on carbon supports provides a deeper understanding of the support effect, enabling precise nanocatalyst design and reducing unnecessary research and development costs.","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":"74 1","pages":""},"PeriodicalIF":9.4,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144516252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanoscale heat management enhanced photothermal methane dry reforming with carbon dioxide 纳米级热管理增强了甲烷与二氧化碳的光热干重整

IF 9.4

Chem Catalysis Pub Date : 2025-06-27 DOI: 10.1016/j.checat.2025.101437

Jiakun Wang, Jianheng Xu, Zeshu Zhang, Zhongyi Chen, Kaijie Liu, Cheng Rao, Yong Men, Mengjia Li, Junan Lai, Liwei Sun, Xiaolu Zhuo, Lu Wang, Xiangguang Yang, Yibo Zhang, Wuping Liao

引用次数: 0

Efficient urea photosynthesis via CuFe dual-atom synergistic catalysis 通过CuFe双原子协同催化高效尿素光合作用

IF 9.4

Chem Catalysis Pub Date : 2025-06-26 DOI: 10.1016/j.checat.2025.101433

Yan-Fei Mu, Ji-Li Zhou, Su-Xian Yuan, Meng-Ran Zhang, Huan Pang, Min Zhang, Tong-Bu Lu

{"title":"Efficient urea photosynthesis via CuFe dual-atom synergistic catalysis","authors":"Yan-Fei Mu, Ji-Li Zhou, Su-Xian Yuan, Meng-Ran Zhang, Huan Pang, Min Zhang, Tong-Bu Lu","doi":"10.1016/j.checat.2025.101433","DOIUrl":"https://doi.org/10.1016/j.checat.2025.101433","url":null,"abstract":"Photocatalytic conversion of N2 and CO2 into urea is a highly desirable yet formidable challenge given the inherent inertness of N2/CO2 and poor C–N coupling activity. Herein, we introduce a Cu single-atom-decorated porous Fe2O3 nanorod (Cu-Fe2O3) photocatalyst with a Cu–O–Fe configuration for efficient photocatalytic N2/CO2 co-reduction to urea. Because the d-orbitals of the Cu/Fe sites are close to the molecular orbitals of CO2/N2, the CuFe dual active sites can selectively adsorb and activate N2/CO2, thereby facilitating efficient C–N coupling. The incorporation of the high-electrostatic-potential Cu creates a localized electrostatic-potential difference over Fe2O3, enabling the sequential activation of CO2 and N2. Consequently, Cu-Fe2O3 offers the highest urea activity (171 ± 12 μmol g−1 h−1) and selectivity (>90%) reported to date. This work showcases a promising avenue for green urea synthesis as well as the asymmetric coupling reaction.","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":"10 1","pages":""},"PeriodicalIF":9.4,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144488406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancing carbon nanotube production from carbon dioxide and ethane using bimetallic catalysts 利用双金属催化剂提高二氧化碳和乙烷生产碳纳米管的性能

IF 9.4

Chem Catalysis Pub Date : 2025-06-23 DOI: 10.1016/j.checat.2025.101428

Yong Yuan, Bipin Lamichhane, William N. Porter, Sooyeon Hwang, Lu Ma, Dali Yang, Akhil Tayal, Nebojsa S. Marinkovic, Shyam Kattel, Jingguang G. Chen

{"title":"Enhancing carbon nanotube production from carbon dioxide and ethane using bimetallic catalysts","authors":"Yong Yuan, Bipin Lamichhane, William N. Porter, Sooyeon Hwang, Lu Ma, Dali Yang, Akhil Tayal, Nebojsa S. Marinkovic, Shyam Kattel, Jingguang G. Chen","doi":"10.1016/j.checat.2025.101428","DOIUrl":"https://doi.org/10.1016/j.checat.2025.101428","url":null,"abstract":"Converting CO2 into carbon nanotubes (CNTs) offers a promising method of CO2 utilization and sequestration, potentially mitigating environmental impacts from anthropogenic emissions. This study reports that bimetallic CoFe catalysts can increase CNT production from the reaction of CO2 and C2H6 by an order of magnitude compared to their monometallic counterparts. The active sites and CNT morphologies are composition dependent: Co-rich catalysts (Co/Fe ratio ≥ 5) form stable face-centered cubic (fcc) CoFe alloys, producing cylindrical CNTs, and Fe-containing catalysts (Co/Fe ≤ 2) favor body-centered cubic (bcc) CoFe alloys upon reduction, which transforms into carbides, resulting in bamboo-like CNTs. Experimental evidence and density functional theory (DFT) calculations reveal that adjacent Fe and Co atoms modulate CO and CxHy adsorption, regulating CNT production pathways through the CO Boudouard reaction and C2H6 decomposition. These results highlight the dual benefits of bimetallic catalysts in enhancing CNT yield and controlling CNT morphology through adjustment of catalyst compositions.","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":"51 1","pages":""},"PeriodicalIF":9.4,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144341409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An aryl radical reservoir based on the activation of organoboronic acids by polytelluroxane 基于聚碲氧烷对有机硼酸活化的芳基自由基库

IF 9.4

Chem Catalysis Pub Date : 2025-06-23 DOI: 10.1016/j.checat.2025.101429

Jun Guan, Ruihao Zhou, Hengxue Shi, Shenghan Zhang, Chaowei He, Muqing Cao, Lei Jiao, Huaping Xu

引用次数: 0

Unveiling the support LUMO-activity correlation in single-atom catalysis 揭示单原子催化中支持lumo -活度的相关性

IF 9.4

Chem Catalysis Pub Date : 2025-06-19 DOI: 10.1016/j.checat.2025.101396

Huayu Gu, Dongshuang Wu

引用次数: 0

Engineering ultrathin 2D ceria architecture with superior catalytic performance for industrial redox reactions 工程超薄二维二氧化铈结构，具有优异的工业氧化还原反应催化性能