Geochemistry Geophysics Geosystems最新文献

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Mercury Deposition in South China Across the Ordovician-Silurian Transition: Implications for Climate Change 中国南方奥陶—志留纪过渡时期的汞沉积:对气候变化的影响
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-07-02 DOI: 10.1029/2024GC012122
Weiliang Kong, Zhen Qiu, Jiaqiang Zhang, Wen Liu, Qin Zhang
{"title":"Mercury Deposition in South China Across the Ordovician-Silurian Transition: Implications for Climate Change","authors":"Weiliang Kong,&nbsp;Zhen Qiu,&nbsp;Jiaqiang Zhang,&nbsp;Wen Liu,&nbsp;Qin Zhang","doi":"10.1029/2024GC012122","DOIUrl":"https://doi.org/10.1029/2024GC012122","url":null,"abstract":"<p>Most of the global climate changes are closely associated with volcanic activity. However, the link between global cooling during the Ordovician-Silurian (O-S) transition and volcanism remains unclear due to limited constraints on large volcanic events before, during, and after the peak of the Hirnantian glaciation (PHG). Here, we present high-resolution mercury (Hg) concentrations and isotopes from South China across the O-S transition to assess volcanic activity and its contributions to climate changes. Anomalous Hg enrichments and volcanic-range Hg isotopes in samples above volcanic ash layers confirm the effectiveness of Hg as a tracer of volcanic events. Variations in Hg isotopes across the O-S transition reveal multiple Hg sources related to volcanic activity, that is, dominant volcanic Hg input during pre-PHG and post-PHG-2, deposition of volcanic-sourced atmospheric Hg(II) to seawater during PHG, and increased terrestrial Hg input from enhanced weathering during post-PHG-1. We propose that prolonged global cooling was driven by an albedo catastrophe caused by volcanic aerosols and sustained by reduced atmospheric CO<sub>2</sub> levels due to enhanced organic carbon burial and weathering. This study highlights Hg as a tracer of volcanic activity and provides new evidence on the role of volcanism in driving climate changes across the O-S transition.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 7","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC012122","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144524691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toward Solving the Mystery of Elevated Tectonic Degassing in South Eastern Europe: Insights From Gas Discharges Along the Vardar Suture (North Macedonia) 解开东南欧高架构造脱气之谜:北马其顿瓦尔达尔缝合带天然气排放的启示
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-30 DOI: 10.1029/2025GC012177
L. Li Vigni, M. Temovski, C. Cardellini, K. Molnár, A. Ionescu, V. Mirčovski, K. Daskalopoulou, G. Chiodini, F. Parello, W. D’Alessandro
{"title":"Toward Solving the Mystery of Elevated Tectonic Degassing in South Eastern Europe: Insights From Gas Discharges Along the Vardar Suture (North Macedonia)","authors":"L. Li Vigni,&nbsp;M. Temovski,&nbsp;C. Cardellini,&nbsp;K. Molnár,&nbsp;A. Ionescu,&nbsp;V. Mirčovski,&nbsp;K. Daskalopoulou,&nbsp;G. Chiodini,&nbsp;F. Parello,&nbsp;W. D’Alessandro","doi":"10.1029/2025GC012177","DOIUrl":"https://doi.org/10.1029/2025GC012177","url":null,"abstract":"<p>Tectonic carbon degassing is an important contributor to the global carbon cycle. South Eastern Europe is an active extensional tectonic region. This is the result of intense geodynamic events related to the closure of the Tethys Ocean, whose remnants include an ophiolite orogenic belt and the Vardar megasuture. In North Macedonia, regional active fault systems, seismic activity, Cenozoic-Quaternary volcanism, large-scale degassing, and low-enthalpy geothermal resources are widespread. Nonetheless, a geochemical characterization of the gas manifestations is missing from the literature. Toward this contribution, we report the first characterization of chemical and isotopic compositions of fluids from the main geothermal and cold gas manifestations of North Macedonia, and we explore their origins, the processes controlling their chemistry, and their relationships with the regional geodynamic situation. Gas samples were collected along the whole country, and were analyzed for both their chemical (He, H<sub>2</sub>, H<sub>2</sub>S, O<sub>2</sub>, N<sub>2</sub>, CO<sub>2</sub>, CH<sub>4</sub>, Ar) and isotopic composition (δ<sup>13</sup>C-CO<sub>2</sub>, He, Ar). Based on their chemistry, samples can be subdivided into three groups: (a) N<sub>2</sub>-dominated, (b) CO<sub>2</sub>-dominated, and (c) H<sub>2</sub>S-rich, which are geographically well separated, following regional distributions. The CO<sub>2</sub>-dominated group is the most widespread, highlighting the importance of geogenic carbon degassing in the study area. Its origin is prevailingly crustal (δ<sup>13</sup>C-CO<sub>2</sub> = −4.6–+1.0‰ vs. V-PDB; R/R<sub>A</sub> = 0.1–1.8), but a significant, up to 25%, mantle contribution can be inferred from the He isotope composition.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 7","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012177","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Environmental and Calcification Impacts on the δ18O and δ2H Values of Cold-Water Coral Skeleton Fluid Inclusions 环境和钙化对冷水珊瑚骨架流体包裹体δ18O和δ2H值的影响
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-24 DOI: 10.1029/2024GC011981
Yao Wu, Dana Hölkermann, Amrei Grund, Sophie Warken, Norbert Frank
{"title":"Environmental and Calcification Impacts on the δ18O and δ2H Values of Cold-Water Coral Skeleton Fluid Inclusions","authors":"Yao Wu,&nbsp;Dana Hölkermann,&nbsp;Amrei Grund,&nbsp;Sophie Warken,&nbsp;Norbert Frank","doi":"10.1029/2024GC011981","DOIUrl":"https://doi.org/10.1029/2024GC011981","url":null,"abstract":"<p>Coral skeletons exhibit a complex composition of mineral and organic components, with the water content playing a significant role in their structure. Water associated with organic matrices constitutes the major share, whereas nonstructural water (skeleton inclusion water) is present in much smaller amounts, typically less than 0.5 wt% of the coral skeleton. The isotopic composition of this water may reflect biomineralization processes or environmental conditions during skeleton formation. Here, we present fluid inclusion hydrogen and oxygen isotopic compositions of cold-water coral skeletons from Angola and Iceland. We confirmed the kinetic isotope fractionation when coral skeletons were crushed at a temperature of 120°C using a cavity ring-down spectroscopy analyzer. δ<sup>18</sup>O and δ<sup>2</sup>H values are not reproducible across analytical setups with varying temperature parameters. When coral fragments are encapsulated in a glass tube, the amount of released water and its isotopic signature are far more reproducible. δ<sup>18</sup>O and δ<sup>2</sup>H values of coral skeleton inclusion water from Angola show no significant differences between the Holocene and the last glacial period. The δ<sup>2</sup>H values are characterized by strong isotopic fractionation compared to seawater. Our study highlights that current methods do not adequately capture the variability in the initial δ<sup>18</sup>O and δ<sup>2</sup>H of the “quasi-free” skeleton inclusion water in coral aragonite. It is also possible that there are varying degrees of exchange of skeleton inclusion water with seawater. A better understanding of the coral calcification process is still necessary to establish a clearer link between the isotopic compositions of seawater and skeleton inclusion water.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011981","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144473152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tracking the Caribbean Magmatic Evolution: The British Virgin Islands as a Transition Between the Greater and Lesser Antilles Arcs 追踪加勒比海岩浆演化:英属维尔京群岛作为大安的列斯弧和小安的列斯弧之间的过渡
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-19 DOI: 10.1029/2024GC012057
Noémie Bosc, Delphine Bosch, Mélanie Noury, Olivier Bruguier, Lény Montheil, Douwe J. J. van Hinsbergen, Jean-Jacques Cornée, Jonathan Outin, Mélody Philippon
{"title":"Tracking the Caribbean Magmatic Evolution: The British Virgin Islands as a Transition Between the Greater and Lesser Antilles Arcs","authors":"Noémie Bosc,&nbsp;Delphine Bosch,&nbsp;Mélanie Noury,&nbsp;Olivier Bruguier,&nbsp;Lény Montheil,&nbsp;Douwe J. J. van Hinsbergen,&nbsp;Jean-Jacques Cornée,&nbsp;Jonathan Outin,&nbsp;Mélody Philippon","doi":"10.1029/2024GC012057","DOIUrl":"https://doi.org/10.1029/2024GC012057","url":null,"abstract":"<p>The British Virgin Islands (BVI) archipelago, located between the Greater Antilles and the Lesser Antilles, is a key location to study the geodynamic evolution of the Caribbean plate. Geochemistry of the studied samples reveals typical volcanic arc signatures, including a calc-alkaline affinity, strong negative HFSE anomalies, and LILE enrichment. The ɛHf values are homogeneous, indicative of a MORB-type mantle. Magmas were sourced from a homogeneous mantle wedge with less than 2% slab-derived sediment inputs, dominated by aqueous fluids. A concomitant melt component has been detected in the Peter and Norman Islands. U-Pb dating emphasizes an active magmatic period spanning over ca. 13 Myr (43–30 Ma), with a NE/SW decreasing age gradient. Thermobarometry data display a SW increasing emplacement depth from ∼6 to 13 km. Compared to the Greater and Lesser Antilles, this archipelago shows strong similarities with the extinct northern Lesser Antilles arc in terms of source and age. A geodynamical evolution model is proposed in which this archipelago represents a transition between the Greater and the Lesser Antilles arcs. The Oligocene cessation of magmatism (ca. 30 Ma) may coincide with a regionally documented lull in arc magmatic activity during which the Bahamas bank collided to the north. Paleomagnetic evidence of forearc sliver motion along the northeastern boundary of the Caribbean indicates a northward translation of the archipelago from a position above the Lesser Antilles subduction zone to its modern location along the highly oblique, strike-slip-dominated plate boundary, thus preventing the re-establishment of arc magmatism in the eastern Caribbean.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC012057","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144315039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Petrochronology of Alkaline Intrusive Magmatism in the Central High-Atlas (Morocco) and Relationships With Jurassic Salt Diapirism 摩洛哥中部高阿特拉斯地区碱性侵入岩浆作用的岩石年代学及其与侏罗纪盐底液作用的关系
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-19 DOI: 10.1029/2025GC012178
Youssef Ahechach, Muhammad Ouabid, Françoise Roger, Fleurice Parat, Otmane Raji, Jean-Marie Dautria, Valérie Bosse, Cheikh Elwali Malainine, Hicham El Messbahi, Hamza Skikra, Jean-Louis Bodinier
{"title":"Petrochronology of Alkaline Intrusive Magmatism in the Central High-Atlas (Morocco) and Relationships With Jurassic Salt Diapirism","authors":"Youssef Ahechach,&nbsp;Muhammad Ouabid,&nbsp;Françoise Roger,&nbsp;Fleurice Parat,&nbsp;Otmane Raji,&nbsp;Jean-Marie Dautria,&nbsp;Valérie Bosse,&nbsp;Cheikh Elwali Malainine,&nbsp;Hicham El Messbahi,&nbsp;Hamza Skikra,&nbsp;Jean-Louis Bodinier","doi":"10.1029/2025GC012178","DOIUrl":"https://doi.org/10.1029/2025GC012178","url":null,"abstract":"<p>A striking feature of the Imilchil alkaline province, in the Moroccan Central High Atlas, is the close association of magmatic intrusions with Triassic sediments exhumed by diapirism. This study reports field, petrographic, geochemical and Sr-Nd isotopic data, as well as new U-Pb zircon ages, which allow us to constrain the timing of the intrusions and to discuss their relationship to diapiric structures and the magmatic and hydrothermal processes. Our results indicate a restricted range of Late Jurassic ages (ca. 163 ± 1—ca. 149 ± 2 Ma) for the paroxysm of magmatic activity and confirm the diachronicity between diapirism and magmatism, albeit with a short interval of only a few My between the end of diapirism and the magmatic paroxysm. Deep-seated faults associated with transtensional tectonics, accommodating the increasing spreading rate of the Central Atlantic during the Jurassic, played a key role in the close association of magmatic intrusions with diapirs. The faults first triggered active diapirism in the Early- Jurassic and then guided OIB-type partial melts formed by local decompression melting of the mantle. At shallower depths, the diapiric structures acted as corridors for magma migration, probably using evaporites as preferential pathways. Magmas underwent fractional crystallization and interacted with evaporites to produce pervasive Na-rich hydrothermal fluids.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012178","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144315040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Uplift of Armorica and the Bretonian Movements of the Variscan Orogeny-New Insights From Detrital Zircons in the Early Carboniferous Terrigenous Rocks of the Laval Basin (Armorican Massif, France) Armorica隆升与Variscan造山带布列塔尼运动——法国拉瓦尔盆地早石炭世陆源岩碎屑锆石的新认识
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-19 DOI: 10.1029/2024GC011944
Wei Lin, Michel Faure, Lingtong Meng
{"title":"The Uplift of Armorica and the Bretonian Movements of the Variscan Orogeny-New Insights From Detrital Zircons in the Early Carboniferous Terrigenous Rocks of the Laval Basin (Armorican Massif, France)","authors":"Wei Lin,&nbsp;Michel Faure,&nbsp;Lingtong Meng","doi":"10.1029/2024GC011944","DOIUrl":"https://doi.org/10.1029/2024GC011944","url":null,"abstract":"<p>In the French Armorican Massif, the Bretonian phase of the Variscan orogeny has been defined by the Late Devonian (Famennian-Frasnian) erosion gap, and the Early Carboniferous (Tournaisian) syntectonic terrigenous deposits of the l’Huisserie formation in the Laval basin in the Central-North Armorican Domain, ascribed to the Armorica microcontinent. This phase is coeval with vertical (epeirogenic) movements. In addition to Neo-, and Paleo-Proterozoic peaks, ascribed to the Cadomian and Icartian events, respectively, the detrital zircon age populations of the l’Huisserie formation reveal the existence of a 388–358 Ma magmatic event previously recognized by the ca 367–360 Ma dolerite dyke swarms exposed in the N. part of the Central-North Armorican Domain. The isotopic (εHf) signature of these grains documents a pre-orogenic Variscan mantle contribution for the mafic magmatism interpreted here as the indication of the south-directed subduction of the Le Conquet-Teplá ocean, that is, a branch of the Rheic ocean, below the Armorica microcontinent during the Bretonian phase. The intraplate opening of the Laval, Ménez-Bélair, and Châteaulin basins was coeval with this subduction. In the Laval area, the final closure of the basin, accommodated by north-directed folds-and-thrusts, took place after the Bashkirian (ca 320 Ma).</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011944","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144315103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geomagnetic Excursions Recorded in North Atlantic IODP Expedition 395C Sites U1555 and U1563 北大西洋IODP考察队395C站点U1555和U1563记录的地磁偏移
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-18 DOI: 10.1029/2025GC012220
Anita Di Chiara, Sara Satolli, Sarah A. Friedman, Deepa Dwyer, Gary D. Acton, Tom Dunkley Jones, Boris Theofanis Karatsolis, Paul N. Pearson, Takuma Suzuki, Sevasti Modestou, Suzanne O'Connell, Halima Ibrahim, Claire E. Jasper, Danielle E. LeBlanc, Saran Lee-Takeda, Thena Thulasi, Deborah E. Eason, Matthias Sinnesael, Katharina Hochmuth, Anne Briais, Ross Parnell-Turner, Leah J. LeVay, Expedition 395C/395 Science Party
{"title":"Geomagnetic Excursions Recorded in North Atlantic IODP Expedition 395C Sites U1555 and U1563","authors":"Anita Di Chiara,&nbsp;Sara Satolli,&nbsp;Sarah A. Friedman,&nbsp;Deepa Dwyer,&nbsp;Gary D. Acton,&nbsp;Tom Dunkley Jones,&nbsp;Boris Theofanis Karatsolis,&nbsp;Paul N. Pearson,&nbsp;Takuma Suzuki,&nbsp;Sevasti Modestou,&nbsp;Suzanne O'Connell,&nbsp;Halima Ibrahim,&nbsp;Claire E. Jasper,&nbsp;Danielle E. LeBlanc,&nbsp;Saran Lee-Takeda,&nbsp;Thena Thulasi,&nbsp;Deborah E. Eason,&nbsp;Matthias Sinnesael,&nbsp;Katharina Hochmuth,&nbsp;Anne Briais,&nbsp;Ross Parnell-Turner,&nbsp;Leah J. LeVay,&nbsp;Expedition 395C/395 Science Party","doi":"10.1029/2025GC012220","DOIUrl":"https://doi.org/10.1029/2025GC012220","url":null,"abstract":"<p>By studying deep-sea drilled records from the North Atlantic Ocean, several magnetic instabilities of short duration, such as the Iceland Basin (188 ka), the Björn (1,255 ka) and the Gardar (1,460 ka) excursions, were discovered. These records have contributed to our understanding of Earth's magnetic field and are the foundation of the Geomagnetic Instability Time Scale (GITS) in the Quaternary. Here, we present the magnetostratigraphy from Sites U1555 (0 to ∼2.7 Ma) and U1563 (0 to ∼5.2 Ma) drilled during the International Ocean Discovery Program Expedition 395C on the eastern side of the modern Mid-Atlantic Ridge (∼60°N, 20–30°W). Shipboard paleomagnetic and microfossil data provided a preliminary age model, extending the regional record to 3.4 Ma. The Virtual Geomagnetic Pole latitudes from archive halves, corroborated with data from discrete samples, were used to build a high-resolution magnetostratigraphy, which contained the expected Brunhes and Matuyama Chrons and their respective Subchrons. We also identified most of the magnetic events reported in the GITS, including the less well-documented ones, such as Osaka, Kamitzukara, Huckleberry Ridge, Reunion, Gardar, Halawa and L4 events. The high-resolution magnetostratigraphy from Sites U1555 and U1563 is compared with two previous legacy sites and contributes toward an increasingly robust GITS, expanding its use as a correlation and dating tool.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012220","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144309017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Using Kgen to Generate Cross-Verified Apparent Equilibrium Constants (K∗’s) for Palaeoseawater Carbonate Chemistry 用Kgen生成古海水碳酸盐化学的交叉验证表观平衡常数(K * s)
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-09 DOI: 10.1029/2023GC011417
Ross Whiteford, Oscar Branson, Dennis Mayk
{"title":"Using Kgen to Generate Cross-Verified Apparent Equilibrium Constants (K∗’s) for Palaeoseawater Carbonate Chemistry","authors":"Ross Whiteford,&nbsp;Oscar Branson,&nbsp;Dennis Mayk","doi":"10.1029/2023GC011417","DOIUrl":"https://doi.org/10.1029/2023GC011417","url":null,"abstract":"<p>Quantification of palaeo pH and palaeo CO<sub>2</sub> from marine proxies requires the use of apparent equilibrium constants (K<sup>∗</sup>’s). The K<sup>∗</sup>’s required to calculate seawater carbonate chemistry are described by empirically determined calibrations, and for palaeoseawater these calibrations must be adjusted to account for changes in seawater composition. There are a number of possible calibrations that can be used to calculate K<sup>∗</sup>’s, and each software package for calculating carbonate chemistry separately implements these K<sup>∗</sup> calibrations, which are manually verified against previous implementations. Palaeo applications typically only implement a single calibration for each K<sup>∗</sup>, but have additional complexity from the need to adjust each calibration for changing seawater composition through time. The fragmented approach to K<sup>∗</sup> calculation can result in unintended and difficult to resolve discrepancies between outputs calculated by different pieces of software. We present “Kgen,” a synchronised collection of three pieces of software to consistently calculate palaeoseawater K<sup>∗</sup>’s in Python, R, and Matlab. Kgen provides a simple, and nearly identical interface in each language. Through use of a Continuous Integration/Continuous Delivery (CI/CD) pipeline, Kgen guarantees consistent outputs between languages by automatically cross-checking results from all three implementations. Unifying the approach to K<sup>∗</sup> calculation in this way provides an extensible platform for verifiable K<sup>∗</sup> generation for palaeoseawater, which can be integrated into existing carbon speciation calculators to improve the consistency of results.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023GC011417","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144244759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pulsed Injections of Metal-Rich Magmatic Fluids: Key Drivers of Mineralization in a Back-Arc Basin Hydrothermal System 富金属岩浆流体脉冲注入:弧后盆地热液系统成矿的关键驱动因素
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-07 DOI: 10.1029/2025GC012318
Xia Zhang, Zhilei Sun, Yachun Cai, Yue Xu, Nengyou Wu, Hong Cao
{"title":"Pulsed Injections of Metal-Rich Magmatic Fluids: Key Drivers of Mineralization in a Back-Arc Basin Hydrothermal System","authors":"Xia Zhang,&nbsp;Zhilei Sun,&nbsp;Yachun Cai,&nbsp;Yue Xu,&nbsp;Nengyou Wu,&nbsp;Hong Cao","doi":"10.1029/2025GC012318","DOIUrl":"https://doi.org/10.1029/2025GC012318","url":null,"abstract":"<p>Submarine magmatic–hydrothermal systems, where magmatic volatiles and fluids possibly serve as major sources of mineralization elements, have been extensively documented in numerous felsic-hosted hydrothermal fields. Previous studies have primarily focused on the contribution of magmatic volatiles in such hydrothermal systems. Although evidence has indicated that magmatic fluids have a greater capacity for transporting metals to overlying hydrothermal systems, their specific role in magmatic–hydrothermal systems remains inadequately understood. This study provides compelling evidence for the contribution of metal-rich magmatic fluid to the Minami–Ensei (ME) hydrothermal system. Pulsed injections of metal-rich magmatic fluids into the overlying hydrothermal system during mineralization process result in the elevated salinity (6.1–9.7 wt.% NaCl equiv) and <i>δ</i><sup>18</sup>O values (1.1–8.0‰) in ME hydrothermal fluids, which are recorded by barite fluid inclusions and oxygen (O) isotope compositions, respectively. Laser-induced breakdown spectroscopy analysis indicated that the magmatic fluids injected into the ME were likely Fe-rich. Metal concentrations in magmatic fluids are several orders of magnitude higher than those in hydrothermal fluids generated via leaching, and their contribution to overlying hydrothermal systems can substantially enhance sulfide mineralization efficiency in magmatic–hydrothermal deposits. This study underscores the potential of magmatic–hydrothermal systems as promising targets for future sulfide ore exploration.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012318","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144237301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D Reconstruction of Complex Fault Systems From Volumetric Geodynamic Shear Zones Using Medial Axis Transform 基于中轴变换的体动力剪切带复杂断层系统三维重建
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2025-06-07 DOI: 10.1029/2025GC012169
Anthony Jourdon, Dave A. May, Jorge N. Hayek, Alice-Agnes Gabriel
{"title":"3D Reconstruction of Complex Fault Systems From Volumetric Geodynamic Shear Zones Using Medial Axis Transform","authors":"Anthony Jourdon,&nbsp;Dave A. May,&nbsp;Jorge N. Hayek,&nbsp;Alice-Agnes Gabriel","doi":"10.1029/2025GC012169","DOIUrl":"https://doi.org/10.1029/2025GC012169","url":null,"abstract":"<p>Reconstructing fault surfaces from volumetric data is a longstanding challenge in geosciences. We present a novel 3D method based on the medial axis to transform a volumetric strain-rate invariant field from long-term geodynamic simulations into fault surfaces. In these geodynamic models, faults correspond to regions of locally high values of the second invariant of the strain-rate commonly referred to as shear zones. The proposed workflow begins by normalizing the strain-rate to define fault indicator field <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>ξ</mi>\u0000 </mrow>\u0000 <annotation> $xi $</annotation>\u0000 </semantics></math>. An iso-surface of a chosen <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>ξ</mi>\u0000 </mrow>\u0000 <annotation> $xi $</annotation>\u0000 </semantics></math> value is then extracted to form an envelope around the shear zones. Using the shrinking ball algorithm (Ma et al., 2012, https://doi.org/10.1007/s00371-011-0594-7), we compute the medial axis of this 3D envelope to generate a point cloud representing the geometric skeleton of the shear zones. We reconstruct fault surfaces by applying Delaunay triangulation followed by Laplacian smoothing. For models involving multiple intersecting faults, we perform a local principal component analysis (PCA) of the coordinates defining the medial axis and use the resulting eigenvectors to detect first-order orientation variations, enabling the separation and individualization of faults. We demonstrate the generality and robustness of the method by applying it several diverse 3D geodynamic scenarios: A single strike-slip fault, a branching strike-slip fault in a restraining bend, a dense strike-slip fault network, a rift system, and a subduction zone with a megathrust and a conjugate thrust fault.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 6","pages":""},"PeriodicalIF":2.9,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012169","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144237300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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