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Removing Climatic Overprints in Sedimentary Cosmogenic Beryllium Records: Potentials and Limits 去除沉积宇宙成因铍记录中的气候套印:潜力与局限
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-12-14 DOI: 10.1029/2024GC011761
Tatiana Savranskaia, Ramon Egli, Quentin Simon, Jean-Pierre Valet, Franck Bassinot, Nicolas Thouveny
{"title":"Removing Climatic Overprints in Sedimentary Cosmogenic Beryllium Records: Potentials and Limits","authors":"Tatiana Savranskaia,&nbsp;Ramon Egli,&nbsp;Quentin Simon,&nbsp;Jean-Pierre Valet,&nbsp;Franck Bassinot,&nbsp;Nicolas Thouveny","doi":"10.1029/2024GC011761","DOIUrl":"https://doi.org/10.1029/2024GC011761","url":null,"abstract":"<p>Continuous reconstructions of past variations of the Earth's magnetic field are based mainly on paleomagnetic and cosmogenic <sup>10</sup>Be records in marine sediments. In both cases, the recording mechanisms can be affected by environmental processes. Climatic overprints are only partially removed by normalization procedures, so that stacking is used to further remove site-specific effects. Regionally or globally correlated artifacts, however, cannot be removed by stacking. Here we present a modified approach where geomagnetic records are complemented by environmental proxies representing processes that might affect the field recording mechanism. Geomagnetic and environmental records are jointly processed with principal component analysis to obtain a set of components supposed to represent true variations of the geomagnetic field and climatic overprints, respectively. After discussing the theoretical background of this new approach and its underlying assumptions, a practical example is presented, using a worst-case scenario based on a single <sup>10</sup>Be record from the North Atlantic with strong climatic overprints, covering the last 600 ka. The first two principal components, which represent the modulation of <sup>10</sup>Be by global climatic variations and by the geomagnetic field, respectively, explain 66.3% of the signal variance. Comparison of the geomagnetic principal component with global relative paleointensity stacks shows that the original climatic overprint can be reduced by a factor of 2, outperforming a <sup>10</sup>Be/<sup>9</sup>Be stack obtained from two sites with little glacial-interglacial variability. The proposed method for removing climatic overprints can be applied to multiple sites more efficiently than conventional stacking.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011761","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142851289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Spectral Directors Method for Modeling the Coupled Evolution of Flow and CPO in Polycrystalline Olivine 多晶橄榄石中流动与CPO耦合演化的光谱指示法
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-12-14 DOI: 10.1029/2024GC011831
Nicholas M. Rathmann, Klaus Mosegaard, Ivanka M. O. Bekkevold, David A. Lilien, David J. Prior
{"title":"A Spectral Directors Method for Modeling the Coupled Evolution of Flow and CPO in Polycrystalline Olivine","authors":"Nicholas M. Rathmann,&nbsp;Klaus Mosegaard,&nbsp;Ivanka M. O. Bekkevold,&nbsp;David A. Lilien,&nbsp;David J. Prior","doi":"10.1029/2024GC011831","DOIUrl":"https://doi.org/10.1029/2024GC011831","url":null,"abstract":"<p>The crystallographic preferred orientation (CPO) of polycrystalline olivine affects both the viscous and seismic anisotropy of Earth's upper mantle with wide geodynamical implications. In this methods paper, we present a continuous field formulation of the popular directors method for modeling the strain-induced evolution of olivine CPOs, assuming the activation of a single preferred crystal slip system. The formulation reduces the problem of CPO evolution to a linear matrix problem that can easily be integrated alongside large-scale geodynamical flow models, and conveniently minimizes the degrees of freedom necessary to represent CPO fields. We validate the CPO model against existing deformation experiments and naturally deformed samples, as well as the popular discrete grain model D-Rex. A numerical model of viscoplastic thermal convection is built to illustrate how flow and CPO evolution may be two-way coupled, suggesting that CPO-induced viscous anisotropy does not necessarily strongly affect convection time scales, boundary (lid) stresses, and seismic anisotropy, compared to isotropic viscoplastic rheologies. As a consequence, geodynamical modeling that relies on an isotropic rheology (one-way coupling) might suffice for predicting seismic anisotropy under some circumstances. Finally, we discuss limitations and shortcomings of our method, such as representing D- and E-type fabrics or modeling flows with mixed fabric types, and potential improvements such as accounting for the effect of dynamic recrystallization.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011831","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elasticity of Nacrite: Implications for Subduction Zone Dynamics 紫榴石的弹性:俯冲带动力学的意义
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-12-12 DOI: 10.1029/2024GC011786
Ishita Das, Gaurav Shukla
{"title":"Elasticity of Nacrite: Implications for Subduction Zone Dynamics","authors":"Ishita Das,&nbsp;Gaurav Shukla","doi":"10.1029/2024GC011786","DOIUrl":"https://doi.org/10.1029/2024GC011786","url":null,"abstract":"<p>Subduction zones exhibit heterogeneities in composition due to different mineral assemblages transported into the mantle by the descending slabs, thus affecting the seismic properties of the region. These minerals are typically rich in alumina and silica and often contain hydrous phases. Nacrite, Al<sub>2</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub>, a mineral consisting of these components, forms in basaltic crust through hydrothermal alteration and is frequently overlooked due to its structural alikeness with its polytypes, making it hard to distinguish by traditional methods. Its occurrence in oceanic sediments and altered basaltic crust significantly impacts the subduction process by facilitating the transport of water into deeper mantle regions. In this study, we investigate the equation of state and elasticity of nacrite using first-principles calculations based on density functional theory corrected for dispersive forces over its pressure stability range. Anomalous behavior of elastic coefficients are suggestive of a polytypic transformation, evidenced by anomalous softening in the shear modulus and a decrease of approximately 3% in shear wave velocity observed at low pressures (<span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mo>∼</mo>\u0000 </mrow>\u0000 <annotation> ${sim} $</annotation>\u0000 </semantics></math> 2 GPa). Our studies indicate that nacrite exhibits a significantly lower shear wave velocity compared to the surrounding mantle, resulting in very high V<sub>P</sub>/V<sub>S</sub> ratios. These findings emphasize the role of nacrite in the subduction zones of Japan and Alaska, particularly in the formation of low-velocity layers. We propose that nacrite's presence is a significant factor explaining these observations, alongside other hydrous minerals like lawsonite, glaucophane, etc., contributing to the low-velocity layers in these regions.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011786","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142851342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seventeen Million Years of Episodic Volcanism Recorded Within the Geologist Seamounts: Implications for Tectonic Drivers of Intraplate Volcanism 地质学家海底山记录的1700万年间歇火山活动:对板块内火山活动构造驱动因素的启示
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-12-11 DOI: 10.1029/2024GC011806
Brandon Scott, Kevin Konrad
{"title":"Seventeen Million Years of Episodic Volcanism Recorded Within the Geologist Seamounts: Implications for Tectonic Drivers of Intraplate Volcanism","authors":"Brandon Scott,&nbsp;Kevin Konrad","doi":"10.1029/2024GC011806","DOIUrl":"https://doi.org/10.1029/2024GC011806","url":null,"abstract":"<p>Upwelling and decompression of mantle plumes is the primary mechanism for large volumes of intraplate volcanism; however, many seamounts do not correlate spatially, temporally, or geochemically with plumes. One region of enigmatic volcanism in the ocean basins that is not clearly attributable to plume-derived magmatism is the Geologist Seamounts and the wider South Hawaiian Seamount Province (∼19°N, 157°W). Here we present new bathymetric maps as well as <sup>40</sup>Ar/<sup>39</sup>Ar age determinations and major and trace element geochemistry for six remote-operated vehicle recovered igneous rock samples (NOAA-OER EX1504L3) and two dredged samples (KK840824-02) from the Geologist Seamounts. The new ages indicate that volcanism was active from 90 to 87 Ma and 74 to 73 Ma, inferring that in conjunction with previous ages of ∼84 Ma, seamount emplacement initiated near the paleo Pacific-Farallon spreading ridge and volcanism spanned at least ∼17 m.y. Geochemical analyses indicate that Geologist Seamount lava flows are highly alkalic and represent low-degree partial mantle melts primarily formed from a mixture of melting within the garnet and spinel stability field. The ages and morphology inferred that the seamounts were likely not related to an extinct plume. Instead, we build upon previous models that local microblock formation corresponded to regional lithospheric extension. We propose that the microblock was bounded by the Molokai and short-lived Kana Keoki fracture zones. Regional deformation and corresponding volcanism among the Geologist Seamounts associated with the microblock potentially occurred in pulses contemporaneous to independently constrained changes in Pacific Plate motion—indicating that major changes in plate vectors can generate intraplate volcanism.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011806","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142851351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Jurassic–Cretaceous Transition in the Slovenian Basin (Alpine Atlantic): Further Evidence for Palaeoenvironmental Record in Pelagic Sediments 斯洛文尼亚盆地(阿尔卑斯大西洋)的侏罗纪-白垩纪过渡:深海沉积物古环境记录的进一步证据
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-12-11 DOI: 10.1029/2024GC011728
D. G. Lodowski, J. Grabowski, B. Rožič, P. Žvab-Rožič, D. Reháková, L. Slapnik, J. Iwańczuk, A. Chmielewski, A. Teodorski
{"title":"The Jurassic–Cretaceous Transition in the Slovenian Basin (Alpine Atlantic): Further Evidence for Palaeoenvironmental Record in Pelagic Sediments","authors":"D. G. Lodowski,&nbsp;J. Grabowski,&nbsp;B. Rožič,&nbsp;P. Žvab-Rožič,&nbsp;D. Reháková,&nbsp;L. Slapnik,&nbsp;J. Iwańczuk,&nbsp;A. Chmielewski,&nbsp;A. Teodorski","doi":"10.1029/2024GC011728","DOIUrl":"https://doi.org/10.1029/2024GC011728","url":null,"abstract":"<p>Over the vast area of present-day Europe, the Tithonian–Berriasian transition was a time of climate aridization, which was supposedly related to the more general trend of the latest Jurassic–earliest Cretaceous cooling and restrictions in atmospheric circulation. Recent studies suggest that such conditions affected also some other paleoenvironmental processes such as monsoonal upwellings, seafloor ventilation and circulation of nutrients within the water column. In order to test this model, the uppermost Jurassic–lowermost Cretaceous sedimentary succession of the Slovenian Basin was correlated with a reference data from the Bakony Basin (Transdanubian Range, Hungary). Stratigraphic calibration was ensured by integrated stratigraphy, utilizing bio- (calpionellids, calcareous dinocysts) and chemostratigraphic tools (δ<sup>13</sup>C stratigraphy) as well as regional correlations of magnetic susceptibility and terrigenous input. Paleoclimate, paleoredox and paleoproductivity conditions were evaluated based on various geochemical proxies. Both the Slovenian and the Bakony basin sections were found to document late Tithonian–early Berriasian climate aridization as well as related signals of seafloor hypoxia and elevated accumulations of micronutrients. Significant geochemical contrast between the basal (lower Tithonian) radiolarites and overlying upper Tithonian–Berriasian carbonates evidences the inverse relation between the surface productivity and the amount of nutrient-type trace metals buried in sediments. The rhythm of paleoclimatically controlled environmental changes, with relatively humid early Tithonian, arid late Tithonian–early Berriasian, and again humid late Berriasian, correlates with those estimated for Vocontian Basin (SE France) and the Sub-Boreal domain of Western and Central Europe. This indicates that climatic stratigraphy is a useful tool for global correlation of the Jurassic/Cretaceous boundary interval.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011728","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142860911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetic Isotopic Degassing of CO2 During the 2021 Fagradalsfjall Eruption and the δ13C Signature of the Icelandic Mantle 2021年Fagradalsfjall火山喷发CO2的动力学同位素脱气及冰岛地幔的δ13C特征
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-12-06 DOI: 10.1029/2024GC011997
Yves Moussallam, Estelle F. Rose-Koga, Tobias P. Fischer, Guillaume Georgeais, Hyun Joo Lee, Janine Birnbaum, Melissa A. Pfeffer, Talfan Barnie, Edouard Regis
{"title":"Kinetic Isotopic Degassing of CO2 During the 2021 Fagradalsfjall Eruption and the δ13C Signature of the Icelandic Mantle","authors":"Yves Moussallam,&nbsp;Estelle F. Rose-Koga,&nbsp;Tobias P. Fischer,&nbsp;Guillaume Georgeais,&nbsp;Hyun Joo Lee,&nbsp;Janine Birnbaum,&nbsp;Melissa A. Pfeffer,&nbsp;Talfan Barnie,&nbsp;Edouard Regis","doi":"10.1029/2024GC011997","DOIUrl":"https://doi.org/10.1029/2024GC011997","url":null,"abstract":"<p>CO<sub>2</sub> is the first volatile to exsolve in magmatic systems and plays a crucial role in driving magma ascent and volcanic eruptions. Carbon stable isotopes serve as valuable tracers for understanding the transfer of CO<sub>2</sub> from the melt to the gas phase during passive degassing or active eruptions. In this study, we present δ<sup>1</sup><sup>3</sup>C measurements from the 2021 Fagradalsfjall eruption, obtained from (a) volcanic gases emitted during the eruption and collected via unmanned aerial systems (UAS), and (b) a series of mineral-hosted melt inclusions from the corresponding tephra deposits. These data sets jointly track the carbon isotopic evolution of the melt and gas phases during the last 10 km of magma ascent. The isotopic evolution of both phases indicates that kinetic degassing, a process previously only identified in mid-ocean ridge basalts, took place in the 10 to 1 km depth range, followed by equilibrium degassing at near-surface conditions in the last kilometer. Postulating that the melt was first saturated with CO<sub>2</sub> at 27 km depth and that degassing from then to 10 km depth took place via equilibrium isotopic fractionation, the melt inclusion data constrain the initial δ<sup>1</sup><sup>3</sup>C signature of the Icelandic mantle to −6.5 ± 2.5‰ but also show indications of possible isotopic heterogeneity in the mantle source.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011997","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142860362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microseismicity Around Loki's Castle Hydrothermal Vent Field Reveals the Early Stages of Detachment Faulting at the Mohns-Knipovich Ridge Intersection 洛基城堡热液喷口周围的微震活动揭示了Mohns-Knipovich岭交点的早期滑脱断裂
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-12-03 DOI: 10.1029/2024GC011732
Matthias Pilot, Marie Jakobsen Lien, Vera Schlindwein, Lars Ottemöller, Thibaut Barreyre
{"title":"Microseismicity Around Loki's Castle Hydrothermal Vent Field Reveals the Early Stages of Detachment Faulting at the Mohns-Knipovich Ridge Intersection","authors":"Matthias Pilot,&nbsp;Marie Jakobsen Lien,&nbsp;Vera Schlindwein,&nbsp;Lars Ottemöller,&nbsp;Thibaut Barreyre","doi":"10.1029/2024GC011732","DOIUrl":"https://doi.org/10.1029/2024GC011732","url":null,"abstract":"<p>At slow to ultraslow spreading ridges, the limited melt supply results in tectonic accretion and the exhumation of mantle rocks. Melt supply is focused toward volcanic centers where magmatic accretion dominates. In areas where the ridges reorientate, both types of accretion can occur across the ridge axis with detachment faults developing on the inside corners and hydrothermal vent fields located in close proximity. Microseismicity studies improve the understanding of the tectonic processes at detachment faults and their interplay with hydrothermal vent systems, but are mostly limited to mature detachment faults or short deployment times. This study presents results from a ∼11 months ocean bottom seismometer deployment around the Loki's Castle hydrothermal vent field at the intersection of the slow to ultraslow spreading Mohns and Knipovich Ridge. We observe seismicity to be highly asymmetric with the majority of the plate divergence being accommodated by an emerging detachment fault at the inside corner of the intersection west of Loki's Castle. Seismic activity related to the detachment fault displays a distinct contrast, with continuous low-magnitude events occurring at depth and episodic large-magnitude events concentrated in clusters within the footwall. The detachment fault shows no significant roll-over at shallow depths and the locus of spreading is located east of the detachment. These results suggest that the detachment fault west of Loki’s Castle is at an early development stage.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011732","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142762476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Auriferous Fluid Evolution and the Role of Carbonaceous Matter in a Saddle-Reef Gold Deposit: Dufferin Deposit, Meguma Terrane, Nova Scotia, Canada 含金流体演化及碳质物质在鞍礁金矿床中的作用:加拿大新斯科舍省Meguma地体Dufferin矿床
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-11-29 DOI: 10.1029/2024GC011861
Mitchell J. Kerr, Jacob J. Hanley, Daniel J. Kontak, Preetysha Ramlochund, Zoltán Zajacz
{"title":"Auriferous Fluid Evolution and the Role of Carbonaceous Matter in a Saddle-Reef Gold Deposit: Dufferin Deposit, Meguma Terrane, Nova Scotia, Canada","authors":"Mitchell J. Kerr,&nbsp;Jacob J. Hanley,&nbsp;Daniel J. Kontak,&nbsp;Preetysha Ramlochund,&nbsp;Zoltán Zajacz","doi":"10.1029/2024GC011861","DOIUrl":"https://doi.org/10.1029/2024GC011861","url":null,"abstract":"<p>The metaturbidite-hosted, ∼380 Ma Dufferin gold deposit, Meguma terrane, northeastern Appalachian Orogen (Nova Scotia, Canada) is an orogenic gold deposit with mineralized saddle reef-type quartz veins hosted by metasandstones and black slates in a tightly folded anticline. Together with native gold inclusions, genetically related hydrothermal carbonaceous material (CM) in veins occurs as pyrobitumen in cavities and along fractures/grain boundaries proximal to vein contacts and wallrock fragments. Integrating several microanalytical methods we document the precipitation of gold via coupled fluid-<i>f</i>O<sub>2</sub> reduction (via interaction with CM) and pH increase. These changes in fluid chemistry destabilized gold bisulfide complexes, leading to efficient Au precipitation from a gold-undersaturated (0.045 ± 0.024 ppm Au; 1σ; <i>n</i> = 58 fluid inclusions) aqueous-carbonic fluid (H<sub>2</sub>O-NaCl-CO<sub>2</sub> ± N<sub>2</sub> ± CH<sub>4</sub>). The proposed mineralization mechanism is supported by: (a) a complementary decrease in Au and redox-sensitive semimetals (As, Sb), and increase in wall rock-derived elements (i.e., Mg, K, Ca, Sr, Fe) concentrations in fluid inclusions with time; (b) a corresponding decrease in the X<sub>CO2</sub>, consistent with CO<sub>2</sub> removal via reduction/respeciation and late carbonate precipitation; and (c) gold embedding in, or on, the surface of CM inside mineralized cavities and fractures. Despite mineralizing fluids transporting low concentrations of Au far from saturation, precipitation of gold was locally evidently high where such fluids interacted with CM, contributing to the overall gold endowment of Meguma deposits. This work re-emphasizes CM as a potential prerequisite for efficient gold precipitation within the overall genetic model for similar orogenic metasedimentary settings globally where the presence and/or role of CM has been documented.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011861","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142749262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magma Chamber Response to Ice Unloading: Applications to Volcanism in the West Antarctic Rift System 岩浆房对冰卸载的响应:在南极西部裂谷系火山作用中的应用
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-11-27 DOI: 10.1029/2024GC011743
A. N. Coonin, C. Huber, J. Troch, M. Townsend, K. Scholz, B. S. Singer
{"title":"Magma Chamber Response to Ice Unloading: Applications to Volcanism in the West Antarctic Rift System","authors":"A. N. Coonin,&nbsp;C. Huber,&nbsp;J. Troch,&nbsp;M. Townsend,&nbsp;K. Scholz,&nbsp;B. S. Singer","doi":"10.1029/2024GC011743","DOIUrl":"https://doi.org/10.1029/2024GC011743","url":null,"abstract":"<p>Volcanic activity has been shown to affect Earth's climate in a myriad of ways. One such example is that eruptions proximate to surface ice will promote ice melting. In turn, the crustal unloading associated with melting an ice sheet affects the internal dynamics of the underlying magma plumbing system. Geochronologic data from the Andes over the last two glacial cycles suggest that glaciation and volcanism may interact via a positive feedback loop. At present, accurate sea-level predictions hinge on our ability to forecast the stability of the West Antarctic Ice Sheet, and thus require consideration of two-way subglacial volcano-deglaciation processes. The West Antarctic Ice Sheet is particularly vulnerable to collapse, yet its position atop an active volcanic rift is seldom considered. Ice unloading deepens the zone of melting and alters the crustal stress field, impacting conditions for dike initiation, propagation, and arrest. However, the consequences for internal magma chamber dynamics and long-term eruption behavior remain elusive. Given that unloading-triggered volcanism in West Antarctica may contribute to the uncertainty of ice loss projections, we adapt a previously published thermomechanical magma chamber model and simulate a shrinking ice load through a prescribed lithostatic pressure decrease. We investigate the impacts of varying unloading scenarios on magma volatile partitioning and eruptive trajectory. Considering the removal of km-thick ice sheets, we demonstrate that the rate of unloading influences the cumulative mass erupted and consequently the heat released into the ice. These findings provide fundamental insights into the complex volcano-ice interactions in West Antarctica and other subglacial volcanic settings.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"25 12","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024GC011743","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748945","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Slab-Plume Interactions Beneath Australia and New Zealand: New Insight From Whole-Mantle Tomography 澳大利亚和新西兰地下的板岩-岩体相互作用:全幔层析成像的新发现
IF 2.9 2区 地球科学
Geochemistry Geophysics Geosystems Pub Date : 2024-11-26 DOI: 10.1029/2024GC011739
Genti Toyokuni, Dapeng Zhao
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