Cave Dripwater Magnetic Minerals Record Seasonal Rainfall Variability: New Insights From a 5-Years Field Monitoring in Central China

IF 3 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Taiheng Shi, Zongmin Zhu, Yuhang Jia, Lingtao Yan, Hongbin Zhang, Shuyu Xue, Qian Luo, Jianyu Ding
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Abstract

Stalagmites provide an invaluable archive at high-resolution for paleoclimate studies. However, it is challenging to extract independent hydroclimate signals from stalagmites due to the scarcity of reliable hydrological proxies. Although the magnetic parameters of stalagmites have shown great potential in recording regional hydrological signals, the mechanistic linkages between magnetic minerals and hydroclimate variability remain unresolved, limiting the broader application of stalagmite magnetism. This study addresses this knowledge gap through a 5-year monitoring campaign targeting Heshang (HSD), Haozhu (HZD), and Chang (CD) caves in central China. We systematically analyzed the magnetic minerals in coupled soil-bedrock-dripwater-stalagmite systems using integrated environmental magnetic techniques. The results demonstrate that magnetic minerals in the dripwater are dominated by magnetite/maghemite (detrital origin from overlying soils) and goethite (mixed sources including pedogenic, bedrock derived, and authigenic contributions, but not specifically). Seasonal analysis reveals that magnetite/maghemite flux (MMag/Mgh-flux) in the HSD dripwater exhibits pronounced wet-season (May to September) enhancement, which is closely correlated with the rainfall-driven soil flushing. This pattern attenuates in the HZD and CD systems due to their reduced soil-bedrock cover thickness. In contrast, the relative concentration of goethite (RGt) displays a consistent sensitivity to regional rainfall across all the monitored caves, especially HSD, suggesting its broader utility as a hydroclimate proxy. Our findings establish a mechanistic framework linking stalagmite magnetic mineralogy to rainfall dynamics, identifying MMag/Mgh-flux and RGt as robust dual proxies for reconstructing past hydrological variability in karst systems.

Abstract Image

洞穴滴水磁性矿物记录降水季节变化:来自中部地区5年野外监测的新见解
石笋为古气候研究提供了高分辨率的宝贵资料。然而,由于缺乏可靠的水文代理,从石笋中提取独立的水文气候信号具有挑战性。尽管石笋的磁性参数在记录区域水文信号方面显示出巨大的潜力,但磁性矿物与水文气候变率之间的机制联系仍未得到解决,限制了石笋磁性的广泛应用。本研究通过对中国中部河上(HSD)、好珠(HZD)和昌(CD)洞穴进行为期5年的监测活动,解决了这一知识缺口。应用综合环境磁技术系统分析了土壤-基岩-滴水-石笋耦合系统中的磁性矿物。结果表明,滴水中的磁性矿物主要为磁铁矿/磁赤铁矿(碎屑来源为上覆土壤)和针铁矿(混合来源包括成土、基岩和自生贡献,但不明确)。季节分析表明,在5 ~ 9月的湿润季节,HSD降水中磁铁矿/磁铁矿通量(MMag/Mgh-flux)明显增强,与降雨驱动的土壤冲刷密切相关。这种模式在HZD和CD系统中减弱,因为它们的土壤-基岩覆盖厚度减少。相比之下,针铁矿的相对浓度(RGt)对所有监测洞穴(尤其是HSD)的区域降雨表现出一致的敏感性,表明其作为水文气候指标的广泛用途。我们的研究结果建立了一个将石笋磁性矿物学与降雨动力学联系起来的机制框架,确定了MMag/ mgh -通量和RGt是重建喀斯特系统过去水文变化的可靠的双重代理。
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来源期刊
Geochemistry Geophysics Geosystems
Geochemistry Geophysics Geosystems 地学-地球化学与地球物理
CiteScore
5.90
自引率
11.40%
发文量
252
审稿时长
1 months
期刊介绍: Geochemistry, Geophysics, Geosystems (G3) publishes research papers on Earth and planetary processes with a focus on understanding the Earth as a system. Observational, experimental, and theoretical investigations of the solid Earth, hydrosphere, atmosphere, biosphere, and solar system at all spatial and temporal scales are welcome. Articles should be of broad interest, and interdisciplinary approaches are encouraged. Areas of interest for this peer-reviewed journal include, but are not limited to: The physics and chemistry of the Earth, including its structure, composition, physical properties, dynamics, and evolution Principles and applications of geochemical proxies to studies of Earth history The physical properties, composition, and temporal evolution of the Earth''s major reservoirs and the coupling between them The dynamics of geochemical and biogeochemical cycles at all spatial and temporal scales Physical and cosmochemical constraints on the composition, origin, and evolution of the Earth and other terrestrial planets The chemistry and physics of solar system materials that are relevant to the formation, evolution, and current state of the Earth and the planets Advances in modeling, observation, and experimentation that are of widespread interest in the geosciences.
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