{"title":"Cave Dripwater Magnetic Minerals Record Seasonal Rainfall Variability: New Insights From a 5-Years Field Monitoring in Central China","authors":"Taiheng Shi, Zongmin Zhu, Yuhang Jia, Lingtao Yan, Hongbin Zhang, Shuyu Xue, Qian Luo, Jianyu Ding","doi":"10.1029/2025GC012427","DOIUrl":null,"url":null,"abstract":"<p>Stalagmites provide an invaluable archive at high-resolution for paleoclimate studies. However, it is challenging to extract independent hydroclimate signals from stalagmites due to the scarcity of reliable hydrological proxies. Although the magnetic parameters of stalagmites have shown great potential in recording regional hydrological signals, the mechanistic linkages between magnetic minerals and hydroclimate variability remain unresolved, limiting the broader application of stalagmite magnetism. This study addresses this knowledge gap through a 5-year monitoring campaign targeting Heshang (HSD), Haozhu (HZD), and Chang (CD) caves in central China. We systematically analyzed the magnetic minerals in coupled soil-bedrock-dripwater-stalagmite systems using integrated environmental magnetic techniques. The results demonstrate that magnetic minerals in the dripwater are dominated by magnetite/maghemite (detrital origin from overlying soils) and goethite (mixed sources including pedogenic, bedrock derived, and authigenic contributions, but not specifically). Seasonal analysis reveals that magnetite/maghemite flux (M<sub>Mag/Mgh-flux</sub>) in the HSD dripwater exhibits pronounced wet-season (May to September) enhancement, which is closely correlated with the rainfall-driven soil flushing. This pattern attenuates in the HZD and CD systems due to their reduced soil-bedrock cover thickness. In contrast, the relative concentration of goethite (R<sub>Gt</sub>) displays a consistent sensitivity to regional rainfall across all the monitored caves, especially HSD, suggesting its broader utility as a hydroclimate proxy. Our findings establish a mechanistic framework linking stalagmite magnetic mineralogy to rainfall dynamics, identifying M<sub>Mag/Mgh-flux</sub> and R<sub>Gt</sub> as robust dual proxies for reconstructing past hydrological variability in karst systems.</p>","PeriodicalId":50422,"journal":{"name":"Geochemistry Geophysics Geosystems","volume":"26 10","pages":""},"PeriodicalIF":3.0000,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://agupubs.onlinelibrary.wiley.com/doi/epdf/10.1029/2025GC012427","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Geochemistry Geophysics Geosystems","FirstCategoryId":"89","ListUrlMain":"https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2025GC012427","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
Abstract
Stalagmites provide an invaluable archive at high-resolution for paleoclimate studies. However, it is challenging to extract independent hydroclimate signals from stalagmites due to the scarcity of reliable hydrological proxies. Although the magnetic parameters of stalagmites have shown great potential in recording regional hydrological signals, the mechanistic linkages between magnetic minerals and hydroclimate variability remain unresolved, limiting the broader application of stalagmite magnetism. This study addresses this knowledge gap through a 5-year monitoring campaign targeting Heshang (HSD), Haozhu (HZD), and Chang (CD) caves in central China. We systematically analyzed the magnetic minerals in coupled soil-bedrock-dripwater-stalagmite systems using integrated environmental magnetic techniques. The results demonstrate that magnetic minerals in the dripwater are dominated by magnetite/maghemite (detrital origin from overlying soils) and goethite (mixed sources including pedogenic, bedrock derived, and authigenic contributions, but not specifically). Seasonal analysis reveals that magnetite/maghemite flux (MMag/Mgh-flux) in the HSD dripwater exhibits pronounced wet-season (May to September) enhancement, which is closely correlated with the rainfall-driven soil flushing. This pattern attenuates in the HZD and CD systems due to their reduced soil-bedrock cover thickness. In contrast, the relative concentration of goethite (RGt) displays a consistent sensitivity to regional rainfall across all the monitored caves, especially HSD, suggesting its broader utility as a hydroclimate proxy. Our findings establish a mechanistic framework linking stalagmite magnetic mineralogy to rainfall dynamics, identifying MMag/Mgh-flux and RGt as robust dual proxies for reconstructing past hydrological variability in karst systems.
期刊介绍:
Geochemistry, Geophysics, Geosystems (G3) publishes research papers on Earth and planetary processes with a focus on understanding the Earth as a system. Observational, experimental, and theoretical investigations of the solid Earth, hydrosphere, atmosphere, biosphere, and solar system at all spatial and temporal scales are welcome. Articles should be of broad interest, and interdisciplinary approaches are encouraged.
Areas of interest for this peer-reviewed journal include, but are not limited to:
The physics and chemistry of the Earth, including its structure, composition, physical properties, dynamics, and evolution
Principles and applications of geochemical proxies to studies of Earth history
The physical properties, composition, and temporal evolution of the Earth''s major reservoirs and the coupling between them
The dynamics of geochemical and biogeochemical cycles at all spatial and temporal scales
Physical and cosmochemical constraints on the composition, origin, and evolution of the Earth and other terrestrial planets
The chemistry and physics of solar system materials that are relevant to the formation, evolution, and current state of the Earth and the planets
Advances in modeling, observation, and experimentation that are of widespread interest in the geosciences.