Rory Leslie, A. Cavanagh, R. Haszeldine, G. Johnson, S. Gilfillan
{"title":"Quantification of solubility trapping in natural and engineered CO2 reservoirs","authors":"Rory Leslie, A. Cavanagh, R. Haszeldine, G. Johnson, S. Gilfillan","doi":"10.1144/petgeo2020-120","DOIUrl":"https://doi.org/10.1144/petgeo2020-120","url":null,"abstract":"Secure retention of CO2 in geological reservoirs is essential for effective storage. Solubility trapping, the dissolution of CO2 into formation water, is a major sink on geological timescales in natural CO2 reservoirs. Observations during CO2 injection, combined with models of CO2 reservoirs, indicate the immediate onset of solubility trapping. There is uncertainty regarding the evolution of dissolution rates between the observable engineered timescale of years and decades, and the >10 kyr state represented by natural CO2 reservoirs. A small number of studies have constrained dissolution rates within natural analogues. The studies show that solubility trapping is the principal storage mechanism after structural trapping, removing 10–50% of CO2 across whole reservoirs. Natural analogues, engineered reservoirs and model studies produce a wide range of estimates on the fraction of CO2 dissolved and the dissolution rate. Analogue and engineered reservoirs do not show the high fractions of dissolved CO2 seen in several models. Evidence from natural analogues supports a model of most dissolution occurring during emplacement and migration, before the establishment of a stable gas–water contact. A rapid decline in CO2 dissolution rate over time suggests that analogue reservoirs are in dissolution equilibrium for most of the CO2 residence time. Supplementary material: Dissolution rate for all plots and exponential function curves for scenarios A and B are available at https://doi.org/10.6084/m9.figshare.c.5476199 Thematic collection: This article is part of the Geoscience for CO2 storage collection available at: https://www.lyellcollection.org/cc/geoscience-for-co2-storage","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45517226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Laura-Jane C. Fyfe, N. Schofield, S. Holford, A. Hartley, A. Heafford, D. Muirhead, J. Howell
{"title":"Geology and petroleum prospectivity of the Sea of Hebrides Basin and Minch Basin, offshore NW Scotland","authors":"Laura-Jane C. Fyfe, N. Schofield, S. Holford, A. Hartley, A. Heafford, D. Muirhead, J. Howell","doi":"10.1144/petgeo2021-003","DOIUrl":"https://doi.org/10.1144/petgeo2021-003","url":null,"abstract":"The Sea of Hebrides Basin and Minch Basin are late Paleozoic–Mesozoic rift basins located to the NW of the Scottish mainland. The basins were the target of small-scale petroleum exploration from the late 1960s to the early 1990s, with a total of three wells drilled within the two basins between 1989 and 1991. Although no commercially viable petroleum discoveries were made, numerous petroleum shows were identified within both basins, including a gas show within the Upper Glen 1 well in Lower Jurassic limestones. Organic-rich shales have been identified throughout the Jurassic succession within the Sea of Hebrides Basin, with one Middle Jurassic (Bajocian–Bathonian) shale exhibiting a total organic carbon content of up to 15 wt%. The focus of this study is to review the historical petroleum exploration within these basins, and to evaluate whether the conclusions drawn in the early 1990s of a lack of prospectivity remains the case. This was undertaken by analysis of seismic reflection data, gravity and aeromagnetic data, and sedimentological data from both onshore and offshore wells, boreholes and previously published studies. The key findings from our study suggest that there is a low probability of commercially sized petroleum accumulations within either the Sea of Hebrides Basin or the Minch Basin. Ineffective source rocks, likely to be due to low maturities (due to lack of burial) and the fact that the encountered Jurassic and Permian–Triassic reservoirs are of poor quality (low porosity and permeability), has led to our interpretation of future exploration being high risk, with any potential accumulations being small in size. While petroleum accumulations are unlikely within the basin, applying the knowledge obtained from this study could provide additional datasets and insight into petroleum exploration within other NE Atlantic margin basins, such as the Rockall Trough and the Faroe–Shetland Basin.","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46655679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Pantopoulos, Gustavo Kenji Lacerda Orita, G. Armelenti, Camila Eliza Althaus, J. Kuchle, C. Scherer, A. G. Rodrigues, L. F. De Ros
{"title":"Depositional conditions at the Aptian pre-salt margins: evidence from quantitative petrography and textural analysis of the Mucuri Member, Espírito Santo Basin, Brazil","authors":"G. Pantopoulos, Gustavo Kenji Lacerda Orita, G. Armelenti, Camila Eliza Althaus, J. Kuchle, C. Scherer, A. G. Rodrigues, L. F. De Ros","doi":"10.1144/petgeo2020-112","DOIUrl":"https://doi.org/10.1144/petgeo2020-112","url":null,"abstract":"Aptian siliciclastic onshore deposits of the Mucuri Member are important reservoirs in the Espírito Santo Basin (eastern Brazil). A detailed quantitative petrographical and textural analysis of well core samples was performed in order to unravel their depositional processes and conditions, in relation to previously proposed depositional models. The results allowed differentiation between two groups of sandstone samples, characterized by different textural characteristics associated to different depositional processes and environments within the Mucuri depositional system. Fluvial sandstones are represented by medium- to coarse-grained, poorly sorted arkoses, rich in plutonic rock fragments and feldspar grains, mainly transported by traction. Coastal-lacustrine sandstones correspond to very fine- to fine-grained, moderately sorted micaceous arkoses, mainly transported in suspension. The application of a discriminant function based on grain-size parameters validated previously proposed depositional settings for the studied sample groups. The combination of grain-size and shape data revealed differences in hydraulic equivalence and shape between grains from different depositional settings. In terms of hydraulic equivalence, micas in the fluvial sediments present lower settling velocity values, in contrast to the relatively large mica grains in the coastal sediments, which are hydraulically equivalent with the associated quartz and feldspar grains. The results of this study provide key information regarding depositional conditions (transportation mechanisms, grain-settling velocity and mineral hydraulic fractionation) at the margins of the Aptian pre-salt system, which can constrain the hydrological conditions and the sediment type available for distal lacustrine areas.","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41390801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuan-Jian Lin, Jiang-feng Liu, Tao Chen, Shimin Ma, Pei-Lin Wang, H. Bai
{"title":"Gas Permeability Change with Deformation and Cracking of a Sandstone under Triaxial Compression","authors":"Yuan-Jian Lin, Jiang-feng Liu, Tao Chen, Shimin Ma, Pei-Lin Wang, H. Bai","doi":"10.21203/rs.3.rs-392045/v1","DOIUrl":"https://doi.org/10.21203/rs.3.rs-392045/v1","url":null,"abstract":"\u0000 In this paper, a THMC multi-field coupling triaxial cell was used to systematically study the evolution of gas permeability and the deformation characteristics of sandstone. The effects of confining pressure, axial pressure and air pressure on gas permeability characteristics were fully considered in the test. The gas permeability of sandstone decreases with increasing confining pressure. When the confining pressure is low, the variation of gas permeability is greater than the variation of gas permeability at high confining pressure. The gas injection pressure has a significant effect on the gas permeability evolution of sandstone. As the gas injection pressure increases, the gas permeability of sandstone tends to decrease. At the same confining pressure, the gas permeability of the sample during the unloading path is less than the gas permeability of the sample in the loading path. When axial pressure is applied, the axial stress has a significant influence on the permeability evolution of sandstone. When the axial pressure is less than 30 MPa, the gas permeability of the sandstone increases as the axial pressure increases. At axial pressures greater than 30 MPa, the permeability decreases as the axial pressure increases. Finally, the micro-pore/fracture structure of the sample after the gas permeability test was observed using 3D X-ray CT imaging.","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46824691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Pearce, A. L. La Croix, F. Brink, P. Hayes, J. Underschultz
{"title":"CO2 mineral trapping comparison in different regions: predicted geochemical reactivity of the Precipice Sandstone reservoir and overlying Evergreen Formation","authors":"J. Pearce, A. L. La Croix, F. Brink, P. Hayes, J. Underschultz","doi":"10.1144/petgeo2020-106","DOIUrl":"https://doi.org/10.1144/petgeo2020-106","url":null,"abstract":"Injected CO2 streams may have geochemical reactivity to different rock types in a CO2 storage complex depending on solubility and formation water chemistry. The Precipice Sandstone and Evergreen Formation are a low-salinity reservoir–seal pair in the Surat Basin, Australia, targeted for potential CO2 storage. The kinetic geochemical CO2 reactivity of different rock facies from three regions were predicted over 30 and 1000 year time periods. No material CO2 mineral trapping in the quartz-rich Precipice Sandstone reservoir was predicted, owing to the low rock reactivity. Predicted CO2 mineral trapping in the Evergreen Formation was more variable due to different amounts of more reactive feldspars, clays, calcite and siderite. Predicted mineral trapping as siderite and ankerite was between 0.03 and 8.4 kg m−3 CO2, and mainly depends on chlorite and plagioclase content. Predicted pH was between 5 and 7.5 after 1000 years. Pyrite precipitation was also predicted with SO2 present in the injectate. QEMSCAN and SEM-EDS (scanning electron microscopy and energy-dispersive spectroscopy) spot imaging of samples from the seal containing natural fractures filled by siderite, pyrite, clays, ankerite, calcite, barite and apatite represent a natural analogue for natural mineral trapping. These are in good agreement with our model predictions. This study suggests that, from a geochemical perspective, the Precipice Sandstone is a suitable storage reservoir, whereas mineral trapping would occur in the overlying Evergreen Formation. Supplementary material: Additional model inputs, characterization and model images, and an excel file of QEMSCAN mineral and porosity components, are available at https://doi.org/10.6084/m9.figshare.c.5395393 Thematic collection: This article is part of the Geoscience for CO2 storage collection available at: https://www.lyellcollection.org/cc/geoscience-for-co2-storage","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47550843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Qu, P. Frykman, L. Stemmerik, K. Mosegaard, L. Nielsen
{"title":"Upscaling of outcrop information for improved reservoir modelling – exemplified by a case study on chalk","authors":"D. Qu, P. Frykman, L. Stemmerik, K. Mosegaard, L. Nielsen","doi":"10.1144/petgeo2020-126","DOIUrl":"https://doi.org/10.1144/petgeo2020-126","url":null,"abstract":"Outcrops are valuable for analogous subsurface reservoirs in supplying knowledge of fine-scale spatial heterogeneity pattern and stratification types, which are difficult to obtain from subsurface reservoir cores, well logs or seismic data. For petrophysical properties in a domain where the variations are relatively continuous and not dominated by abrupt contrasts, the spatial heterogeneity pattern can be characterized by a semivariogram model. The outcrop information therefore has the potential to constrain the semivariogram for subsurface reservoir modelling, even though it represents different locations and depths, and the petrophysical properties may differ in magnitude or variance. However, the use of outcrop-derived spatial correlation information for petrophysical property modelling in practice has been challenged by the scale difference between the small support volume of the property measurements from outcrops and the typically much larger grid cells used in reservoir models. With an example of modelling the porosity of an outcrop chalk unit in eastern Denmark, this paper illustrates how the fine-scale spatial correlation information obtained from the sampling of outcrops can be transferred to coarser-scale models of analogue rocks. The workflow can be applied to subsurface reservoirs and ultimately improves the representation of geological patterns in reservoir models.","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44708231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Maul, M. Cetale, C. Guizan, P. Corbett, J. Underhill, L. Teixeira, R. Pontes, María González
{"title":"The impact of heterogeneous salt velocity models on the gross rock volume estimation: an example from the Santos Basin pre-salt, Brazil","authors":"A. Maul, M. Cetale, C. Guizan, P. Corbett, J. Underhill, L. Teixeira, R. Pontes, María González","doi":"10.1144/petgeo2020-105","DOIUrl":"https://doi.org/10.1144/petgeo2020-105","url":null,"abstract":"The thick and heterogeneous salt section in the Santos Basin, offshore Brazil, imposes great challenges in accessing the pre-salt hydrocarbon reservoirs, especially in relation to seismic imaging, signal quality and depth positioning. Some problems arise from the current velocity models for the salt section, which, for the majority, assume that the salt is a homogeneous halite layer. In the Santos Basin, the commonly assumed salt – halite – only makes up to 80% of the mineral in this section. The inclusion of other salts as stratification in the velocity models, based on seismic attributes, has achieved good results in the last decade, especially for depth resolution. In this work, we analyse the benefits of different velocity models, considering presence/absence of salt stratification and comparing the gross rock volume above the oil–water contact. The results show a significant effect on the depth resolution of the events, as well as on volume estimation, indicating that the greater the reliability captured by the complex velocity models, the greater the confidence in the resulting volumetric information.","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42315932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Intra-salt structure and strain partitioning in layered evaporites: implications for drilling through Messinian salt in the eastern Mediterranean","authors":"S. Evans, C. Jackson","doi":"10.1144/petgeo2020-072","DOIUrl":"https://doi.org/10.1144/petgeo2020-072","url":null,"abstract":"We use 3D seismic reflection data from the Levant margin, offshore Lebanon to investigate the structural evolution of the Messinian evaporite sequence, and how intra-salt structure and strain varies within a thick salt sheet during early-stage salt tectonics. Intra-Messinian reflectivity reveals lithological heterogeneity within the otherwise halite-dominated sequence. This leads to rheological heterogeneity, with the different mechanical properties of the various units controlling strain accommodation within the deforming salt sheet. We assess the distribution and orientation of structures, and show how intra-salt strain varies both laterally and vertically along the margin. We argue that units appearing weakly strained in seismic data may in fact accommodate considerable subseismic or cryptic strain. We also discuss how the intra-salt stress state varies through time and space in response to the gravitational forces driving deformation. We conclude that efficient drilling through thick, heterogeneous salt requires a holistic understanding of the mechanical and kinematic development of the salt and its overburden. This will also enable us to build better velocity models that account for intra-salt lithological and structural complexity in order to accurately image sub-salt geological structures.","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43678930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. P. Wennberg, G. McQueen, P. H. Vieira de Luca, F. Lapponi, D. Hunt, A. S. Chandler, A. Waldum, G. Nery Camargo, E. Castro, L. Loures
{"title":"Open fractures in pre-salt silicified carbonate reservoirs in block BM-C-33, the Outer Campos Basin, offshore Brazil","authors":"O. P. Wennberg, G. McQueen, P. H. Vieira de Luca, F. Lapponi, D. Hunt, A. S. Chandler, A. Waldum, G. Nery Camargo, E. Castro, L. Loures","doi":"10.1144/petgeo2020-125","DOIUrl":"https://doi.org/10.1144/petgeo2020-125","url":null,"abstract":"Natural open fractures are present in sidewall cores and in whole-core samples from pre-salt reservoirs in the licence block BM-C-33 in the Campos Basin, Brazil. Open fractures are also observed in borehole image logs, and fracture densities are in general high. The highest density of open fractures is seen in the damage zones above and below larger cavities (amalgamated cavern damage zones (ACDZs)). Outside the ACDZs the fracture density is high in silicified carbonates, where it tends to increase with decreasing porosity. Clean dolomites are less fractured than the silicified interval, while the less brittle argillaceous dolomites have the lowest fracture density. Some fractures appear vuggy on borehole image logs, and fracture densities are high close to vugs and larger cavities. The positive correlation between fractures and vugs is caused by flow of dissolving fluids through open fractures, and fracturing at stress concentrations around vugs. Two major fault zones have been interpreted from borehole image logs that have damage zones with very high fracture density. The well-test permeability is much greater than the matrix permeability estimated from sidewall core and log measurements. This excess permeability is attributed to fractures, in combination with caverns and intervals with frequent vugs.","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42279974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Michelle R. Plampin, M. Blondes, E. Sonnenthal, W. Craddock
{"title":"Potential Pb2+ mobilization, transport, and sequestration in shallow aquifers impacted by multiphase CO2 leakage: a natural analogue study from the Virgin River Basin in SW Utah","authors":"Michelle R. Plampin, M. Blondes, E. Sonnenthal, W. Craddock","doi":"10.1144/petgeo2020-109","DOIUrl":"https://doi.org/10.1144/petgeo2020-109","url":null,"abstract":"Geological carbon sequestration (GCS) is necessary to help meet goals for emissions reduction, but groundwater contamination may occur if CO2 and/or brine were to leak out of deep storage formations into the shallow subsurface. For this study, a natural analogue was investigated: in the Virgin River Basin of SW Utah, water with moderate salinity and high CO2 concentrations is leaking upwards into shallow aquifers that contain heavy-metal-bearing concretions. The aquifer system is comprised of the Navajo and Kayenta formations, which are pervasive across southern Utah and have been considered as a potential GCS injection unit where they are sufficiently deep. Numerical models of the site were constructed based on measured water chemistry and head distributions from previous studies. Simulations were used to improve understanding of the rate and distribution of the upwelling flow into the aquifers, and to assess the reactive transport processes that may occur if the upwelling fluids were to interact with a zone of iron oxide and other heavy metals, representing the concretions that are common in the area. Various mineralogies were tested, including one in which Pb2+ was adsorbed onto ferrihydrite, and another in which it was bound within a solid mixture of litharge (PbO) and hematite (Fe2O3). Results indicate that metal mobilization depends strongly on the source-zone composition and that Pb2+ transport can be naturally attenuated by gas-phase formation and carbonate-mineral precipitation. These findings could be used to improve risk assessment and mitigation strategies at geological carbon sequestration sites. Thematic collection: This article is part of the Geoscience for CO2 storage collection available at: https://www.lyellcollection.org/cc/geoscience-for-co2-storage","PeriodicalId":49704,"journal":{"name":"Petroleum Geoscience","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2021-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41281608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}