Ultrasonics Sonochemistry最新文献

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Ultrasound-assisted extraction with deep eutectic solvents for valorization of agro-food waste: A sustainable and eco-friendly approach. 超声辅助萃取深度共晶溶剂用于农业食品垃圾的增值:可持续和环保的方法。
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-09-01 Epub Date: 2025-08-06 DOI: 10.1016/j.ultsonch.2025.107500
Rui Xu, Kashmala Chaudhary, Ammar B Altemimi, Samran Khalid, Sadia Ansar, Namrah Abid, Gholamreza Abdi, Rana Muhammad Aadil
{"title":"Ultrasound-assisted extraction with deep eutectic solvents for valorization of agro-food waste: A sustainable and eco-friendly approach.","authors":"Rui Xu, Kashmala Chaudhary, Ammar B Altemimi, Samran Khalid, Sadia Ansar, Namrah Abid, Gholamreza Abdi, Rana Muhammad Aadil","doi":"10.1016/j.ultsonch.2025.107500","DOIUrl":"10.1016/j.ultsonch.2025.107500","url":null,"abstract":"<p><p>The growing need for innovative, sustainable, and eco-friendly solutions worldwide has intensified efforts to valorize agro-food waste, which is generated in vast quantities worldwide and is rich in valuable substances with diverse industrial applications. Conventional extraction methods using organic solvents have long been employed for this purpose, but their significant drawbacks highlight the need for alternative approaches. This review explores the application of non-thermal ultrasound-assisted extraction (UAE) with deep eutectic solvents (DESs) for extracting valuable substances from agro-food waste. It critically examines recent innovations in the UAE with DESs, including mechanisms, applications to agro-food waste, limitations, and aspects of safety, sustainability, and scalability. The key findings indicate that UAE with DESs outperforms conventional and other novel extraction techniques for agro-food waste valorization. This approach offers significant benefits, such as enhanced extraction efficiency, high-quality extracts, reduced processing time and energy consumption, biodegradability, low toxicity, and the reusability and tunability of DESs, all of which align with eco-friendly practices. While identifying a single best DES is challenging due to their varying extraction efficiencies with different waste materials, but optimal ultrasonication parameters commonly reported in the literature include 300-400 W power, 30 min extraction time, 40 °C temperature, and a solid-to-solvent ratio (SSR) of 1:30 g/mL to achieve high extraction efficiency. Future studies should investigate a wider range of plant and animal-based waste, optimize ultrasonic parameters and DES compositions, explore combinative extraction methods, enhance compound purification and solvent recovery, and assess industrial scalability through TEA, LCA, safety testing, and regulatory alignment.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"120 ","pages":"107500"},"PeriodicalIF":9.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12356026/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144811602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Effects and improvement mechanisms of ultrasonic pretreatment on the quality of fermented skim milk”. [Ultrason. Sonochem. 108 (2024) 106958] “超声波预处理对发酵脱脂乳质量的影响及改善机理”的更正。[Ultrason。声学化学,108 (2024)106958 [j]。
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-09-01 DOI: 10.1016/j.ultsonch.2025.107454
Hongsen Yu , Xinyue Cheng , Hang Li , Qiwei Du , Xiaoqun Zeng , Zhen Wu , Yuxing Guo , Daodong Pan
{"title":"Corrigendum to “Effects and improvement mechanisms of ultrasonic pretreatment on the quality of fermented skim milk”. [Ultrason. Sonochem. 108 (2024) 106958]","authors":"Hongsen Yu ,&nbsp;Xinyue Cheng ,&nbsp;Hang Li ,&nbsp;Qiwei Du ,&nbsp;Xiaoqun Zeng ,&nbsp;Zhen Wu ,&nbsp;Yuxing Guo ,&nbsp;Daodong Pan","doi":"10.1016/j.ultsonch.2025.107454","DOIUrl":"10.1016/j.ultsonch.2025.107454","url":null,"abstract":"","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"120 ","pages":"Article 107454"},"PeriodicalIF":9.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144658096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasound-assisted extraction and flavor quality assessment of in vitro biomimetically fermented Kopi Luwak. 体外仿生发酵香浓茶的超声辅助提取及风味品质评价。
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-09-01 Epub Date: 2025-08-06 DOI: 10.1016/j.ultsonch.2025.107499
Shengjie Duan, Ziqian Qiao, Yuanfeng Chen, Yan Shen, Zezhu Du, Jinya Dong, Lihui Yu, Yanmei Li, Ruijuan Yang, Chongye Fang
{"title":"Ultrasound-assisted extraction and flavor quality assessment of in vitro biomimetically fermented Kopi Luwak.","authors":"Shengjie Duan, Ziqian Qiao, Yuanfeng Chen, Yan Shen, Zezhu Du, Jinya Dong, Lihui Yu, Yanmei Li, Ruijuan Yang, Chongye Fang","doi":"10.1016/j.ultsonch.2025.107499","DOIUrl":"10.1016/j.ultsonch.2025.107499","url":null,"abstract":"<p><p>Kopi Luwak, renowned for its distinctive flavor profile, has long been esteemed in specialty coffee circles; however, the conventional animal digestive process is fraught with significant ethical and sustainability controversies. Building upon these findings, the present study established a tightly controlled in vitro biomimetic fermentation system, complemented by ultrasound-assisted extraction and multi-omics analyses, to faithfully reconstruct and elevate the hallmark flavour of civet coffee. Leveraging metagenomic data from the civet gut, thirty core functional strains were selected from 1870 isolates to create a synthetic symbiotic consortium. Fermentation parameters were optimised in three stages-single-factor experiments, Box-Behnken response-surface design, and a genetic-algorithm-artificial-neural-network (GA-ANN) model. Fermentation products were recovered by ultrasound-assisted extraction (40 kHz, 400 W, 10 min); volatile and non-volatile metabolites were quantified in both targeted and untargeted modes via GC-MS and UHPLC-MS/MS, and their temporal dynamics were deciphered through time-series clustering and metabolic-network analysis. The optimal conditions-16.5 % inoculum, initial pH 6.25, 33 ℃, 135 h-yielded an average SCA cupping score of 82.92, with a maximum of 85.25, significantly higher than those of natural fermentation and conventional civet coffee (P < 0.05). Total acidity increased to 0.78 g L<sup>-1</sup>, total polyphenol content reached 225.3 mg L<sup>-1</sup>, and key bioactive compounds remained stable. GC-MS quantification showed 1.9-2.3-fold increases in 2,3-dimethoxyphenol, phenylethanol, and 5-methylfurfural, alongside 63 % and 41 % reductions in 2-methylpyrazine and caffeine, respectively. Multi-omics evidence indicated that lipid β-oxidation, the amino-acid Ehrlich pathway, and esterification jointly enriched fruity, nutty, and floral notes; the elevated copy numbers of ndmA/B and pyoA/B genes underpinned the attenuation of bitter compounds. Relative to conventional solvent and Soxhlet extraction, ultrasound-assisted extraction improved volatile recovery by approximately 28 %, reduced energy consumption by ≥66 %, and halved solvent usage. Overall, this work achieves a high-fidelity in vitro replication of the civet gut microbiome and its metabolic functions, enables precision flavour modulation through intelligent optimisation and green extraction, and demonstrates industrial feasibility-the processing cost per kilogram of raw beans is 76.7 % lower than that of the traditional animal-derived method.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"120 ","pages":"107499"},"PeriodicalIF":9.7,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12357160/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144815499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid lipidic and fluorinated polymer microbubbles for blood-brain barrier opening: a comparative study with SonoVue 混合脂质和氟化聚合物微泡用于血脑屏障打开:与索诺维的比较研究
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-08-31 DOI: 10.1016/j.ultsonch.2025.107540
Ambre Dauba , Thi Hong Van Nguyen , Thomas Ador , Claire Spitzlei , Estelle Porret , Laurène Jourdain , Erwan Selingue , Laurence Moine , Jean-Luc Gennisson , Charles Truillet , Benoit Larrat , Sébastien Mériaux , Anthony Delalande , Nicolas Tsapis , Anthony Novell
{"title":"Hybrid lipidic and fluorinated polymer microbubbles for blood-brain barrier opening: a comparative study with SonoVue","authors":"Ambre Dauba ,&nbsp;Thi Hong Van Nguyen ,&nbsp;Thomas Ador ,&nbsp;Claire Spitzlei ,&nbsp;Estelle Porret ,&nbsp;Laurène Jourdain ,&nbsp;Erwan Selingue ,&nbsp;Laurence Moine ,&nbsp;Jean-Luc Gennisson ,&nbsp;Charles Truillet ,&nbsp;Benoit Larrat ,&nbsp;Sébastien Mériaux ,&nbsp;Anthony Delalande ,&nbsp;Nicolas Tsapis ,&nbsp;Anthony Novell","doi":"10.1016/j.ultsonch.2025.107540","DOIUrl":"10.1016/j.ultsonch.2025.107540","url":null,"abstract":"<div><div>Microbubble-mediated focused ultrasound is a promising strategy for transient and localized blood-brain barrier (BBB) permeabilization, enabling drug delivery to the brain. Optimizing microbubble stability and acoustic response is essential to maximize treatment efficiency and minimize potential damage. This study introduces an innovative microbubble formulation with a phospholipid-fluoropolymer shell (LIP-POL), designed to enhance circulation persistence while maintaining a low cavitation threshold. The physicochemical and acoustic properties of LIP-POL microbubbles were systematically compared with phospholipid-shell microbubbles (LIP) and the commercial agent SonoVue®. Both SonoVue and LIP-POL microbubbles have similar concentrations and sizes (approximately 5 × 10<sup>8</sup> bubbles/mL, mean size of 2.5-2.7 µm), whereas LIP microbubbles are around 100 times more concentrated (7.3 × 10<sup>10</sup> bubbles/mL) and slightly smaller (1.9 µm). <em>In vitro</em>, ultra-harmonics appeared at 120 kPa for LIP, 150 kPa for LIP-POL, and 200 kPa for SonoVue (<em>fc</em> = 1 MHz, PRF = 10 kHz, 40 cycles). Consistent with microbubbles’ acoustic signature, the BBB opening threshold (<em>fc</em> = 1.5 MHz) occurred at lower Mechanical Indices (MI) for LIP and LIP-POL microbubbles (MI = 0.16) compared to SonoVue (MI = 0.20). Stability of circulating microbubbles was assessed using BBB permeabilization protocol at various time points post microbubble-injection. LIP-POL microbubbles remained effective for up to 15 min post-injection, compared to 7.5 min for LIP and 5 min for SonoVue (2 × 10<sup>7</sup> microbubbles injected). The prolonged efficacy of LIP-POL microbubbles (three times longer than SonoVue) opens the possibility for extended ultrasound treatments, particularly for BBB permeabilization across larger areas in large animal models or humans.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"121 ","pages":"Article 107540"},"PeriodicalIF":9.7,"publicationDate":"2025-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144989071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasonic-assisted acidified aqueous two-phase extraction for one-step production and recovery of flavonoid aglycones from Malvaviscus arboreus Cav. flower: Process exploration, composition analysis and activity validation 超声辅助酸化双水相萃取一步法提取木耳黄酮苷元。花:工艺探索、成分分析和活性验证
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-08-30 DOI: 10.1016/j.ultsonch.2025.107545
Tiefeng Yuan , Chen Lin , Qingqing Yu , Xingyu Shi , Peiyi Jin , Jilong Huang , Liping Wang , Huajun Fan
{"title":"Ultrasonic-assisted acidified aqueous two-phase extraction for one-step production and recovery of flavonoid aglycones from Malvaviscus arboreus Cav. flower: Process exploration, composition analysis and activity validation","authors":"Tiefeng Yuan ,&nbsp;Chen Lin ,&nbsp;Qingqing Yu ,&nbsp;Xingyu Shi ,&nbsp;Peiyi Jin ,&nbsp;Jilong Huang ,&nbsp;Liping Wang ,&nbsp;Huajun Fan","doi":"10.1016/j.ultsonch.2025.107545","DOIUrl":"10.1016/j.ultsonch.2025.107545","url":null,"abstract":"<div><div>Using a polyethylene glycol (PEG)/ammonium sulfate system, a novel approach for one-step extraction and separation of the flavonoid aglycones from <em>Malvaviscus arboreus</em> Cav. flower (MACF) was developed by combining ultrasonic-assisted extraction (UAE) with acidified aqueous two-phase extraction (AATPE). Under the optimized UAE-AATPE conditions of PEG 600 of 22.8 % (w/w), ammonium sulfate of 22.5 % (w/w), 1.5 mol/L HCl, hydrolysis temperature of 85 ℃, and reaction time of 60 min, MACF flavonoid glycosides were not only fully extracted but also completely hydrolyzed, and the produced aglycones were purified by biphasic separation with a yield of 35.90 ± 0.96 mg/g. The mechanism in the UAE-AATPE process including UAE and ultrasonic-assisted acid hydrolysis (UAAH), was explored by investigating the different procedures and chemical composition under an ultrasonic field. The deglycosylated/glycosylated flavonoids were identified and quantified by high-resolution ultrahigh-performance liquid chromatography with quadrupole orbitrap mass spectrometry (UHPLC-Q/Orbitrap-MS) and UHPLC-DAD, revealing that MACF flavonoids were mainly composed of pelargonidin, kaempferol, catechin, cyanidin and quercetin in descending order of their content. The inhibitory assay on pancreatic lipase (PL) confirmed that the activity of the extracted aglycones with IC<sub>50</sub> of 563.01 ± 280.63 μg/mL was stronger than their glycosides. Kinetic and molecular docking analyses further explored and validated the PL inhibitory mechanism. The above results proved that UAE-AATPE integrating the multiple procedures, including extraction, hydrolysis and separation, greatly simplified the complex procedures and significantly improved extraction efficiency, providing a simple, rapid and efficient alternative for direct obtainment of the flavonoid aglycones from MACF.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"121 ","pages":"Article 107545"},"PeriodicalIF":9.7,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145045615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metabolomic insights into ultrasound-assisted fermentation of grape juice 超声辅助葡萄汁发酵的代谢组学研究
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-08-30 DOI: 10.1016/j.ultsonch.2025.107537
Liyue Fei , Dongsheng Zhang , Yu Li , Johane Johari Mkunga , Zinan Zhang , Chenglong He , Chunhui Shan , Muhammad Iqbal Choudhary , Xinquan Yang , Wenchao Cai
{"title":"Metabolomic insights into ultrasound-assisted fermentation of grape juice","authors":"Liyue Fei ,&nbsp;Dongsheng Zhang ,&nbsp;Yu Li ,&nbsp;Johane Johari Mkunga ,&nbsp;Zinan Zhang ,&nbsp;Chenglong He ,&nbsp;Chunhui Shan ,&nbsp;Muhammad Iqbal Choudhary ,&nbsp;Xinquan Yang ,&nbsp;Wenchao Cai","doi":"10.1016/j.ultsonch.2025.107537","DOIUrl":"10.1016/j.ultsonch.2025.107537","url":null,"abstract":"<div><div>Numerous studies have demonstrated that both lactic acid bacteria (LAB) fermentation and ultrasound-assisted fermentation can enhance the antioxidant activity of fruit juices; however, the effects of these two treatments on metabolites and antioxidant activity in grape juice (GJ) have yet to be investigated. Therefore, this study aimed to analyze the specific effects of LAB fermented grape juice (FGJ) and ultrasound-assisted fermented grape juice (UFGJ) on the antioxidant activity and metabolite production, while also conducting a preliminary investigation into the potential mechanisms underlying the antioxidant action of UFGJ using network pharmacology and molecular docking. The results indicated that UFGJ significantly enhanced the total phenolic content, total flavonoid content, and antioxidant activity of both FGJ and GJ (P &lt; 0.001). Metabolomics analysis revealed highly significant differences in metabolite composition among the three groups (P &lt; 0.001). The major differential metabolite classes and metabolic pathways of the FGJ versus GJ and UFGJ versus GJ groups were the same, with the latter group showing higher levels of shared metabolites. Thus, UFGJ does not alter the metabolic pathway of FGJ, but instead enhances its metabolic efficiency and increases metabolite enrichment. Correlation and network pharmacology analyses revealed that key antioxidant metabolites such as 2-hydroxycinnamic acid, gallic acid, and myricetin 3-rhamnoside primarily target core genes such as PPARG, EGFR, PTGS2, and PPARA, further regulating signaling pathways associated with chemical carcinogenesis-receptor activation, adherens junctions, and PPAR signaling pathway to exert antioxidant effects. Furthermore, molecular docking assays demonstrated that ursolic acid displaying the most stable binding to EGFR.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"121 ","pages":"Article 107537"},"PeriodicalIF":9.7,"publicationDate":"2025-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144921185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of disinfection and cavitation performance of a cylindrical rotational hydrodynamic cavitation reactor: Influence of key geometric parameters of the cavitation generation unit 圆柱形旋转流体动力空化反应器消毒与空化性能评价:空化产生装置关键几何参数的影响
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-08-29 DOI: 10.1016/j.ultsonch.2025.107544
Licheng Xue , Zongrui Hao , Sivakumar Manickam , Gang Liu , Haizeng Wang , Xun Sun , Haiyan Bie
{"title":"Evaluation of disinfection and cavitation performance of a cylindrical rotational hydrodynamic cavitation reactor: Influence of key geometric parameters of the cavitation generation unit","authors":"Licheng Xue ,&nbsp;Zongrui Hao ,&nbsp;Sivakumar Manickam ,&nbsp;Gang Liu ,&nbsp;Haizeng Wang ,&nbsp;Xun Sun ,&nbsp;Haiyan Bie","doi":"10.1016/j.ultsonch.2025.107544","DOIUrl":"10.1016/j.ultsonch.2025.107544","url":null,"abstract":"<div><div>Hydrodynamic cavitation offers a promising technological platform for diverse industrial applications, including water treatment and chemical process intensification, and holds significant potential for widespread adoption in future advanced processing systems. This study investigates the disinfection efficacy of a novel Cylindrical Rotational Hydrodynamic Cavitation Reactor (CRHCR) and elucidates the underlying mechanism of Escherichia coli (<em>E. coli</em>) inactivation induced by hydrodynamic cavitation. Microscopic analysis of <em>E. coli</em> post-treatment revealed that the intense mechanical shear forces produced by collapsing bubbles are primarily responsible for bacterial inactivation. In addition, the influence of key geometric parameters of the cavitation generation unit on the hydrodynamic performance of the CRHCR was systematically examined. The results demonstrate that rectangular grooves exhibit superior cavitation performance compared to trapezoidal and triangular configurations. An increase in groove width and number correlates positively with enhanced cavitation intensity. In contrast, changes in groove depth, oblique tooth angle, and groove angle exhibit a non-linear trend, with cavitation performance initially increasing with as these parameters rise, followed by a decline once optimal thresholds are exceeded. Optimal cavitation performance was attained with a groove depth of 2 mm, an oblique tooth angle of 68°, and a groove angle of 5°. The observed variation in cavitation efficiency across different CRHCR configurations is attributed to the distinct geometries of the cavitation generation units, which modulate the distribution of low-pressure zones. These findings provide valuable insights into the structural design, theoretical understanding, and practical application of advanced hydrodynamic cavitation systems.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"121 ","pages":"Article 107544"},"PeriodicalIF":9.7,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144921184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ study on grain refinement mechanism of Al-13Cu alloys modified by high entropy alloy particles and ultrasonic treatment 高熵合金颗粒和超声改性Al-13Cu合金晶粒细化机理的原位研究
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-08-29 DOI: 10.1016/j.ultsonch.2025.107532
Yuanzheng Cao , Xiaojuan Shang , Guangkai Yang , Jie Wang , Yiwang Jia , Qibin Liu , Yun Che , Sanquan Men , Xiang Li , Yuliang Zhao , Da Shu
{"title":"In-situ study on grain refinement mechanism of Al-13Cu alloys modified by high entropy alloy particles and ultrasonic treatment","authors":"Yuanzheng Cao ,&nbsp;Xiaojuan Shang ,&nbsp;Guangkai Yang ,&nbsp;Jie Wang ,&nbsp;Yiwang Jia ,&nbsp;Qibin Liu ,&nbsp;Yun Che ,&nbsp;Sanquan Men ,&nbsp;Xiang Li ,&nbsp;Yuliang Zhao ,&nbsp;Da Shu","doi":"10.1016/j.ultsonch.2025.107532","DOIUrl":"10.1016/j.ultsonch.2025.107532","url":null,"abstract":"<div><div>This study explores the grain refinement mechanisms of primary α-Al during solidification of Al-13 wt% Cu alloy modified by FeCoCrNiAl high-entropy alloy (HEA) particles via ultrasonic treatment. In situ X-ray radiography combined with machine learning-based computer vision techniques was employed to systematically analyze the nucleation and growth behaviors of α-Al grains. Results indicate a significant grain refinement effect associated with increased HEA particle content and higher cooling rates. Specifically, the addition of 2.0 wt% HEA particles reduce the primary α-Al grain size notably, achieving approximately 213 μm at a cooling rate of 1.0 K/s. At a cooling rate of 0.2 K/s, raising the HEA content from 0.5 to 2.0 wt% markedly increases the maximum nucleation rate (from 8.6 to 30.3 crystals/mm<sup>3</sup>/s), shortens the time required for grain growth cessation (from 18 s to 10 s). Similarly, at a fixed HEA content (1.0 wt%), increasing the cooling rate from 0.2 K/s to 1.0 K/s enhances the maximum nucleation rate (from 25.7 to 93.9 crystals/mm<sup>3</sup>/s) and reduces the grain growth cessation time (from 15 s to 9 s). Grain size distributions consistently exhibit normal distribution patterns. The addition of HEA particles significantly inhibits grain growth and reduces solute enrichment during solidification. These findings demonstrate that FeCoCrNiAl HEA particles facilitate grain refinement by effectively promoting heterogeneous nucleation and inhibiting grain growth.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"121 ","pages":"Article 107532"},"PeriodicalIF":9.7,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144926002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasonic engineering of bovine serum albumin nanoparticles for high internal phase Pickering emulsions: Interfacial behavior, microstructural evolution and stabilization enhancement 用于高内相皮克林乳剂的牛血清白蛋白纳米粒子的超声工程:界面行为、微观结构演变和稳定性增强
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-08-28 DOI: 10.1016/j.ultsonch.2025.107543
Liyuan Ma , Jie Li , Yixiang Liu , Jie Zheng
{"title":"Ultrasonic engineering of bovine serum albumin nanoparticles for high internal phase Pickering emulsions: Interfacial behavior, microstructural evolution and stabilization enhancement","authors":"Liyuan Ma ,&nbsp;Jie Li ,&nbsp;Yixiang Liu ,&nbsp;Jie Zheng","doi":"10.1016/j.ultsonch.2025.107543","DOIUrl":"10.1016/j.ultsonch.2025.107543","url":null,"abstract":"<div><div>This study investigated the influence of ultrasonic treatment on the physicochemical properties of bovine serum albumin (BSA) and its applicability in stabilizing high internal phase Pickering emulsions (HIPPEs). Under optimized sonication conditions (250 W, 12 min), stable ultrasonically modified BSA (UBSA) particles were generated, exhibiting a small particle size (41.39 nm), a polydispersity index &lt; 0.17, a higher absolute zeta potential (&gt; 20 mV), and favorable wettability (three-phase contact angle: 78.71°), accompanied by reduced surface hydrophobicity. Intrinsic fluorescence spectra and circular dichroism (CD) analysis confirmed that ultrasonication altered the secondary structure of BSA, leading to the exposure of hydrophobic groups. Dynamic interfacial tension and adsorption kinetics analyses revealed that UBSA particles exhibited lower interfacial tension and significantly higher diffusion coefficient (<em>K<sub>diff</sub></em>) and penetration coefficient (<em>K<sub>p</sub></em>) than native BSA, indicating enhanced diffusion and adsorption capabilities of UBSA at the oil–water interface. Rheological analyses demonstrated that UBSA-stabilized HIPPEs possessed higher viscosity and larger storage (<em>G′</em>) and loss (<em>G″</em>) moduli. Optical and confocal laser scanning microscopy confirmed the successful formation of HIPPEs at UBSA concentrations ≥ 1.0 % (w/v). UBSA-stabilized HIPPEs displayed a reduced droplet size (10.59 µm) and a more densely packed droplet structure, which conferred enhanced resistance against droplet coalescence compared to emulsions stabilized by native BSA. Moreover, stability assessments indicated that the centrifugal, freeze–thaw and storage stability of the prepared HIPPEs were significantly improved. Importantly, UBSA-based HIPPEs serving as a delivery vehicle also effectively enhanced the thermal processing stability of β-carotene. The findings demonstrate the potential of ultrasound-modified BSA nanoparticles as effective stabilizers for HIPPEs, providing valuable insights for the development of healthy and safe food-grade emulsion systems.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"121 ","pages":"Article 107543"},"PeriodicalIF":9.7,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144917347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-friendly sonochemical synthesis of BaTiO3/Ag nanocomposite particles: Investigation of Ag-nanoparticle formation and growth behavior under ultrasound irradiation 环保声化学合成BaTiO3/Ag纳米复合颗粒:超声辐照下Ag纳米颗粒形成和生长行为的研究
IF 9.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2025-08-28 DOI: 10.1016/j.ultsonch.2025.107539
Tatsuya Shishido , Yamato Hayashi , Hirotsugu Takizawa , Minoru Ueshima
{"title":"Eco-friendly sonochemical synthesis of BaTiO3/Ag nanocomposite particles: Investigation of Ag-nanoparticle formation and growth behavior under ultrasound irradiation","authors":"Tatsuya Shishido ,&nbsp;Yamato Hayashi ,&nbsp;Hirotsugu Takizawa ,&nbsp;Minoru Ueshima","doi":"10.1016/j.ultsonch.2025.107539","DOIUrl":"10.1016/j.ultsonch.2025.107539","url":null,"abstract":"<div><div>This study synthesizes BaTiO<sub>3</sub>/Ag nanocomposite particles using an eco-friendly sonochemical method and investigates the mechanism of Ag-nanoparticle deposition. BaTiO<sub>3</sub> and Ag<sub>2</sub>O were ultrasonically irradiated in methanol at 20 ˚C, and samples and solvents were characterized using X-ray diffraction, scanning electron microscopy, scanning transmission electron microscopy with energy-dispersive X-ray spectroscopy, ultraviolet–visible spectroscopy, Brunauer-Emmett-Teller method, X-ray photoelectron spectroscopy and gas chromatography-mass spectrometry. Nanocomposite particles uniformly decorated with fine Ag nanoparticles were obtained via ultrasonication (&gt;45 kHz) for 3 h. The average size of the Ag nanoparticles increased with increasing irradiation time, which was presumed to be due to the thermal and physical effects of the ultrasound. Even at 10 vol% Ag loading, nanocomposites exhibited uniform particle distribution. Ultrasound irradiation produced nanocomposite particles with finer Ag nanoparticles and accelerated the reduction of Ag<sub>2</sub>O compared with mechanical stirring. In this deposition reaction, Ag<sub>2</sub>O was presumed to be reduced by methanol and its radical derivatives, and BaTiO<sub>3</sub> exhibited catalytic activity for Ag<sub>2</sub>O reduction. This study not only contributes to the understanding of the mechanism of Ag-nanoparticle deposition in alcohol-Ag<sub>2</sub>O systems but also offers a promising room-temperature and waste-reducing synthesis route for nanocomposite particles toward a sustainable society.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"121 ","pages":"Article 107539"},"PeriodicalIF":9.7,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144926000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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