Ultrasonics Sonochemistry最新文献

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Bubble shape instability of acoustic cavitation in molten metal used in ultrasonic casting 超声波铸造所用熔融金属中声波空化的气泡形状不稳定性
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-13 DOI: 10.1016/j.ultsonch.2024.107064
{"title":"Bubble shape instability of acoustic cavitation in molten metal used in ultrasonic casting","authors":"","doi":"10.1016/j.ultsonch.2024.107064","DOIUrl":"10.1016/j.ultsonch.2024.107064","url":null,"abstract":"<div><p>In this study, we estimated the equilibrium bubble size of acoustic cavitation in a molten metal, which is basic information in ultrasonic casting. For this, the bubble shape instability of acoustic cavitation in the melt was numerically investigated by solving the Keller–Miksis equation and dynamic equation of the distortion amplitude. The acoustic cavitation bubbles are more stable in aluminum and magnesium melts than in water, and the <em>parametric instability</em> mainly determines the bubble stability at 20–160 kHz in molten metals. However, the <em>afterbounce instability</em> does not significantly affect the bubble stability in molten metals owing to the small number of bubble oscillations after the first rapid compression, and the distortion amplitude cannot grow significantly after the first compression. The bubbles in the melt become more unstable with an increase in the ultrasonic frequency owing to the corresponding increase in the bubble wall velocity. Through this stability analysis, we can estimate that the stable bubble size in the aluminum or magnesium melt is approximately three or four times larger than that in water at the same ultrasonic pressure amplitude.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003122/pdfft?md5=62e4e88425966b2b76259c65bfffe671&pid=1-s2.0-S1350417724003122-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dissolution of EAF slag minerals in aqueous media: Effects of sonication on brownmillerite and gehlenite 电解铝炉渣矿物在水介质中的溶解:超声对褐铁矿和辉绿岩的影响
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-11 DOI: 10.1016/j.ultsonch.2024.107065
{"title":"Dissolution of EAF slag minerals in aqueous media: Effects of sonication on brownmillerite and gehlenite","authors":"","doi":"10.1016/j.ultsonch.2024.107065","DOIUrl":"10.1016/j.ultsonch.2024.107065","url":null,"abstract":"<div><p>The accumulation of electric arc furnace slag (EAFS) in landfills has been causing severe environmental problems. This study examines the dissolution properties of EAFS minerals, including brownmillerite and gehlenite, essential for their possible use in resource recovery. An investigation was conducted to compare the effects of sonication and stirring on mineral dissolution while also assessing the usage of citrate as a complexing agent for gehlenite. Synthetic brownmillerite and gehlenite minerals were dissolved in aqueous solutions at room temperature using a 1:100 g/ml ratio. The dissolved elements were measured using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES), while zeta potential and X-ray Photoelectron Spectroscopy (XPS) were used to assess changes in surface chemistry. Brownmillerite had significant dissolution extents, with Al and Ca dissolving up to 16 % and 8 %, respectively, in contrast to gehlenite, which dissolved less than 2 % under similar conditions. Sonication significantly increased the dissolution of brownmillerite by up to 100 %, although its impact on gehlenite dissolution varied depending on the duration of time. Besides, adding citrate enhanced the leaching of Al and Ca from gehlenite by facilitating complexation. XPS data demonstrated differences in elemental ratios on brownmillerite and gehlenite surfaces affected by the method used and the presence of citrate. Lastly, the dissolution extents of Al and Ca from EAFS were up to 12 %, depending on time and mixing method, with a preference for sonication over stirring. In conclusion, this study showed that minerals in EAFS have distinct dissolution characteristics, and sonication and citrate can considerably enhance dissolution.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003134/pdfft?md5=64eb000729a885a9907c6407e8f7bb6a&pid=1-s2.0-S1350417724003134-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142173351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Insight into the effects of ultrasound-assisted intermittent tumbling on the gelation properties of myofibrillar proteins: Conformational modifications, intermolecular interactions, rheological properties and microstructure 深入了解超声波辅助间歇翻滚对肌纤维蛋白凝胶特性的影响:构象修饰、分子间相互作用、流变特性和微观结构
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-05 DOI: 10.1016/j.ultsonch.2024.107059
{"title":"Insight into the effects of ultrasound-assisted intermittent tumbling on the gelation properties of myofibrillar proteins: Conformational modifications, intermolecular interactions, rheological properties and microstructure","authors":"","doi":"10.1016/j.ultsonch.2024.107059","DOIUrl":"10.1016/j.ultsonch.2024.107059","url":null,"abstract":"<div><p>The aim of the present study was to evaluate the effects of ultrasound-assisted intermittent tumbling (UT) at 300 W, 20 kHz and 40 min on the conformation, intermolecular interactions and aggregation of myofibrillar proteins (MPs) and its induced gelation properties at various tumbling times (4 and 6 h). Raman results showed that all tumbling treatments led the helical structure of MPs to unfold. In comparison to the single intermittent tumbling treatment (ST), UT treatment exerted more pronounced effects on strengthening the intermolecular hydrogen bonds and facilitating the formation of an ordered β-sheet structure. When the tumbling time was the same, UT treatment caused higher surface hydrophobicity, fluorescence intensity and disulfide bond content in the MPs, inducing the occurrence of hydrophobic interaction and disulfide cross-linking between MPs molecules, thus forming the MPs aggregates. Additionally, results from the solubility, particle size, atomic force microscopy and SDS-PAGE further indicated that, relative to the ST treatment, UT treatment was more potent in promoting the polymerization of myosin heavy chain. The MPs aggregates in the UT group were more uniform than those in the ST group. During the gelation process, the pre-formed MPs aggregates in the UT treatment increased the thermal stability of myosin, rendering it more resistant to heat-induced unfolding of the myosin rod region. Furthermore, they improved the protein tail–tail interaction, resulting in the formation of a well-structured gel network with higher gel strength and cooking yield compared to the ST treatment.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003079/pdfft?md5=6aa781ff3a0f1232f2c4d90bd356ef85&pid=1-s2.0-S1350417724003079-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142157765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The improvement mechanism of volatile for cooked Tibetan pork assisted with ultrasound at low-temperature: Based on the differences in oxidation of lipid and protein 低温超声波辅助熟制藏香猪肉挥发性的改善机理:基于脂质和蛋白质氧化的差异
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-05 DOI: 10.1016/j.ultsonch.2024.107060
{"title":"The improvement mechanism of volatile for cooked Tibetan pork assisted with ultrasound at low-temperature: Based on the differences in oxidation of lipid and protein","authors":"","doi":"10.1016/j.ultsonch.2024.107060","DOIUrl":"10.1016/j.ultsonch.2024.107060","url":null,"abstract":"<div><p>Low-temperature cooking causes flavor weakness while improving the texture and digestive properties of meat. To enhance the flavor of low-temperature cooked Tibetan pork, samples were cooked at low-temperature with or without ultrasound-assisted (UBTP, BTP) for different times (30 min, 90 min) and then analyzed using GC–MS and LC-MS. The results showed that ultrasound-assisted cooking caused a significant increase in lipid oxidation by 9.10% in the early stage of the treatment. Additionally, at the later stage of ultrasound-assisted processing, proteins were oxidized and degraded, which resulted in a remarkable rise in the protein carbonyl content by 6.84%. With prolonged effects of ultrasound and low-temperature cooking, the formation of phenylacetaldehyde in UBTP-90 sample originated from the degradation of phenylalanine through multivariate statistics and correlation analysis. Meanwhile, trans, cis-2,6-nonadienal and 1-octen-3-one originated from the degradation of linolenic acid and arachidonic acid. This study clarified the mechanism of ultrasound-assisted treatment improving the flavor of low-temperature-cooked Tibetan pork based on the perspective of lipids and proteins oxidation, providing theoretical supports for flavor enhancement in Tibetan pork-related products.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003080/pdfft?md5=931e4e7486324c861c70dd84b983bf7b&pid=1-s2.0-S1350417724003080-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142161725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatial regulation of hydrogel polymerization reaction using ultrasound-driven streaming vortex 利用超声波驱动流涡对水凝胶聚合反应进行空间调控
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-04 DOI: 10.1016/j.ultsonch.2024.107053
{"title":"Spatial regulation of hydrogel polymerization reaction using ultrasound-driven streaming vortex","authors":"","doi":"10.1016/j.ultsonch.2024.107053","DOIUrl":"10.1016/j.ultsonch.2024.107053","url":null,"abstract":"<div><p>Ultrasound is gaining attention as an alternative tool to regulate chemical processes due to its advantages such as high cost-effectiveness, rapid response, and contact-free operation. Previous studies have demonstrated that acoustic bubble cavitation can generate energy to synthesize functional materials. In this study, we introduce a method to control the spatial distribution of physical and chemical properties of hydrogels by using an ultrasound-mediated particle manipulation technique. We developed a surface acoustic wave device that can localize micro-hydrogel particles, which are formed during gelation, in a hydrogel solution. The hydrogel fabricated with the application of surface acoustic waves exhibited gradients in mechanical, mass transport, and structural properties. We demonstrated that the gel having the property gradients could be utilized as a cell-culture substrate dictating cellular shapes, which is beneficial for interfacial tissue engineering. The acoustic method and fabricated hydrogels with property gradients can be applied to design flexible polymeric materials for soft robotics, biomedical sensors, or bioelectronics applications.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003018/pdfft?md5=5d73f2442c226271c0be3b3fa3f99e75&pid=1-s2.0-S1350417724003018-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142169481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modifying physicochemical properties, rheology, and creaming stability of milk fat globule and membrane through ultrasound treatment 通过超声波处理改变乳脂球和乳脂膜的理化性质、流变性和起泡稳定性
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-04 DOI: 10.1016/j.ultsonch.2024.107058
{"title":"Modifying physicochemical properties, rheology, and creaming stability of milk fat globule and membrane through ultrasound treatment","authors":"","doi":"10.1016/j.ultsonch.2024.107058","DOIUrl":"10.1016/j.ultsonch.2024.107058","url":null,"abstract":"<div><p>The healthy benefits of milk fat globules and membrane (MFGs/MFGM) ingredients are increasingly recognized in the dairy industry. In this research, we examined the effects of ultrasonic treatment on the physicochemical and rheological properties, as well as the emulsions stability of MFGs/MFGM derived from bovine raw milk. Fresh milk was subjected to sonication at frequencies of 20 kHz and 40 kHz, either individually or simultaneously, for durations of 5 min or 15 min, using work/rest cycles of 5 s on and 3 s off. Bovine milk, without any treatment, served as the control. Regardless of the intensity difference, ultrasonic treatment for 5 min resulted in more pronounced changes in the regions of Amide Ⅱ (1600–1500 cm<sup>−1</sup>), Amide Ⅲ (1500–1200 cm<sup>−1</sup>), and fingerprint region (1200–1900 cm<sup>−1</sup>) compared to both the 15 min treatments and control MFGs/MFGM. Principal component analysis (PCA) conducted on the entire spectra, as well as in the regions of Amide Ⅰ, Amide Ⅱ, and the fingerprint spectra, clustered the 5 min treatment distinctly from the control and MFGs/MFGM ultrasonically treated for 15 min. MFGs/MFGM samples following 20 kHz and 40 kHz synchronous treatment for 15 min exhibited lower absorbance bands at 1727–1726 cm<sup>−1</sup>, whereas a higher content at 1740 cm<sup>−1</sup> was observed compared to control MFGs/MFGM. Additionally, a more significant reduction in the intramolecular β-sheet content in 20 + 40 kHz/ 15 min treatment was observed. According to the sodium dodecyl sulphate polyacrylamide gel electrophoresis (SDS-PAGE) patterns, a diminished intensity of Periodic Acid Schiff 6/7 (PAS 6/7) bands was observed across all the MFGs/MFGM. Ultrasonic treatment retained more caseins while reducing the β –LG levels compared to the controls, enhancing the stability of MFGs/MFGM, except in MFGs/ MFGM subjected to 20 and 40 kHz simultaneously treated for 15 min. The irregular sphericity of fat globules was noted particularly in MFGs/MFGM treated at 20 kHz independently or in combination with 40 kHz for 15 min. According to the confocal laser scanning microscopy (CLSM), ultrasonic treatment facilitated the binding of caseins or whey proteins to the MFGs surface and induced flocculation of membrane proteins. Hierarchical cluster analysis (HCA) heat map further underscored the impact of ultrasonic treatments on the structural and compositional changes, as well as rheology and emulsions stability, of MFGs/MFGM.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003067/pdfft?md5=526cb44d388d49885c7d5d5d93ca4038&pid=1-s2.0-S1350417724003067-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142232652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasound-assisted extraction of withanolides from Tubocapsicum anomalum: Process optimization, isolation and identification, and antiproliferative activity 用超声波辅助从 Tubocapsicum anomalum 中萃取山奈酚内酯:工艺优化、分离和鉴定以及抗增殖活性。
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-02 DOI: 10.1016/j.ultsonch.2024.107052
{"title":"Ultrasound-assisted extraction of withanolides from Tubocapsicum anomalum: Process optimization, isolation and identification, and antiproliferative activity","authors":"","doi":"10.1016/j.ultsonch.2024.107052","DOIUrl":"10.1016/j.ultsonch.2024.107052","url":null,"abstract":"<div><p><em>Tubocapsicum anomalum</em>, a Chinese medicinal plant rich in anti-tumor withanolides, requires efficient extraction methods. In this paper, an HPLC method was first established for the detection of withanolides, and gradient elution was carried out using a methanol–water solvent system. It was found that the content of withanolides was the highest in the leaves of <em>T. anomalum</em>, followed by the stems and fruits, and almost none in the roots. During the actual picking process, the quantity of leaves collected was relatively small, while the number of stems was the highest. Therefore, the Box-Behnken response surface method was used to optimize the ultrasonic-assisted extraction process of withanolides from the stems of <em>T. anomalum</em>. The optimal extraction conditions were determined as follows: the liquid–solid ratio was 20:1, the extraction solvent was 70 % ethanol, the ultrasonic power was 250 W, the ultrasonic time was 40 min, and the ultrasonic temperature was 50 °C. Under these conditions, the average yields of tubocapsenolide A (Te-A) and tubocapsanolide A (Ta-A) can reach 2.87 ± 0.12 mg/g and 1.18 ± 0.05 mg/g, respectively. We further compared extraction rates of two withanolides from different parts of <em>T. anomalum</em> using ultrasonic and traditional extraction methods. Ultrasonic extraction significantly increased rates, with the highest yields from leaves, followed by stems and fruits. The results show that ultrasonic optimization can improve extraction rate, reduce time, lower costs, enhance quality, and increase yield. Therefore, the optimized ultrasonic-assisted extraction process was adopted to extract the aerial parts of <em>T. anomalum</em> and separate the components. After optimization, the extract underwent several chromatographic separations to isolate eight previously undescribed withanolides (<strong>1</strong>–<strong>8</strong>) and two artificial withanolides (<strong>9</strong>–<strong>10</strong>), in addition to fifteen known compounds (<strong>11</strong>–<strong>25</strong>). Their structures were established through extensive spectroscopic data analysis. The compounds were evaluated for their antiproliferative effects against multiple cancer cell lines, including human hepatocellular carcinoma cells (HepG2, Hep3B, and MHCC97-H), human lung cancer cells (A549), human fibro-sarcoma cancer cells (HT1080), human chronic myeloid leukemia cells (K562), and human breast cancer cells (MDA-MB-231 and MCF7). Compounds <strong>1</strong>–<strong>3</strong>, <strong>5, 7</strong>, <strong>11</strong>, <strong>13</strong>, <strong>15</strong>–<strong>16</strong>, and <strong>22</strong> displayed significant activity with IC<sub>50</sub> values of 5.14–19.87 μM. The above results indicate that ultrasonic-assisted extraction technology can be used to obtain new withanolides more efficiently from <em>T. anomalum</em>, thereby enhancing the utilization rate of <em>T. anomalum</em> resources.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003006/pdfft?md5=8605662063b725c7fb70c1cd1b1a9a10&pid=1-s2.0-S1350417724003006-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142144856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasonically assisted fabrication of electrochemical platform for tinidazole detection 超声辅助制造用于检测替硝唑的电化学平台
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-09-01 DOI: 10.1016/j.ultsonch.2024.107056
{"title":"Ultrasonically assisted fabrication of electrochemical platform for tinidazole detection","authors":"","doi":"10.1016/j.ultsonch.2024.107056","DOIUrl":"10.1016/j.ultsonch.2024.107056","url":null,"abstract":"<div><p>Based on sonochemistry, green synthesis methods play an important role in the development of nanomaterials. In this work, a novel chitosan modified MnMoO<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> (MnMoO<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>/CHIT) was developed using ultrasonic cell disruptor (500 W, 30 kHz) for ultra-sensitive electrochemical detection of tinidazole (TNZ) in the environment. The morphology and surface properties of the synthesized MnMoO<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>/CHIT electrode were characterized using X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM) and transmission electron microscope (TEM). Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) techniques were utilized to assess the electrochemical performance of TNZ. The results indicate that the electrochemical detection performance of TNZ is highly efficient, with a detection limit (LOD) of 3.78 nM, sensitivity of 1.320 µA·µM<sup>−1</sup>·cm<sup>−2</sup>, and a detection range of 0.1–200 μM. Additionally, the prepared electrode exhibits excellent selectivity, desirable anti-interference capability, and decent stability. MnMoO<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>/CHIT can be successfully employed to detect TNZ in both the Songhua River and tap water, achieving good recovery rates within the range of 93.0 % to 106.6 %. Consequently, MnMoO<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>/CHIT’s simple synthesis might provide a new electrode for the sensitive, repeatable, and selective measurement of TNZ in real-time applications. Using the MnMoO<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub>/CHIT electrode can effectively monitor and detect the concentration of TNZ in environmental water, guiding the sewage treatment process and reducing the pollution level of antibiotics in the water environment.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003043/pdfft?md5=8138db2024a1852f0053674d0245f7ce&pid=1-s2.0-S1350417724003043-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142128635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of organic solvent additives on the enhancement of ultrasonic cavitation effects in water for lithium-ion battery electrode delamination 有机溶剂添加剂对增强锂离子电池电极脱层的水中超声空化效应的影响
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-08-31 DOI: 10.1016/j.ultsonch.2024.107049
{"title":"Effect of organic solvent additives on the enhancement of ultrasonic cavitation effects in water for lithium-ion battery electrode delamination","authors":"","doi":"10.1016/j.ultsonch.2024.107049","DOIUrl":"10.1016/j.ultsonch.2024.107049","url":null,"abstract":"<div><p>Ultrasonic delamination is a low energy approach for direct recycling of spent lithium-ion batteries. The efficiency of the ultrasonic delamination relies both on the thermophysical properties (such as viscosity, surface tension, and vapour pressure) of the solvent in which the delamination process is carried out, and the properties of the ultrasound source as well as the geometry of the containment vessel. However, the effect of tailoring solutions to optimise cavitation and delamination of battery cathode coatings has not yet been sufficiently investigated. Acoustic detection, high-speed imaging, and sonochemiluminescence (SCL) are employed to study the cavitation processes in water-glycol systems and identify the effect of tailoring solvent composition on cavitation strength. The addition of small volume fractions of organic solvent (ca. 10–30 vol%), including ethylene glycol or glycerol, to the aqueous delamination solution were found to significantly improve the delamination efficiency of lithium-ion battery cathode coatings due to the alteration of these thermophysical properties. However, greater volume fractions of glycol decrease delamination efficiency due to the signal-dampening effect of viscosity on the ultrasonic waves. The findings of this study offer valuable insights for optimising ultrasonic bath solution composition to enhance film delamination processes.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002979/pdfft?md5=ad2f058d7eb3cf51a06bbafd097437b1&pid=1-s2.0-S1350417724002979-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142122893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of ultrasound-attenuation on technological and functional properties of two strains of Lactiplantibacillus plantarum isolated from table olives 超声衰减对从食用橄榄中分离出的两株植物乳杆菌的技术和功能特性的影响
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-08-31 DOI: 10.1016/j.ultsonch.2024.107057
{"title":"Effect of ultrasound-attenuation on technological and functional properties of two strains of Lactiplantibacillus plantarum isolated from table olives","authors":"","doi":"10.1016/j.ultsonch.2024.107057","DOIUrl":"10.1016/j.ultsonch.2024.107057","url":null,"abstract":"<div><p>While probiotics have a wide range of beneficial properties, they can also negatively affect the taste or aroma of foods products by resulting in the phenomenon of post-acidification. Ultrasound (US) is a tool to modulate the metabolism of probiotic bacteria, counteracting post-acidification and improving the performance and functional properties of microorganisms without affecting their viability. The purpose of this paper was to evaluate the effect of 10 different combinations of power (20 and 40 %) and duration (2, 4, 6, 8 and 10 min) of US treatment on two functional strains of <em>Lactiplantibacillus plantarum</em> (c16 and c19) isolated from table olives, with the aim of understanding how, some of the main functional and technological traits (viability, acidification, growth profile under different conditions, antibiotic resistance, viability at pH 2.0 and 0.3 % bile salts), were affected. It was found that the effects were strain dependent, and the best results were obtained for strain c19 in the combinations at 20 % for 8 and 10 min and 40 % for 2 min, where an improvement in functional characteristics was found, with some effects on biofilm stability, inhibition of acidification, without adverse results on some technological properties.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724003055/pdfft?md5=9d526d3f8c322e4230899145f49996ca&pid=1-s2.0-S1350417724003055-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142136975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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