Ultrasonics Sonochemistry最新文献

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Ultrasound-tailored structural remodeling of oleosome-derived proteins enables interfacial engineering and stability of probiotic-loaded high internal phase emulsions. 超声定制的油质体衍生蛋白的结构重塑使益生菌负载高内相乳剂的界面工程和稳定性成为可能。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-18 DOI: 10.1016/j.ultsonch.2026.108123
Rongrong Yu, Yuan Huang, Ziyun Tao, Maria Rahman, Shahzad Farooq, Xiu Wang, Juanyan Pan
{"title":"Ultrasound-tailored structural remodeling of oleosome-derived proteins enables interfacial engineering and stability of probiotic-loaded high internal phase emulsions.","authors":"Rongrong Yu, Yuan Huang, Ziyun Tao, Maria Rahman, Shahzad Farooq, Xiu Wang, Juanyan Pan","doi":"10.1016/j.ultsonch.2026.108123","DOIUrl":"https://doi.org/10.1016/j.ultsonch.2026.108123","url":null,"abstract":"<p><p>Oleosomes are intracellular lipid-storage organelles found in oilseeds and represent a promising yet underexplored source of proteinaceous emulsifiers for structuring food-grade colloidal systems. In this study, extrinsic proteins (OP) from soybean oleosomes were extracted under controlled alkaline-ultrasonic treatment (0-400 W) to elucidate how ultrasound-mediated protein remodeling governs interfacial adsorption kinetics, high-internal-phase emulsion (HIPE) formation, rheological behavior, and probiotic protection. Alkaline-ultrasonic treatment from 0 to 300 W significantly increased the protein recovery from 40.15% to 58.84%, solubility from 74.10% to 87.61%, and zeta potential from -8.81 to -13.31 mV, while reduced the particle size from 651 to 389 nm. Spectroscopic analyses revealed controlled protein remodeling characterized by increased exposure of hydrophobic and aromatic residues, reduced α-helix content from 22.95% to 15.03%, and increased β-sheet structures from 34.16% to 42.14%. Ultrasonic treatment (300 W) effectively improved the protein diffusion rate (0.106 to 0.182 mNm<sup>-1</sup>s<sup>-0.5</sup>) and penetration rate (3.971 × 10<sup>-4</sup> to 4.682 × 10<sup>-4</sup> s<sup>-1</sup>) at the oil-water interface, indicating the formation of strengthened interfacial protein films. HIPEs stabilized by OP-300 revealed the smallest droplet size, intensified droplet-droplet interactions, superior viscoelastic properties, and excellent storage stability. LAOS analysis further confirmed that HIPEs prepared with OP-200 and OP-300 maintained structural integrity under large deformation amplitudes ≤100%, compared to the untreated sample ≤10%, indicating the formation of stronger and more cohesive gel networks. Moreover, encapsulated Lactobacillus reuteri showed improved survival rate during simulated digestion, increasing viable cell counts from 4.12 × 10<sup>7</sup> to 7.21 × 10<sup>7</sup> CFU/mL. These findings established that ultrasound tailors OP structure-function relationships, enabling their use as sustainable emulsifiers for robust HIPEs with enhanced probiotic delivery.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"134 ","pages":"108123"},"PeriodicalIF":10.2,"publicationDate":"2026-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149223138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cavitation erosion-corrosion properties of as-cast NiTi and LPBF NiTi in 3.5 wt% NaCl solution: A comparison investigation. 铸态NiTi和LPBF NiTi在3.5 wt% NaCl溶液中的空化冲刷腐蚀性能对比研究。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-17 DOI: 10.1016/j.ultsonch.2026.108122
Ruoyu Fei, Zhou Yang, Huiling Zhou, Xiang Cai, Lianmin Zhang, Lanlan Yang, Feng Xiao, Qichao Zhang, Yanxin Qiao
{"title":"Cavitation erosion-corrosion properties of as-cast NiTi and LPBF NiTi in 3.5 wt% NaCl solution: A comparison investigation.","authors":"Ruoyu Fei, Zhou Yang, Huiling Zhou, Xiang Cai, Lianmin Zhang, Lanlan Yang, Feng Xiao, Qichao Zhang, Yanxin Qiao","doi":"10.1016/j.ultsonch.2026.108122","DOIUrl":"https://doi.org/10.1016/j.ultsonch.2026.108122","url":null,"abstract":"<p><p>This study aimed to clarify how the laser powder bed fusion (LPBF) process modifies the cavitation erosion-corrosion (CE-corrosion) behaviour of NiTi alloys in a 3.5 wt% NaCl solution, through a systematic comparison with an as-cast NiTi counterpart. Ultrasonic CE-corrosion mass-loss tests, potentiodynamic and potentiostatic polarisation, Mott-Schottky analysis, and X-ray photoelectron spectroscopy were combined to correlate microstructure, passive-film properties, and damage evolution. After 20 h of CE, the cumulative mass loss of the LPBF NiTi alloy reached 5.65 mg, approximately 2.57 times that of the as-cast alloy (2.20 mg), and its steady-state mass-loss rate (∼0.28 mg·h<sup>-1</sup>) was about 2.6 times that of the as-cast alloy (∼0.11 mg·h<sup>-1</sup>). Rapid solidification generated a metastable B19' martensitic phase and a high density of process-induced defects in the LPBF alloy. Its passive film contained a higher fraction of low-valence oxides (TiO) and exhibited a higher donor density than that of the as-cast alloy, indicating a less protective barrier layer. Failure mechanism analysis revealed that microgalvanic corrosion and stress acted synergistically to accelerate passive-film rupture and substrate damage in the LPBF alloy. These findings establish the relationships among microstructure, passive-film characteristics, electrochemical behaviour, and CE resistance, thereby providing an experimental and mechanistic basis for enhancing the marine-service performance of LPBF NiTi alloys.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"134 ","pages":"108122"},"PeriodicalIF":10.2,"publicationDate":"2026-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149223070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acoustic-Cavitation-Assisted chemical removal of gypsum Scale: Mechanisms and process intensification. 声空化辅助化学去除石膏水垢:机理与过程强化。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-17 DOI: 10.1016/j.ultsonch.2026.108124
Chiara Canciani, Ghassan Alaseri, Ahmad Alguydi, Areej Alzuwaid, Faisal Alissa, William L Roberts, Qasim Sahu
{"title":"Acoustic-Cavitation-Assisted chemical removal of gypsum Scale: Mechanisms and process intensification.","authors":"Chiara Canciani, Ghassan Alaseri, Ahmad Alguydi, Areej Alzuwaid, Faisal Alissa, William L Roberts, Qasim Sahu","doi":"10.1016/j.ultsonch.2026.108124","DOIUrl":"https://doi.org/10.1016/j.ultsonch.2026.108124","url":null,"abstract":"<p><p>Calcium sulfate (gypsum) scale removal is a major operational issue concerning oil production facilities, as the deposits damage equipment and their removal causes prolonged downtime. Therefore, investigating process intensification techniques is pivotal for reducing scale removal time. This study focuses on the application of acoustic cavitation to the dissolution of gypsum, using two different types of dissolvers: potassium carbonate, a converter, and tetrasodium EDTA, a chelating agent. Compared with soaking at ambient temperature, ultrasound-assisted treatment increased gypsum removal 8.5-fold with potassium carbonate and 56-fold with tetrasodium EDTA. Silent experiments following the same temperature profile showed that heating accounts for much of this gain, with cavitation providing a further 1.6-fold and 2.9-fold increase, respectively. Electron microscopy indicated different mechanisms. Potassium carbonate converts gypsum layer by layer under silent conditions, whereas ultrasound produced deep cavities beyond the surface layer, consistent with localized cavitation-induced penetration. With tetrasodium EDTA, surface morphology was unchanged, suggesting that enhanced mass transfer dominates. These bench-scale findings support acoustic cavitation as a process intensification tool for scale removal, warranting further studies on field applicability.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"134 ","pages":"108124"},"PeriodicalIF":10.2,"publicationDate":"2026-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149223086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sonication: A sensory engineering approach reshaping consumer acceptance for novel foods. 超声:一种重塑消费者对新食品接受度的感官工程方法。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-17 DOI: 10.1016/j.ultsonch.2026.108117
Muhammad Faisal Manzoor, Zahoor Ahmed, Rana Muhammad Aadil, Muhammad Talha Afraz, Xin-An Zeng, Gholamreza Abdi
{"title":"Sonication: A sensory engineering approach reshaping consumer acceptance for novel foods.","authors":"Muhammad Faisal Manzoor, Zahoor Ahmed, Rana Muhammad Aadil, Muhammad Talha Afraz, Xin-An Zeng, Gholamreza Abdi","doi":"10.1016/j.ultsonch.2026.108117","DOIUrl":"https://doi.org/10.1016/j.ultsonch.2026.108117","url":null,"abstract":"<p><p>Non-thermal ultrasound (US) is a powerful processing technology that alters the textural, physicochemical, and volatile properties of novel foods such as cultured meat, plant-based meat alternatives (PBMA), precision fermentation-derived products, insect-based proteins, and algae-based foods through cavitation-driven acoustic effects. These changes directly affect the sensory attributes that shape consumer perceptions and acceptance of novel foods. This review examines the mechanistic relationship between US food processing and the consumer sensory-acceptance barrier, drawing on evidence from sonochemistry, behavioral economics, sensory science, food policy, and digital marketing. We stated that US-induced modifications in flavor (through modulation of Maillard reaction precursors, volatile compound generation, and lipid oxidation control), texture (through starch gelatinization, emulsion stabilization, and myofibrillar disruption), aroma (through controlled release of encapsulated volatile compounds), and color (through Maillard browning and pigment stability) potentially contribute to consumer acceptance by affecting sensory attributes. However, these relationships should be considered as proposed pathways rather than experimentally validated causal mechanisms, as direct consumer acceptance studies remain limited. Specifically, US-modified flavor and texture profiles of PBMAs, microalgae ingredients, and insect protein powders address the most consistently cited sensory barriers to consumer trial and repeat purchase. The review further combines cross-domain moderators, cultural disgust, food neophobia, behavioral nudges, labeling framing, digital and social media influence, and pricing that operate at higher cognitive and policy levels, demonstrating how US sensory improvements must be coupled with consumer-centered communication strategies to translate physicochemical gains into marketplace acceptance. A comparative analysis of existing studies indicates a persistent attitude-behavior gap, suggesting that US-optimized sensory quality alone does not fully determine consumer acceptance.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"134 ","pages":"108117"},"PeriodicalIF":10.2,"publicationDate":"2026-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149223129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasound-triggered metabolic responses of Lactobacillus acidophilus at different growth phases enhance the functional quality of Citrus aurantium L. juice. 超声触发嗜酸乳杆菌在不同生长阶段的代谢反应提高了柑桔汁的功能品质。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-17 DOI: 10.1016/j.ultsonch.2026.108120
Binbin Li, Ningning Shen, Linxiao Wang, Shun Li, Longquan Xiao, Lin Zhou, Zhengnan Ren, Xinhui Wang
{"title":"Ultrasound-triggered metabolic responses of Lactobacillus acidophilus at different growth phases enhance the functional quality of Citrus aurantium L. juice.","authors":"Binbin Li, Ningning Shen, Linxiao Wang, Shun Li, Longquan Xiao, Lin Zhou, Zhengnan Ren, Xinhui Wang","doi":"10.1016/j.ultsonch.2026.108120","DOIUrl":"https://doi.org/10.1016/j.ultsonch.2026.108120","url":null,"abstract":"<p><p>Accumulating evidence has demonstrated that ultrasound-assisted lactic acid bacteria (LAB) fermentation can improve the functional quality of fruit juices. However, the growth phase-dependent metabolic responses of LAB to low-frequency ultrasonication remain poorly understood. In this study, low-frequency ultrasonication (83.6 and 119.17 W/L) was applied during the lag, logarithmic, and stationary phases of Lactobacillus acidophilus LA137 fermentation in Citrus aurantium L. juice. Microbial growth, physicochemical properties, β-glucosidase activity, total phenolic and flavonoid contents, and antioxidant capacity were evaluated in this study. Ultrasonication applied during the logarithmic and stationary phases exerted greater effects on microbial metabolism and functional quality than treatment during the lag phase. Among all treatments, ultrasonication at 119.17 W/L during the logarithmic phase (LU4) and 83.6 W/L during the stationary phase (LU5) showed superior enhancement of β-glucosidase activity, phenolic/flavonoid accumulation, and antioxidant capacity. Integrated untargeted metabolomics revealed distinct metabolic responses between LU4 and LU5. LU4 preferentially promoted phenylpropanoid and flavonoid metabolism, resulting in the accumulation of antioxidant-related metabolites, including gallic acid, taxifolin, and 7-galloylcatechin. In contrast, LU5 mainly enhanced amino acid and organic acid metabolism, leading to increased levels of lactic acid, γ-aminobutyric acid, alanine, and serine. Correlation analysis further linked these metabolites to improved antioxidant properties. These findings demonstrate that low-frequency ultrasonication redirects microbial metabolism toward distinct functional routes depending on the growth phase of L. acidophilus, providing new mechanistic insights into the precise regulation of ultrasound-assisted LAB fermentation.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"134 ","pages":"108120"},"PeriodicalIF":10.2,"publicationDate":"2026-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149223083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Time-optimized ultrasonic synthesis of α-MnO2 nanoflower: controlling structural evolution and agglomeration for stable electrochemical performance. 时间优化超声合成α-MnO2纳米花:控制结构演变和团聚以稳定电化学性能。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-17 DOI: 10.1016/j.ultsonch.2026.108119
S V Divyalekshmi, M A Anu, T S Xavier, R Murali
{"title":"Time-optimized ultrasonic synthesis of α-MnO<sub>2</sub> nanoflower: controlling structural evolution and agglomeration for stable electrochemical performance.","authors":"S V Divyalekshmi, M A Anu, T S Xavier, R Murali","doi":"10.1016/j.ultsonch.2026.108119","DOIUrl":"https://doi.org/10.1016/j.ultsonch.2026.108119","url":null,"abstract":"<p><p>This study presents a simple ultrasonication-assisted route for the synthesis of α-MnO<sub>2</sub> nanoflowers at room temperature. The process employs acoustic cavitation at 40 kHz and 100 W with test synthesis times of 0, 20, 40, and 60 min. The best results were obtained with 40 min of sonication, yielding uniform nanoflower structures with (2 × 2) tunnel framework of α-MnO<sub>2</sub>, a maximum specific BET surface area of 182 m<sup>2</sup> g<sup>-1</sup> and total pore volume of 0.41 cm<sup>3</sup> g<sup>-1</sup>. Besides, the electrochemical measurements of α-MnO<sub>2</sub> nanoflowers were carried out using a three-electrode configuration, achieving a specific capacitance of 121F g<sup>-1</sup> in 1 M Na<sub>2</sub>SO<sub>4</sub> and 116F g<sup>-1</sup> in 1 M LiCl electrolytes at 2 mV s<sup>-1</sup> for 40 min sonicated sample. Moreover, the electrochemical impedance spectroscopy indicates notable reduction in the charge transfer resistance upon optimization. The fabricated symmetric device exhibits a coulombic efficiency of ∼99% over 10,000 cycles in a 1 M Na<sub>2</sub>SO<sub>4</sub> electrolyte. The ambient, template-free synthesis condition offer clear pathways to industrial scalability. This work establishes sonication duration as a versatile parameter for engineering metal oxides with tailored morphology, delivering reliable performance and long-term stability in neutral aqueous supercapacitors.</p>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"134 ","pages":"108119"},"PeriodicalIF":10.2,"publicationDate":"2026-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149223058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Regulation of ultrasonic atomization behavior and preparation of low-melting-point alloy powders 超声雾化行为的调控及低熔点合金粉末的制备
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-01 Epub Date: 2026-09-26 DOI: 10.1016/j.ultsonch.2026.108082
Xiaofeng Yang, Haodi Li, Dingying Ren, Hao Lan, Xiaoqiang Hu, Qian Wang, Peng Yu
{"title":"Regulation of ultrasonic atomization behavior and preparation of low-melting-point alloy powders","authors":"Xiaofeng Yang,&nbsp;Haodi Li,&nbsp;Dingying Ren,&nbsp;Hao Lan,&nbsp;Xiaoqiang Hu,&nbsp;Qian Wang,&nbsp;Peng Yu","doi":"10.1016/j.ultsonch.2026.108082","DOIUrl":"10.1016/j.ultsonch.2026.108082","url":null,"abstract":"<div><div>Viscous damping and acoustic radiation pressure challenge the ultrasonic atomization of high-viscosity and high-surface-tension fluids. To address this issue and reveal the underlying mechanisms, a rotational ultrasonic atomization platform was developed. The effects of ultrasonic power, liquid viscosity, horn geometry, rotation speed, and initial momentum on atomization behavior were investigated using high-speed imaging. For low-viscosity liquids, increasing ultrasonic power elevated the Weber number, widened the spray angle from 63 degrees to 142 degrees, and shortened the atomization incubation period from 10.86 s to 8.15 s. For high-viscosity liquids, viscous damping suppressed the capillary wave pathway, making cavitation the dominant mechanism. Driven by the secondary Bjerknes force, cavitation bubbles bridged into branched, neural-network-like clusters. Their collective collapse overcame the viscous dissipation barrier, providing experimental validation for Boguslavskii’s hypothesis. A critical rotation threshold of 60 revolutions per minute was identified. Below this threshold, acoustic pinning confined the liquid on the horn end-face; above it, centrifugal force forcibly thinned the liquid film, triggering atomization. Furthermore, horn geometry determined the atomization onset location, while increased initial momentum accelerated initiation. Experiments on Sn-58Bi melt verified that coupling optimized horn geometry with a centrifugal force field effectively overcomes the surface energy barrier. Based on these findings, a six-stage atomization model is proposed. The capillary wave mechanism primarily achieves initial film thinning by stripping large droplets, while cavitation dominates fine fragmentation. This work systematically investigates the atomization mechanism of high-resistance fluids and demonstrates the fabrication of metal powders via rotational ultrasonic atomization.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"133 ","pages":"Article 108082"},"PeriodicalIF":10.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149049957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement of lateral seepage and mass transfer in ionic rare earth ores by ultrasonic stimulation during in-situ leaching 超声刺激对离子型稀土矿原位浸出过程中侧向渗流和传质的促进作用。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-01 Epub Date: 2026-09-23 DOI: 10.1016/j.ultsonch.2026.108074
Yi Zhao, Xiaoyu Sun, Mu Li, Mangen Li, Xianping Luo, Zhihong Zheng, Chao Liu, Yongwen Zhang, Haiyan Liu, Chuan He, Zhiyuan Ma
{"title":"Enhancement of lateral seepage and mass transfer in ionic rare earth ores by ultrasonic stimulation during in-situ leaching","authors":"Yi Zhao,&nbsp;Xiaoyu Sun,&nbsp;Mu Li,&nbsp;Mangen Li,&nbsp;Xianping Luo,&nbsp;Zhihong Zheng,&nbsp;Chao Liu,&nbsp;Yongwen Zhang,&nbsp;Haiyan Liu,&nbsp;Chuan He,&nbsp;Zhiyuan Ma","doi":"10.1016/j.ultsonch.2026.108074","DOIUrl":"10.1016/j.ultsonch.2026.108074","url":null,"abstract":"<div><div>To overcome the issues of low recovery and non-uniform mining caused by gravity-driven vertical preferential flow during the in-situ leaching (ISL) of ion-adsorption type rare earth ores (IREOs), this study systematically investigated the enhancement laws of ultrasound on lateral seepage and mass transfer. This study constructed an ultrasonic coupling lateral column leaching system to simulate the in-situ leaching process. The effects of ultrasonic parameters (probe position, power and mode) on the lateral seepage rate and leaching efficiency were investigated. Influence of thermal effect and ultrasonic effect on leaching was distinguished. The results indicate that applying ultrasound in the middle position of the ore body achieves the higher leaching efficiency and lateral seepage rate compared to other positions. Under an optimized pulsed mode (360 W, 5 min on/5 min off, 5 h), the leaching efficiency of rare earth elements (REEs) reached 94.4 %, representing a 9 % increase over the temperature control and a 22 % increase over conventional leaching. Concurrently, the average lateral seepage rate increased by 0.317 mL/min, and the leaching duration was shortened by 37.8 %. Although the leaching efficiency of the 5/15 mode is slightly lower, its superior energy efficiency is more attractive in industry. Characterization results revealed that ultrasound induced particle benign refinement, surface erosion, and pore development, increasing the specific surface area by 42 %. Kinetic analysis confirmed that ultrasound shifted the rate-limiting step from external diffusion control to chemical reaction control, effectively eliminating mass transfer resistance. This enhancement is attributed to the synergistic effects of mechanical vibration and cavitation, which reconstruct the pore structure and improve the reaction interface. This work provides insights into overcoming physical seepage barriers to achieve efficient and green mining of IREOs.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"133 ","pages":"Article 108074"},"PeriodicalIF":10.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149073089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasound-assisted deep eutectic solvent extraction combined with gradient ethanol precipitation of polysaccharides from Paulownia fortunei flowers: Process optimization, physicochemical characterization, bioactivity evaluation 超声辅助深度共晶溶剂萃取-梯度乙醇沉淀法提取泡桐花多糖:工艺优化、理化性质及生物活性评价
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-01 Epub Date: 2026-09-24 DOI: 10.1016/j.ultsonch.2026.108076
Na Guo, Le Yang, Xi-Bing Cao, Xiao-Qiao Zhai, Guo-Qiang Fan
{"title":"Ultrasound-assisted deep eutectic solvent extraction combined with gradient ethanol precipitation of polysaccharides from Paulownia fortunei flowers: Process optimization, physicochemical characterization, bioactivity evaluation","authors":"Na Guo,&nbsp;Le Yang,&nbsp;Xi-Bing Cao,&nbsp;Xiao-Qiao Zhai,&nbsp;Guo-Qiang Fan","doi":"10.1016/j.ultsonch.2026.108076","DOIUrl":"10.1016/j.ultsonch.2026.108076","url":null,"abstract":"<div><div>The traditional methods for extraction and separation of polysaccharides usually have the shortcomings of long processing time and complex operation procedures. The objective of this study was to develop an efficient and integrated strategy for synergistic extraction and separation of polysaccharides from <em>Paulownia fortunei</em> flowers by ultrasound-assisted deep eutectic solvents extraction (UADES) combined with gradient ethanol precipitation (GEP). The extraction conditions were successively optimized using single-factor experiments and response surface methodology. Under the optimal conditions, the maximum extraction yield of <em>P. fortunei</em> flowers polysaccharides (PFP) reached 5.91 ± 0.29%, which was 3.05-fold higher than that of conventional hot water extraction (CHWE). Analysis of tissue morphology, and molecular dynamics simulations of DES and PFP both indicated that this extraction method was superior to CHWE. Meanwhile, PFP can be fractionated and purified through GEP. Three polysaccharide fractions, namely PFP-40, PFP-60, and PFP-80, were obtained at the final ethanol precipitation concentrations of 40%, 60%, and 80% (v/v), respectively. All fractions also showed differences in structural characterizations. <em>In vitro</em> activity assays demonstrated that all polysaccharide fractions exhibited antioxidant activity and tyrosinase inhibitory activity, and PFP-80 showed the strongest bioactivity. Further mechanistic studies indicated that the inhibition of tyrosinase by PFP-80 was reversible and mixed-type, their interaction occurred through a static quenching mechanism. This study introduced a strategy for DES recycling post-GEP for polysaccharide extraction, and the PFP showed potential for applications in the food and pharmaceutical industries.</div></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":"133 ","pages":"Article 108076"},"PeriodicalIF":10.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149049546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pea protein isolate modified by Persian gum and ultrasound treatment as a thickening agent for dysphagia-oriented instant rice porridge 用波斯胶改性的豌豆分离蛋白和超声处理作为消化困难型即食米粥的增稠剂。
IF 10.2 1区 化学
Ultrasonics Sonochemistry Pub Date : 2026-10-01 Epub Date: 2026-09-26 DOI: 10.1016/j.ultsonch.2026.108083
Yasamin Damroudi, Mehdi Farhoodi, Leila Mirmoghtadaie, Kooshan Nayebzadeh, Fereshte Bahmanyar
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