Ultrasonics Sonochemistry最新文献

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Optimization of ultrasound heating with Pickering droplets using core–shell scattering theory 利用核壳散射理论优化皮克林液滴的超声波加热
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-07-02 DOI: 10.1016/j.ultsonch.2024.106965
{"title":"Optimization of ultrasound heating with Pickering droplets using core–shell scattering theory","authors":"","doi":"10.1016/j.ultsonch.2024.106965","DOIUrl":"10.1016/j.ultsonch.2024.106965","url":null,"abstract":"<div><p>Nanoparticles find widespread application in various medical contexts, including targeted nanomedicine and enhancing therapeutic efficacy. Moreover, they are employed to stabilize emulsions, giving rise to stabilized droplets known as Pickering droplets. Among the various methods to improve anti-cancer treatment, ultrasound hyperthermia stands out as an efficient approach. This research proposes Pickering droplets as promising sonosensitizer candidates, to enhance the attenuation of ultrasound with simultaneous potential to act as drug carriers. The enhanced ultrasound energy dissipation could be, therefore, optimized by changing the parameters of Pickering droplets.</p><p>The ultrasound scattering theory, based on the core–shell model, was employed to calculate theoretical ultrasound properties such as attenuation and velocity. Additionally, computer simulations, based on a bioheat transfer model, were utilized to compute heat generation in agar-based phantoms of tissues under different ultrasound wave frequencies. Two types of phantoms were simulated: a pure agar phantom and an agar phantom incorporating spherical inclusions. The spherical inclusions, with a diameter of 10 mm, were doped with various sizes of Pickering droplets, considering their core radius and shell thickness.</p><p>Computer simulation of these spherical inclusions incorporated within agar phantom resulted in different enhancement of achieved temperature elevation, which depending on the core radius, shell thickness, and the material properties of the system. Notably, spherical inclusions doped with Pickering droplets stabilized by magnetite nanoparticles exhibited a higher temperature rise compared to droplets stabilized by silica nanoparticles. Moreover, nanodroplets with a core radius below 400 nm demonstrated better heating performance compared to microdroplets. Furthermore, Pickering droplets incorporated into agar phantom could allow obtaining a similar effect of local heating as sophisticated focused ultrasound devices.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S135041772400213X/pdfft?md5=81d524e3e066c8ea08fb607b52bb450a&pid=1-s2.0-S135041772400213X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141714939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physicochemical and rheological properties of ultrasonic-assisted pregelatinized rice flour 超声波辅助预糊化米粉的物理化学和流变特性
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-07-02 DOI: 10.1016/j.ultsonch.2024.106977
{"title":"Physicochemical and rheological properties of ultrasonic-assisted pregelatinized rice flour","authors":"","doi":"10.1016/j.ultsonch.2024.106977","DOIUrl":"10.1016/j.ultsonch.2024.106977","url":null,"abstract":"<div><p>This study evaluated the physical and rheological properties of whole rice flour treated for different sonication times (0–15 min). Ultrasonication reduces the particle size of rice flour and improves its solubility. Viscosity tests using RVA and steady shear showed a notable decrease in the viscosity of the rehydrated pregelatinized rice flour. Although no unusual patterns were observed in the XRD analysis, the FT-IR and microstructure morphology findings suggest that ultrasonication led to structural changes in the rice flour. Overall, the study indicates that ultrasonication is a practical and clean method for producing plant-based drinks from rice flour, which could expand its limited applications in the beverage industry.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002256/pdfft?md5=5a4f058222d0777a0c3269740d7befc0&pid=1-s2.0-S1350417724002256-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141716838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sonochemical decomposition effects of nickelocene aiming for low-temperature and dispersant-free synthesis of nickel fine particle 以低温无分散剂合成镍微粒为目标的二茂镍的声化学分解效应
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-28 DOI: 10.1016/j.ultsonch.2024.106976
Tatsuya Shishido, Yamato Hayashi, Hirotsugu Takizawa
{"title":"Sonochemical decomposition effects of nickelocene aiming for low-temperature and dispersant-free synthesis of nickel fine particle","authors":"Tatsuya Shishido,&nbsp;Yamato Hayashi,&nbsp;Hirotsugu Takizawa","doi":"10.1016/j.ultsonch.2024.106976","DOIUrl":"10.1016/j.ultsonch.2024.106976","url":null,"abstract":"<div><p>Sonochemical decomposition effects of nickelocene, which sublimates easily were investigated to synthesize dispersant-free nickel fine particles at low temperature. In a hydrazine monohydrate and 2-propanol mixed solvent, the reduction of nickelocene was promoted by ultrasound irradiation, and nickel fine particles were synthesized while precluding the sublimation of nickelocene. Unlike the common hydrazine reduction of nickel salts, which requires multiple-step reactions, nickelocene was reduced directly without forming intermediates. The effect of the water-bath temperature (20–60 °C) was investigated, where larger fine particles were synthesized using a higher water-bath temperature (60 °C). When irradiated at 20 °C, the reduction rate of nickelocene was low, leading to the formation of nickel fine particles and organic nanoparticles via the reduction and decomposition of nickelocene. The ultrasound frequency was also investigated, where fine nickel particles were synthesized using low-frequency ultrasound irradiation. The formation of high-temperature hotspots led to the diffusion and growth of nickel on the surface of the nickel fine particles; therefore, raspberry-like nickel fine particles were synthesized. In this study, the difficult-to-handle nature of nickelocene, owing to its sublimation properties, was easily overcome by ultrasound irradiation. Instantaneous and localized reactions at hotspots contributed to inhibiting particle growth. Furthermore, Ni fine particles were synthesized via a direct reduction pathway, which differs from previous reactions. This method represents a new, dispersant-free, low-temperature process for synthesizing Ni fine particles.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002244/pdfft?md5=05aa021f9f18748ee3a22ffee2dc42db&pid=1-s2.0-S1350417724002244-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141464154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasound-assisted extraction and encapsulation of betalain from prickly pear: Process optimization, in-vitro digestive stability, and development of functional gummies 超声辅助提取和封装刺梨中的甜菜素:工艺优化、体外消化稳定性和功能软糖的开发
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-27 DOI: 10.1016/j.ultsonch.2024.106975
Deepak Mehta , Kritika Kuksal , Kamlendra Yadav , Sudesh Kumar Yadav , Yuqin Zhang , Shivraj Hariram Nile
{"title":"Ultrasound-assisted extraction and encapsulation of betalain from prickly pear: Process optimization, in-vitro digestive stability, and development of functional gummies","authors":"Deepak Mehta ,&nbsp;Kritika Kuksal ,&nbsp;Kamlendra Yadav ,&nbsp;Sudesh Kumar Yadav ,&nbsp;Yuqin Zhang ,&nbsp;Shivraj Hariram Nile","doi":"10.1016/j.ultsonch.2024.106975","DOIUrl":"10.1016/j.ultsonch.2024.106975","url":null,"abstract":"<div><p>The study aimed to extract and encapsulate betalain pigment from prickly pear (<em>Opuntia ficus</em>-indica) using ultrasound-assisted extraction and eco-friendly glycerol. Subsequent analysis encompassed assessing its thermal stability, shelf-life, bio-accessibility, and biological properties. The process optimization employed Response Surface Methodology (RSM), focusing on glycerol concentration (20–50 %), sample to solvent ratio (1:10–1:20), temperature (30–60 °C), and time (10–30 min). Optimal conditions were determined as 23.15 % glycerol, 1:10 sample to solvent ratio, 10.43 min treatment time, and 31.15 °C temperature. Under these conditions, betalain content reached 858.28 mg/L with a 93.76 % encapsulation efficiency. Thermal stability tests (80–180 °C; 30 &amp; 60 min) showed degradation of betalain with higher temperatures and longer durations, affecting the visual aspect (ΔE) of the pigment. Encapsulated betalain exhibited favorable shelf stability, with optimal storage life of 404.27 days at 4 °C in amber conditions, compared to 271.99 days at 4 °C without amber, 141.92 days at 25 °C without amber, and 134.22 days at 25 °C with amber. Bio-accessibility of encapsulated betalain was significantly higher (2.05 ± 0.03 %) than conventionally extracted pigment (1.03 ± 0.09 %). The encapsulated pigment displayed strong anti-inflammatory properties in dosages of 2–20 µL, with no cytotoxic effects. Additionally, incorporation into gummies was successful and visually approved by sensory panellists. Glycerol proved to be a green encapsulating agent for betalain, offering high shelf life and bio-accessibility, making it suitable for food industry applications. The encapsulated pigment demonstrated robust thermal stability and shelf life, making it suitable for food industry applications. This study highlights glycerol’s potential as a sustainable alternative for natural pigment extraction.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002232/pdfft?md5=8908138fffeb3b50684f48e2aec5e572&pid=1-s2.0-S1350417724002232-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141464196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of emerging applications of ultrasonication in Comparison with non-ionizing technologies for meat decontamination 超声波与非电离技术在肉类去污方面的新兴应用对比综述
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-26 DOI: 10.1016/j.ultsonch.2024.106962
Bo-Ru Chen , Ume Roobab , Ghulam Muhammad Madni , Gholamreza Abdi , Xin-An Zeng , Rana Muhammad Aadil
{"title":"A review of emerging applications of ultrasonication in Comparison with non-ionizing technologies for meat decontamination","authors":"Bo-Ru Chen ,&nbsp;Ume Roobab ,&nbsp;Ghulam Muhammad Madni ,&nbsp;Gholamreza Abdi ,&nbsp;Xin-An Zeng ,&nbsp;Rana Muhammad Aadil","doi":"10.1016/j.ultsonch.2024.106962","DOIUrl":"10.1016/j.ultsonch.2024.106962","url":null,"abstract":"<div><p>Meat is highly susceptible to contamination with harmful microorganisms throughout the production, processing, and storage chain, posing a significant public health risk. Traditional decontamination methods like chemical sanitizers and heat treatments often compromise meat quality, generate harmful residues, and require high energy inputs. This necessitates the exploration of alternative non-ionizing technologies for ensuring meat safety and quality. This review provides a comprehensive analysis of the latest advancements, limitations, and future prospects of non-ionizing technologies for meat decontamination, with a specific focus on ultrasonication. It further investigates the comparative advantages and disadvantages of ultrasonication against other prominent non-ionizing technologies such as microwaves, ultraviolet (UV) light, and pulsed light. Additionally, it explores the potential of integrating these technologies within a multi-hurdle strategy to achieve enhanced decontamination across the meat surface and within the matrix. While non-ionizing technologies have demonstrated promising results in reducing microbial populations while preserving meat quality attributes, challenges remain. These include optimizing processing parameters, addressing regulatory considerations, and ensuring cost-effectiveness for large-scale adoption. Combining these technologies with other methods like antimicrobial agents, packaging, and hurdle technology holds promise for further enhancing pathogen elimination while safeguarding meat quality.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002104/pdfft?md5=c44261e43270f8ed2a6a856e3870ffaa&pid=1-s2.0-S1350417724002104-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141464167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-flux ultrasonic processing for lithium separation using ionic liquid impregnated composite membranes 利用离子液体浸渍复合膜进行高通量超声波处理以分离锂
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-26 DOI: 10.1016/j.ultsonch.2024.106974
Behrang Golmohammadi, Hemayat Shekaari
{"title":"High-flux ultrasonic processing for lithium separation using ionic liquid impregnated composite membranes","authors":"Behrang Golmohammadi,&nbsp;Hemayat Shekaari","doi":"10.1016/j.ultsonch.2024.106974","DOIUrl":"https://doi.org/10.1016/j.ultsonch.2024.106974","url":null,"abstract":"<div><p>Battery industry, one of the most crucial components of the modern world, relies heavily on lithium production, and brines from the spent battery materials is one of the most important sources to exploit lithium. A new ultrasonic assisted membrane processing is proposed for lithium separation simulated brine. The effects of membrane composition, feed concentration, and ultrasonic conditions on the lithium extraction efficiency have been explored. The composite membrane including polysulfone (PSF) as the support and 1-alkyl-3-methylimidazolium hexafluorophosphate and tributyl phosphate as ionic liquid membrane. A porous PVC membrane has been used for prevention of the ILM loss. The optimal ultrasonic frequency is approximately 250 kHz, which matches the bulk modulus of the membrane and enhances the separation efficiency. Higher frequencies and optimized amplitude and pulse cycle settings further improve the lithium flux and selectivity. Moreover, higher flux and selectivity are achieved when separating lithium from alkali metal chlorides at higher feed concentrations, ranging from 250 ppm to 1000 ppm. The mechanism of enhanced lithium extraction by ultrasonics is attributed to the combination of microbubble formation, cavitation, and heat generation, which disrupt the concentration gradient and facilitate lithium transport across the membrane.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002220/pdfft?md5=9e5afb63db370424f1a523a531d51dc5&pid=1-s2.0-S1350417724002220-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141487256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of process conditions for ionic liquid-based ultrasound-enzyme-assisted extraction of resveratrol from Polygonum Cuspidatum 优化基于离子液体的超声酶辅助提取何首乌中白藜芦醇的工艺条件
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-26 DOI: 10.1016/j.ultsonch.2024.106973
Hongyi Zhao , Junping Wang , Yutong Han , Xin Wang , Zunlai Sheng
{"title":"Optimization of process conditions for ionic liquid-based ultrasound-enzyme-assisted extraction of resveratrol from Polygonum Cuspidatum","authors":"Hongyi Zhao ,&nbsp;Junping Wang ,&nbsp;Yutong Han ,&nbsp;Xin Wang ,&nbsp;Zunlai Sheng","doi":"10.1016/j.ultsonch.2024.106973","DOIUrl":"10.1016/j.ultsonch.2024.106973","url":null,"abstract":"<div><p>This work offered a productive technique for resveratrol extraction from <em>Polygonum Cuspidatum</em> (<em>P. Cuspidatum</em>) using ionic liquids in synergy with ultrasound-enzyme-assisted extraction (UEAE). Firstly, ionic liquids with different carbon chains and anions were evaluated. Subsequently, a comprehensive investigation was carried out to evaluate the effect of seven crucial parameters on the resveratrol yield: pH value, enzyme concentration, extraction temperature, extraction time, ultrasonic power, concentration of ionic liquid (IL concentration) and the liquid–solid ratio. Employing the Plackett-Burman Design (PBD), the critical factors were effectively identified. Building upon this foundation, the process was further optimized through the application of Response Surface Methodology (RSM) and an Artificial Neural Network-Genetic Algorithm (ANN-GA). The following criteria were determined to be the ideal extraction conditions: an enzyme concentration of 2.18%, extraction temperature of 58 °C, a liquid–solid ratio of 29 mL/g, pH value of 5.5, extraction time of 30 min, ultrasonic power of 250 W, and extraction solvent of 0.5 mol/L 1-butyl-3-methylimidazolium bromide. Under these conditions, the resveratrol yield was determined to be 2.90 ± 0.15 mg/g. Comparative analysis revealed that the ANN-GA model provided a better fit to the experimental data of resveratrol yield than the RSM model, suggesting superior predictive capabilities of the ANN-GA approach. The introduction of a novel green solvent system in this experiment not only simplifies the extraction process but also enhances safety and feasibility. This research paves the way for innovative approaches to extracting resveratrol from botanical sources, showcasing its significant potential for a wide range of applications.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002219/pdfft?md5=187f6c65ce90762b60f900c3b69128ba&pid=1-s2.0-S1350417724002219-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141464104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of Microbubble-Blood cell system Oscillation/Cavitation influenced by ultrasound Forces: Conjugate applications of FEM and LBM 受超声力影响的微泡-血细胞系统振荡/空化分析:FEM 和 LBM 的共轭应用
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-26 DOI: 10.1016/j.ultsonch.2024.106972
Ramyar Doustikhah, Saeed Dinarvand, Pedram Tehrani, Mohammad Eftekhari Yazdi, Gholamreza Salehi
{"title":"Analysis of Microbubble-Blood cell system Oscillation/Cavitation influenced by ultrasound Forces: Conjugate applications of FEM and LBM","authors":"Ramyar Doustikhah,&nbsp;Saeed Dinarvand,&nbsp;Pedram Tehrani,&nbsp;Mohammad Eftekhari Yazdi,&nbsp;Gholamreza Salehi","doi":"10.1016/j.ultsonch.2024.106972","DOIUrl":"10.1016/j.ultsonch.2024.106972","url":null,"abstract":"<div><p>Sonoporation is a non-invasive method that uses ultrasound for drug and gene delivery for therapeutic purposes. Here, both Finite Element Method (FEM) and Lattice Boltzmann Method (LBM) are applied to study the interaction physics of microbubble oscillation and collapse near flexible tissue. After validating the Finite Element Method with the nonlinear excited lipid-coated microbubble as well as the Lattice Boltzmann Method with experimental results, we have studied the behavior of a three-dimensional compressible microbubble in the vicinity of tissue. In the FEM phase, the oscillation microbubble with a lipid shell interacts with the boundary. The range of pressure and ultrasound frequency have been considered in the field of therapeutic applications of sonoporation. The viscoelastic and interfacial tension as the coating properties of the microbubble shell have been investigated. The presence of an elastic boundary increases the resonance frequency of the microbubble compared to that of a free microbubble. The increase in pressure leads to an expansion in the range of the microbubble’s motion, the velocity induced in the fluid, and the shear stress on the boundary walls of tissue. An enhancement in the surface tension of the microbubble can influence fluid flow and reduce the shear stress on the boundary. The multi-pseudo-potential interaction LBM is used to reduce thermodynamic inconsistency and high-density ratio in a two-phase system for modeling the cavitation process. The three-dimensional shape of the microbubble during the collapse stages and the counter of pressure are displayed. There is a time difference between the occurrence of maximum velocity and pressure. All results in detail are presented in the article bodies.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002207/pdfft?md5=e2c0c19a536fa0e0887cf1456a92040c&pid=1-s2.0-S1350417724002207-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141464160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamics of crevice microbubbles that cause the twinkling artifact 缝隙微气泡的动态变化导致闪烁艺术品的产生
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-25 DOI: 10.1016/j.ultsonch.2024.106971
Eric Rokni, Eusila C. Kitur, Julianna C. Simon
{"title":"Dynamics of crevice microbubbles that cause the twinkling artifact","authors":"Eric Rokni,&nbsp;Eusila C. Kitur,&nbsp;Julianna C. Simon","doi":"10.1016/j.ultsonch.2024.106971","DOIUrl":"10.1016/j.ultsonch.2024.106971","url":null,"abstract":"<div><p>The Doppler ultrasound twinkling artifact, a rapid color shift, appears on pathological mineralizations and is theorized to arise from scattering off micron-sized crevice microbubbles. However, the influence of crevice number and size as well as the bubble dynamics on twinkling is not well-understood. Cylinders with diameters of 0.8–1.2 µm and depths of 1 µm were etched into a silicon wafer and crevice bubbles were driven at 0.75, 2.5, and 5.0 MHz while monitoring with high-speed photography. Experimental results were compared to a derived crevice bubble model. On three separate wafers, cylindrical crevices (10 or 100) with diameters of 1, 10, or 100 µm and depths of 10 µm were etched and imaged with a research ultrasound system in Doppler mode at 5, 7.8, and 18.5 MHz. Within the pressure ranges studied here (∼1<!--> <!-->MPa), no bubble oscillation was observed for the 0.8–1.2 µm crevice bubbles which matched computational results. Crevices with 1 and 10 µm diameters produced more twinkling than 100 µm crevices at 5 and 7.8 MHz. In contrast, 100 µm crevices produced more twinkling than 1 or 10 µm crevices at 18.5 MHz (p &lt; 0.001 in all cases). These results provide better insight into how crevice bubbles cause twinkling on pathological mineralizations.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002190/pdfft?md5=98b71a5754f82c488a9d9605dd3ca4b0&pid=1-s2.0-S1350417724002190-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141464146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kelvin-Helmholtz instability as one of the key features for fast and efficient emulsification by hydrodynamic cavitation 开尔文-赫尔姆霍兹不稳定性是流体动力空化快速高效乳化的关键特征之一
IF 8.7 1区 化学
Ultrasonics Sonochemistry Pub Date : 2024-06-25 DOI: 10.1016/j.ultsonch.2024.106970
Žan Boček , Martin Petkovšek , Samuel J. Clark , Kamel Fezzaa , Matevž Dular
{"title":"Kelvin-Helmholtz instability as one of the key features for fast and efficient emulsification by hydrodynamic cavitation","authors":"Žan Boček ,&nbsp;Martin Petkovšek ,&nbsp;Samuel J. Clark ,&nbsp;Kamel Fezzaa ,&nbsp;Matevž Dular","doi":"10.1016/j.ultsonch.2024.106970","DOIUrl":"10.1016/j.ultsonch.2024.106970","url":null,"abstract":"<div><p>The paper investigates the oil–water emulsification process inside a micro-venturi channel. More specifically, the possible influence of Kelvin-Helmholtz instability on the emulsification process. High-speed visualizations were conducted inside a square venturi constriction with throat dimensions of 450 µm by 450 µm, both under visible light and X-Rays. We show that cavity shedding caused by the instability results in the formation of several cavity vortices. Their rotation causes the deformation of the oil stream into a distinct wave-like shape, combined with fragmentation into larger drops due to cavitation bubble collapse. Later on, the cavity collapse further disperses the larger drops into a finer emulsion. Thus, it turns out that the Kelvin-Helmholtz instability is similarly characteristic for hydrodynamic cavitation emulsification inside a microchannel as is the Rayleigh-Taylor instability for acoustically driven emulsion formation.</p></div>","PeriodicalId":442,"journal":{"name":"Ultrasonics Sonochemistry","volume":null,"pages":null},"PeriodicalIF":8.7,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1350417724002189/pdfft?md5=c0986eaad444f7fa36703c12a6386e9e&pid=1-s2.0-S1350417724002189-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141464144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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