Solar Energy Materials and Solar Cells最新文献

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Tandem radiative cooling with latent thermal energy storage for enhanced passive cooling and thermal shock resistance 串联辐射冷却与潜热储能增强被动冷却和抗热冲击
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-10 DOI: 10.1016/j.solmat.2025.113565
Zuoxin Hu, Xinru Yang, Yu Qiu
{"title":"Tandem radiative cooling with latent thermal energy storage for enhanced passive cooling and thermal shock resistance","authors":"Zuoxin Hu,&nbsp;Xinru Yang,&nbsp;Yu Qiu","doi":"10.1016/j.solmat.2025.113565","DOIUrl":"10.1016/j.solmat.2025.113565","url":null,"abstract":"<div><div>Radiative cooling and latent thermal energy storage, requiring no additional energy consumption, are recognized as promising strategies for thermal management. However, the limited theoretical cooling power and strict weather condition requirements of radiative cooling, coupled with the high solar energy absorption of latent thermal energy storage, hinder their practical applications in thermal shock resistance. Here, a tandem passive cooler, combining radiative cooling and latent thermal energy storage, is presented to achieve the dual functionalities of passive cooling and thermal shock resistance. Specifically, the radiative cooling performance of this cooler is enabled by its high solar reflectivity (0.928) and high infrared emissivity (0.947), while its efficient isothermal heat release and absorption ensure temperature stability and high thermal energy storage. Consequently, by overcoming the limitations of both radiative cooling and latent heat thermal energy storage, this tandem passive cooler achieves a maximum temperature reduction of 5.37 °C and an average passive cooling temperature of 3.01 °C, enabling effective radiative cooling. Furthermore, this cooler reduces the maximum temperature of a heated silicon wafer by 27.56 °C compared to radiative cooling alone under thermal shock situations, demonstrating superior thermal shock resistance. Upon cessation of the thermal shock, the solidified latent thermal energy storage materials release their stored energy, mitigating excess heat and preventing overcooling of electronic devices, thereby ensuring the stable operation of electronic systems. This strategy offers a promising path to efficient thermal management under extreme temperature fluctuations, significantly expanding the practical applications of radiative cooling and latent thermal energy storage technologies.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113565"},"PeriodicalIF":6.3,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mitigating contaminant-induced surface degradation in TOPCon solar cells: Mechanisms, impacts, and mitigation 减轻TOPCon太阳能电池中污染物引起的表面降解:机制、影响和缓解
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-10 DOI: 10.1016/j.solmat.2025.113558
Hongbo Tong , Xinyuan Wu , Xutao Wang , Xinxing Xu , Menglong Guo , Baochen Liao , Sheng Ma , Zhenguo Li , Bram Hoex
{"title":"Mitigating contaminant-induced surface degradation in TOPCon solar cells: Mechanisms, impacts, and mitigation","authors":"Hongbo Tong ,&nbsp;Xinyuan Wu ,&nbsp;Xutao Wang ,&nbsp;Xinxing Xu ,&nbsp;Menglong Guo ,&nbsp;Baochen Liao ,&nbsp;Sheng Ma ,&nbsp;Zhenguo Li ,&nbsp;Bram Hoex","doi":"10.1016/j.solmat.2025.113558","DOIUrl":"10.1016/j.solmat.2025.113558","url":null,"abstract":"<div><div>The tunnel oxide passivated contact (TOPCon) solar cell has become the dominant technology for high-efficiency silicon photovoltaics. Despite its success, TOPCon solar cells face significant reliability challenges under environmental stresses such as damp heat (DH) exposure. In this study, we investigate the degradation mechanisms affecting TOPCon cells, particularly focusing on contamination-induced surface passivation loss, which varies between the front and rear surfaces. Our results show that the rear side of TOPCon cells, in particular the silicon nitride (SiN<sub>x</sub>) layer, is prone to chemical degradation under exposure to sodium-based salts, resulting in a significant loss of open-circuit voltage (V<sub>oc</sub>). Sodium acetate and sodium chloride are found to accelerate surface passivation degradation through enhanced surface oxidation and diffusion of contaminants. We propose a novel approach utilizing a 10 nm aluminum oxide (AlO<sub>x</sub>) barrier layer, deposited through atomic layer deposition (ALD), to mitigate these degradation pathways effectively. Accelerated DH testing demonstrates that this barrier improves the long-term stability of TOPCon solar cells, reducing degradation and maintaining performance over extended periods. This study highlights the importance of surface protection to enhance the durability and operational lifetime of TOPCon solar cells in harsh environments.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113558"},"PeriodicalIF":6.3,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143576987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recoverable degradation of FAPbBr3 perovskite solar cells under reverse-bias: A combined electro-optical investigation 反向偏压下FAPbBr3钙钛矿太阳能电池的可回收降解:光电联合研究
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-09 DOI: 10.1016/j.solmat.2025.113547
Noah Tormena , Alessandro Caria , Matteo Buffolo , Carlo De Santi , Andrea Cester , Gaudenzio Meneghesso , Enrico Zanoni , Fabio Matteocci , Aldo Di Carlo , Nicola Trivellin , Matteo Meneghini
{"title":"Recoverable degradation of FAPbBr3 perovskite solar cells under reverse-bias: A combined electro-optical investigation","authors":"Noah Tormena ,&nbsp;Alessandro Caria ,&nbsp;Matteo Buffolo ,&nbsp;Carlo De Santi ,&nbsp;Andrea Cester ,&nbsp;Gaudenzio Meneghesso ,&nbsp;Enrico Zanoni ,&nbsp;Fabio Matteocci ,&nbsp;Aldo Di Carlo ,&nbsp;Nicola Trivellin ,&nbsp;Matteo Meneghini","doi":"10.1016/j.solmat.2025.113547","DOIUrl":"10.1016/j.solmat.2025.113547","url":null,"abstract":"<div><div>Reverse-bias stability in PV devices is critical to guarantee adequate reliability during sporadic shading instances or when deliberately applying reverse-bias in photodetection applications. Testing reverse-bias stability on PSCs is crucial in providing characterizing insights both into the current state and performance of such devices and also towards their iterative improvement. This paper describes reverse-bias stability testing of semi-transparent FAPbBr<sub>3</sub> perovskite solar cells. Stability against reverse-bias was extensively evaluated through both reverse-bias step-stress (RBSS) tests and constant-bias stress (CBS) tests at different voltage bias intensities. During a series of 10 ks tests, cells were revealed to be stable when operated down to −1.5 V (corresponding to approximately 20 % of the breakdown voltage threshold), whereas at −3 V the observed degradation mainly consists in a decrease in open-circuit voltage (from ∼1.5 ÷ 1.6 V to as low as 0.3 V) and parallel resistance (from ∼10<sup>8</sup> Ω to as low as ∼10<sup>2</sup> Ω), occurring after ∼100 s; a complete recovery is observed, if cells are left in resting conditions after removing the reverse-bias. The observed degradation is ascribed to a temporary shunt-like mechanism, triggered by ion and vacancy displacement and relocation, which causes a drastic energy-band distortion and internal potential compensation. Additional open-circuit voltage decay (OCVD) testing before and after stress reinforces this hypothesis. Reverse-bias step-stress testing until failure confirms that the mechanism occurs across the whole cell, leading to reverse-current magnitudes of over 300 mA/cm<sup>2</sup>.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113547"},"PeriodicalIF":6.3,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review on the utilization of industrial solid waste in thermal energy storage field 工业固体废弃物在热能储存领域的综合利用综述
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-09 DOI: 10.1016/j.solmat.2025.113562
Yaxuan Xiong , Miao He , Yuting Wu , Yanan Su , Meng Li , Meichao Yin , Aitonglu Zhang , Xiang Li , Shuo Li , Yang Yang , Xi Tian , Yulong Ding
{"title":"A comprehensive review on the utilization of industrial solid waste in thermal energy storage field","authors":"Yaxuan Xiong ,&nbsp;Miao He ,&nbsp;Yuting Wu ,&nbsp;Yanan Su ,&nbsp;Meng Li ,&nbsp;Meichao Yin ,&nbsp;Aitonglu Zhang ,&nbsp;Xiang Li ,&nbsp;Shuo Li ,&nbsp;Yang Yang ,&nbsp;Xi Tian ,&nbsp;Yulong Ding","doi":"10.1016/j.solmat.2025.113562","DOIUrl":"10.1016/j.solmat.2025.113562","url":null,"abstract":"<div><div>The utilization of industrial solid waste for thermal energy storage represents an innovative approach to address environmental challenges while advancing energy storage technologies. This review comprehensively examines the potential of industrial solid wastes, including coal fly ash, red mud, sewage sludge, gypsum, metallurgical slag, and waste concrete, as thermal energy storage materials. The discussion encompasses the material properties, preparation methods, and applications of industrial solid wastes in both sensible and composite heat storage systems. The study highlights their capacity for high-temperature stability, enhanced thermal conductivity, and phase change material integration, offering significant energy density improvements. Moreover, the review identifies challenges such as material heterogeneity and long-term thermal cycling performance. Strategies for industrial solid waste modification, encapsulation of phase change materials, and innovative composite designs are analyzed to enhance their applicability in sustainable thermal energy storage systems. This work aims to provide a foundation for future research and industrial applications, emphasizing the dual benefits of environmental protection and energy efficiency improvement.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113562"},"PeriodicalIF":6.3,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Active W-VO2-based Kirigami-structured films with digital control for energy efficient smart window 主动w - vo2基里伽米结构薄膜与数字控制节能智能窗口
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-08 DOI: 10.1016/j.solmat.2025.113551
Zhengjie Chen , Chengchen Feng , Lin Jiang , Yujie Ke , Xiaoxue Han , Xinghai Liu
{"title":"Active W-VO2-based Kirigami-structured films with digital control for energy efficient smart window","authors":"Zhengjie Chen ,&nbsp;Chengchen Feng ,&nbsp;Lin Jiang ,&nbsp;Yujie Ke ,&nbsp;Xiaoxue Han ,&nbsp;Xinghai Liu","doi":"10.1016/j.solmat.2025.113551","DOIUrl":"10.1016/j.solmat.2025.113551","url":null,"abstract":"<div><div>Smart window promises to enhance the building energy efficiency by dynamically controlling the indoor solar irradiation. In this study, a new thermochromic smart films for smart window applications were proposed. This film is based on polyvinylpyrrolidone (PVP)-coated tungsten-doped VO<sub>2</sub> (W-VO<sub>2</sub>) and polyurethane acrylate (PUA). It is demonstrated that the PVP-coating technique plays a vital role in improving the optical properties of the film and the dispersion of W-VO<sub>2</sub> in PUA. The optimized 3D-printed Kirigami-structured films exhibit favorable tensile properties and improved optical properties. Furthermore, an innovative device has been developed to enable automatic adjustment of the film stretch rate in response to the angle of sunlight, ensuring the smart window's dynamic response to sunlight. The film's solar transmittance varies between 48.50 % and 78.56 % during stretching, accompanied by a solar modulation up to 30.05 %. In the indoor and outdoor demo experiments, the temperature drops by 5.2 °C and 4.8 °C, respectively, compared to a PUA film window. The work developed a new film for energy-efficient smart windows and provides a systematic technological route from materials synthesis, structural optimization, system digital control, to practical demo assessment, which promises to facilitate the development of VO<sub>2</sub>-based materials and energy-efficient windows.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113551"},"PeriodicalIF":6.3,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143577650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study and mitigation of moisture-induced degradation in SHJ modules by modifying cell structure 通过改变细胞结构来研究和缓解SHJ模块中水分诱导的降解
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-07 DOI: 10.1016/j.solmat.2025.113557
Lucie Pirot-Berson , Romain Couderc , Romain Bodeux , Frédéric Jay , Paul Lefillastre , Julien Dupuis
{"title":"Study and mitigation of moisture-induced degradation in SHJ modules by modifying cell structure","authors":"Lucie Pirot-Berson ,&nbsp;Romain Couderc ,&nbsp;Romain Bodeux ,&nbsp;Frédéric Jay ,&nbsp;Paul Lefillastre ,&nbsp;Julien Dupuis","doi":"10.1016/j.solmat.2025.113557","DOIUrl":"10.1016/j.solmat.2025.113557","url":null,"abstract":"<div><div>Silicon heterojunction (SHJ) modules are known for their high efficiency and are expected to gain significant market share in the coming years. In terms of reliability, SHJ technology can be sensitive to moisture-induced degradation and sodium-induced degradation from sodium ions released from the glass. In these degradation mechanisms, the different layers of the SHJ cell structure could play an important role that needs to be understood. This work investigates the moisture-induced degradation in SHJ modules under damp heat (DH) by varying the cell structure with different types and thicknesses of transparent conductive oxide (TCO). Due to the migration of sodium ions, the thinner the TCO layer, the higher the degradation induced. The protective effect of dielectric capping layers is also investigated, allowing at the same time to reduce the indium consumption, which is a crucial issue for SHJ cells. These layers provide protection against degradation. Finally, a schematic model is proposed to summarize the degradation mechanisms, including the effect of cell structure on them.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113557"},"PeriodicalIF":6.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143563846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physics-informed machine learning for TCO-layer thickness prediction and process analysis from multi-spectral images 基于物理的机器学习用于多光谱图像的tco层厚度预测和过程分析
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-07 DOI: 10.1016/j.solmat.2025.113541
Alexandra Wörnhör, Saravana Kumar, Daniel Burkhardt, Jonas Schönauer, Sebastian Pingel, Ioan Voicu Vulcanean, Anamaria Steinmetz, Stefan Rein, Matthias Demant
{"title":"Physics-informed machine learning for TCO-layer thickness prediction and process analysis from multi-spectral images","authors":"Alexandra Wörnhör,&nbsp;Saravana Kumar,&nbsp;Daniel Burkhardt,&nbsp;Jonas Schönauer,&nbsp;Sebastian Pingel,&nbsp;Ioan Voicu Vulcanean,&nbsp;Anamaria Steinmetz,&nbsp;Stefan Rein,&nbsp;Matthias Demant","doi":"10.1016/j.solmat.2025.113541","DOIUrl":"10.1016/j.solmat.2025.113541","url":null,"abstract":"<div><div>We present a machine learning model for a robust and fast evaluation of thickness maps of Transparent Conducting Oxide (TCO) layers based on multichannel spectral images only. The model is applicable for the quality inspection of heterojunction solar cells with textured surfaces and an amorphous silicon layer stack beneath the TCO layer. Within our physics-informed approach, synthetic data are created online for model training by simulating reflection maps for given TCO thickness variations.</div><div>The developed method determines a full-scale TCO-thickness map in 1 s from inline measurable RGB image data. The spatially resolved analysis allows inline quality inspection of the thickness distributions. Additionally, the thickness profile at the edges is inspected with high spatial resolution in Silicon heterojunction solar cell precursors, where TCO edge exclusion at the rear side is required to avoid shunting. We demonstrate our approach by quantifying the completeness and masking area for narrow masks, which is a process optimization step for increasing cell efficiency. We derive sorting criteria for an early-stage process control regarding shunts and quantify the influence of the positioning accuracy of the mask on the short-circuit current.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113541"},"PeriodicalIF":6.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143563845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integration of aluminum contacts in TOPCon solar cells: A pathway to reduce silver usage TOPCon太阳能电池中铝触点的集成:减少银用量的途径
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-07 DOI: 10.1016/j.solmat.2025.113559
Yuhao Cheng , Yuchao Zhang , Yuwen Xu , Alex Stokes , Marwan Dhamrin , Shuo Deng , Lizhi Sun , Kosuke Tsuji , Jan Seidel , Daming Chen , Yifeng Chen , Martin Green , Ning Song
{"title":"Integration of aluminum contacts in TOPCon solar cells: A pathway to reduce silver usage","authors":"Yuhao Cheng ,&nbsp;Yuchao Zhang ,&nbsp;Yuwen Xu ,&nbsp;Alex Stokes ,&nbsp;Marwan Dhamrin ,&nbsp;Shuo Deng ,&nbsp;Lizhi Sun ,&nbsp;Kosuke Tsuji ,&nbsp;Jan Seidel ,&nbsp;Daming Chen ,&nbsp;Yifeng Chen ,&nbsp;Martin Green ,&nbsp;Ning Song","doi":"10.1016/j.solmat.2025.113559","DOIUrl":"10.1016/j.solmat.2025.113559","url":null,"abstract":"<div><div>The high silver consumption in Tunnel Oxide Passivated Contact (TOPCon) solar cells presents significant challenges regarding material costs and availability. This work demonstrates the feasibility of replacing silver (Ag) contacts with aluminum (Al) contacts on the rear side of industrial n-type TOPCon cells. Our findings indicate that specially formulated Al pastes effectively suppress excessive alloying with the poly-Si layer, achieving much lower contact recombination (J<sub>0, metal</sub>) compared to conventional Al pastes. The contact mechanisms between Al pastes and n<sup>+</sup> poly-Si layers under varying firing conditions were systematically investigated, leading to the identification of optimised firing conditions that achieve low contact resistivity (<span><math><mrow><msub><mi>ρ</mi><mi>c</mi></msub></mrow></math></span>) while maintaining high surface passivation quality. The rear-Al champion cell achieved a promising efficiency of 22.9 %, exhibiting a 0.8 % efficiency gap with the 23.7 % rear-Ag reference cell. Additionally, numerical simulation has identified key pathways to enhance rear-Al cell performance, providing a roadmap to achieve the efficiency of reference cells with Ag contacts. These findings highlight the potential for aluminum pastes as a cost-effective and sustainable alternative for significantly reducing silver consumption in terawatt-scale photovoltaic manufacturing.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113559"},"PeriodicalIF":6.3,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143563844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of environmental footprint: Life Cycle Assessment of Laboratory-scale thermal and chemical processes used for materials extraction from waste silicon solar panels 环境足迹评估:从废硅太阳能电池板中提取材料的实验室规模热和化学过程的生命周期评估
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-06 DOI: 10.1016/j.solmat.2025.113556
Chitra Sulkan , Prashant Kumar Thakur , Rebecca Yang , Sushil Kumar , Vivian WY. Tam , Cuong Tran
{"title":"Evaluation of environmental footprint: Life Cycle Assessment of Laboratory-scale thermal and chemical processes used for materials extraction from waste silicon solar panels","authors":"Chitra Sulkan ,&nbsp;Prashant Kumar Thakur ,&nbsp;Rebecca Yang ,&nbsp;Sushil Kumar ,&nbsp;Vivian WY. Tam ,&nbsp;Cuong Tran","doi":"10.1016/j.solmat.2025.113556","DOIUrl":"10.1016/j.solmat.2025.113556","url":null,"abstract":"<div><div>This study explores recycling methods for recovering valuable components from discarded silicon solar panels, focusing on high-temperature thermal treatment and chemical processing with toluene as a solvent. The environmental impacts of these methods were comprehensively investigated using a detailed Life Cycle Assessment (LCA). During thermal treatment, emissions were analyzed by adsorbing them onto quartz filter paper. XRF, TGA-DTG, and FT-IR analyses confirmed the presence of emitted elements, including Si, C, O, B, Na, Mg, Ca, K, P, S, Cl, and Fe, some of which could pose environmental and health risks. The LCA results revealed significant environmental trade-offs between the two approaches. The chemical method demonstrated superior material recovery and solvent management capabilities but had a higher carbon footprint and fossil fuel potential (5.42kg-eq) compared to thermal treatment (0.235kg-eq). Thermal treatment showed lower impacts on climate change, fossil fuel potential, water consumption, ecotoxicity, human toxicity, and particulate matter production but had more pronounced effects on ozone depletion and land use. Choosing between methods depends on specific environmental priorities. To achieve sustainable disposal and material recovery of solar panels, broader considerations including carbon emissions, resource utilization, and waste management strategies are crucial. This study provides insights to promote environmentally responsible practices in solar panel recycling.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113556"},"PeriodicalIF":6.3,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143563843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation on the combustion performance of single-glass and double-glazed photovoltaic modules 单、双层玻璃光伏组件燃烧性能的实验研究
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-06 DOI: 10.1016/j.solmat.2025.113528
Yue Wang , Shouxiang Wang , Qianyu Zhao
{"title":"Experimental investigation on the combustion performance of single-glass and double-glazed photovoltaic modules","authors":"Yue Wang ,&nbsp;Shouxiang Wang ,&nbsp;Qianyu Zhao","doi":"10.1016/j.solmat.2025.113528","DOIUrl":"10.1016/j.solmat.2025.113528","url":null,"abstract":"<div><div>In pursuit of ‘carbon peaking and carbon neutrality’ objectives, fire incidents have become increasingly common in photovoltaic power generation systems. The combustion performance of photovoltaic modules and EVA film directly influences the overall combustion behavior. To analyze the combustion performance of single-glass and double-glazed modules from leading brands in the market, this study conducted experimental tests using specialized devices such as Fire Propagation Apparatus (FPA) and Single Burning Item (SBI). These tests yielded photovoltaic module's parameters including ignition time and heat release rate. Analysis of the experimental results led to several conclusions. When exposed to thermal radiation, backsheet materials in single-glass modules were more prone to be ignited compared to glass plates, resulting in a broader horizontal flame spread. Double-glazed modules utilized fire-resistant glass instead of PET backsheets in single-glass modules, effectively reducing combustible content. Additionally, fire-resistant glass provided specific fire protection capabilities, making it more challenging for double-glazed modules to be ignited while also lowering total heat release post-ignition. Under similar glass material conditions, double-glazed modules exhibited superior combustion performance compared to their single-glass counterparts. Therefore, locations with high fire risks are recommended to opt for double-glazed photovoltaic modules. Based on these findings from combustion performance testing, this research provides valuable insights for selecting appropriate types of photovoltaic modules based on specific environmental considerations.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113528"},"PeriodicalIF":6.3,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143552182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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