Solar Energy Materials and Solar Cells最新文献

筛选
英文 中文
High-performance metasurface based daytime radiative cooler designed by random forest method 基于随机森林方法设计的高性能超表面日间辐射冷却器
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-19 DOI: 10.1016/j.solmat.2025.113591
Riaz Ali , Wei Su , Muhammad Ali , Ali Akhtar , Muhammad Usman , Zaib Ullah Khan
{"title":"High-performance metasurface based daytime radiative cooler designed by random forest method","authors":"Riaz Ali ,&nbsp;Wei Su ,&nbsp;Muhammad Ali ,&nbsp;Ali Akhtar ,&nbsp;Muhammad Usman ,&nbsp;Zaib Ullah Khan","doi":"10.1016/j.solmat.2025.113591","DOIUrl":"10.1016/j.solmat.2025.113591","url":null,"abstract":"<div><div>The consumption of fossil fuels is the primary source of the energy crisis and global warming, which have emerged as the world's most pressing issues. As time goes, the previous methods of designing radiative coolers are no longer viable due to the difficulty in achieving the desired performances. In this paper, the machine learning (ML) approach known as the Random Forest (RF) regression model is utilized to forecast and enhance the performance of a metasurface-based daytime radiative cooler. The proposed radiative cooler achieved an average absorptivity/emissivity of 99.69 % in the first atmospheric window (AW1) and 98.12 % in the second atmospheric window (AW2), with an Ultra-wide perfect absorption bandwidth of 19.9 μm. It is also estimated that the solar band has a reflection of 94.50 %. The Random Forest (RF) regression model has a Mean Absolute Percentage Error (MAPE) of 0.4955 %, which is far less than any other machine learning algorithms. Besides this, for better understanding of the absorption mechanism, the electric and magnetic fields distribution theory is investigated at different absorption peaks. Further the structure is polarization and incidence angle insensitive and show a good absorption performance even at larger angle of incidence. The proposed radiative cooler device got a net cooling power of 170.65 Wm<sup>-2</sup> at ambient temperature. This innovative method of enhancing the designing process might make the radiative cooler device considerably more precise.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113591"},"PeriodicalIF":6.3,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photon-enhanced thermionic emission devices with perovskite photovoltaic anodes for conversion of concentrated sunlight 钙钛矿光伏阳极的光子增强热离子发射装置,用于转换集中的太阳光
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-18 DOI: 10.1016/j.solmat.2025.113588
A. Bellucci , Y. Raoui , E. Bolli , M. Mastellone , R. Salerno , V. Valentini , R. Polini , A. Mezzi , A. Di Carlo , L. Vesce , D.M. Trucchi
{"title":"Photon-enhanced thermionic emission devices with perovskite photovoltaic anodes for conversion of concentrated sunlight","authors":"A. Bellucci ,&nbsp;Y. Raoui ,&nbsp;E. Bolli ,&nbsp;M. Mastellone ,&nbsp;R. Salerno ,&nbsp;V. Valentini ,&nbsp;R. Polini ,&nbsp;A. Mezzi ,&nbsp;A. Di Carlo ,&nbsp;L. Vesce ,&nbsp;D.M. Trucchi","doi":"10.1016/j.solmat.2025.113588","DOIUrl":"10.1016/j.solmat.2025.113588","url":null,"abstract":"<div><div>Perovskite photovoltaic (PV) structures have been applied for the first time as anodes in photon-enhanced thermionic emission (PETE) devices to collect electrons as well as to photoelectrically convert the radiation emitted from high temperature silicon/diamond cathodes. Hybrid PETE-PV devices have been tested under concentrated sunlight, reaching the maximum cathode temperature of 650 °C. Experiments show that the PV anodes can operate without damage up to a cathode temperature of 560 °C, corresponding to an approximate surface anode temperature of 130 °C. The proposed converters in a 2-terminals configuration confirm an output voltage boost with respect to the mere PETE converters. Additionally, an effective reduction of the anode work function between 0.45 and 0.6 eV is achieved by depositing a 20 nm-thick scandium oxide coating. Even if the materials used for these proof-of-concept experiments are not optimized for the investigated operating temperature range, this study highlights the feasibility of using perovskites as photovoltaic anodes in PETE devices for the conversion of the concentrated solar radiation, thus opening the path for future development of the concept to large-area and low production cost perovskite PV-based structures in thermionic-based energy converters.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113588"},"PeriodicalIF":6.3,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143643860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spectrum-tailorable two-dimensional silicon–titanium nitride selective emitter by photon recycling for thermophotovoltaic applications 热光伏应用中光子回收的可定制光谱的二维硅-氮化钛选择性发射器
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-17 DOI: 10.1016/j.solmat.2025.113560
Xiaoqi Zhou , Man Zhang , Shengyu Sun, Yixin Sun, Zhongyan Li, Shipei Zhang, Xiawa Wang
{"title":"Spectrum-tailorable two-dimensional silicon–titanium nitride selective emitter by photon recycling for thermophotovoltaic applications","authors":"Xiaoqi Zhou ,&nbsp;Man Zhang ,&nbsp;Shengyu Sun,&nbsp;Yixin Sun,&nbsp;Zhongyan Li,&nbsp;Shipei Zhang,&nbsp;Xiawa Wang","doi":"10.1016/j.solmat.2025.113560","DOIUrl":"10.1016/j.solmat.2025.113560","url":null,"abstract":"<div><div>Thermophotovoltaic (TPV) systems have gained attention for their ability to convert radiant energy from heat sources into electricity. One major challenge is fabricating a spectrum-tailorable selective emitter with high performance at elevated temperatures. In this study, two-dimensional (2D) silicon-titanium nitride (Si–TiN) photonic crystals (PhCs) with TiN-coated Si cavities were fabricated using nanosphere lithography (NSL). The lossy nature and high reflectivity of TiN in the long-wavelength range allow the Si–TiN PhC to achieve up to <span><math><mo>∼</mo></math></span>92% broadband optical emissivity (200 nm – cut-off wavelength) while minimizing heat radiation to <span><math><mo>∼</mo></math></span>27% in the long-wavelength range (5 – 10<span><math><mrow><mspace></mspace><mi>μ</mi><mi>m</mi></mrow></math></span>). More importantly, thanks to the isotropy of the NSL method based on oxygen plasma etching (OPE), different periods and radius of the Si–TiN PhC can be achieved by controlling the OPE time or the initial polystyrene sphere diameter. This enables precise control over the cut-off wavelength and emission spectrum to match various PV cells. The 2D Si–TiN PhC produced 3.13 times more power than a flat Si emitter. This approach provides a promising path forward for enhancing TPV system performance and practical applications.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113560"},"PeriodicalIF":6.3,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143631950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic optimization analysis of droplet cleaning efficiency on photovoltaic surfaces through volume regulation and dust removal dynamic mechanism 基于体积调节和除尘动力学机制的光伏表面液滴清洁效率协同优化分析
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-17 DOI: 10.1016/j.solmat.2025.113570
Chengtao Yan , Dong Zhang , Luyuan Gong , Denghui Zhao , Zhuorui Li
{"title":"Synergistic optimization analysis of droplet cleaning efficiency on photovoltaic surfaces through volume regulation and dust removal dynamic mechanism","authors":"Chengtao Yan ,&nbsp;Dong Zhang ,&nbsp;Luyuan Gong ,&nbsp;Denghui Zhao ,&nbsp;Zhuorui Li","doi":"10.1016/j.solmat.2025.113570","DOIUrl":"10.1016/j.solmat.2025.113570","url":null,"abstract":"<div><div>Dust accumulation on photovoltaic (PV) modules can result in significant energy losses. While conventional cleaning methods require amounts of water, the application of droplets cleaning technology on superhydrophobic surfaces offers a more sustainable solution. Our study presents an investigation into the optimization of droplet cleaning efficiency on superhydrophobic PV glass by regulating droplet volume. The study explored the dynamics of droplet motion and critical dust carrying capacity, introduced a quantitative relationship between droplet volume and dust removal efficiency, systematically analyzed droplet dynamics and dust entrainment mechanism, and revealed three findings: (1) The dust carrying motion of the droplet exhibits two distinct motion stages, from accelerated linear motion to trailing state triggered by saturated dust capacity (4.8 mg, 5.9 mg, and 6.2 mg for 10, 30, 50 μL droplets). (2) Post trailing velocity declines sharply by 84.90 %, 53.66 %, and 41.81 % for 10, 30, 50 μL droplets. (3) A linear volume efficiency relationship is established, where 50 μL droplets achieve 28 % dust removal efficiency (14 mg capacity), with each 1 μL volume increment enhancing mass removal by 0.28 mg and efficiency by 6.25 %. Our research optimizes the self-cleaning technology of photovoltaic module. Research results are expected to further improve the cleaning efficiency and water saving advantages of the droplet cleaning method, which is essential for the sustainability of solar systems, especially in water-scarce regions.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113570"},"PeriodicalIF":6.3,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143642508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal stability and corrosion characteristic analysis of low melting point ternary molten salt for thermal energy storage 蓄热用低熔点三元熔盐的热稳定性及腐蚀特性分析
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-16 DOI: 10.1016/j.solmat.2025.113587
Heya Na , Cancan Zhang , Yuting Wu , Guoqiang Wang , Guang Bao , Yuanwei Lu
{"title":"Thermal stability and corrosion characteristic analysis of low melting point ternary molten salt for thermal energy storage","authors":"Heya Na ,&nbsp;Cancan Zhang ,&nbsp;Yuting Wu ,&nbsp;Guoqiang Wang ,&nbsp;Guang Bao ,&nbsp;Yuanwei Lu","doi":"10.1016/j.solmat.2025.113587","DOIUrl":"10.1016/j.solmat.2025.113587","url":null,"abstract":"<div><div>Molten salt is used as an important heat transfer and storage medium in thermal energy storage application. Thermal stability as well as corrosion characteristic are important for system safe operation. In this paper, a low melting point ternary hybrid salt was prepared and subjected to 1000h of constant temperature experiments and 1000h of static corrosion experiments on 304 at a high temperature of 600 °C. The results show that the low melting point mixed salt has a melting point of 143.1 °C, an initial crystal point of 136.1 °C, a decomposition temperature of 666.8 °C, and an average specific heat and thermal conductivity of 1.45 J g<sup>−1</sup>k<sup>−1</sup> and 0.34 W m<sup>−1</sup>K<sup>−1</sup>. After a constant temperature of 1000 h at 600 °C, the melting point and initial crystal point have increased by 38 % and 49 %, the decomposition temperature has decreased by 8 %, and the specific heat and thermal conductivity have increased by 0.7 % and 0.3 %, respectively, compared with the base salt. 0.3 %. The weight loss per unit volume after 1000h of static corrosion was 6.2 mg cm<sup>−2</sup> and the annual corrosion rate was 0.068 mm y<sup>−1</sup>.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113587"},"PeriodicalIF":6.3,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143629148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of CH3COONa·3H2O-Glycine-KCl composite phase change material for the swimming pool heating system 游泳池供热系统用CH3COONa·3h2o -甘氨酸- kcl复合相变材料的研制
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-15 DOI: 10.1016/j.solmat.2025.113574
Tao Xu , Fuyu Qin , Jiaming Zhang , Zhidong Li , Shen Wei , Lingzhi Zhong , Yue Han , Ximin Lin , Junyi Wei , Yi Yang , Weitao Shao
{"title":"Development of CH3COONa·3H2O-Glycine-KCl composite phase change material for the swimming pool heating system","authors":"Tao Xu ,&nbsp;Fuyu Qin ,&nbsp;Jiaming Zhang ,&nbsp;Zhidong Li ,&nbsp;Shen Wei ,&nbsp;Lingzhi Zhong ,&nbsp;Yue Han ,&nbsp;Ximin Lin ,&nbsp;Junyi Wei ,&nbsp;Yi Yang ,&nbsp;Weitao Shao","doi":"10.1016/j.solmat.2025.113574","DOIUrl":"10.1016/j.solmat.2025.113574","url":null,"abstract":"<div><div>With the improvement of modern living standards, the number of indoor and outdoor swimming pools has increased. However, the high energy consumption and heating costs in winter do not align with the requirements of green development. Therefore, in this study, a novel Composite Phase Change Material (CPCM) was developed to be integrated with a solar-air source heat pump swimming pool heating system. This system aims to provide longer heating durations and reduce temperature fluctuations, while also alleviating the pressure on national energy supply during peak energy consumption. Glycine (Gly) and potassium chloride (KCl) were combined with sodium acetate trihydrate (SAT) to prepare a shape-stabilized CPCM (SAT- Gly- KCl CPCM). It was integrated into a swimming pool heating system to justify the impact of the new material. Experimental results have demonstrated some major properties of this material, the melting point, latent heat value and supercooling degree were 40.3 °C, 274.4 J/g and 1.36 °C for the laboratory preparation, and 40.9 °C, 249.5 J/g and 1.42 °C for the large-scale preparation, respectively. The material also exhibited good stability and thermal reliability. When SAT-Gly-KCl CPCM was applied to a swimming pool heating system, it was found that 100 and 200 phase change thermal storage modules increased heating durations by 9.89 and 10.59 times, respectively, compared to the control group. Therefore, the SAT-Gly-KCl CPCM presents a promising solution for swimming pool heating systems. This study contributes to the further development and application of CPCMs in such systems, offering improved energy efficiency and stability.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113574"},"PeriodicalIF":6.3,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143629152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The photovoltaic Dyson sphere 光伏戴森球
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-15 DOI: 10.1016/j.solmat.2025.113589
Ian Marius Peters
{"title":"The photovoltaic Dyson sphere","authors":"Ian Marius Peters","doi":"10.1016/j.solmat.2025.113589","DOIUrl":"10.1016/j.solmat.2025.113589","url":null,"abstract":"<div><div>This study explores the concept of a photovoltaic Dyson sphere, a megastructure designed to capture and convert a star's energy for use in advanced technological applications. The temperature of a Dyson sphere composed of both blackbody and grey body materials is investigated. For efficient photovoltaic conversion, the semiconductor sphere must be coated with a black material to regulate temperature, ensuring it remains low enough for photovoltaic generation. The environmental impact on planetary conditions is also analyzed, revealing that only a Dyson sphere with an extension beyond Earth's orbit could allow life to persist on Earth while maintaining suitable temperatures for photovoltaic efficiency. Such a structure would still increase Earth’s temperature, necessitating planetary temperature control systems—an issue that parallels the challenges of mitigating global warming. Considering material availability in the solar system, it was found that a partial Dyson sphere at 2.13 AU, using 1.3 × 10<sup>23</sup> kg of silicon, could generate 4 % of the Sun’s power, yielding 15.6 YW of electricity while increasing temperature on Earth by less than 3K.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113589"},"PeriodicalIF":6.3,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143629489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-interface porous coating for efficient sub-ambient daytime radiative cooling 多界面多孔涂层,高效亚环境白天辐射冷却
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-14 DOI: 10.1016/j.solmat.2025.113577
Cheng Jin , Wenshuo Zhang , Jiahao Ni , Lanxin Li , Yong Hao , Gang Pei , Bin Zhao
{"title":"Multi-interface porous coating for efficient sub-ambient daytime radiative cooling","authors":"Cheng Jin ,&nbsp;Wenshuo Zhang ,&nbsp;Jiahao Ni ,&nbsp;Lanxin Li ,&nbsp;Yong Hao ,&nbsp;Gang Pei ,&nbsp;Bin Zhao","doi":"10.1016/j.solmat.2025.113577","DOIUrl":"10.1016/j.solmat.2025.113577","url":null,"abstract":"<div><div>Daytime radiative cooling can achieve a sub-ambient phenomenon passively, holding great promise for energy-saving applications. Polymer coating based on the Mie scattering effect has been widely developed for efficient daytime radiative cooling due to its scalable potential. However, current studies mainly concentrate on the properties of a single scattering interface, neglecting the potential synergistic effects among multiple scattering interfaces. Consequently, we develop a multi-interface porous radiative cooling coating (MIPRC coating) for efficient sub-ambient radiative cooling relying on the emulsion templating method. MIPRC coating consists of three kinds of interfaces with refractive index gradient for photon scattering, including air/polymer, SiO<sub>2</sub> particle/polymer, and air/SiO<sub>2</sub> particle, resulting in a high solar reflectivity of 97.6 % and an emissivity of 0.964 within the atmospheric window. In radiative cooling experiments, the MIPRC coating achieved a minimum temperature reduction of 5.0 °C below ambient during daytime, and a maximum temperature reduction of 16.0 °C below ambient at nighttime. The corresponding maximum radiative cooling power reached 61.0 W m<sup>−2</sup> during the day and 105.5 W m<sup>−2</sup> at night. When the MIPRC coating is applied to a foam roof and exposed to ambient air, a roof temperature of 1.2 °C below the ambient under an average solar irradiance of 900W·m<sup>−2</sup> is achieved. Building energy-saving measures within 25.8 %–84.6 % can be achieved by applying MIPRC coating in Haikou, Nairobi, Singapore, Miami, and Hawaii. This work provides an untapped perspective on designing highly efficient radiative cooling coatings.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113577"},"PeriodicalIF":6.3,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143629490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects and mechanisms of argon flow rate on the quality of cast multicrystalline silicon 氩气流量对铸态多晶硅质量的影响及其机理
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-14 DOI: 10.1016/j.solmat.2025.113572
Liang He , Yunfei Xu , Zuozuo Wu , Zhenchao Hong , Hongzhi Luo , Jianmin Li , Qi Lei , Xiaojuan Cheng , Fahui Wang , Shengquan Gan , Shuai Yuan
{"title":"Effects and mechanisms of argon flow rate on the quality of cast multicrystalline silicon","authors":"Liang He ,&nbsp;Yunfei Xu ,&nbsp;Zuozuo Wu ,&nbsp;Zhenchao Hong ,&nbsp;Hongzhi Luo ,&nbsp;Jianmin Li ,&nbsp;Qi Lei ,&nbsp;Xiaojuan Cheng ,&nbsp;Fahui Wang ,&nbsp;Shengquan Gan ,&nbsp;Shuai Yuan","doi":"10.1016/j.solmat.2025.113572","DOIUrl":"10.1016/j.solmat.2025.113572","url":null,"abstract":"<div><div>Cast multicrystalline silicon is a well-established crystal growth technique, widely utilized not only as a direct material for photovoltaic cells but also as an effective method for purifying low-purity silicon feedstock. This study, based on a mature industrial process for small-grain cast multicrystalline silicon, examines the impact of varying argon flow rates on material quality. Increasing the argon flow rate enhances heat transfer, reducing crystal growth time, and strengthens melt convection, which mitigates residual stress. Consequently, this reduces the concentration of detrimental defects, extends carrier recombination lifetime, and improves purification efficiency. Furthermore, a higher argon flow rate effectively lowers interstitial oxygen content in the cast silicon. However, excessively high flow rates may compromise the crucible coating, introducing additional contaminants and inclusions into the crystal.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113572"},"PeriodicalIF":6.3,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143620832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of PV panel recycling process enabling complete recyclability of end-of-life silicon photovoltaic panels 开发光伏板回收工艺,使报废硅光伏板完全可回收
IF 6.3 2区 材料科学
Solar Energy Materials and Solar Cells Pub Date : 2025-03-14 DOI: 10.1016/j.solmat.2025.113571
Pradeep Padhamnath , Srinath Nalluri , Filip Kuśmierczyk , Mateusz Kopyściański , Joanna Karbowniczek , Tomasz Kozieł , Shin Woei Leow , Thomas Reindl
{"title":"Development of PV panel recycling process enabling complete recyclability of end-of-life silicon photovoltaic panels","authors":"Pradeep Padhamnath ,&nbsp;Srinath Nalluri ,&nbsp;Filip Kuśmierczyk ,&nbsp;Mateusz Kopyściański ,&nbsp;Joanna Karbowniczek ,&nbsp;Tomasz Kozieł ,&nbsp;Shin Woei Leow ,&nbsp;Thomas Reindl","doi":"10.1016/j.solmat.2025.113571","DOIUrl":"10.1016/j.solmat.2025.113571","url":null,"abstract":"<div><div>The cumulative PV panel waste is expected to reach ≈8 million tonnes by 2030 and ≈ 80 million tonnes by 2050. This presents an opportunity to pursue new avenues in terms of recycling and improving the circularity of the PV panels. In this work we present experimental results for recycling c-Si PV panels using recently developed electrohydraulic shock-wave fragmentation (EHF) of PV panels. The EHF process allows for the recovery of all materials used in the manufacturing of PV panels. We use different types of panels for the recycling process and analyse the material recoverability in each condition. Further, we analyse the effectiveness of chemical treatment in isolating metals from the silicon obtained from recycled c-Si PV panels, providing an opportunity of recovering high quality metal and silicon. The separation process allows for the high-quality material recovery and could potentially improve the economic feasibility of the overall recycling process.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"286 ","pages":"Article 113571"},"PeriodicalIF":6.3,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143620833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信