Progress in Energy and Combustion Science最新文献

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Ammonia pyrolysis and oxidation chemistry 氨热解和氧化化学
IF 32 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-08-23 DOI: 10.1016/j.pecs.2024.101177
Manuel Monge-Palacios , Xiaoyuan Zhang , Natalia Morlanes , Hisashi Nakamura , Giuseppe Pezzella , S. Mani Sarathy
{"title":"Ammonia pyrolysis and oxidation chemistry","authors":"Manuel Monge-Palacios ,&nbsp;Xiaoyuan Zhang ,&nbsp;Natalia Morlanes ,&nbsp;Hisashi Nakamura ,&nbsp;Giuseppe Pezzella ,&nbsp;S. Mani Sarathy","doi":"10.1016/j.pecs.2024.101177","DOIUrl":"10.1016/j.pecs.2024.101177","url":null,"abstract":"<div><p>Ammonia has been essential to human activities for centuries. It is widely used as feedstock for fertilizers, industrial chemicals, and emission after-treatment systems. Owing to its properties, ammonia has garnered interest as a carrier for hydrogen in energy applications. It can be generated from carbon-free emission sources and pyrolyzed to produce pure hydrogen for various applications. The combustion of ammonia for power generation has been previously reviewed in this journal besides several aspects of ammonia oxidation chemistry, as it relates to emission after-treatment and reburn systems. However, the pyrolysis and oxidation chemistry of ammonia requires further elucidation to improve its use as a hydrogen carrier and as a fuel for combustion systems. This article provides an in-depth review of ammonia pyrolysis and oxidation chemistry in noncatalytic and catalytic systems. The catalytic pyrolysis chemistry of ammonia to produce pure hydrogen is reviewed to understand catalyst and reactor requirements for scaling up this technology. The combustion properties of ammonia as a pure fuel and in mixtures, including ignition, flame propagation, and extinction characteristics; its pyrolysis and oxidation reactions; and its potential to produce pollutant emissions are extensively reviewed. Ammonia combustion reaction mechanisms are reported based on results from pyrolysis and oxidation reactors, shock tubes, rapid compression machines, and research engines. The experimental work is complemented by the development of detailed combustion models via chemical kinetic and quantum chemistry simulations. Herein, recent results on ammonia pyrolysis and oxidation chemistry are introduced and summarized by highlighting the pertinent aspects of this rich and rapidly increasing body of information.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"105 ","pages":"Article 101177"},"PeriodicalIF":32.0,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142049668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The potential of RuBisCO in CO2 capture and utilization RuBisCO 在二氧化碳捕获和利用方面的潜力
IF 32 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-08-12 DOI: 10.1016/j.pecs.2024.101184
Kamyll Dawn Cocon , Patricia Luis
{"title":"The potential of RuBisCO in CO2 capture and utilization","authors":"Kamyll Dawn Cocon ,&nbsp;Patricia Luis","doi":"10.1016/j.pecs.2024.101184","DOIUrl":"10.1016/j.pecs.2024.101184","url":null,"abstract":"<div><p>Carbon capture technology is currently considered one of the promising technologies to mitigate atmospheric CO<sub>2</sub> concentration. CO<sub>2</sub> capture and utilization (CCU) captures anthropogenic waste CO<sub>2</sub> and valorizes it into useful products, supporting a circular transition pathway towards carbon neutrality. Unfortunately, the thermodynamic stability of CO<sub>2</sub> requires a high-energy input for its conversion, resulting in processes with a net positive carbon footprint. The incorporation of enzymes as biocatalysts in a process is attractive, as it facilitates CO<sub>2</sub> conversion under ambient conditions. In Nature, the conversion of CO<sub>2</sub> into organic compounds is done through photosynthesis, using an enzyme called ribulose-1,5-biphosphate carboxylase/oxygenase (RuBisCO). RuBisCO plays a central role in the natural assimilation of CO<sub>2</sub>, making it the enzyme chosen in Nature upon which all life forms depend. However, the slow carboxylation rate of RuBisCO (1–10/s) has caused it to be overlooked by faster enzymes such as carbonic anhydrase (CA), which has a carboxylation rate of 10<sup>6</sup>/s. Despite this, RuBisCO has a rate enhancement of 10<sup>8</sup> to 10<sup>10</sup> times higher than CA. Thus, this review aims to take a closer look at RuBisCO and examine its potential in CCU. Various aspects are considered, such as RuBisCO’s performance in comparison to other enzymes, approaches to overcome its limitations, its applications and implications in CCU, the valuable chemicals that can be derived from it, recent developments in RuBisCO-integrated processes, and its economic and environmental considerations. Through this, RuBisCO’s potential as one of the key enzymes in CCU will be explored.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"105 ","pages":"Article 101184"},"PeriodicalIF":32.0,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141979773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional fluidized bed reactors for process intensification 用于强化工艺的多功能流化床反应器
IF 32 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-07-26 DOI: 10.1016/j.pecs.2024.101176
D. Zapater , S.R. Kulkarni , F. Wery , M. Cui , J. Herguido , M. Menendez , G.J. Heynderickx , K.M. Van Geem , J. Gascon , P. Castaño
{"title":"Multifunctional fluidized bed reactors for process intensification","authors":"D. Zapater ,&nbsp;S.R. Kulkarni ,&nbsp;F. Wery ,&nbsp;M. Cui ,&nbsp;J. Herguido ,&nbsp;M. Menendez ,&nbsp;G.J. Heynderickx ,&nbsp;K.M. Van Geem ,&nbsp;J. Gascon ,&nbsp;P. Castaño","doi":"10.1016/j.pecs.2024.101176","DOIUrl":"10.1016/j.pecs.2024.101176","url":null,"abstract":"<div><p>Fluidized bed reactors (FBRs) are crucial in the chemical industry, serving essential roles in gasoline production, manufacturing materials, and waste treatment. However, traditional up-flow FBRs have limitations in applications where rapid kinetics, catalyst deactivation, sluggish mass/heat transfer processes, particle erosion or agglomeration (clustering) occur. This review investigates multifunctional FBRs that can function in multiple ways and intensify processes. These reactors can reduce reaction steps and costs, enhance heat and mass transfer, make processes more compact, couple different phenomena, improve energy efficiency, operate in extreme fluidized regimes, have augmented throughput, or solve problems inherited by traditional reactor configurations. They address constraints associated with conventional counterparts and contribute to favorable energy, fuels, and environmental footprints. These reactors can be classified as two-zone, vortex, and internal circulating FBRs, with each concept summarized, including their advantages, disadvantages, process applicability, intensification, visualization, and simulation work. This discussion also includes shared considerations for these reactor types, along with perspectives on future advancements and opportunities for enhancing their performance.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"105 ","pages":"Article 101176"},"PeriodicalIF":32.0,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0360128524000340/pdfft?md5=f1cacfb5a9ad528cdeb178943af719ae&pid=1-s2.0-S0360128524000340-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141950288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances and challenges of the Conditional Source-term Estimation model for turbulent reacting flows 湍流反应流条件源项估计模型的进展与挑战
IF 32 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-07-10 DOI: 10.1016/j.pecs.2024.101172
M. Mahdi Salehi , Cecile Devaud , W. Kendal Bushe
{"title":"Advances and challenges of the Conditional Source-term Estimation model for turbulent reacting flows","authors":"M. Mahdi Salehi ,&nbsp;Cecile Devaud ,&nbsp;W. Kendal Bushe","doi":"10.1016/j.pecs.2024.101172","DOIUrl":"https://doi.org/10.1016/j.pecs.2024.101172","url":null,"abstract":"<div><p>Conditional Source-term Estimation (CSE) is a turbulence–chemistry interaction model to simulate reacting flows. This model is similar to the Conditional Moment Closure (CMC) approach in using the conditional scalar field to calculate the conditional reaction rates. However, unlike CMC, where transport equations are solved for the conditional scalars, an integral equation is inverted in CSE to estimate the conditional scalars. The model has been developed and applied to a wide range of combustion regimes, including diffusion, premixed, stratified premixed, mixed-mode combustion in lifted flames, spray combustion and MILD combustion in the past two decades. It has been tested against several Direct Numerical Simulation (DNS) databases in <em>a priori</em> analyses and also coupled with both Large-Eddy Simulation (LES) and Reynolds-Averaged Navier–Stokes (RANS) flow solvers to simulate benchmark burners. The CSE model has also been used in the simulation of practical combustion devices such as internal combustion engines and industrial furnaces. In this paper, the fundamental basis of the CSE model is first presented, and the model’s limitations and strengths are described. The challenges of the application of CSE to different combustion regimes are discussed through a comprehensive review of the past published works. Mathematical and numerical implementation techniques are presented, and future challenges in developing this turbulence–chemistry interaction model are also proposed.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"104 ","pages":"Article 101172"},"PeriodicalIF":32.0,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141596746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure-performance relationships in MOF-derived electrocatalysts for CO2 reduction 源自 MOF 的二氧化碳还原电催化剂的结构-性能关系
IF 32 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-07-08 DOI: 10.1016/j.pecs.2024.101175
Ziman Chen , Yuman Guo , Lin Han , Jian Zhang , Yi Liu , Jan Baeyens , Yongqin Lv
{"title":"Structure-performance relationships in MOF-derived electrocatalysts for CO2 reduction","authors":"Ziman Chen ,&nbsp;Yuman Guo ,&nbsp;Lin Han ,&nbsp;Jian Zhang ,&nbsp;Yi Liu ,&nbsp;Jan Baeyens ,&nbsp;Yongqin Lv","doi":"10.1016/j.pecs.2024.101175","DOIUrl":"https://doi.org/10.1016/j.pecs.2024.101175","url":null,"abstract":"<div><p>Metal-organic frameworks (MOFs) hold great potential as electrocatalysts for the reduction of carbon dioxide (CO<sub>2</sub>), due to their highly tunable and porous structures. However, unlocking their full potential necessitates a comprehensive understanding of structure-performance relationships to guide rational design. This review provides a meticulous analysis of MOF electrocatalysts for electrocatalytic CO<sub>2</sub> reduction (ECR), emphasizing correlations between composition, morphology, and catalytic performance. Key structure-function aspects are explored across various MOF-derived materials, encompassing the impact of metal identity, organic linker chemistry, porosity, defect concentration, and particle morphology. Physicochemical properties related to substrate adsorption and active site availability are linked to catalytic activities, product selectivities, energy efficiencies, and overpotentials. The review identifies several performance-limiting factors, including suboptimally tuned active sites and weak structure-selectivity linkages. However, the modular nature of MOFs presents opportunities to address these challenges through synthetic tuning. Future prospects, involving advanced characterization techniques, are also discussed. Finally, a separate section is devoted to the potential (industrial) valorization of the process. This critical review aims to distill guiding principles for design and optimization from existing trends, facilitating the development of MOF electrocatalysts capable of driving sustainable CO<sub>2</sub> reduction at industrial scales. The realization of this promising technology holds the potential to provide renewable fuels and mitigate climate change through carbon capture and conversion utilizing intermittent renewable energy sources.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"104 ","pages":"Article 101175"},"PeriodicalIF":32.0,"publicationDate":"2024-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141596745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Premixed flame ignition: Theoretical development 预混合火焰点火:理论发展
IF 32 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-07-06 DOI: 10.1016/j.pecs.2024.101174
Dehai Yu , Zheng Chen
{"title":"Premixed flame ignition: Theoretical development","authors":"Dehai Yu ,&nbsp;Zheng Chen","doi":"10.1016/j.pecs.2024.101174","DOIUrl":"https://doi.org/10.1016/j.pecs.2024.101174","url":null,"abstract":"<div><p>Premixed flame ignition is a fundamental issue in combustion. A basic understanding of this phenomenon is crucial for fire safety control and for the development of advanced combustion engines. Significant efforts have been devoted to understanding the mechanisms of ignition and determining critical ignition conditions, such as critical flame radius, minimum ignition energy, and minimum ignition power, which have remained challenging research topics for centuries. This review provides an in-depth investigation of the forced-ignition of laminar premixed flames in a quiescent flammable mixture, with emphasis on theoretical developments, particularly those based on activation energy analysis. First, the fundamental concepts are overviewed, including spark ignition, characteristic time scales, and critical ignition conditions. Then, the chronological development of premixed flame ignition theories is discussed, including homogeneous explosion, thermal ignition theory, flame ball theory, quasi-steady ignition theory, and, more importantly, transient ignition theory. Premixed flame ignition consists of three stages: flame kernel formation, flame kernel expansion, and transition to a self-sustaining flame. These stages are profoundly affected by the coupling of positive stretch with preferential diffusion, characterized by the Lewis number. Specifically, positive stretch makes the expanding ignition kernel weaker at larger Lewis numbers, consequently increasing the critical ignition radius and MIE. The premixed flame ignition process is dominated by flame propagation dynamics. Both quasi-steady and transient ignition theories demonstrate that the critical flame radius for premixed ignition differs from either flame thickness (by thermal ignition theory) or flame ball radius (by flame ball theory). Particularly, the transient ignition theory appropriately acknowledges the “memory effect” of external heating, offering the most accurate description of the evolution of the ignition kernel and the most sensible evaluation of minimum ignition energy. In addition, the effects of transport and chain-branching reactions of radicals, finite droplet vaporization, and repetitive heating pulses on premixed flame ignition are discussed. Finally, a summary of major advances is provided, along with comments on the applications of premixed flame ignition theory in ignition enhancement. Suggested directions for future research are presented.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"104 ","pages":"Article 101174"},"PeriodicalIF":32.0,"publicationDate":"2024-07-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141596744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential of oxymethylene ethers as renewable diesel substitute 氧亚甲基醚作为可再生柴油替代品的潜力
IF 32 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-07-01 DOI: 10.1016/j.pecs.2024.101173
Heinz Pitsch , Dominik Goeb , Liming Cai , Werner Willems
{"title":"Potential of oxymethylene ethers as renewable diesel substitute","authors":"Heinz Pitsch ,&nbsp;Dominik Goeb ,&nbsp;Liming Cai ,&nbsp;Werner Willems","doi":"10.1016/j.pecs.2024.101173","DOIUrl":"https://doi.org/10.1016/j.pecs.2024.101173","url":null,"abstract":"<div><p>Oxymethylene ethers (OME<sub>x</sub>), are a promising renewable replacement fuel for compression ignition engines. OME<sub>x</sub> are largely compatible with current engines, can help to significantly reduce engine-out and tail-pipe emissions while simultaneously reducing the transport sector’s net carbon emissions by gradually replacing fossil diesel fuel. This paper aims to compile and critically review recent research progress on OME<sub>x</sub>, following the entire value chain from production to engine application. First, pathways for OME<sub>x</sub> production are compiled and compared regarding energy efficiency, fuel production costs and life cycle CO<sub>2</sub> balance, showcasing advantages and disadvantages of more advanced production pathways with reduced hydrogen consumption. On the application side, chemical kinetics play a fundamental role in understanding OME<sub>x</sub> combustion. Recent progress in understanding the decomposition and combustion of OME<sub>x</sub> is discussed and resulting detailed chemical reaction mechanisms from the literature are investigated regarding their accuracy and capabilities. Furthermore, the liquid fuel properties of OME<sub>x</sub> are presented and compared with conventional fossil diesel fuel as well as selected other renewable and surrogate fuels, pointing out possible issues and potentials for engine application. In particular, material compatibility is discussed, and suitable sealing materials are identified. Subsequently, the application of OME<sub>x</sub> in CI engines is discussed in detail, including the fuel’s potential for engine efficiency increase and significant decrease in engine-out particulate and NO<sub>x</sub> emissions. Necessary and possible changes to engine design and control, such as longer injection duration or larger injector holes, are outlined. Finally, on a high level, the potential for large-scale application of e-fuels such as OME<sub>x</sub> is discussed, and necessary political incentives are pointed out.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"104 ","pages":"Article 101173"},"PeriodicalIF":32.0,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0360128524000315/pdfft?md5=515f252e3a1a631d0d40ed5f984fdc1b&pid=1-s2.0-S0360128524000315-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141483610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nano-enhanced phase change materials: Fundamentals and applications 纳米增强相变材料:基本原理与应用
IF 29.5 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-06-17 DOI: 10.1016/j.pecs.2024.101162
Zafar Said , A.K. Pandey , Arun Kumar Tiwari , B. Kalidasan , Furqan Jamil , Amrit Kumar Thakur , V.V. Tyagi , Ahmet Sarı , Hafiz Muhammad Ali
{"title":"Nano-enhanced phase change materials: Fundamentals and applications","authors":"Zafar Said ,&nbsp;A.K. Pandey ,&nbsp;Arun Kumar Tiwari ,&nbsp;B. Kalidasan ,&nbsp;Furqan Jamil ,&nbsp;Amrit Kumar Thakur ,&nbsp;V.V. Tyagi ,&nbsp;Ahmet Sarı ,&nbsp;Hafiz Muhammad Ali","doi":"10.1016/j.pecs.2024.101162","DOIUrl":"https://doi.org/10.1016/j.pecs.2024.101162","url":null,"abstract":"&lt;div&gt;&lt;p&gt;Phase Change Materials (PCMs) enable thermal energy storage in the form of latent heat during phase transition. PCMs significantly improve the efficiency of solar power systems by storing excess energy, which can be used during peak demand. Likewise, they also contribute to reduced overall energy demand through passive thermal regulation. Nonetheless, thermal energy charging and discharging are restricted due to the low conducting nature of the energy storage medium. Various research investigations are being carried out to improve the thermal characteristics of PCMs through techniques such as a) dispersion of nanoparticles, b) inserting fins, and c) cascading PCMs. Among the techniques mentioned above, the dispersion of nanoparticles is reliable and economically viable. These materials are so-called nano-enhanced PCMs (NePCMs) that facilitate the charging and discharging processes of the thermal energy storage (TES) units owing to their improved thermo physical properties and long term stability. This paper presents a comprehensive review with implications and inferences on research conducted using nano-enhanced phase change materials (NePCMs) in recent years. Initially, the article discusses the highly preferred synthesis methods of NePCMs in addition to its morphological and thermophysical characterization techniques. Then, an acute focus on the impact of distinct dimensional nano additives like zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) on inclusion with PCMs are elaborately discussed. A deep discussion on emerging and hybrid nanoparticles dispersed PCMs with emphasis on a) the interaction mechanism of nanoparticle &amp; phase change material (PCM) and b) influences on enhancing the thermophysical properties (melting point, thermal conductivity, latent heat capacity, thermal diffusivity, and thermal stability) of NePCMs are discussed. Indeed, including nanomaterials within the PCM matrix resulted in variations in thermal conductivity and heat storage enthalpy. With nanomaterial NePCM displayed 80–150 % increment in organic PCM as their proportion of nanomaterial inclusion is about 1–2 %, whereas for form and shape stable PCM enhancement of 700–900 % in thermal conductivity is noticed; however, there was a drop in heat storage enthalpy owing to the inclusion of nanomaterial in weight fraction of 5–20 %. Furthermore included in this review article are insights on significant advances, challenges, and outlooks for enhancing NePCMs in the field of advanced thermal applications. This review article is expected to have a particular reference value that would provide notable insight to readers to explore the fundamental properties of NePCM further. Additionally, as there is alarming interest in the field of TES late after the framework of sustainable development goals (SDG)s by the United Nations in 2015, this review article is anticipated to make a remarkable impact towards SDG 7-Affordable ","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"104 ","pages":"Article 101162"},"PeriodicalIF":29.5,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0360128524000200/pdfft?md5=fccf19280fa0103524055f1d572204f5&pid=1-s2.0-S0360128524000200-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141423854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MILD combustion of low calorific value gases 低热值气体的温和燃烧
IF 29.5 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-06-12 DOI: 10.1016/j.pecs.2024.101163
Shengquan Zhou , Beibei Yan , Mohy Mansour , Zhongshan Li , Zhanjun Cheng , Junyu Tao , Guanyi Chen , Xue-Song Bai
{"title":"MILD combustion of low calorific value gases","authors":"Shengquan Zhou ,&nbsp;Beibei Yan ,&nbsp;Mohy Mansour ,&nbsp;Zhongshan Li ,&nbsp;Zhanjun Cheng ,&nbsp;Junyu Tao ,&nbsp;Guanyi Chen ,&nbsp;Xue-Song Bai","doi":"10.1016/j.pecs.2024.101163","DOIUrl":"https://doi.org/10.1016/j.pecs.2024.101163","url":null,"abstract":"<div><p>The utilization of low calorific value gases (LCVG) in combustion devices presents particular challenges in terms of ignition and sustained combustion stability due to the presence of non-combustible components. Moderate or intense low-oxygen dilution (MILD) combustion has emerged as a promising technology for LCVG combustion, offering numerous advantages such as high combustion efficiency, reduced pollutant emissions, and increased fuel flexibility. However, the current body of research in this area is fragmented, making it challenging to draw meaningful comparisons between studies and hindering its practical application. This paper provides a comprehensive review of conventional and MILD combustion of LCVG. To understand the impact of composition on combustion, the fuels are classified based on their composition of hydrogen, carbon monoxide, methane, carbon dioxide, nitrogen, and water. We also delve into the chemical and physical effects of composition, including reaction kinetics and turbulence mixing, and provide an overview of the burners and methods used in establishing MILD combustion. Furthermore, computational fluid dynamics (CFD) models and chemical kinetics in MILD combustion are also thoroughly discussed.</p><p>The presence of a large amount of dilution gas in LCVG increases the self-ignition temperature and ignition delay time of the mixture, making preheating the reactants a critical consideration. In MILD combustion, it is crucial to have an inlet reactant temperature higher than the self-ignition temperature (<span><math><mrow><msub><mi>T</mi><mtext>in</mtext></msub><mo>&gt;</mo><msub><mi>T</mi><mtext>si</mtext></msub></mrow></math></span>) to mitigate the difficulties associated with ignition and unstable combustion. The heat release in MILD combustion should be moderate to ensure that the combustion temperature does not become too high. The non-combustible components of LCVG are beneficial in this regard, as they allow for a temperature increase of less than the self-ignition temperature (<span><math><mrow><mo>Δ</mo><mi>T</mi><mo>&lt;</mo><msub><mi>T</mi><mtext>si</mtext></msub></mrow></math></span>). Hydrogen is the most reactive component in LCVG, and its content directly impacts the establishment, efficiency, and pollutant emissions of MILD combustion. Carbon dioxide, nitrogen, and water act as diluents, helping to reduce NOx emissions in MILD combustion. Although a burner may have the potential to be used for MILD combustion, it must be optimised for LCVG with variable composition in order to achieve the lowest pollutant emissions. Further research is necessary to verify and improve simulation models and chemical kinetics. This article provides theoretical support for the practical application of MILD combustion of LCVG with variable composition.</p></div>","PeriodicalId":410,"journal":{"name":"Progress in Energy and Combustion Science","volume":"104 ","pages":"Article 101163"},"PeriodicalIF":29.5,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141314273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Energy crop-based rhizoremediation and lignocellulosic biomass production as sustainable bioeconomy-driven solution for biofuel generation and waste mitigation 基于能源作物的根瘤修复和木质纤维素生物质生产是生物燃料生产和废物减排的可持续生物经济驱动型解决方案
IF 29.5 1区 工程技术
Progress in Energy and Combustion Science Pub Date : 2024-06-04 DOI: 10.1016/j.pecs.2024.101161
Nandita Das , Dinesh Kumar Maheshwari , Piyush Pandey
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