Nano-Structures & Nano-Objects最新文献

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Oxalic acid capped tungsten oxide nanozyme mimicking peroxidase activity, its synthesis characterization, and kinetic data validation via spectrophotometric studies 草酸封端氧化钨纳米酶模拟过氧化物酶活性、其合成表征以及通过分光光度法研究验证动力学数据
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-25 DOI: 10.1016/j.nanoso.2024.101340
Ravishankar H. Sadashivanna , Honnur Krishna , Anantharaman Shivakumar , Nikhil Y. Gangadhara , K.S. Mahesh Lohith , Avinash Krishnegowda
{"title":"Oxalic acid capped tungsten oxide nanozyme mimicking peroxidase activity, its synthesis characterization, and kinetic data validation via spectrophotometric studies","authors":"Ravishankar H. Sadashivanna ,&nbsp;Honnur Krishna ,&nbsp;Anantharaman Shivakumar ,&nbsp;Nikhil Y. Gangadhara ,&nbsp;K.S. Mahesh Lohith ,&nbsp;Avinash Krishnegowda","doi":"10.1016/j.nanoso.2024.101340","DOIUrl":"10.1016/j.nanoso.2024.101340","url":null,"abstract":"<div><div>The need for parody enzymes has attracted the interest of researchers globally. Nanomaterials have provided promising results as mimic catalysts termed nanozymes (NZMs). This article briefs the peroxidase mimicking behavior of Oxalic acid-capped WO<sub>3</sub> nanoparticles (Ox-WO<sub>3</sub> NPs), which were hydrothermally synthesized. The peroxidase parodying behavior of the synthesized NZMs was studied for H<sub>2</sub>O<sub>2</sub> as substrate and PPDD-NEDA and TMB as a chromogenic reagent in Phosphate buffer at pH 6.5. The coupled product of PPDD-NEDA showed λ<sub>max</sub>=480 nm, and the method was linear between 0.2413 and 1.93 mM. The oxidized product of TMB λ<sub>max</sub>=650 nm was linear in the range of 0.1938–1.9386 mM. K<sub>m</sub> values corresponding to TMB, and PPDD-NEDA were 0.5308 and 0.3957 mM. Kinetic constants with respect to PPDD-NEDA i.e., V<sub>max</sub>, K<sub>cat</sub>, K<sub>eff</sub>, and K<sub>pow</sub> were found to be 0.1913 mM/min, 3.3639 min<sup>−1</sup>, 8.4999 mM<sup>−1</sup> min<sup>−1</sup>, and 0.4833 min<sup>−1</sup>. The precision study for intra-day (1.27–2.49 %) and inter-day (1.09–1.52 %) has been calculated. LOD and LOQ of the reaction was found to be 56.34 and 170.73 µM respectively. Characterization of synthesized NPs were carried out with respect to morphology, crystallinity, size, zeta potential and others. The XRD of the sample revealed the crystallite size to be 42.6 nm (Williamson-Hall equation) and 35 nm (Scherrer equation), Crystal structure was identified to be a mixture of monoclinic and orthorhombic as compared with the JCPDS file and the crystallinity of the sample was found to be 79.75 %. The SEM images provided the morphology to be spherical in nature with more aggregation due to lower zeta potential value as recorded by the DLS. The elemental composition by EDS recorded the formation of WO<sub>3</sub> NPs. The broad peak of FT-IR spectra between 2900 and 3900 cm<sup>−1</sup> confirms the capping of oxalic acid to WO<sub>3</sub> NPs.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101340"},"PeriodicalIF":5.45,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142320066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser-induced graphene in energy storage- batteries 储能电池中的激光诱导石墨烯
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-24 DOI: 10.1016/j.nanoso.2024.101347
Farzane Hasheminia , Sadegh Sadeghzadeh
{"title":"Laser-induced graphene in energy storage- batteries","authors":"Farzane Hasheminia ,&nbsp;Sadegh Sadeghzadeh","doi":"10.1016/j.nanoso.2024.101347","DOIUrl":"10.1016/j.nanoso.2024.101347","url":null,"abstract":"<div><div>Laser-induced graphene (LIG) offers a promising avenue for creating graphene electrodes for battery uses. This review article discusses the implementation of LIG for energy storage purposes, especially batteries. Since 1991, lithium-ion batteries have been a research subject for energy storage uses in electronics. The uneven distribution of lithium resources and rising costs hamper lithium-based battery growth. Multivalent ion batteries, or MIBs, have gained significant traction as an alternative for large-scale energy storage. Earth's crust is mainly composed of polyvalent ions, such as calcium (Ca2+), magnesium (Mg2+), aluminum (Al3+), zinc (Zn2+), etc. As a result, a lot of research has been done on lithium-ion batteries (LIBs), sodium-ion batteries (SIBs), lithium metal batteries (LMBs), zinc blue ion batteries (ZIBs), etc. Graphite anode is more useful in these batteries due to its high theoretical capacity of 372 mAh g<sup>−1</sup> and proper stability. Recent technological breakthroughs have driven the emergence of graphene-based anodes. Graphene, a single-layer sheet of carbon atoms, offers a large surface area and can serve as a platform adaptable to many needs. There are multiple methods to produce graphene, and the League method stands out with its simplicity, effectiveness, and low cost, making it ideal for diverse applications. It also enables the creation of graphene with tunable properties. In addition, it is a green method and can reduce concerns regarding the increasing production of electronic waste. Green LIG is produced from cellulose materials such as paper and wood, which are environmentally friendly raw materials. Next, it discusses LIG's production process and the laser's critical parameters for graphene fabrication and functionalization. Following this, we delve into recent and promising research in battery research, developed using laser processing techniques, with a particular focus on battery applications. The review concludes by discussing laser technology's main challenges and Potential applications for graphene in energy device manufacturing. One of the main challenges of LIG is that it is difficult to produce thick films. Another challenge is that LIG has high resistance, which can cause ohmic loss in electronic applications. Researchers are currently working on ways to reduce the resistance of LIG without sacrificing its other useful features. Also, this factor can affect its stability and cause aging. Despite these challenges, LIG has the potential to revolutionize the way graphene electrodes are produced, sparking excitement and optimism about the outlook for energy storage solutions. LIG offers a simple, cost-effective approach to producing graphene electrodes with customizable properties, making it a promising candidate to revolutionize the field.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101347"},"PeriodicalIF":5.45,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142314128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Upgraded theragnostic strategies of multivariate nano gold in the management of hepatocellular carcinoma 多变量纳米金在肝细胞癌治疗中的升级治疗策略
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-24 DOI: 10.1016/j.nanoso.2024.101342
Debojyoti Halder , Ashutosh Gupta , Subhasis Chakraborty , Partha Roy , Kalyan Kumar Sen
{"title":"Upgraded theragnostic strategies of multivariate nano gold in the management of hepatocellular carcinoma","authors":"Debojyoti Halder ,&nbsp;Ashutosh Gupta ,&nbsp;Subhasis Chakraborty ,&nbsp;Partha Roy ,&nbsp;Kalyan Kumar Sen","doi":"10.1016/j.nanoso.2024.101342","DOIUrl":"10.1016/j.nanoso.2024.101342","url":null,"abstract":"<div><div>Hepatocellular Carcinoma is one of the detrimental forms of liver cancer perceived to be the fourth most dangerous disease on a global forum. The prevalence of HCC is increasing day by day &amp; complicated health status. Presently, there are different treatment strategies for overcoming HCC. But none of them are stable enough to overcome this permanently. The failure of treatment has abundant reasons, such as inadequate pharmacokinetics and pharmacodynamics features of existing treatment, low drug targeting, drug resistance, and so on. Therefore, researchers have investigated various nano-structured gold to diagnose and treat HCC. Concerning this concept, gold nanoparticles (AuNPs) have shown tremendous potential in synergizing chemotherapy and have unique intrinsic theragnostic properties. These nano-golds enhance the retention of the therapeutics in the tumor cells due to the enhanced permeability and retention (EPR) effect. The EPR effect can increase the permeability effect through different membranes, and thereby, the nano-gold can strike the specific area successfully. In the field of biomedicine, particularly in drug delivery, molecular imaging, and cancer treatment, nano-structured golds are extensively utilized. This evidence indicates that AuNPs decrease the proliferation of cancer cells and ultimately reduce the chances of cancer metastasis. This review will further focus on the theragnostic applications of gold nanoparticles, including their synthesis and applications to mitigate HCC and other malignancies. The limitations associated with these nano-golds are also highlighted in this review.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101342"},"PeriodicalIF":5.45,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142314210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing nanotechnology for breast cancer management: UiO-66 (NH2) metal-organic frameworks functionalized with chitosan and folic acid for the efficient delivery of doxorubicin 利用纳米技术治疗乳腺癌:用壳聚糖和叶酸功能化的 UiO-66 (NH2) 金属有机框架高效输送多柔比星
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-24 DOI: 10.1016/j.nanoso.2024.101360
Soji Soman , Sanjay Kulkarni , P. Vineeth , Sajan D George , Srinivas Mutalik
{"title":"Harnessing nanotechnology for breast cancer management: UiO-66 (NH2) metal-organic frameworks functionalized with chitosan and folic acid for the efficient delivery of doxorubicin","authors":"Soji Soman ,&nbsp;Sanjay Kulkarni ,&nbsp;P. Vineeth ,&nbsp;Sajan D George ,&nbsp;Srinivas Mutalik","doi":"10.1016/j.nanoso.2024.101360","DOIUrl":"10.1016/j.nanoso.2024.101360","url":null,"abstract":"<div><div>Cancer is a leading cause of morbidity globally, which could be due to a lack of effective treatments. The inherent inadequacies of traditional medicines in terms of tumour selectivity and undesired toxicity urge us to seek alternative therapies to address these drawbacks. Metal<img>organic frameworks (MOFs) have been synthesized for use in drug delivery systems (DDS) because of their improved porosity and larger specific surface area. In this research, UiO-66-NH<sub>2</sub> MOFs were synthesized via a solvothermal technique and functionalized with chitosan-folic acid (CS-FA) as a DDS for targeted doxorubicin (DOX) delivery. The MOF nanoplatforms were characterized via different techniques, including FTIR, PXRD, BET, TEM, DLS, TGA, SEM, and TGA. Remarkably, compared with the unmodified MOF, UiO-DOX@CS-FA delayed DOX release due to a gated effect induced by the CS-FA surface coating. pH-sensitive DOX release was observed, where 39.76 % of the drug was released in the tumour-mimicking pH of 5.2, whereas 5.84 % of the drug was released at physiological pH (7.4). In vitro cellular toxicity and uptake investigations demonstrated that UiO-DOX@CS-FA is a highly effective targeted DDS against MCF-7 breast cancer cells. Furthermore, in vivo toxicity studies in Wistar rats revealed no evidence of serious adverse effects. The variety of pharmacokinetic characteristics tested indicated that the bioavailability and release kinetics of DOX improved. Our findings lay the groundwork for the development and production of novel polymer conjugate-based nanoparticles with increased tumour-targeting efficacy.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101360"},"PeriodicalIF":5.45,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2352507X24002725/pdfft?md5=d90e6553f76e9c4f990837fd122c6c59&pid=1-s2.0-S2352507X24002725-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142314209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigations on electrical and sensing behaviors of Fe doped ZnO nanoparticles 掺铁氧化锌纳米粒子的电学和传感行为研究
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-23 DOI: 10.1016/j.nanoso.2024.101356
V.R. Rathod , Mukesh Tiwari , Mehul Parmar , Himitri Trivedi , Apexa Maru , N.A. Chondagar , Rujuta Lehru , Jaydeep Radhanpura , V.S. Vadgama , Himanshu Dadhich , R.J. Gohel , Puneet Negi , P.P. Bardapurkar , N.P. Barde , M.J. Keshvani , Y.N. Jani , N.A. Shah , P.S. Solanki
{"title":"Investigations on electrical and sensing behaviors of Fe doped ZnO nanoparticles","authors":"V.R. Rathod ,&nbsp;Mukesh Tiwari ,&nbsp;Mehul Parmar ,&nbsp;Himitri Trivedi ,&nbsp;Apexa Maru ,&nbsp;N.A. Chondagar ,&nbsp;Rujuta Lehru ,&nbsp;Jaydeep Radhanpura ,&nbsp;V.S. Vadgama ,&nbsp;Himanshu Dadhich ,&nbsp;R.J. Gohel ,&nbsp;Puneet Negi ,&nbsp;P.P. Bardapurkar ,&nbsp;N.P. Barde ,&nbsp;M.J. Keshvani ,&nbsp;Y.N. Jani ,&nbsp;N.A. Shah ,&nbsp;P.S. Solanki","doi":"10.1016/j.nanoso.2024.101356","DOIUrl":"10.1016/j.nanoso.2024.101356","url":null,"abstract":"<div><div>Zn<sub>1–x</sub>Fe<sub>x</sub>O (ZnFeO; x = 0.10, 0.15 and 0.20) nanoparticles were prepared by using modified sol–gel method by employing acetate precursor route. Structural and microstructural aspects strongly suggest the presence of dual crystalline phases, namely, ZnFeO and ZnFe<sub>2</sub>O<sub>4</sub> fractions where crystallite size of ZnFeO gets suppressed from ∼ 41.71 nm to ∼ 36.85 nm and crystallite size of ZnFe<sub>2</sub>O<sub>4</sub> gets enhanced from ∼ 13.22 nm to ∼ 1715 nm with Fe content within ZnFeO nanoparticles. In the present extended investigations, ac conductivity, impedance and dielectric loss have been understood with their dependence on temperature, magnetic field and Fe content within ZnFeO nanoparticles. Role of crystallite size, crystallite boundary density and ZnFe<sub>2</sub>O<sub>4</sub> phase fraction has been considered to recognize electrical behaviors. Various models and mechanisms including Jonscher’s power law and universal dielectric response (UDR) have been employed to understand the dipole relaxation processes and charge conduction mechanisms. Temperature dependent dc resistivity has been understood on the basis of next nearest hopping mechanism (NNHM) of conduction. Activation energy, derived through the fitting of NNHM to recorded resistivity data, is found to decrease from 16.22 meV to 9.06 meV with increase in Fe content within ZnFeO nanoparticles. Acetone gas sensing capability of all studied ZnFeO nanoparticles has been investigated at room temperature on the basis of crystallite and grain sizes and boundary density. Gas sensing behaviors clearly indicates that the doping of Fe at Zn site in ZnFeO nanoparticle lattice enhances the acetone gas (in 400 ppm at 300 K) sensing response from 20.73 % to 91.13 %. Also, with increase in Fe content in ZnFeO lattice, gas sensing (for 400 ppm at 300 K) response time gets suppressed from 60 s to 15 s and recovery time gets reduced from 100 s to 35 s which has been ascribed to the reduced grain size and improved grain boundary density.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101356"},"PeriodicalIF":5.45,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142311976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of semiconductor properties of fabricated graphene materials 制备石墨烯材料的半导体特性分析
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-23 DOI: 10.1016/j.nanoso.2024.101354
Rajib Nandee , Mohammad Asaduzzaman Chowdhury , Md. Masud Rana , Nayem Hossain , Md. Aminul Islam , Hasanuzzaman Aoyon
{"title":"Analysis of semiconductor properties of fabricated graphene materials","authors":"Rajib Nandee ,&nbsp;Mohammad Asaduzzaman Chowdhury ,&nbsp;Md. Masud Rana ,&nbsp;Nayem Hossain ,&nbsp;Md. Aminul Islam ,&nbsp;Hasanuzzaman Aoyon","doi":"10.1016/j.nanoso.2024.101354","DOIUrl":"10.1016/j.nanoso.2024.101354","url":null,"abstract":"<div><div>Introducing dopant elements into graphene is a crucial process for creating bandgaps, which will have significant importance in developing nanoelectronic devices in the future. In this study, we provide an analysis of the electrical and carrier mobility properties of graphene doped with BN in ratios of 1 %, 3 %, and 5 %, graphene 95 %, ZnO-3 %, and BN2 %, graphene-95 %, Al<sub>2</sub>O<sub>3</sub>-3 % and BN-2 %, graphene-95 %, TiO<sub>2</sub>-3 % and BN-2 % by using a sintering process. Upon analyzing the band structure, it was determined that the mentioned materials demonstrate a bandgap in graphene. The resistivity values for fabricated graphene materials doped with different nanoparticles are estimated using the Source-meter Unit (SMU) at room temperature (25°C), 100°C and 200°C. The conductivity of graphene is 8.93E+07 Ω<sup>−1</sup>cm<sup>−1</sup> and reduced gradually with the doping percentages. The resistivity of graphene is measured at 1.12 E-08 Ω.cmand increases with the doping percentages, and carrier mobility is measured to be 9239 cm<sup>2</sup>V<sup>−1</sup>s<sup>−1</sup> and gradually reduced with the doping percentages. The temperature-dependent conductivity is determined using electrical conductivity under the constant relaxation time approximation.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101354"},"PeriodicalIF":5.45,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142311975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-mode sensing with L-phenylalanine-stabilized copper nanoparticles: Real-time detection of Fe3+ and pH monitoring 使用 L-苯丙氨酸稳定的纳米铜粒子进行双模式传感:实时检测 Fe3+ 和 pH 值监测
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-21 DOI: 10.1016/j.nanoso.2024.101357
Ramakrishnan AbhijnaKrishna , M. Yuvarani , Shu-Pao Wu , Sivan Velmathi
{"title":"Dual-mode sensing with L-phenylalanine-stabilized copper nanoparticles: Real-time detection of Fe3+ and pH monitoring","authors":"Ramakrishnan AbhijnaKrishna ,&nbsp;M. Yuvarani ,&nbsp;Shu-Pao Wu ,&nbsp;Sivan Velmathi","doi":"10.1016/j.nanoso.2024.101357","DOIUrl":"10.1016/j.nanoso.2024.101357","url":null,"abstract":"<div><p>Water-soluble copper nanoparticles stabilized with L-Phenylalanine (L-PCuNPs) were synthesized and characterized for dual sensing of Fe<sup>3+</sup> ions and pH levels. These nanoparticles exhibited green fluorescence at 486 nm, which was quenched by Fe<sup>3+</sup> ions, resulting in a color shift from colorless to yellow. Additionally, L-PCuNPs showed pH responsiveness, with increased fluorescence intensity as the pH shifted from acidic to basic. Their effectiveness was further validated through analysis of environmental, biological, and food samples, demonstrating their practical utility across diverse real-world applications.</p></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101357"},"PeriodicalIF":5.45,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142272690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling acoustic characteristics of artificial bone alloys for medical and surgical use under thermodynamic conditions 模拟热力学条件下医用和外科用人工骨合金的声学特性
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-20 DOI: 10.1016/j.nanoso.2024.101343
Yahya Al-Sayaad , Radman Alnahari , Linda Achou , Muhammad Nadeem , Ali Saad Alwesabi , Abdellaziz Doghmane
{"title":"Modeling acoustic characteristics of artificial bone alloys for medical and surgical use under thermodynamic conditions","authors":"Yahya Al-Sayaad ,&nbsp;Radman Alnahari ,&nbsp;Linda Achou ,&nbsp;Muhammad Nadeem ,&nbsp;Ali Saad Alwesabi ,&nbsp;Abdellaziz Doghmane","doi":"10.1016/j.nanoso.2024.101343","DOIUrl":"10.1016/j.nanoso.2024.101343","url":null,"abstract":"<div><p>The study examines the impact of porosity on mechanical, acoustic, and behavioral properties of (Ti-6Al-4 V alloy) alloys, which are manufactured to mimic human bones. It investigates how porosity, controlled through factors like pressure, particle size, and temperature during sintering, affects properties such as modulus of elasticity, surface acoustic wave (SAW) velocities, hardness coefficients, and acoustic resistance.</p><p>The findings suggest that different levels of porosity at varying sintering temperatures significantly alter the dynamic elastic modulus of the alloys. Specifically, increasing porosity values seem to correlate with a decrease in elastic constants, elastic modulus values, and surface acoustic wave types. This phenomenon may be attributed to the transitional crystalline structure phases of Ti6Al4V alloy and the manufacturing process.</p><p>Remarkably, the study concludes that these (Ti-6Al-4 V alloy) alloys exhibit superior porosity, mechanical, and acoustic qualities compared to various types of human bone, including cortical, trabecular, and cancellous bone.</p></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101343"},"PeriodicalIF":5.45,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142272156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and application of biomass-based graphene oxide using microwave-assisted pyrolysis method 利用微波辅助热解法合成生物质基氧化石墨烯及其应用
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-20 DOI: 10.1016/j.nanoso.2024.101338
Scarlett Allende , Yang Liu , Muhammad Adeel Zafar , Mohan V. Jacob
{"title":"Synthesis and application of biomass-based graphene oxide using microwave-assisted pyrolysis method","authors":"Scarlett Allende ,&nbsp;Yang Liu ,&nbsp;Muhammad Adeel Zafar ,&nbsp;Mohan V. Jacob","doi":"10.1016/j.nanoso.2024.101338","DOIUrl":"10.1016/j.nanoso.2024.101338","url":null,"abstract":"<div><p>Graphene and related materials have excellent potential to revolutionise many emerging fields, but the large quantity synthesis using environmentally sustainable methods is still challenging. This work studies the synthesis of graphene oxide from food waste biochar with negatively charged properties, which is initially produced using microwave pyrolysis. The synthesised graphene oxide achieved 64.53 % carbon content, 345.79 m<sup>2</sup>/g surface area, 0.074 cm<sup>3</sup>/g micropore volume, large reactive surface area, and ribbon/banded organisation. The performance of carbon-based material is evaluated in the fabrication of a modified screen-printed carbon electrode (SPCE) for selective dopamine (DA) detection in the coexistence of ascorbic acid (AA) and uric acid (UA). The electrostatic interactions between the negatively charged biochar-based graphene oxide (BBGO) on the surface SPCE and opposite-charged dopamine assisted the oxidation potential with interfering species by electrostatic repulsion of AA and UA. This manuscript substantiates the resource recovery from organic materials and sustainable graphene oxide synthesis, underscoring their application in detecting positively charged species.</p></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"40 ","pages":"Article 101338"},"PeriodicalIF":5.45,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142272689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical study of unsteady flow behavior of Cu-ethylene glycol nanoparticle on radially stretching sheet with Joule Heating effect 具有焦耳热效应的纳米铜-乙二醇在径向拉伸薄片上的非稳态流动行为的数值研究
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2024-09-19 DOI: 10.1016/j.nanoso.2024.101334
Azhar Iqbal , Taswar Abbas , Adil Jhangeer , Azeem Shahzad , Ijaz Ali , Umer Hayat
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