Nano-Structures & Nano-Objects最新文献

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A CMMT/APU Hydrogel-Based Triboelectric Nanogenerator for High-Precision Self-Powered Human-Motion Monitoring 用于高精度自供电人体运动监测的CMMT/APU水凝胶摩擦电纳米发电机
Nano-Structures & Nano-Objects Pub Date : 2026-05-29 DOI: 10.1142/s1793292026501377
Xiuchang Yang, Jikai Si
{"title":"A CMMT/APU Hydrogel-Based Triboelectric Nanogenerator for High-Precision Self-Powered Human-Motion Monitoring","authors":"Xiuchang Yang, Jikai Si","doi":"10.1142/s1793292026501377","DOIUrl":"https://doi.org/10.1142/s1793292026501377","url":null,"abstract":"Developing flexible self-powered sensors capable of simultaneously converting biomechanical stimuli into electrical signals and supporting wearable motion analysis is of considerable importance for next-generation intelligent monitoring systems. In this work, a conductive montmorillonite/amphiphilic polyurethane (CMMT/APU) hydrogel-based triboelectric nanogenerator (CA-TENG) is constructed by integrating a conductive montmorillonite-modified hydrogel electrode with a contact-separation triboelectric configuration. Polytetrafluoroethylene (PTFE) and nylon are selected as the triboelectric layers, while the CMMT/APU hydrogel is employed as the flexible conductive electrode. Owing to the cooperative effect between conductive montmorillonite and the amphiphilic polyurethane network, the hydrogel exhibits good flexibility, structural stability, and mechanical adaptability, and the composition containing 5% CMMT presents the most suitable tensile performance for device fabrication. The optimized CA-TENG delivers a peak open-circuit voltage ([Formula: see text] of 777[Formula: see text]V, a short-circuit current ([Formula: see text] of 39[Formula: see text][Formula: see text]A, and a transferred charge ([Formula: see text] of 250[Formula: see text]nC, together with a maximum output power of 598[Formula: see text][Formula: see text]W. Moreover, the device shows stable output under different working frequencies, separation distances, and humidity conditions, and it can effectively distinguish walking, running, jumping, and joint-bending motions, demonstrating strong potential for self-powered wearable-motion monitoring and biomechanical analysis.","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148305552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exciton and biexciton states in III-nitride quantum dots: Effects of internal polarization fields and indium composition on optical response iii -氮化物量子点中的激子和双激子态:内部偏振场和铟成分对光学响应的影响
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-04-25 DOI: 10.1016/j.nanoso.2026.101650
Gor Kharatyan , David Hayrapetyan , Rodion Reznik , Nabil Zeiri , Sotirios Baskoutas , Paytsar Mantashyan
{"title":"Exciton and biexciton states in III-nitride quantum dots: Effects of internal polarization fields and indium composition on optical response","authors":"Gor Kharatyan ,&nbsp;David Hayrapetyan ,&nbsp;Rodion Reznik ,&nbsp;Nabil Zeiri ,&nbsp;Sotirios Baskoutas ,&nbsp;Paytsar Mantashyan","doi":"10.1016/j.nanoso.2026.101650","DOIUrl":"10.1016/j.nanoso.2026.101650","url":null,"abstract":"<div><div>This work presents a theoretical investigation of excitonic and biexcitonic states in cylindrical wurtzite III-nitride quantum dots, focusing on the influence of internal polarization fields and indium composition on their electronic and optical properties. The confinement potential is modeled using a bimodal Woods–Saxon profile that incorporates both band offsets and dielectric self-energy corrections, providing a realistic description of carrier confinement. Single-particle states are calculated using the finite element method, while exciton and biexciton complexes are analyzed through a variational Monte Carlo approach.</div><div>The results reveal that the combined effects of piezoelectric polarization and spontaneous polarization significantly distort the confinement potential, leading to strong spatial separation of electron and hole wave functions and substantial modifications of exciton and biexciton binding energies. Increasing indium concentration three times enhances the internal electric field and leads to a clear redistribution of carrier density across the quantum dot. This effect reduces the electron–hole overlap and results in a decrease of both exciton and biexciton binding energies in larger quantum dots, while in smaller structures (heights below ∼2 nm) the confinement dominates, leading to an opposite trend and partial stabilization of biexciton states. The calculated exciton transition energy for a cylindrical quantum dot with 2 nm height and 10 nm radius is approximately 2.5 eV, in good agreement with reported experimental values (∼2.55 eV) for similar structures, confirming the validity of the model.</div><div>In addition, the nonlinear optical response is analyzed using a three-level exciton–biexciton scheme. Biexciton transitions exhibit about two times stronger response than excitonic ones. Lower indium content induces a blue shift, while higher concentration reduces peak intensity due to enhanced carrier separation. These findings demonstrate how the interplay between internal polarization, composition, and quantum confinement governs excitonic complexes and nonlinear optical properties in III-nitride quantum dots.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101650"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147798539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient nanolignocellulose synthesis from edamame peel waste using an Amberlite IR-120 catalytic route 利用Amberlite IR-120催化途径从毛豆皮废料中高效合成纳米纤维素
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-05-05 DOI: 10.1016/j.nanoso.2026.101669
Merdieta Amelia , Holilah , Didik Prasetyoko , RH Fitri Faradilla , Asranudin , Agus Wedi Pratama , Zuratul Ain Abdul Hamid , Bambang Piluharto , Dwi Indarti , Mohd Saiful Asmal Rani , Dina Wahyu Indriani , Lisman Suryanegara , Mohd Nor Faiz Norrrahim , Noureddine El Messaoudi
{"title":"Efficient nanolignocellulose synthesis from edamame peel waste using an Amberlite IR-120 catalytic route","authors":"Merdieta Amelia ,&nbsp;Holilah ,&nbsp;Didik Prasetyoko ,&nbsp;RH Fitri Faradilla ,&nbsp;Asranudin ,&nbsp;Agus Wedi Pratama ,&nbsp;Zuratul Ain Abdul Hamid ,&nbsp;Bambang Piluharto ,&nbsp;Dwi Indarti ,&nbsp;Mohd Saiful Asmal Rani ,&nbsp;Dina Wahyu Indriani ,&nbsp;Lisman Suryanegara ,&nbsp;Mohd Nor Faiz Norrrahim ,&nbsp;Noureddine El Messaoudi","doi":"10.1016/j.nanoso.2026.101669","DOIUrl":"10.1016/j.nanoso.2026.101669","url":null,"abstract":"<div><div>The development of efficient synthesis methods to valorize biomass feedstocks is essential for a circular bioeconomy. This study details the synthesis of nanolignocellulose (NLC) from edamame peel waste, an underutilized agro-industrial residue, using an Amberlite IR-120 catalytic route. The synthesis was optimized by varying catalyst concentration (0.5–2.0 M) at 80 °C for 3 h. The efficiency of this route was confirmed by the successful production of NLC with high crystallinity (up to 49.94%) and fine nanofibrillar diameters (down to 4.24 nm) at the optimal concentration of 1 M. Fourier Transform Infrared (FTIR) analysis confirmed the effective removal of amorphous hemicellulose and lignin. Catalyst reusability was systematically evaluated over three successive cycles. The average fibril diameter increased to 6.10 nm (RNLC1), 9.46 nm (RNLC2), and 10.10 nm (RNLC3), indicating progressive loss of catalytic efficiency with repeated use. Correspondingly, the crystallinity index increased slightly to 52.95% after the first reuse but decreased sharply to 39.32% after the second cycle before partially recovering to 50.13% in the third cycle. This study validates that the use of Amberlite IR-120 is a sustainable alternative to liquid acids, producing high-value NLC suitable for applications in biocomposites and packaging.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101669"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147850276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis of phaleria macrocarpa–mediated V–Mn bimetallic nanoparticles: Structural, magnetic, antimicrobial, and anticancer properties 绿色合成大竹节草介导的V-Mn双金属纳米颗粒:结构、磁性、抗菌和抗癌特性
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-05-30 DOI: 10.1016/j.nanoso.2026.101706
R. Shanmugapriya , G. Nedunchezhian , C. Vijayaraj , S. Ramalingam
{"title":"Green synthesis of phaleria macrocarpa–mediated V–Mn bimetallic nanoparticles: Structural, magnetic, antimicrobial, and anticancer properties","authors":"R. Shanmugapriya ,&nbsp;G. Nedunchezhian ,&nbsp;C. Vijayaraj ,&nbsp;S. Ramalingam","doi":"10.1016/j.nanoso.2026.101706","DOIUrl":"10.1016/j.nanoso.2026.101706","url":null,"abstract":"<div><div>Biological synthesis of multifunctional nanomaterials has been explored as a novel approach towards meeting the escalating challenges of antimicrobial resistance and cancer treatment. In the current investigation, the successful synthesis of V₂O₅-MnCl₂ bimetallic nanoparticles was accomplished using a phyto-mediated coprecipitation method, where the reducing and stabilizing agent was the fruit extract of the Phaleria macrocarpa plant. The resulting biologically synthesized nanoparticles were subjected to a post-synthesis annealing process at 400, 500, and 600 °C, which enabled the assessment of the temperature-dependent structural, optical, magnetic, antimicrobial, and anticancer characteristics. X-ray diffraction studies confirmed the successful formation of the bimetallic phases, which exhibited a progressive enhancement in crystal perfection and lattice order, validated through FWHM and Williamson-Hall plot analyses. FT-IR studies confirmed the role of the functional groups present in the phytochemicals, which contributed towards the improved metal-oxygen bonds after the annealing process. UV-Vis studies clearly indicated the improved absorbance, which was accompanied by the modification of the band structures, especially in the 500 °C annealed sample. SEM and DLS studies clearly revealed the progressive development from the agglomerated nanoparticles towards the defined nanostructures at the 500 °C annealed sample, which was later accompanied by the development of larger grains at the 600 °C annealed sample. VSM studies clearly revealed the paramagnetic nature, which was accompanied by the improved magnetic susceptibility values after the annealing treatment. Results from the antimicrobial studies clearly indicated the strong antimicrobial activities towards the Gram-positive and Gram-negative bacteria, which were observed in the annealed samples, which exhibited improved inhibition compared to the unannealed sample. Finally, the cytotoxicity studies, which were conducted using the MTT assay, clearly demonstrated the dose-dependent cytotoxicity towards the breast cancer cells, indicating the improved anticancer efficacy. Based on the current investigation, the results clearly validated that the annealing treatment at 500–600 °C was optimal towards the improved multifunctionality of the biologically synthesized V-Mn bimetallic nanoparticles, which have the potential towards the development of novel biomedicine.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101706"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148184121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling the temperature and magnetic field dependence of the band gap in narrow-gap quantum well semiconductors 窄隙量子阱半导体中带隙对温度和磁场依赖性的建模
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-06-01 DOI: 10.1016/j.nanoso.2026.101707
U.I. Erkaboev, R.G. Rakhimov, J.I. Mirzaev, N.A. Sayidov, M.G. Dadamirzaev, Q.A. Temirov
{"title":"Modeling the temperature and magnetic field dependence of the band gap in narrow-gap quantum well semiconductors","authors":"U.I. Erkaboev,&nbsp;R.G. Rakhimov,&nbsp;J.I. Mirzaev,&nbsp;N.A. Sayidov,&nbsp;M.G. Dadamirzaev,&nbsp;Q.A. Temirov","doi":"10.1016/j.nanoso.2026.101707","DOIUrl":"10.1016/j.nanoso.2026.101707","url":null,"abstract":"<div><div>The fundamental physical parameter of both bulk and low-dimensional semiconductor structures is the band gap <span><math><mrow><mfenced><mrow><msubsup><mrow><mi>E</mi></mrow><mrow><mi>g</mi></mrow><mrow><mn>3</mn><mi>d</mi></mrow></msubsup><mo>,</mo><msubsup><mrow><mi>E</mi></mrow><mrow><mi>g</mi></mrow><mrow><mn>2</mn><mi>d</mi></mrow></msubsup></mrow></mfenced></mrow></math></span>, whose energetic width allows the prediction of the operational parameters of semiconductor-based devices in advance. Therefore, the determination of <span><math><mrow><msubsup><mrow><mi>E</mi></mrow><mrow><mi>g</mi></mrow><mrow><mn>3</mn><mi>d</mi></mrow></msubsup><mspace></mspace></mrow></math></span>and <span><math><msubsup><mrow><mi>E</mi></mrow><mrow><mi>g</mi></mrow><mrow><mn>2</mn><mi>d</mi></mrow></msubsup></math></span> (in cases where the band gap of newly synthesized materials is not known) is considered one of the primary tasks in semiconductor heterostructure technology. Furthermore, another important feature of <span><math><msub><mrow><mi>E</mi></mrow><mrow><mi>g</mi></mrow></msub></math></span> is its strong sensitivity to external influences. Indeed, variations in <span><math><msub><mrow><mi>E</mi></mrow><mrow><mi>g</mi></mrow></msub></math></span> resulting from such effects can fundamentally alter the physical and chemical properties of semiconductor devices.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101707"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148184122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cubosomes as smart nanocarriers in targeted therapy of skin cancer and cosmetic delivery systems 立方体体作为智能纳米载体在皮肤癌靶向治疗和化妆品输送系统中的应用
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-05-09 DOI: 10.1016/j.nanoso.2026.101681
D. Nagashree , A.M. Deepika , D. Shabnam , Nimbagal Raghavendra Naveen
{"title":"Cubosomes as smart nanocarriers in targeted therapy of skin cancer and cosmetic delivery systems","authors":"D. Nagashree ,&nbsp;A.M. Deepika ,&nbsp;D. Shabnam ,&nbsp;Nimbagal Raghavendra Naveen","doi":"10.1016/j.nanoso.2026.101681","DOIUrl":"10.1016/j.nanoso.2026.101681","url":null,"abstract":"<div><div>Cubosomes have gained increasingly popular as nanostructured carriers in dermatological applications due to their unique BI continuous cubic shape, which allows for effective loading and regulated release of a wide range of bioactive substances. Traditional topical formulations are frequently limited by inadequate skin penetration, unstable active chemicals, and the possibility of systemic side effects, particularly in skin cancer care and sophisticated cosmetic operations. Cubosomes, on the other hand, offer advantages such as enhanced skin retention, site-specific drug administration, and high biocompatibility. A recent study shows that they are effective at transporting chemotherapeutics, photosensitizers, antioxidants, peptides, and vitamins for therapeutic and cosmetic applications. Furthermore, developments in stimuli-responsive architectures and ligand-modified cubosomes suggest more accurate and individualized dermatological delivery techniques. Cubosomes form a versatile and evolving platform with great potential for improving skin-directed medicines and cosmetic applications.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101681"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147849699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green synthesis and dielectric characterization of ZnO nanoparticles using Achyranthes bidentata leaf extract 牛膝叶提取物制备氧化锌纳米粒子的绿色合成及介电特性研究
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-05-05 DOI: 10.1016/j.nanoso.2026.101678
Nasreen Sayed, Stanly Zachariah, Vijayaraghavan G V, Ravanan Indirajith
{"title":"Green synthesis and dielectric characterization of ZnO nanoparticles using Achyranthes bidentata leaf extract","authors":"Nasreen Sayed,&nbsp;Stanly Zachariah,&nbsp;Vijayaraghavan G V,&nbsp;Ravanan Indirajith","doi":"10.1016/j.nanoso.2026.101678","DOIUrl":"10.1016/j.nanoso.2026.101678","url":null,"abstract":"<div><div>Zinc Oxide (ZnO) Nanoparticles were successfully synthesized via an eco-friendly green route using <em>Achyranthes bidentata</em> leaf extract as a natural reducing and stabilizing agent. The extract was prepared by stirring fresh leaves in distilled water at 60 °C, followed by mixing with Zinc nitrate hexahydrate precursor and calcining at 400 °C to yield phase-pure ZnO. Utilizing a fixed precursor concentration optimized at 50 wt% ensured consistent nucleation kinetics and defect formation, facilitating a focused investigation into structure–property correlations without compositional variability. Comprehensive characterisation using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and UV–Vis spectroscopy confirmed the formation of highly crystalline hexagonal wurtzite ZnO nanoparticles exhibiting quasi-spherical morphologies influenced by phytochemical capping. The optical bandgap, determined via Tauc’s method, was estimated at ∼3.2 eV, indicating preserved semiconducting behavior and optical transparency. Dielectric analysis revealed a high dielectric constant (112 at 1 kHz), moderate loss (0.08), a very low activation energy E<sub>a</sub>≈ 1.3 × 10 −4, E<sub>a</sub>≈ 1.3 × 10 −4 eV, and enhanced AC conductivity (1.2 × 10⁻⁶ S·m⁻¹), Debye relaxation analysis confirms interfacial polarization with τ = 3.08 ms, f_max ≈ 52 Hz (R² = 0.747), establishing quantitative mechanism for high-K performance. all arising from defect-assisted hopping and Maxwell–Wagner–Sillars interfacial polarization, as well as space-charge and dipolar polarization mechanisms facilitated by the nanoscale morphology and bio-derived surface functional groups of the green-synthesized ZnO nanoparticles. This study demonstrates that <em>Achyranthes bidentata</em>-mediated synthesis is a promising sustainable platform for producing high-K dielectric ZnO nanomaterials suitable for capacitors, optoelectronic devices, and electroceramics. The targeted single-composition approach advances understanding of bio-assisted formation mechanisms and their impact on dielectric performance, establishing a foundation for future eco-friendly electronic materials.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101678"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147850274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and numerical study of Fe3O4 enhanced composite phase change materials incorporated in concrete with a novel tube-and-fin macro-encapsulation for thermal energy storage 新型管翅复合相变材料储热性能的试验与数值研究
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-06-01 DOI: 10.1016/j.nanoso.2026.101709
Muhammad Fauzi , Budhy Kurniawan , Anggito P. Tetuko , Amdy Fachredzy , Muhammad A.H. Nabawi , Eko A. Setiadi
{"title":"Experimental and numerical study of Fe3O4 enhanced composite phase change materials incorporated in concrete with a novel tube-and-fin macro-encapsulation for thermal energy storage","authors":"Muhammad Fauzi ,&nbsp;Budhy Kurniawan ,&nbsp;Anggito P. Tetuko ,&nbsp;Amdy Fachredzy ,&nbsp;Muhammad A.H. Nabawi ,&nbsp;Eko A. Setiadi","doi":"10.1016/j.nanoso.2026.101709","DOIUrl":"10.1016/j.nanoso.2026.101709","url":null,"abstract":"<div><div>The building sector contributes substantially to global energy consumption and CO<sub>2</sub> emissions, while air-conditioning demand further emphasizes the need for efficient thermal management strategies. Thermal energy storage (TES) systems based on phase change materials (PCMs) offer strategies to improve building energy efficiency and support renewable energy utilization. This study developed paraffin based PCMs composites enhanced with Fe<sub>3</sub>O<sub>4</sub> nanoparticles at mass fractions of 1, 3, 5, and 7 wt% and stabilized using sodium dodecyl benzene sulfonate (SDBS) at a 1:2 mass ratio relative to Fe<sub>3</sub>O<sub>4</sub>. The composites were prepared through magnetic stirring and ultrasonication, followed by evaluation of physicochemical compatibility, microstructural stability, thermophysical properties, thermal reliability, concrete performance, and numerical phase change behavior. The results confirmed compatibility and stable dispersion between paraffin, SDBS, and Fe<sub>3</sub>O<sub>4</sub>. The 7 wt% Fe<sub>3</sub>O<sub>4</sub> composite achieved thermal conductivity of 0.42 W/m·K, corresponding to a 60.73% enhancement compared with pristine paraffin. All composites retained latent heat values above 150 J/g, with enthalpy efficiency above 90%, indicating reliable heat storage. Thermal stability analysis showed that the composites remained stable above the phase change operating range. Macro encapsulation tests in concrete demonstrated heat absorption and delayed heat transfer, producing a temperature difference of up to 50 °C between exposed and shielded surfaces. Numerical simulation supported the results by showing faster melting and more uniform temperature distribution with increasing Fe<sub>3</sub>O<sub>4</sub> content. Overall, the 7 wt% Fe<sub>3</sub>O<sub>4</sub> composite showed the best balance between thermal conductivity enhancement, latent heat retention, and thermal stability, demonstrating potential for concrete integrated TES systems in energy efficient buildings.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101709"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148183983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Accelerating the design of stimuli- responsive chitosan nanocomposites for preservation: A machine learning and polymer informatics framework 加速刺激反应壳聚糖纳米复合材料的设计:一个机器学习和聚合物信息学框架
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-05-27 DOI: 10.1016/j.nanoso.2026.101698
Fizza Saleem , Amir Hosseinvand
{"title":"Accelerating the design of stimuli- responsive chitosan nanocomposites for preservation: A machine learning and polymer informatics framework","authors":"Fizza Saleem ,&nbsp;Amir Hosseinvand","doi":"10.1016/j.nanoso.2026.101698","DOIUrl":"10.1016/j.nanoso.2026.101698","url":null,"abstract":"<div><div>This article provides an in-depth overview of how much has changed with respect to intelligent AI-guided chitosan-based packaging systems specifically for predictive food preservation. Chitosan is a biopolymer that is biodegradable, as well as antimicrobial. The authors present a \"programmatic\" or \"data-driven\" way to think about it and mention Chitosan as a polymer that because of its tunability can serve in an adaptive and innovative way to provide sustainable types of packaging. In this article, the authors present empirical formulation methods have moved to AI-accelerated way to make use of machine learning and polymer informatics in order to achieve reported reductions in experimental effort ranging from 60% to 80%, though these figures assume well-characterized descriptor spaces and have not been validated across multiple laboratories or chitosan sources, optimise multiple performance parameters (tensile strength, pore size and antimicrobial functionality). The authors then highlight some examples, including digitally engineered Chitosan systems that use nanofillers, bioactive agents and linkages that react based on outside stimuli, resulting in controlled releases of nutrients and other chemical compounds, together with the increased capability for self-learning packaging systems in order to exploit real-time detecting of pH, moisture levels and microbial contamination with respect to spoilage of food products. Finally, this article covers digital twin technology, reinforcements based on machine learning, and the intersection of digitally connected systems with respect to Industry 4.0 paradigma. Ultimately, the review reveals the most prominent research needs, such as the need for standardised chitosan AI data sets, ways of digital communication between devices (APIs), and ethical bases for enabling autonomous decision-making for material selection. This roadmap will allow for the creation of a chitosan packaging system that is able to optimise itself and create a transparent, sustainable and intuitive solution based on next-generation food preservation techniques.</div></div>","PeriodicalId":397,"journal":{"name":"Nano-Structures & Nano-Objects","volume":"46 ","pages":"Article 101698"},"PeriodicalIF":5.45,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148184107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and characterization of zinc oxide nanorods: Short review 氧化锌纳米棒的研究进展与表征
IF 5.45
Nano-Structures & Nano-Objects Pub Date : 2026-05-01 Epub Date: 2026-05-08 DOI: 10.1016/j.nanoso.2026.101670
J.D.L. de Sousa , L.A.P. Gonçalves , L.K.C.S. de Assis , R. Peña-Garcia , A.S. de Carvalho , K.S. da Silva , E. Padrón-Hernández
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