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Multi-objective field-based collaborative design of multi-layer IWP lattice enhancement mechanisms and mechanical properties 多层IWP晶格增强机制与力学性能的多目标协同设计
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-01-30 DOI: 10.1016/j.matdes.2026.115588
Mingzhi Yao , Penghuan Wang , Senlin Wang , Minzheng Zhu , Mingkai Tang
{"title":"Multi-objective field-based collaborative design of multi-layer IWP lattice enhancement mechanisms and mechanical properties","authors":"Mingzhi Yao ,&nbsp;Penghuan Wang ,&nbsp;Senlin Wang ,&nbsp;Minzheng Zhu ,&nbsp;Mingkai Tang","doi":"10.1016/j.matdes.2026.115588","DOIUrl":"10.1016/j.matdes.2026.115588","url":null,"abstract":"<div><div>Triply periodic minimal surface (TPMS) structures face challenges in balancing lightweighting with mechanical performance. This study proposes a multi-objective field-driven design strategy. Using laser powder bed fusion (LPBF) technology, we fabricated multi-layer lattice structures from 316 L stainless steel, including isotropic (IWP-IWP) and anisotropic (IWP-D) configurations. Through quasi-static compression experiments, finite element simulations, and theoretical predictions, their compressive behavior, energy absorption characteristics, and deformation mechanisms were systematically investigated. Results demonstrate that multi-layer structures exhibit significant performance enhancements over primary structures at equivalent densities. Specifically, the heterogeneous IWP-D-21% structure achieved maximum increases of 57.46% and 64.72% in yield strength and elastic modulus, respectively. While the IWP-IWP-27% structure achieved maximum increases of 76.11% and 59.87% in plateau stress and energy absorption per unit volume, respectively. The deformation mechanisms differ markedly: IWP-IWP exhibits “drum-shaped” deformation, while IWP-D demonstrates uniform overall deformation. The established finite element model based on Johnson-Cook constitutive mechanics accurately predicts mechanical properties with an error below 9.82%. This strategy opens new avenues for designing high-performance multifunctional lattice structures in fields such as aerospace critical load-bearing components.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115588"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
LPBF-processed high-density Nd-Fe-B Magnets: From gas atomized powders lpbf加工的高密度钕铁硼磁体:来自气体雾化粉末
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-02-03 DOI: 10.1016/j.matdes.2026.115610
Sudha Krishnan , Qilin Guo , Balamurugan Balasubramanian , Jeffrey E. Shield
{"title":"LPBF-processed high-density Nd-Fe-B Magnets: From gas atomized powders","authors":"Sudha Krishnan ,&nbsp;Qilin Guo ,&nbsp;Balamurugan Balasubramanian ,&nbsp;Jeffrey E. Shield","doi":"10.1016/j.matdes.2026.115610","DOIUrl":"10.1016/j.matdes.2026.115610","url":null,"abstract":"<div><div>Nd-Fe-B permanent magnets are crucial for high-performance applications, yet their fabrication by laser powder bed fusion (LPBF) is limited by defects, microstructural instability, and degradation of magnetic properties. This work examines printability, microstructure evolution, and defect formation in two Nd-rich gas-atomized Nd–Fe–B powders (Alloy A and Alloy B) as a function of laser power, scan speed, and hatch spacing. X-ray computed tomography (XCT) reveals that Alloy A consistently achieves &gt; 99% relative density but attains a maximum coercivity of 0.58 kOe, whereas a specific processing condition for Alloy B reaches ∼99.99% density with a coercivity of 0.49 kOe at higher energy input. These results demonstrate that the optimal LPBF processing window is strongly composition dependent, and the resulting insights provide practical guidelines for tailoring process parameters to improve the performance and reliability of Nd-Fe-B permanent magnets.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115610"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biomineralized manganese-based cascade nanosystem for augmented combinational therapy of oral cancer and dual-modal imaging-guided diagnosis 基于生物矿化锰级联纳米系统的口腔癌增强联合治疗和双模态成像引导诊断
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-02-01 DOI: 10.1016/j.matdes.2026.115575
Jinhuan Li , Ling Cai , Zhen Fu , Xiaodong Zhu , Yanqiang Huang , Yuan Wu , Jin Chen
{"title":"Biomineralized manganese-based cascade nanosystem for augmented combinational therapy of oral cancer and dual-modal imaging-guided diagnosis","authors":"Jinhuan Li ,&nbsp;Ling Cai ,&nbsp;Zhen Fu ,&nbsp;Xiaodong Zhu ,&nbsp;Yanqiang Huang ,&nbsp;Yuan Wu ,&nbsp;Jin Chen","doi":"10.1016/j.matdes.2026.115575","DOIUrl":"10.1016/j.matdes.2026.115575","url":null,"abstract":"<div><div>Due to the spatiotemporal specificity and high efficacy, tumor microenvironment (TME)-responsive nanozyme catalytic therapy has attracted considerable attentions. Nevertheless, it remained challenging to remodel TME for improving therapeutic benefits. Here, a TME-responsive nanozyme termed p-GOx-MnO<sub>2</sub>-ICG (p-GMI) was synthesized via biomimetic mineralization using ε-poly-L-lysine (EPL) as the template. The obtained p-GMI comprised glucose oxidase (GOx), MnO<sub>2</sub> nanoparticles, and photosensitizer indocyanine green (ICG), which exhibited prominent triple-enzyme activities (glucose oxidase, catalase-like, and peroxidase-like) enabling multimodal therapy. Specifically, starvation therapy (ST) was initiated through glutathione peroxidase-mediated glucose depletion. The released Mn<sup>2+</sup> in TME utilized the produced H<sub>2</sub>O<sub>2</sub> and gluconic acid to initiate Fenton-like reaction, enhancing chemodynamic therapy (CDT) efficacy. Meanwhile, the generated O<sub>2</sub> by catalase-like nanozyme can not only activate GOx but serve as the photodynamic therapy (PDT) substrate, leading to synergistically improved ST and PDT outcomes. Both <em>in vitro</em> and <em>in vivo</em> experiments indicated p-GMI nanozyme enabled fluorescence imaging/magnetic resonance imaging-guided ST/CDT/PDT combinational therapy, while also exhibiting favorable biosafety in the CAL-27 xenograft mouse model. Therefore, the built TME-responsive and dual-modal imaging guided p-GMI nanozymes as integrated cascade nanosystem held potentials in dealing with oral cancer.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115575"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving ultrahigh modulus of resilience and enhanced thermal stability in ZnOx/SU-8 interpenetrating network polymer nanocomposite nanopillars 在ZnOx/SU-8互穿网络聚合物纳米复合纳米柱中实现超高弹性模量和增强的热稳定性
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-01-28 DOI: 10.1016/j.matdes.2026.115577
Zhongyuan Li , Won-Il Lee , Nikhil Tiwale , Kyle P. Wade , Mark Aindow , Chang-Yong Nam , Seok-Woo Lee
{"title":"Achieving ultrahigh modulus of resilience and enhanced thermal stability in ZnOx/SU-8 interpenetrating network polymer nanocomposite nanopillars","authors":"Zhongyuan Li ,&nbsp;Won-Il Lee ,&nbsp;Nikhil Tiwale ,&nbsp;Kyle P. Wade ,&nbsp;Mark Aindow ,&nbsp;Chang-Yong Nam ,&nbsp;Seok-Woo Lee","doi":"10.1016/j.matdes.2026.115577","DOIUrl":"10.1016/j.matdes.2026.115577","url":null,"abstract":"<div><div>The modulus of resilience, a mechanical property that quantifies the maximum strain energy density a material can store during elastic deformation, is a crucial parameter for materials used in flexible displays, micro/nano-electro-mechanical system (M/NEMS) actuators, and ultra-sensitive pressure sensors. In this study, ZnO<sub>x</sub>/SU-8 nanocomposite nanopillars with a diameter of 300 nm, fully infiltrated with a uniformly distributed, interpenetrating amorphous ZnO<sub>x</sub> filler network, were synthesized via vapor-phase infiltration (VPI). In-situ uniaxial nano-compression tests revealed that the modulus of resilience of ZnO<sub>x</sub>/SU-8 reaches ∼ 12 MJ/m<sup>3</sup>, which is an ultrahigh value among all engineering materials with comparable strength. In addition, the synthesis fidelity, inorganic infiltration depth, and mechanical performance were all significantly improved compared to VPI-synthesized AlO<sub>x</sub> nanocomposites. Thermal stability, another key requirement for M/NEMS device materials operating under extreme environments, was also notably enhanced. Furthermore, partial crystallization of the amorphous ZnO<sub>x</sub> fillers during annealing contributed to an additional increase in modulus of resilience, reaching up to ∼ 13.9 MJ/m<sup>3</sup>. This work presents an effective fabrication strategy for producing nanostructured organic–inorganic hybrid nanocomposites with ultrahigh modulus of resilience and superior thermal stability, paving the way for their integration into next-generation flexible displays and high-performance M/NEMS devices working under harsh environments.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115577"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of Si accumulation in a 7108 Al–Zn–Mg alloy in the context of recycling 7108 Al-Zn-Mg合金中Si积累对回收利用的影响
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-01-28 DOI: 10.1016/j.matdes.2026.115578
Calin D. Marioara , Constantinos Hatzoglou , Yngve Langsrud , Grethe Waterloo
{"title":"The effect of Si accumulation in a 7108 Al–Zn–Mg alloy in the context of recycling","authors":"Calin D. Marioara ,&nbsp;Constantinos Hatzoglou ,&nbsp;Yngve Langsrud ,&nbsp;Grethe Waterloo","doi":"10.1016/j.matdes.2026.115578","DOIUrl":"10.1016/j.matdes.2026.115578","url":null,"abstract":"<div><div>Recycled 7108 alloys were simulated by additions of 0.2–0.3 wt% Si, alone or in combination with Mn or Cu. Si had a negative impact on mechanical properties by slowing precipitation kinetics and reducing the overall hardness due to the formation of L-phase needle/laths of the Al–Mg–Si-Cu alloy system co-existing with typical metastable η precipitates of the Al–Zn–Mg(–Cu) alloys, which led to a coarsening of the later. Annular dark field scanning transmission electron microscopy confirmed the presence of a new type of metastable η consisting of overlapping and laterally intertwined ORR<sup>−1</sup> and OR<sup>−1</sup>R sequences of stacked R and O units across the platelet thickness. Most L-phase precipitates contained C sub-units with Zn replacing Cu positions, associated with a local Zn enrichment of adjacent {1 0 0}Al planes at the interface. Adding 0.29 wt% Mn to a 7108 alloy with 0.20 wt% Si led to partial removal of Si from solid solution into α-AlSi(Fe + Mn) dispersoids. This increased the hardness, although at levels below the standard alloy with no Si added. The addition of 0.17 wt% Cu to the same alloy enhanced the precipitation of L-phase leading to the highest peak hardness and a shift of the hardening curve to longer aging times.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115578"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring interfacial reactive layer for high-strength maraging steel/high-entropy alloy dissimilar joints 高强度马氏体时效钢/高熵合金异种接头的裁剪界面反应层
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-01-30 DOI: 10.1016/j.matdes.2026.115540
Qianning Dai , Bijun Xie , Bin Xu , Yujie Song , Honglin Zhang , Zhengwang Zhu , Mingyue Sun , Dianzhong Li
{"title":"Tailoring interfacial reactive layer for high-strength maraging steel/high-entropy alloy dissimilar joints","authors":"Qianning Dai ,&nbsp;Bijun Xie ,&nbsp;Bin Xu ,&nbsp;Yujie Song ,&nbsp;Honglin Zhang ,&nbsp;Zhengwang Zhu ,&nbsp;Mingyue Sun ,&nbsp;Dianzhong Li","doi":"10.1016/j.matdes.2026.115540","DOIUrl":"10.1016/j.matdes.2026.115540","url":null,"abstract":"<div><div>Joining ultra-high-strength maraging steels and high-entropy alloys (HEAs) is crucial for advanced applications. However, the formation of brittle intermetallics often limits interfacial performance. Here, we demonstrate a rapid hot-compression bonding strategy that uses a niobium (Nb) interlayer to control interfacial reactions and produce a high-strength joint between 18Ni350 maraging steel and AlNbTi<sub>3</sub>Zr<sub>1.5</sub> HEA. The effects of bonding temperatures on the interfacial microstructures, mechanical properties, and fracture mechanisms were systematically investigated. An exceptional joint tensile strength exceeding 1 GPa was achieved at an optimal bonding temperature of 850 °C. This is attributed to the formation of a continuous, ultra-thin nanocrystalline Fe<sub>2</sub>Nb reactive layer (RL) at the 18Ni350/Nb interface, coupled with a well-bonded, intermetallic-free HEA/Nb interface. However, increasing the temperature to 1000 °C thickens the Fe<sub>2</sub>Nb RL to over 300 nm and promotes grain coarsening, reducing the joint strength to 747 MPa. Correspondingly, the fracture mode transitions from a complex path involving both interfaces and the interlayer at low temperatures to preferential fracture along the thickened Fe<sub>2</sub>Nb RL at 1000 °C. These findings reveal the central role of intermetallic design in governing interfacial performance, demonstrating that controlling interfacial nanostructures is a critical strategy for fabricating high-strength dissimilar joints.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115540"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced anti-plasticizer migration in GO/EPDM insulation for composite solid propellants: Experimental study and molecular dynamics simulation 复合固体推进剂在氧化石墨烯/三元乙丙橡胶绝缘中增强抗增塑剂迁移:实验研究和分子动力学模拟
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-02-05 DOI: 10.1016/j.matdes.2026.115622
Zhehong Lu , Fuyao Chen , Baoying Liu , Yuanqing Xu , Xiaomin Fang , Wei Zhao , Tao Ding , Jiantong Li , Yubing Hu , Yiqing Xue , Wei Jiang
{"title":"Enhanced anti-plasticizer migration in GO/EPDM insulation for composite solid propellants: Experimental study and molecular dynamics simulation","authors":"Zhehong Lu ,&nbsp;Fuyao Chen ,&nbsp;Baoying Liu ,&nbsp;Yuanqing Xu ,&nbsp;Xiaomin Fang ,&nbsp;Wei Zhao ,&nbsp;Tao Ding ,&nbsp;Jiantong Li ,&nbsp;Yubing Hu ,&nbsp;Yiqing Xue ,&nbsp;Wei Jiang","doi":"10.1016/j.matdes.2026.115622","DOIUrl":"10.1016/j.matdes.2026.115622","url":null,"abstract":"<div><div>Ethylene–propylene–diene monomer (EPDM) is widely used as an insulation in composite solid propellants. However, the migration of plasticizers from the propellant into the insulation seriously affects the long-term reliability. In this study, graphene oxide (GO)/EPDM insulation were prepared and their anti-migration behavior against typical plasticizers, including dioctyl sebacate (DOS), N-butyl-N-(2-nitroxyethyl) nitramine (Bu-NENA), and nitroethyl nitrate (En), was systematically investigated. The incorporation of GO significantly reduced the migration of plasticizers through nanobarrier mechanism. Migration experiments showed that the overall performance was optimized at a GO content of 3 phr. Compared with pure EPDM, the equilibrium migration amount of DOS decreased to 37.17%, Bu-NENA to 24.69%, and En to 41.86%. Dynamic mechanical analysis confirmed higher storage modulus and lower tan δ, while contact angle tests revealed reduced wettability to plasticizers, both evidencing stronger interfacial interactions and weaker thermodynamic compatibility. SEM and XRD demonstrated that GO nanosheets were well dispersed, constructing tortuous diffusion pathways. Molecular dynamics simulations (MD simulations) further verified the mechanism, showing that the diffusion coefficient of DOS decreased by ∼ 32% in GO/EPDM, and binding energy analysis indicated reduced compatibility between plasticizers and the GO/EPDM. This research provide a practical route for designing high-performance anti-migration insulation.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115622"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bio-based polyamide 1012 powder with strengthened hydrogen bonding interactions for sustainable laser additive manufacturing 增强氢键相互作用的生物基聚酰胺1012粉末用于可持续激光增材制造
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-02-12 DOI: 10.1016/j.matdes.2026.115659
Siying Xiang , Yi Luo , Jiebin Wen , Minzhe Peng , Guangxian Li , Yajiang Huang
{"title":"Bio-based polyamide 1012 powder with strengthened hydrogen bonding interactions for sustainable laser additive manufacturing","authors":"Siying Xiang ,&nbsp;Yi Luo ,&nbsp;Jiebin Wen ,&nbsp;Minzhe Peng ,&nbsp;Guangxian Li ,&nbsp;Yajiang Huang","doi":"10.1016/j.matdes.2026.115659","DOIUrl":"10.1016/j.matdes.2026.115659","url":null,"abstract":"<div><div>Bio-based polyamide powders, such as polyamide 1012 (PA1012), are promising materials for sustainable laser additive manufacturing (AM) technologies. However, they generally exhibit poor processability and high moisture sensitivity. Herein, we demonstrate that the AM behavior and water resistance of PA1012 could be enhanced by regulating intermolecular hydrogen bonding interactions. Stronger hydrogen bonds formed in PA1012 powders upon incorporating a thermoplastic phenolic resin (PF), leading to broader processing windows and lower melt viscosities, allowing the fabrication of parts with fewer defects and superior mechanical performance. Incorporating 5–15 wt% PF reduced the water absorption of PA1012 parts by 54–57 %, thereby largely improving their mechanical and dimensional stabilities in humid conditions. Moreover, PF suppressed the post-condensation and deterioration of unfused powders. Therefore, strengthening the hydrogen bonding interactions in polyamide powder offers a simple strategy to enhance the part performance in humid conditions and promote the sustainability of laser additive manufacturing.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115659"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Temperature and humidity effects on moisture diffusion in epoxy molding compound based on Fickian, dual-stage and Langmuir models 基于Fickian、dual-stage和Langmuir模型的温度和湿度对环氧成型复合材料中水分扩散的影响
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-01-28 DOI: 10.1016/j.matdes.2026.115550
Yang Yang , Rui Ma , Chen Peng , Haoning Dong , Jingyi Zhao , Hualong Fu , Meiying Su , Qidong Wang , Liqiang Cao
{"title":"Temperature and humidity effects on moisture diffusion in epoxy molding compound based on Fickian, dual-stage and Langmuir models","authors":"Yang Yang ,&nbsp;Rui Ma ,&nbsp;Chen Peng ,&nbsp;Haoning Dong ,&nbsp;Jingyi Zhao ,&nbsp;Hualong Fu ,&nbsp;Meiying Su ,&nbsp;Qidong Wang ,&nbsp;Liqiang Cao","doi":"10.1016/j.matdes.2026.115550","DOIUrl":"10.1016/j.matdes.2026.115550","url":null,"abstract":"<div><div>Epoxy molding compound (EMC) is a critical material in advanced packaging, as its moisture diffusion behavior significantly impacts the long-term reliability of packaged devices. The moisture diffusion behavior of EMC was investigated under varying temperature and humidity conditions through moisture absorption experiments, and the corresponding diffusion mechanisms were analyzed using the Fickian, dual-stage, and Langmuir models. The results showed that the Fickian model was only applicable under low humidity and temperature conditions. Although the dual-stage model fit well, its assumption of “independent diffusion of bound water” contradicted experimental observations. The Langmuir model also achieved high fitting accuracy. This study also established temperature–humidity-dependent functions for EMC moisture-related parameters. As the temperature increased, the bound water content increased exponentially, along with the transformation probability of free-bound water and the diffusion coefficient. Under medium humidity, the moisture content increased linearly with humidity, while the transformation probability and diffusion coefficient decreased linearly. At high humidity, capillary condensation became the dominant process, leading to a sharp increase in saturated moisture content, diffusion coefficient, and conversion probability. Low-temperature liquid-nitrogen adsorption experiments confirmed the occurrence of capillary condensation.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115550"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Graphene/MXene modified polyurethane flexible nanomembrane for dual-functional pressure-temperature sensing 双功能压力-温度传感用石墨烯/MXene改性聚氨酯柔性纳米膜
IF 7.9 2区 材料科学
Materials & Design Pub Date : 2026-03-01 Epub Date: 2026-02-03 DOI: 10.1016/j.matdes.2026.115606
Xue Zhang , Shengbin Cao , Xiaosong Liu , Tianchan Jia , Kai Dong
{"title":"Graphene/MXene modified polyurethane flexible nanomembrane for dual-functional pressure-temperature sensing","authors":"Xue Zhang ,&nbsp;Shengbin Cao ,&nbsp;Xiaosong Liu ,&nbsp;Tianchan Jia ,&nbsp;Kai Dong","doi":"10.1016/j.matdes.2026.115606","DOIUrl":"10.1016/j.matdes.2026.115606","url":null,"abstract":"<div><div>Flexible sensors have shown significant potential for applications in smart wearable devices, electronic skin, and health monitoring. However, developing high-performance sensors with a wide sensing range and high sensitivity using simple and cost-effective fabrication methods remains a challenge. Unlike traditional single-function sensors that can only detect strain, a flexible wearable pressure–temperature dual-functional sensor based on an electrospun nanofiber platform was developed in this study. A resistive pressure sensor was fabricated by spraying a graphene/MXene composite solution onto polyurethane (PU) nanofibers film. Additionally, a resistive temperature sensor was also coupled onto the pressure sensor by combining graphene/MXene with poly(3,4-ethylenedioxythiophene):poly (styrenesulfonate) (PEDOT:PSS), forming a dual-functional sensor. The fabricated sensors exhibit ultra-high sensitivity (GF ≈ 1200), fast response times (110 ms), high durability, and stable performance without degradation even after up to 5,000 cycles of motion. This dual-functional sensor can achieve precise temperature detection with a resolution of 1 °C. In practical applications, the sensor can be comfortably worn on the wrist, enabling real-time monitoring of subtle strain changes such as pulse beats and large strain variations like finger bending, as well as temperature fluctuations such as body temperature.</div></div>","PeriodicalId":383,"journal":{"name":"Materials & Design","volume":"263 ","pages":"Article 115606"},"PeriodicalIF":7.9,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146186003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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