Journal of Colloid and Interface Science最新文献_第8页

Synthesis of polyaniline tannate-modified carbon nanotubes by oxidative copolymerization as highly efficient corrosion inhibitors for mild steel in HCl solution 通过氧化共聚合成聚苯胺鞣酸改性碳纳米管，作为盐酸溶液中低碳钢的高效缓蚀剂。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-11-01 DOI: 10.1016/j.jcis.2024.10.189

Li-Chao Jing , Wen-Hao Geng , Ze-Long Bao , Peng-Fei Qian , Ru-Yu Chang , Tong-Yu Li , Yu-Long Guo , Di Zhang , Hong-Zhang Geng

{"title":"Synthesis of polyaniline tannate-modified carbon nanotubes by oxidative copolymerization as highly efficient corrosion inhibitors for mild steel in HCl solution","authors":"Li-Chao Jing , Wen-Hao Geng , Ze-Long Bao , Peng-Fei Qian , Ru-Yu Chang , Tong-Yu Li , Yu-Long Guo , Di Zhang , Hong-Zhang Geng","doi":"10.1016/j.jcis.2024.10.189","DOIUrl":"10.1016/j.jcis.2024.10.189","url":null,"abstract":"<div><div>Corrosion is a prevalent issue in industrial production, directly impacting the production process and causing severe damages. To mitigate this problem, corrosion inhibitors are highly desired. Herein, a novel type of nano corrosion inhibitor, referred to as PTCNT, was synthesized through an oxidative copolymerization method utilizing aniline, ammonium persulfate (APS), and tannic acid (TA)-modified multiwalled carbon nanotubes (MWCNTs). The results demonstrated that the PTCNT effectively inhibited the corrosion of mild steel in 1 M HCl solution, achieving the corrosion inhibition efficiency of 90.6 % at the concentration of 75 mg/L. Characterization results implied that the PTCNT adsorbed onto the surface of the mild steel, forming a protective shielding layer. Potentiodynamic polarization measurements proved that the PTCNT functioned as the hybrid corrosion inhibitor. Furthermore, the adsorption of PTCNT on the mild steel surface was investigated using adsorption isotherm and adsorption kinetic modeling. Quantum chemical calculations were used to elucidate the adsorption mechanism of PTCNT. These findings raise new avenues for the development of highly efficient corrosion inhibitors for the mild steel in HCl solutions.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 479-495"},"PeriodicalIF":9.4,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stabilizing zinc powder anodes via bifunctional MXene towards flexible zinc-ion batteries 通过双功能 MXene 稳定锌粉阳极，实现柔性锌-离子电池。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-11-01 DOI: 10.1016/j.jcis.2024.10.145

Zixuan Yang , Zhiyu Wang , Junlun Cao , Shana Wang , Weiwei Lei , Xungai Wang , Dan Liu

{"title":"Stabilizing zinc powder anodes via bifunctional MXene towards flexible zinc-ion batteries","authors":"Zixuan Yang , Zhiyu Wang , Junlun Cao , Shana Wang , Weiwei Lei , Xungai Wang , Dan Liu","doi":"10.1016/j.jcis.2024.10.145","DOIUrl":"10.1016/j.jcis.2024.10.145","url":null,"abstract":"<div><div>Flexible zinc (Zn) batteries have gained considerable attention as wearable energy storage devices because of their inherent safety and high theoretical capacity. However, conventional Zn anodes suffer from dendrite growth, high rigidity, and poor cycling stability issues, hindering their practical application in flexible zinc-ion batteries. Herein, a dendrite-free and flexible Zn anode is designed using direct ink writing (DIW) printed MXene as a flexible and highly conductive current collector and MXene-wrapped Zn powder (ZnP) as the active material by carefully optimising the rheological properties of MXene-based dispersion. As a result, the synergistic effects of the MXene-based current collector and the MXene protective layer promoted dendrite-free Zn deposition and prevented side reactions, achieving an outstanding cycling performance that exceeded 130 h at a high depth of discharge of 30%. When paired with a Vanadium pentoxide (V<sub>2</sub>O<sub>5</sub>)-based cathode, the flexible full cell demonstrated stable electrochemical performance under mechanical deformation and can power electronic devices, presenting a promising pathway for the development of flexible zinc-ion batteries.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 657-664"},"PeriodicalIF":9.4,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced electrocatalytic CH amination of toluene via tailored interfacial microenvironment 通过定制的界面微环境增强甲苯的电催化 CH amination。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-11-01 DOI: 10.1016/j.jcis.2024.10.192

Zong-Xu Li , Sheng Tian , Qing Hu , Xin-Yi Huang , Hong-Yi Tan , Jun-Kang Guo , Shuang-Feng Yin

{"title":"Enhanced electrocatalytic CH amination of toluene via tailored interfacial microenvironment","authors":"Zong-Xu Li , Sheng Tian , Qing Hu , Xin-Yi Huang , Hong-Yi Tan , Jun-Kang Guo , Shuang-Feng Yin","doi":"10.1016/j.jcis.2024.10.192","DOIUrl":"10.1016/j.jcis.2024.10.192","url":null,"abstract":"<div><div>Electrocatalytic C<img>H amination of hydrocarbons is a promising avenue for the synthesis of high-value C<img>N compounds. However, efficient activation of C<img>H bonds remains a significant challenge in electrocatalytic C<img>N coupling. Herein, we present a novel strategy to enhance the electrocatalytic conversion of toluene to <em>N</em>-benzylacetamide through a Ritter–type reaction by engineering a hydrophobic electrode–electrolyte interface using polytetrafluoroethylene (PTFE)-coated carbon paper (CP). The hydrophobic CP-based electrode exhibited a superior <em>N</em>-benzylacetamide productivity of 1860.9 mmol m<sup>−2</sup>h<sup>−1</sup> and a substantially higher Faradaic efficiency (FE) of 70.1 % compared to pure CP (41.5 %). Experimental results and density functional theory (DFT) calculations reveal that the PTFE coating promotes toluene adsorption and efficiently lowers the energy barrier for toluene dehydrogenation. Additionally, the hydrophobic interface effectively hinders water adsorption on the electrode, suppressing the competitive water oxidation reaction. This study underscores the crucial role of interfacial engineering in optimizing electrocatalytic C<img>N coupling reactions for the sustainable synthesis of high-value amide compounds.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 578-586"},"PeriodicalIF":9.4,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Surface-deformability dependent contact time of bouncing droplets on sessile soap bubbles 反弹液滴在无柄肥皂泡上的接触时间与表面变形性有关。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-10-31 DOI: 10.1016/j.jcis.2024.10.185

Xurui Zhang, Song-Chuan Zhao

{"title":"Surface-deformability dependent contact time of bouncing droplets on sessile soap bubbles","authors":"Xurui Zhang, Song-Chuan Zhao","doi":"10.1016/j.jcis.2024.10.185","DOIUrl":"10.1016/j.jcis.2024.10.185","url":null,"abstract":"<div><h3>Hypothesis</h3><div>The curvature of the free-standing liquid film is expected to modify its surface deformability, thereby affecting droplet bouncing dynamics and possibly tuning the liquid repellency performance in practical applications.</div></div><div><h3>Experiments</h3><div>In this study, the bouncing dynamics of water droplets on sessile soap bubbles with different curvatures has been experimentally investigated using high-speed camera.</div></div><div><h3>Finds</h3><div>To resist the impacting droplets, the soap bubbles is observed to show two types of deformation: the geometrical deformation caused by the total impacting force and the pressure distribution induced deformation from the droplet dynamics. The variation trend of the contact time of the droplet with the impact velocity is found to be highly dependent on the surface deformability of the soap bubble. This trend becomes non-monotonic when the soap bubble is large and more deformable. The decreasing contact time with increasing impact velocity can be well captured by a phenomenological model of coupled springs. The increasing contact time for the large soap bubbles at high impact velocities is due to the further compression of the soap bubble by the recoiling droplet, leading to the decoupling of the above two types of bubble deformation.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 326-333"},"PeriodicalIF":9.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142602381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mitochondrial dynamics and energy metabolism interference therapy for promoting photothermal sensitization 促进光热敏化的线粒体动力学和能量代谢干扰疗法。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-10-30 DOI: 10.1016/j.jcis.2024.10.180

Cuimei Liu , Sihang Cheng , Xue Zhou , Lu Li , Chungang Wang , Lingyu Zhang

{"title":"Mitochondrial dynamics and energy metabolism interference therapy for promoting photothermal sensitization","authors":"Cuimei Liu , Sihang Cheng , Xue Zhou , Lu Li , Chungang Wang , Lingyu Zhang","doi":"10.1016/j.jcis.2024.10.180","DOIUrl":"10.1016/j.jcis.2024.10.180","url":null,"abstract":"<div><div>Photothermal therapy (PTT) is minimally invasive, precisely controlled, and therapeutically effective treatment method. However, its efficacy is limited by the overexpression of heat shock proteins (HSP), which leads to cellular thermal blockade. Targeting mitochondria with PTT can enhance anticancer efficacy, as mitochondria encode genes related to HSP and provide energy for their production. Nevertheless, mitochondrial dynamics confer resistance to damage from external stimuli. Therefore, disrupting the balance of mitochondrial dynamics is essential to impede HSP production. Herein, we synthesized degradable Cu<sub>3</sub>BiS<sub>3</sub> (CBS) nanosheets (NSs) with one face modified by carboxylated triphenylphosphonium (TPP) to target mitochondria. This modification increases the production of exogenous reactive oxygen species (ROS) and induces the overexpression of dynamin-related protein 1 (Drp1), disrupting mitochondrial dynamic homeostasis. The other face was modified with carboxylated β-cyclodextrin (CD) to load the glycolysis inhibitor (2-deoxyglucose, 2DG), thereby reducing adenosine triphosphate (ATP) production in the extra-mitochondrial space, as glycolysis also occurs in the cytoplasm. The resulting TPP-CBS-2DG Janus NSs (JNSs) not only disrupt mitochondrial energy production, leading to cell starvation, but also inhibit HSP production. Consequently, TPP-CBS-2DG JNSs can enhance tumor thermal sensitivity in PTT, improving its efficacy. This work holds great promise for overcoming tumor heat resistance in PTT and provides a feasible method for fabricating selectively modified multifunctional NSs.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 429-440"},"PeriodicalIF":9.4,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Determination of interaction forces of (sub)-micron sized particles via the capillary rise method and colloidal probe atomic force microscopy: A combined approach 通过毛细管上升法和胶体探针原子力显微镜测定（亚）微米大小颗粒的相互作用力：一种综合方法。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-10-29 DOI: 10.1016/j.jcis.2024.10.187

Nane Kühn , Finn Frankenberg , Arno Kwade, Carsten Schilde

{"title":"Determination of interaction forces of (sub)-micron sized particles via the capillary rise method and colloidal probe atomic force microscopy: A combined approach","authors":"Nane Kühn , Finn Frankenberg , Arno Kwade, Carsten Schilde","doi":"10.1016/j.jcis.2024.10.187","DOIUrl":"10.1016/j.jcis.2024.10.187","url":null,"abstract":"<div><h3>Hypothesis</h3><div>The adhesion forces of particles in the submicron range play a decisive role in many particle processes such as agglomeration. These forces are influenced by many factors such as particle size, surface roughness, and contact area. The quantification of these influences should be possible by linking adhesion forces, measured with colloidal probe atomic force microscopy (cp-AFM), and surface energy, measured with the capillary rise method, using different adhesion force models.</div></div><div><h3>Experiments</h3><div>Silica-silica (SiO<sub>2</sub>-SiO<sub>2</sub>), polystyrene-polystyrene (PS-PS) and mixed adhesive force contacts of micrometer-sized particles were measured by cp-AFM. The surface energy was determined by the capillary rise method using the Owens-Wendt-Rabel-Kaelble (OWRK) method. Various adhesive force models were used to link the experimentally measured forces. In the adhesive force models, the particle size, the distance between the particles, and the roughness were varied.</div></div><div><h3>Findings</h3><div>Adhesion forces measured with the AFM can be linked to the OWRK method via adhesion force models such as the particle–particle Van-der-Waals (VDW) model, Rumpf’s roughness model, and a proprietary model for multiple particle–particle interactions with the surface energy. The main influencing factors are the substrate and particle roughness as well as their plastic or elastic behavior, which influences the contact area of the adhesive contact.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 696-713"},"PeriodicalIF":9.4,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tuning polymer micelle size and dynamics with solvophobic block structure 利用疏溶性嵌段结构调整聚合物胶束的尺寸和动力学。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-10-29 DOI: 10.1016/j.jcis.2024.10.186

Polina S. Kazaryan , Alexander V. Chertovich , Alexey A. Gavrilov

{"title":"Tuning polymer micelle size and dynamics with solvophobic block structure","authors":"Polina S. Kazaryan , Alexander V. Chertovich , Alexey A. Gavrilov","doi":"10.1016/j.jcis.2024.10.186","DOIUrl":"10.1016/j.jcis.2024.10.186","url":null,"abstract":"<div><div><em>Hypothesis:</em> Micelles formed by copolymers with mixed solvophobic blocks have attracted much attention lately. It is expected that changing the mixed blocks sequence can be used as a tool to influence the micellization behavior in a way that is not equivalent to simply varying the incompatibility parameter for pure diblock-copolymers.</div><div><em>Simulations:</em> By using coarse-grained simulations, the micellization behavior of copolymers with twelve types of solvophobic blocks, which differed in the fraction <em>f</em> as well as the sequence of solvophilic units in the solvophobic blocks, was studied. To enable quantitative comparison of systems with different <em>f</em>, an “effective” incompatibility parameter was introduced.</div><div><em>Findings:</em> The micelles size distributions and dynamics were found to be significantly dependent on both <em>f</em> and the fine details of the sequence. When the solvophobic block sequences were obtained statistically using a model of copolymerization, a strong influence of the reactivity ratios on the resulting micelles was found. Even a moderate tendency to form gradient-like sequences resulted in a noticeable increase in the micelles size. The dynamic properties of the micelles were studied by investigating the rate at which the chains escape from them. The addition of soluble units into the solvophobic block was shown to dramatically decrease the tendency to form kinetically frozen states; gradient-like sequences demonstrated more sluggish dynamics. The physical reasons for the observed peculiarities are discussed in detail.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 496-505"},"PeriodicalIF":9.4,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fucoidan-derived carbon dots as nanopenetrants of blood-brain barrier for Parkinson’s disease treatment 褐藻糖胶衍生碳点作为用于帕金森病治疗的血脑屏障纳米渗透剂。

IF 9.4 1区化学

Journal of Colloid and Interface Science Pub Date : 2024-10-28 DOI: 10.1016/j.jcis.2024.10.173

Miaomiao Han , Bingcheng Yi , Ruihan Song , Danyang Wang , Ning Huang , Yongzheng Ma , Longzhu Zhao , Shengnan Liu , Huiwen Zhang , Ruijie Xu , Jiaqi Lu , Xiaoli Shen , Qihui Zhou

{"title":"Fucoidan-derived carbon dots as nanopenetrants of blood-brain barrier for Parkinson’s disease treatment","authors":"Miaomiao Han , Bingcheng Yi , Ruihan Song , Danyang Wang , Ning Huang , Yongzheng Ma , Longzhu Zhao , Shengnan Liu , Huiwen Zhang , Ruijie Xu , Jiaqi Lu , Xiaoli Shen , Qihui Zhou","doi":"10.1016/j.jcis.2024.10.173","DOIUrl":"10.1016/j.jcis.2024.10.173","url":null,"abstract":"<div><div>Parkinson’s Disease (PD) stands as a prevalent neurodegenerative disorder. However, current pharmacotherapies for PD face challenges due to inadequate penetration through the blood–brain barrier (BBB), posing limitations on their therapeutic efficacy. Considering the potential of negatively charged carbon dots (CDs) in retaining functional groups from precursor molecules and vertically crossing the BBB, this study focuses on the utilization of fucoidan (FD), a promising pharmaceutical candidate with neuroprotective effects on dopamine-active neurons, for the development of negatively charged CDs through a one-step hydrothermal method, aiming to achieve efficient BBB penetration for PD treatment. The obtained fucoidan-derived carbon dots (FDCDs) exhibit the fundamental characteristics of CDs, such as nanostructure particles with an average diameter of less than 10 nm and significant photoluminescence ability. They also retain the abundant functional groups of SO<sub>4</sub><sup>2-</sup> from FD, resulting in a negatively charged surface. <em>In vitro</em> cell experiments were conducted to validate the ability of FDCDs to mitigate 1-Methyl-4-phenylpyridinium ion (MPP<sup>+</sup>)-induced damage in PC12 cells via anti-inflammatory pathway, antioxidant capacity, and anti-apoptotic effect. After confirming the ability of FDCDs to traverse the BBB using 3D small animal imaging, the intravenous administration of FDCDs via tail injection was observed to successfully restore the motor function in 1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP)-induced PD mice. Notably, no apparent biotoxic response was observed, highlighting the promising potential of FDCDs for effective PD therapy.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"680 ","pages":"Pages 516-527"},"PeriodicalIF":9.4,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142611363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0