Journal of Colloid and Interface Science最新文献

{"title":"Plasmonic bimetallic Au-Ag nanoclusters embedded in covalent organic frameworks as efficient photocatalysts for simultaneous nizatidine degradation and H2O2 evolution","authors":"Yujuan Guo ,&nbsp;Sheng Liu ,&nbsp;Jun Du ,&nbsp;Yuan Xue ,&nbsp;Zushun Xu ,&nbsp;Fangfang Du ,&nbsp;Qing Li ,&nbsp;Qianyuan He","doi":"10.1016/j.jcis.2026.139960","DOIUrl":"10.1016/j.jcis.2026.139960","url":null,"abstract":"<div><div>Covalent organic frameworks (COFs) demonstrate great potential as photocatalysts for the remediation of organic pollutants; however, their efficiency is often limited by the factor of rapid electron-hole recombination. In response to this challenge, we anchor ultrasmall (∼2.5 nm) bimetallic Au-Ag nanoclusters within the porous architecture of a nitrogen-rich COFs scaffold. The nitrogenated frameworks not only provide a high surface area and abundant active sites but also facilitate electron transfer. Meanwhile, the ultrafine Au-Ag nanoclusters exhibit strong plasmonic coupling, serving as dual light-harvesting units and electron transfer mediators. This synergistic configuration enhances carrier separation, enabling plasmon-exciton co-driven catalysis. The optimized COF-Au-Ag achieves simultaneous degradation of nizatidine (NZTD) and production of hydrogen peroxide <strong>(</strong>H₂O₂<strong>)</strong> via a unified photocatalytic mechanism centered on efficient charge separation and directional migration. This photocatalyst illustrates excellent recyclability in five consecutive cycles of use, offering a novel approach for designing multifunctional COF-based photocatalytic systems.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139960"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146035896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anion-induced dynamic built-in electric field enables directional migration of lithium polysulfides and bidirectional catalysis.","authors":"Li Zhang, Rui Ma, Bowen Lin, Yan Wang, Rongrong Liang, Mengfei Wei, Lifan Wu","doi":"10.1016/j.jcis.2026.140672","DOIUrl":"https://doi.org/10.1016/j.jcis.2026.140672","url":null,"abstract":"<p><p>Lithium‑sulfur batteries (LSBs) are constrained by the shuttle effect and sluggish redox kinetics of lithium polysulfides (LiPSs), originating from the imbalance among adsorption, migration, and conversion at the cathode interface. Herein, we propose an anion-induced dynamic built-in electric field (BIEF) strategy via a homologous CoSe₂/CoS₂@NC heterostructure. Theoretical and experimental results demonstrate that the electronegativity difference between S^2- and Se^2- creates a work-function mismatch, triggering interfacial charge redistribution and forming a moderate, adaptive BIEF. This field not only enhances LiPSs adsorption but also directionally guides their migration during cycling, while simultaneously lowering the energy barriers for SS bond cleavage and Li₂S nucleation/decomposition. As a result, the CoSe₂/CoS₂@NC cathode delivers a reversible capacity of 721.1 mAh g^-1 after 1100 cycles at 0.2C with a decay rate of only 0.04% per cycle, and retains 1090.2 mAh g^-1 under high sulfur loading (4.8 mg cm^-2) and lean electrolyte (E/S = 7.08 μL mg^-1). This work elucidates how anion-modulated dynamic BIEF accelerate bidirectional sulfur electrochemistry, providing a general interface-engineering principle for high performance LSBs and related electrochemical systems.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"720 ","pages":"140672"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147831967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Indium surface gradient doped ZnS for efficient photodegradation under visible-light irradiation.","authors":"Shunhang Wei, Yihui Xu, Zebo Fang, Lirui Yu, Qifeng Liang, Shufang Chang, Jibao Wu","doi":"10.1016/j.jcis.2026.140658","DOIUrl":"https://doi.org/10.1016/j.jcis.2026.140658","url":null,"abstract":"<p><p>ZnS generally exhibits poor photocatalytic activity due to its wide bandgap and rapid carrier recombination. In this work, indium surface gradient doped ZnS was successfully synthesized through a chemical vapor strategy (In₂O₃ served as the evaporation source). Indium surface doping not only expanded the absorption edge to the visible-light region by forming impurity levels, but also efficiently enhanced carrier separation and transfer ability (much superior to In element bulk doping). In addition, it resulted in a more negative conduction band position, which was conducive to the generation of superoxide radicals as the main active species through reduction reactions. Thereby, the optimal indium surface gradient doped ZnS achieved a degradation rate of ∼70% for levofloxacin within 1 h under visible-light irradiation, which was ∼3.3 times that of indium bulk doped ZnS. It also exhibited good dye degradation activity, and its degradation pathway for levofloxacin was also investigated. It is hoped that this work can provide a new perspective for the design of surface-doped photocatalysts.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"720 ","pages":"140658"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147855588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomimetic lipid nanoparticles for RNA delivery to breast cancer microenvironment cells by enhanced homotypic and heterotypic adhesion","authors":"Stefania Garbujo ,&nbsp;Chiara Baioni ,&nbsp;Andrea Banfi ,&nbsp;Leonardo Bolis ,&nbsp;Giulia Bonvini ,&nbsp;Elena Del Favero ,&nbsp;Paola Gagni ,&nbsp;Alessandro Gori ,&nbsp;Linda Barbieri ,&nbsp;Marco Davide Giustra ,&nbsp;Giulia Tomaino ,&nbsp;Lucia Morelli ,&nbsp;Clizia Chinello ,&nbsp;Fulvio Magni ,&nbsp;Lucia Salvioni ,&nbsp;Miriam Colombo ,&nbsp;Davide Prosperi","doi":"10.1016/j.jcis.2026.139972","DOIUrl":"10.1016/j.jcis.2026.139972","url":null,"abstract":"<div><div>Lipid nanoparticles (LNPs) have emerged as a clinically validated nonviral RNA delivery system. However, their limited tumor targeting remains challenging in oncology. In this work, LNPs were functionally integrated with cancer cell membrane components to enhance their targeting capabilities. The natural composition of tumor membranes was leveraged to promote both homotypic and heterotypic adhesion, exploiting cancer cell self-recognition and interactions with stromal cells in the tumor microenvironment. A biomimetic nanocarrier was developed by cloaking RNA-loaded LNPs with nanoghosts obtained from the membrane of triple negative breast cancer cells. Nanoghosts were dye-labeled and comprehensively characterized in terms of size, surface charge, protein composition, and membrane sidedness. The functional orientation of nanoghost membrane-associated proteins mediated homotypic binding with 4 T1 cells and heterotypic recognition of functionally validated cancer-associated fibroblasts and exhibited higher affinity for the latter, as confirmed through flow cytometry and confocal microscopy. RNA-LNPs were incorporated into nanoghosts using ultrasound-assisted fusion, yielding stable biomimetic LNPs with a multilamellar mRNA-LNP core enveloped by a nanoghost shell, as confirmed by Small-Angle X-ray Scattering. While uncoated LNPs showed negligible interaction with heterotypic cells, biomimetic LNPs displayed strong affinity for cancer-associated fibroblasts, enabling efficient internalization and RNA transfection. Additionally, the biomimetic coating enhanced LNP uptake in homotypic 4 T1 cells, resulting in significantly improved biological activity compared to uncoated LNPs. This work provides proof of concept that RNA-LNPs can be effectively integrated into biomimetic carriers to enable dual targeting of tumor and stromal cells. The enhanced selectivity and delivery performance of biomimetic LNPs highlight their therapeutic potential for overcoming stromal barriers in desmoplastic tumors such as triple negative breast cancer.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139972"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146083748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrigendum to “Self-oxygenating nanoplatform integrating CRISPR/Cas9 gene editing and immune activation for highly efficient photodynamic therapy” [J. Colloid Interface Sci. 693 (2025) 137632]","authors":"Shi-Cheng Tian ,&nbsp;Xun-Huan Song ,&nbsp;Ke-Ke Feng ,&nbsp;Cheng-Lei Li ,&nbsp;Yi-Fan Tu ,&nbsp;Yong-Shan Hu ,&nbsp;Jing-Wei Shao","doi":"10.1016/j.jcis.2026.139906","DOIUrl":"10.1016/j.jcis.2026.139906","url":null,"abstract":"","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139906"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146035778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanistic study on the enhanced N2 selectivity for NH3 selective oxidation over Pt-encapsulated Cu-ZSM-5 catalysts","authors":"Weixiang Chen ,&nbsp;Yuxiong Wang ,&nbsp;Yaoyu Zhang ,&nbsp;Yue Liu ,&nbsp;Zhongbiao Wu","doi":"10.1016/j.jcis.2026.139941","DOIUrl":"10.1016/j.jcis.2026.139941","url":null,"abstract":"<div><div>Ammonia (NH₃) has emerged as a promising zero‑carbon energy source for energy and transportation. However, its utilization leads to the emission of NH₃, which contributes to PM_2.5 formation and disrupts the global nitrogen cycle. Selective catalytic oxidation (SCO) represents a mainstream technology for NH₃ treatment, yet achieving both sufficient activity and high N₂ selectivity across a broad temperature window remains challenging. Here, a core-shell Pt@Cu-ZSM-5 catalyst was employed for NH₃ catalytic abatement by encapsulating metallic Pt clusters (Pt⁰) inside the channels of Cu ion-exchanged ZSM-5. The optimal sample achieved a complete NH₃ conversion below 250 °C and maintained over 92% N₂ selectivity from 250 to 500 °C due to the synergism between the Pt−Cu dual sites. Mechanistic studies revealed that NH₃ oxidation preferentially occurred on Pt⁰ sites with excellent redox capacity to produce N₂O and NO_<em>x</em> at relatively low and high temperatures, respectively. And the presence of Cu ions (Cu^δ+) could efficiently both inhibit the formation of N₂O on Pt⁰ sites and reduce NO_<em>x</em> emission, thereby improving the N₂ selectivity. At relatively low temperatures, NH₃-solvated Cu⁺(NH₃)₂ could migrate to the adjacent Pt sites and reduce the adsorbed NO* species from NH₃ oxidation, damping the formation of N₂O. At high temperatures, the NO and NO₂ emitted from Pt⁰ sites could be reduced on Cu^δ+ sites via a typical selective catalytic reduction. This study provides new insights into the rational design of bifunctional SCO catalysts and offers a comprehensive understanding of the synergistic effects in Pt−Cu dual-site systems.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139941"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146035782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Glutathione- responsive Phototheranostic platform for imaging-guided enhanced oxidation photoimmunotherapy-ferroptosis synergistic hepatocellular carcinoma therapy","authors":"Zhuanxia He ,&nbsp;Limin Zhang ,&nbsp;Xiujun Gao ,&nbsp;Jiaxin Zhong ,&nbsp;Yanqi Zhang ,&nbsp;Feng Gao","doi":"10.1016/j.jcis.2026.139927","DOIUrl":"10.1016/j.jcis.2026.139927","url":null,"abstract":"<div><div>Phototheranostics have emerged as a promising approach in precision medicine. However, the poor tumor selectivity of photosensitizers, insufficient oxidative stress and the intrinsic antioxidant system of tumors compromise the efficacy of phototherapeutic strategies. In this study, we designed a novel phototheranostic platform (ICP@SRF-GPC3 NPs) for active tumor-targeted imaging and oxidation-enhanced photoimmunotherapy-ferroptosis combined therapy. The ICP@SRF-GPC3 NPs were fabricated by conjugating near-infrared photosensitizer IR780 with cystine-polyethylene glycol, modifying it with the Glypican-3 monoclonal antibody and encapsulating of the ferroptosis inducer sorafenib (SRF). ICP@SRF-GPC3 NPs with improved water solubility and liver tumor specificity can produce reactive oxygen species (ROS) upon 808 nm laser irradiation and enable photoimmunotherapy-mediated oxidation treatment. In the tumor microenvironment, the high concentration of glutathione (GSH) cleaved the linkage between the IR780 and the cystine moiety, realizing superior near-infrared fluorescence imaging and synergistic photoimmunotherapy-ferroptosis therapy. The released SRF inhibited cystine/glutamate antiporter, thereby blocking cystine uptake in tumor cells and suppressing GSH synthesis. By depleting existing GSH reserves while simultaneously inhibiting its biosynthetic pathway, ICP@SRF-GPC3 NPs effectively exhausted intracellular GSH, weakening the anti-oxidation ability of tumor cells and amplifying oxidative stress. In a BALB/c nude mouse model bearing GPC3-overexpressing Hepa1–6 allografts, the combination of photoimmunotherapy with ferroptosis not only effectively suppressed primary tumor growth through amplified ROS generation, but also promoted damage-associated molecular patterns release, thereby eliciting a robust immune response that eliminated metastatic and distant tumors. Overall, ICP@SRF-GPC3 NPs offers a promising strategy for regulating GSH and ROS levels in synergistic photoimmunotherapy-ferroptosis antitumor therapy, which has potential clinical applications.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139927"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146016802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recycling two wastes for constructing vanadium nitride/vanadium trioxide dual-decorated carbonfiber interlayer and porous carbon to improve Lithium-Sulfur batteries","authors":"Li Wang ,&nbsp;Jiao Li ,&nbsp;Yun Chen ,&nbsp;Qiuyue Shi ,&nbsp;Yan Zheng ,&nbsp;Linyue Qu ,&nbsp;Mingwu Xiang ,&nbsp;Fangkun Li ,&nbsp;Junming Guo ,&nbsp;Wei Bai ,&nbsp;Dengbang Jiang","doi":"10.1016/j.jcis.2026.139934","DOIUrl":"10.1016/j.jcis.2026.139934","url":null,"abstract":"<div><div>Reasonably constructing functional interlayers and sulfur host materials to synergistically suppress the shuttle effect of lithium polysulfides (LiPSs) and enhance reaction kinetics is key to effectively improve electrochemical performance of lithium‑sulfur (Li<img>S) batteries. Herein, two wastes including cotton masks and coffee shells are recycled to prepare the polar vanadium nitride (VN)/vanadium trioxide (V₂O₃) co-decorated carbon fiber functional interlayer and biological porous carbon via facile liquid-phase impregnation and pyrolysis approaches. The functional interlayer as a physical barrier to suppress the dissolution and shutting of the LiPSs, whilst providing an interconnected highly conductive network for boosting electronic transmission. Especially, the V₂O₃ and VN particles exhibit strong synergistic adsorption capacity of the LiPSs by a density functional theory calculation due to the abundant empty 3d orbitals of vanadium atoms and strong polarity of nitrogen/oxygen atoms. Additionally, the redox conversion of the LiPSs is also synchronously accelerated by the conductive VN. So, the functional interlayer endows the biological porous carbon‑sulfur composite cathode materials with good electrochemical performances. The initial discharge capacity is 1018.3 mAh g⁻¹ at 0.2C, whilst 802.5 mAh g⁻¹ can be maintained after 200 cycles. After 500 cycles at 2.0C, the discharge capacity of 540.1 mAh g⁻¹ is also obtained. Even with the high sulfur content of 80 wt% and 90 wt%, the relatively good electrochemical performances are also achieved.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139934"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146035917","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Aqueous-phase synthesis of Ni2P within clay nanotube lumens for efficient catalytic nitroarene hydrogenation","authors":"Guoxi Deng ,&nbsp;Yaotao Huang ,&nbsp;Mingxian Liu ,&nbsp;Xiaodan Chen ,&nbsp;Yuri Lvov","doi":"10.1016/j.jcis.2026.139948","DOIUrl":"10.1016/j.jcis.2026.139948","url":null,"abstract":"<div><div>The widespread application of transition metal phosphides (TMPs) is often constrained by the use of hazardous and costly phosphorus precursors as well as energy-intensive synthetic routes. To address these limitations, we report a green aqueous-phase synthesis of nickel phosphide (Ni₂P) nanomaterials using sodium phosphathynolate (NaOCP) as a safe phosphorus source and nickel (II) chloride as the metal precursor. The resulting Ni₂P nanoparticles exhibit long-term stability, as indicated by the well-maintained X-ray diffraction patterns after 30 days of storage under ambient conditions. This synthetic approach was further extended to fabricate a spatially confined Ni₂P@HNTs nanocomposite through in situ growth inside the lumen of halloysite nanotubes (HNTs). The confined environment led to a significant reduction in Ni₂P particle size (from ∼80 nm to ∼3 nm) and promoted uniform dispersion. Both Ni₂P and Ni₂P@HNTs show high catalytic activity in the transfer hydrogenation of nitroarenes, delivering up to 98% yield with broad substrate scope. Notably, the Ni₂P@HNTs composite displays enhanced stability and recyclability compared to unsupported Ni₂P in the reduction of both nitrobenzene and substituted nitroarenes. This work establishes NaOCP as the phosphorus precursor for the aqueous synthesis of robust TMPs and demonstrates the efficacy of clay nanotube confinement in designing high-performance catalytic systems.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139948"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146045971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interface engineering of nickel molybdenum nitride@nickel cobalt molybdenum layered double hydroxide heterostructure with enhanced hydroxyl ion adsorption ability for supercapacitors","authors":"Liu Wan,&nbsp;Cheng Du,&nbsp;Mingjiang Xie,&nbsp;Jian Chen,&nbsp;Yan Zhang","doi":"10.1016/j.jcis.2026.139937","DOIUrl":"10.1016/j.jcis.2026.139937","url":null,"abstract":"<div><div>The construction of well-defined heterointerfaces represents an efficient strategy for boosting supercapacitor electrode performance. Herein, we fabricated an advanced nickel molybdenum nitride (Ni_0.2Mo_0.8N)@nickel cobalt molybdenum-layered double hydroxide (NiCoMo-LDH) heterostructure by electrodeposition of NiCoMo-LDH on a porous Ni_0.2Mo_0.8N backbone. This heterostructure design integrates Ni_0.2Mo_0.8N and NiCoMo-LDH into an interconnected three-dimensional (3D) nanosheet network, which enhances redox activity, facilitates rapid ion transport, and ensures structural integrity. Density functional theory (DFT) analyses substantiate that the heterointerface engineering between Ni_0.2Mo_0.8N and NiCoMo-LDH induces charge redistribution at the heterointerfaces, improves charge carrier mobility, and enhances hydroxyl ion adsorption capability. The Ni_0.2Mo_0.8N@NiCoMo-LDH heterostructure electrode delivers a specific capacity of 1054.4C g⁻¹ / 2425.2 mC cm⁻² at 1 A g⁻¹ while maintaining 95.7% capacity retention after 5000 cycles, outperforming the pristine Ni_0.2Mo_0.8N and NiCoMo-LDH in both capacity and durability. Furthermore, the hybrid supercapacitor (HSC) device based on the Ni_0.2Mo_0.8N@NiCoMo-LDH cathode achieves an energy density of 82.6 Wh kg⁻¹ at 794.4 W kg⁻¹, coupled with robust long-term cycling performance (96.0% capacity maintenance over 20,000 cycles). These results validate the effectiveness of rational heterostructure design with complementary constituents for next-generation energy storage applications.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"709 ","pages":"Article 139937"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146027846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}