Frontiers in Nanotechnology最新文献

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Epitaxial ferroelectric memristors integrated with silicon 与硅集成的外延铁电忆阻器
Frontiers in Nanotechnology Pub Date : 2022-12-16 DOI: 10.3389/fnano.2022.1092177
Miguel Rengifo, M.H. Aguirre, M. Sirena, U. Lüders, D. Rubi
{"title":"Epitaxial ferroelectric memristors integrated with silicon","authors":"Miguel Rengifo, M.H. Aguirre, M. Sirena, U. Lüders, D. Rubi","doi":"10.3389/fnano.2022.1092177","DOIUrl":"https://doi.org/10.3389/fnano.2022.1092177","url":null,"abstract":"Neuromorphic computing requires the development of solid-state units able to electrically mimic the behavior of biological neurons and synapses. This can be achieved by developing memristive systems based on ferroelectric oxides. In this work we fabricate and characterize high quality epitaxial BaTiO3-based memristors integrated with silicon. After proving the ferroelectric character of BaTiO3 we tested the memristive response of LaNiO3/BaTiO3/Pt microstructures and found a complex behavior which includes the co-existence of volatile and non-volatile effects, arising from the modulation of the BaTiO3/Pt Schottky interface by the direction of the polarization coupled to oxygen vacancy electromigration to/from the interface. This produces remanent resistance loops with tunable ON/OFF ratio and asymmetric resistance relaxations. These properties might be harnessed for the development of neuromorphic hardware compatible with existing silicon-based technology.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43704706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nano-antivirals: A comprehensive review 纳米抗病毒药物:综述
Frontiers in Nanotechnology Pub Date : 2022-12-13 DOI: 10.3389/fnano.2022.1064615
F. Hussain, Naveed Qasim Abro, N. Ahmed, S. Memon, Najma Memon
{"title":"Nano-antivirals: A comprehensive review","authors":"F. Hussain, Naveed Qasim Abro, N. Ahmed, S. Memon, Najma Memon","doi":"10.3389/fnano.2022.1064615","DOIUrl":"https://doi.org/10.3389/fnano.2022.1064615","url":null,"abstract":"Nanoparticles can be used as inhibitory agents against various microorganisms, including bacteria, algae, archaea, fungi, and a huge class of viruses. The mechanism of action includes inhibiting the function of the cell membrane/stopping the synthesis of the cell membrane, disturbing the transduction of energy, producing toxic reactive oxygen species (ROS), and inhibiting or reducing RNA and DNA production. Various nanomaterials, including different metallic, silicon, and carbon-based nanomaterials and nanoarchitectures, have been successfully used against different viruses. Recent research strongly agrees that these nanoarchitecture-based virucidal materials (nano-antivirals) have shown activity in the solid state. Therefore, they are very useful in the development of several products, such as fabric and high-touch surfaces. This review thoroughly and critically identifies recently developed nano-antivirals and their products, nano-antiviral deposition methods on various substrates, and possible mechanisms of action. By considering the commercial viability of nano-antivirals, recommendations are made to develop scalable and sustainable nano-antiviral products with contact-killing properties. Graphical Abstract","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44268584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Layered GeI2: A wide-bandgap semiconductor for thermoelectric applications–A perspective 层状GeI2:热电应用的宽禁带半导体
Frontiers in Nanotechnology Pub Date : 2022-12-12 DOI: 10.3389/fnano.2022.1095291
Archit Dhingra
{"title":"Layered GeI2: A wide-bandgap semiconductor for thermoelectric applications–A perspective","authors":"Archit Dhingra","doi":"10.3389/fnano.2022.1095291","DOIUrl":"https://doi.org/10.3389/fnano.2022.1095291","url":null,"abstract":"Layered GeI2 is a two-dimensional wide-bandgap van der Waals semiconductor, which is theorized to be a promising material for thermoelectric applications. While the value of the experimentally extrapolated indirect optical bandgap of GeI2 is found to be consistent with the existing theoretical calculations, its potential as a thermoelectric material still lacks experimental validation. In this Perspective, recent experimental efforts aimed towards investigating its dynamical properties and tuning its bandgap further, via intercalation, are discussed. A thorough understanding of its dynamical properties elucidates the extent of electron-phonon scattering in this system, knowledge of which is crucial in order to open pathways for future studies aiming to realize GeI2-based thermoelectric devices.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48054616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Semiconductor clusters: Synthetic precursors for colloidal quantum dots 半导体团簇:胶体量子点的合成前体
Frontiers in Nanotechnology Pub Date : 2022-12-09 DOI: 10.3389/fnano.2022.1069178
Ji‐Yong Shin, Mahnmin Choi, Meeree Kim, Sohee Jeong
{"title":"Semiconductor clusters: Synthetic precursors for colloidal quantum dots","authors":"Ji‐Yong Shin, Mahnmin Choi, Meeree Kim, Sohee Jeong","doi":"10.3389/fnano.2022.1069178","DOIUrl":"https://doi.org/10.3389/fnano.2022.1069178","url":null,"abstract":"Semiconductor clusters have been implicated as reaction intermediates between molecular precursors and colloidal quantum dots (CQDs). The success of isolation of semiconductor clusters have enabled detailed investigation of the atomic information of semiconductor clusters. The identification of atomic information has emerged as an important topic because knowledge of the structure-function relationship of intermediate clusters has been helpful to reveal the synthetic mechanism of CQDs. Recently, they have been utilized as the synthetic precursors for CQDs, which was not readily achieved using conventional molecular precursors. This mini review briefly introduces the current understanding of their atomic information such as the composition, structure, and surface. We then discuss advantages, limitations, and the perspective of semiconductor clusters as a precursor for synthesis of CQDs.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43240023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of nanomaterials against SARS-CoV-2: An emphasis on their usefulness against emerging variants of concern 纳米材料抗SARS-CoV-2的应用:强调其对新出现的关注变体的有用性
Frontiers in Nanotechnology Pub Date : 2022-12-09 DOI: 10.3389/fnano.2022.1060756
Reema Iqbal, Sadia Khan, H. M. Ali, Maham Khan, Shahid Wahab, Tariq Khan
{"title":"Application of nanomaterials against SARS-CoV-2: An emphasis on their usefulness against emerging variants of concern","authors":"Reema Iqbal, Sadia Khan, H. M. Ali, Maham Khan, Shahid Wahab, Tariq Khan","doi":"10.3389/fnano.2022.1060756","DOIUrl":"https://doi.org/10.3389/fnano.2022.1060756","url":null,"abstract":"Researchers are now looking to nanomaterials to fight serious infectious diseases that cause outbreaks and even pandemics. SARS-CoV-2 brought chaos to almost every walk of life in the past 2 years and has challenged every available treatment method. Although vaccines were developed in no time against it, the most pressing issue was the emergence of variants of concern arising because of the rapidly evolving viral strains. The higher pathogenicity and, in turn, the higher mortality rate of infections caused by these variants renders the existing vaccines less effective and the effort to produce further vaccines a costly endeavor. While several techniques, such as immunotherapy and repurposed pharmaceutical research, are being studied to minimize viral infection, the fundamentals of nanotechnology must also be considered to enhance the anti-SARS-CoV-2 efforts. For instance, silver nanoparticles (AgNPs) have been applied against SARS-CoV-2 effectively. Similarly, nanomaterials have been tested in masks, gloves, and disinfectants to aid in controlling SARS-CoV-2. Nanotechnology has also contributed to diagnoses such as rapid and accurate detection and treatment such as the delivery of mRNA vaccines and other antiviral agents into the body. The development of polymeric nanoparticles has been dubbed a strategy of choice over traditional drugs because of their tunable release kinetics, specificity, and multimodal drug composition. Our article explores the potential of nanomaterials in managing the variants of concern. This will be achieved by highlighting the inherent ability of nanomaterials to act against the virus on fronts such as inhibition of SARS-CoV-2 entry, inhibition of RNA replication in SARS-CoV-2, and finally, inhibition of their release. In this review, a detailed discussion on the potential of nanomaterials in these areas will be tallied with their potential against the current and emerging future variants of concern.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47559792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controlled CO labilization of tungsten carbonyl precursors for the low-temperature synthesis of tungsten diselenide nanocrystals 低温合成二硒化钨纳米晶的羰基钨前驱体可控CO稳定化
Frontiers in Nanotechnology Pub Date : 2022-12-08 DOI: 10.3389/fnano.2022.1026635
Jessica Q. Geisenhoff, Hang Yin, Natacha Oget, Haeun Chang, Linfeng Chen, Alina M. Schimpf
{"title":"Controlled CO labilization of tungsten carbonyl precursors for the low-temperature synthesis of tungsten diselenide nanocrystals","authors":"Jessica Q. Geisenhoff, Hang Yin, Natacha Oget, Haeun Chang, Linfeng Chen, Alina M. Schimpf","doi":"10.3389/fnano.2022.1026635","DOIUrl":"https://doi.org/10.3389/fnano.2022.1026635","url":null,"abstract":"We report a low-temperature colloidal synthesis of WSe2 nanocrystals from tungsten hexacarbonyl and diphenyl diselenide in trioctylphosphine oxide (TOPO). We identify TOPO-substituted intermediates, W(CO)5TOPO and cis-W(CO)4(TOPO)2 by infrared spectroscopy. To confirm these assignments, we synthesize aryl analogues of phosphine-oxide-substituted intermediates, W(CO)5TPPO (synthesized previously, TPPO = triphenylphosphine oxide) and cis-W(CO)4(TPPO)2 and fac-W(CO)3(TPPO)3 (new structures reported herein). Ligation of the tungsten carbonyl by either the alkyl or aryl phosphine oxides results in facile labilization of the remaining CO, enabling low-temperature decomposition to nucleate WSe2 nanocrystals. The reactivity in phosphine oxides is contrasted with syntheses containing phosphine ligands, where substitution results in decreased CO labilization and higher temperatures are required to induce nanocrystal nucleation.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47686529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanomaterials in the future biotextile industry: A new cosmovision to obtain smart biotextiles 纳米材料在未来生物纺织工业中的应用:获得智能生物纺织品的新视野
Frontiers in Nanotechnology Pub Date : 2022-12-02 DOI: 10.3389/fnano.2022.1056498
Keyla Fuentes, Melissa Gómez, Hernán Rebolledo, José Miguel Figueroa, P. Zamora, Leopoldo Naranjo-Briceño
{"title":"Nanomaterials in the future biotextile industry: A new cosmovision to obtain smart biotextiles","authors":"Keyla Fuentes, Melissa Gómez, Hernán Rebolledo, José Miguel Figueroa, P. Zamora, Leopoldo Naranjo-Briceño","doi":"10.3389/fnano.2022.1056498","DOIUrl":"https://doi.org/10.3389/fnano.2022.1056498","url":null,"abstract":"For centuries, man has dominated the development of fibers and textiles to make clothing that protects them against environmental adversities, and gradually dissimilar cultural and ethnic identity traits have been created. Our garments are composed of natural elements such as animal leather, vegetable fibers, and synthetic textiles that result in ultra-resistant and durable materials. However, the textile industry has a non-sustainable character mainly because population growth will limit the use of natural resources, such as land and water, exclusively for food. At the same time, petrochemical-derived materials will gradually be replaced by more biodegradable alternatives due to their toxic accumulation in the local environment and their contribution to global climate change. The vast inventiveness of human-being is opening the possibility of replacing our clothes by mimicking, reproducing, and scaling up nature’s biosynthetic machinery through cutting-edge biotechnological approaches. Nevertheless, the new cosmovision of biotextiles must meet two requirements: 1) the appearance and performance of the clothes should be preserved to join the current textile market demand, and at the same time, 2) new functionalities should be incorporated into our clothes to embrace the impressive technological advances occurring day to day. In this regard, nanotechnological developments will be able to provide the desired properties so that the textile industry can provide bio-based materials enhanced with nanotechnology-based intelligent functionalities. This perspective article discloses nano-biotechnological approaches to address the challenge of dressing up future societies and new material consciousness.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42166882","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erratum: Bayesian neural networks using magnetic tunnel junction-based probabilistic in-memory computing 勘误表:使用基于磁隧道结的概率内存计算的贝叶斯神经网络
Frontiers in Nanotechnology Pub Date : 2022-12-02 DOI: 10.3389/fnano.2022.1092820
Frontiers Production Office
{"title":"Erratum: Bayesian neural networks using magnetic tunnel junction-based probabilistic in-memory computing","authors":"Frontiers Production Office","doi":"10.3389/fnano.2022.1092820","DOIUrl":"https://doi.org/10.3389/fnano.2022.1092820","url":null,"abstract":"","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45874727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Label-free designed nanomaterials enrichment and separation techniques for phosphoproteomics based on mass spectrometry 基于质谱的磷蛋白组学的无标记纳米材料富集和分离技术
Frontiers in Nanotechnology Pub Date : 2022-12-01 DOI: 10.3389/fnano.2022.1047055
C. Rejeeth, Alok Sharma
{"title":"Label-free designed nanomaterials enrichment and separation techniques for phosphoproteomics based on mass spectrometry","authors":"C. Rejeeth, Alok Sharma","doi":"10.3389/fnano.2022.1047055","DOIUrl":"https://doi.org/10.3389/fnano.2022.1047055","url":null,"abstract":"The surface chemical characteristics of nanomaterials have a substantial impact on the affinity probe used to enrich proteins and peptides for MALDI-MS analysis of a real human sample. Detecting phosphoproteins involved in signalling is always difficult, even with recent developments in mass spectrometry, because protein phosphorylation is often temporary from complicated mixtures. This review summarizes current research on the successful enrichment of various intriguing glycoproteins and glycol peptides using surface affinity materials with distinctive qualities such as low cost, excellent structural stability, diversity, and multifunction. As a consequence, this review will provide a quick overview of the scholars from various backgrounds who are working in this intriguing interdisciplinary field. Label-free cancer biomarkers and other diseases will benefit from future challenges.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43189101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Gel polymer electrolyte for reversible metal electrodeposition dynamic windows enables dual-working electrodes for faster switching and reflectivity control 凝胶聚合物电解质可逆金属电沉积动态窗口使双工作电极更快的开关和反射率控制
Frontiers in Nanotechnology Pub Date : 2022-11-28 DOI: 10.3389/fnano.2022.1083247
Yuchun Cai, Tyler S. Hernandez, Andrew L. Yeang, M. Strand, F. M. Yavitt, E. Abraham, M. McGehee
{"title":"Gel polymer electrolyte for reversible metal electrodeposition dynamic windows enables dual-working electrodes for faster switching and reflectivity control","authors":"Yuchun Cai, Tyler S. Hernandez, Andrew L. Yeang, M. Strand, F. M. Yavitt, E. Abraham, M. McGehee","doi":"10.3389/fnano.2022.1083247","DOIUrl":"https://doi.org/10.3389/fnano.2022.1083247","url":null,"abstract":"Dynamic windows based on reversible metal electrodeposition are an attractive way to enhance the energy efficiency of buildings and show great commercial potential. Dynamic windows that rely on liquid electrolytes are at risk of short circuiting when two electrodes contact, especially at larger-scale. Here we developed a poly (vinyl alcohol) (PVA) gel polymer electrolyte (GPE) with 85% transmittance, that is, sufficiently stiff to act as a separator. The GPE is implemented into windows that exhibit comparable electrochemical and optical properties to windows using a liquid electrolyte. Furthermore, the GPE enables the fabrication of windows with dual-working electrodes (WE) and a metal mesh counter electrode in the center without short-circuiting. Our dual-WE PVA GPE window reaches the 0.1% transmittance state in 101 s, more than twice the speed of liquid windows with one working electrode (207 s). Additionally, each side of the dual-WE GPE window can be tinted individually to demonstrate varied optical effects (i.e., more reflective, or more absorptive), providing users and intelligent building systems with greater control over the appearance and performance of the windows in a single device architecture.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43896244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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