{"title":"Layered GeI2: A wide-bandgap semiconductor for thermoelectric applications–A perspective","authors":"Archit Dhingra","doi":"10.3389/fnano.2022.1095291","DOIUrl":"https://doi.org/10.3389/fnano.2022.1095291","url":null,"abstract":"Layered GeI2 is a two-dimensional wide-bandgap van der Waals semiconductor, which is theorized to be a promising material for thermoelectric applications. While the value of the experimentally extrapolated indirect optical bandgap of GeI2 is found to be consistent with the existing theoretical calculations, its potential as a thermoelectric material still lacks experimental validation. In this Perspective, recent experimental efforts aimed towards investigating its dynamical properties and tuning its bandgap further, via intercalation, are discussed. A thorough understanding of its dynamical properties elucidates the extent of electron-phonon scattering in this system, knowledge of which is crucial in order to open pathways for future studies aiming to realize GeI2-based thermoelectric devices.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48054616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ji‐Yong Shin, Mahnmin Choi, Meeree Kim, Sohee Jeong
{"title":"Semiconductor clusters: Synthetic precursors for colloidal quantum dots","authors":"Ji‐Yong Shin, Mahnmin Choi, Meeree Kim, Sohee Jeong","doi":"10.3389/fnano.2022.1069178","DOIUrl":"https://doi.org/10.3389/fnano.2022.1069178","url":null,"abstract":"Semiconductor clusters have been implicated as reaction intermediates between molecular precursors and colloidal quantum dots (CQDs). The success of isolation of semiconductor clusters have enabled detailed investigation of the atomic information of semiconductor clusters. The identification of atomic information has emerged as an important topic because knowledge of the structure-function relationship of intermediate clusters has been helpful to reveal the synthetic mechanism of CQDs. Recently, they have been utilized as the synthetic precursors for CQDs, which was not readily achieved using conventional molecular precursors. This mini review briefly introduces the current understanding of their atomic information such as the composition, structure, and surface. We then discuss advantages, limitations, and the perspective of semiconductor clusters as a precursor for synthesis of CQDs.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43240023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reema Iqbal, Sadia Khan, H. M. Ali, Maham Khan, Shahid Wahab, Tariq Khan
{"title":"Application of nanomaterials against SARS-CoV-2: An emphasis on their usefulness against emerging variants of concern","authors":"Reema Iqbal, Sadia Khan, H. M. Ali, Maham Khan, Shahid Wahab, Tariq Khan","doi":"10.3389/fnano.2022.1060756","DOIUrl":"https://doi.org/10.3389/fnano.2022.1060756","url":null,"abstract":"Researchers are now looking to nanomaterials to fight serious infectious diseases that cause outbreaks and even pandemics. SARS-CoV-2 brought chaos to almost every walk of life in the past 2 years and has challenged every available treatment method. Although vaccines were developed in no time against it, the most pressing issue was the emergence of variants of concern arising because of the rapidly evolving viral strains. The higher pathogenicity and, in turn, the higher mortality rate of infections caused by these variants renders the existing vaccines less effective and the effort to produce further vaccines a costly endeavor. While several techniques, such as immunotherapy and repurposed pharmaceutical research, are being studied to minimize viral infection, the fundamentals of nanotechnology must also be considered to enhance the anti-SARS-CoV-2 efforts. For instance, silver nanoparticles (AgNPs) have been applied against SARS-CoV-2 effectively. Similarly, nanomaterials have been tested in masks, gloves, and disinfectants to aid in controlling SARS-CoV-2. Nanotechnology has also contributed to diagnoses such as rapid and accurate detection and treatment such as the delivery of mRNA vaccines and other antiviral agents into the body. The development of polymeric nanoparticles has been dubbed a strategy of choice over traditional drugs because of their tunable release kinetics, specificity, and multimodal drug composition. Our article explores the potential of nanomaterials in managing the variants of concern. This will be achieved by highlighting the inherent ability of nanomaterials to act against the virus on fronts such as inhibition of SARS-CoV-2 entry, inhibition of RNA replication in SARS-CoV-2, and finally, inhibition of their release. In this review, a detailed discussion on the potential of nanomaterials in these areas will be tallied with their potential against the current and emerging future variants of concern.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47559792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jessica Q. Geisenhoff, Hang Yin, Natacha Oget, Haeun Chang, Linfeng Chen, Alina M. Schimpf
{"title":"Controlled CO labilization of tungsten carbonyl precursors for the low-temperature synthesis of tungsten diselenide nanocrystals","authors":"Jessica Q. Geisenhoff, Hang Yin, Natacha Oget, Haeun Chang, Linfeng Chen, Alina M. Schimpf","doi":"10.3389/fnano.2022.1026635","DOIUrl":"https://doi.org/10.3389/fnano.2022.1026635","url":null,"abstract":"We report a low-temperature colloidal synthesis of WSe2 nanocrystals from tungsten hexacarbonyl and diphenyl diselenide in trioctylphosphine oxide (TOPO). We identify TOPO-substituted intermediates, W(CO)5TOPO and cis-W(CO)4(TOPO)2 by infrared spectroscopy. To confirm these assignments, we synthesize aryl analogues of phosphine-oxide-substituted intermediates, W(CO)5TPPO (synthesized previously, TPPO = triphenylphosphine oxide) and cis-W(CO)4(TPPO)2 and fac-W(CO)3(TPPO)3 (new structures reported herein). Ligation of the tungsten carbonyl by either the alkyl or aryl phosphine oxides results in facile labilization of the remaining CO, enabling low-temperature decomposition to nucleate WSe2 nanocrystals. The reactivity in phosphine oxides is contrasted with syntheses containing phosphine ligands, where substitution results in decreased CO labilization and higher temperatures are required to induce nanocrystal nucleation.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47686529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Keyla Fuentes, Melissa Gómez, Hernán Rebolledo, José Miguel Figueroa, P. Zamora, Leopoldo Naranjo-Briceño
{"title":"Nanomaterials in the future biotextile industry: A new cosmovision to obtain smart biotextiles","authors":"Keyla Fuentes, Melissa Gómez, Hernán Rebolledo, José Miguel Figueroa, P. Zamora, Leopoldo Naranjo-Briceño","doi":"10.3389/fnano.2022.1056498","DOIUrl":"https://doi.org/10.3389/fnano.2022.1056498","url":null,"abstract":"For centuries, man has dominated the development of fibers and textiles to make clothing that protects them against environmental adversities, and gradually dissimilar cultural and ethnic identity traits have been created. Our garments are composed of natural elements such as animal leather, vegetable fibers, and synthetic textiles that result in ultra-resistant and durable materials. However, the textile industry has a non-sustainable character mainly because population growth will limit the use of natural resources, such as land and water, exclusively for food. At the same time, petrochemical-derived materials will gradually be replaced by more biodegradable alternatives due to their toxic accumulation in the local environment and their contribution to global climate change. The vast inventiveness of human-being is opening the possibility of replacing our clothes by mimicking, reproducing, and scaling up nature’s biosynthetic machinery through cutting-edge biotechnological approaches. Nevertheless, the new cosmovision of biotextiles must meet two requirements: 1) the appearance and performance of the clothes should be preserved to join the current textile market demand, and at the same time, 2) new functionalities should be incorporated into our clothes to embrace the impressive technological advances occurring day to day. In this regard, nanotechnological developments will be able to provide the desired properties so that the textile industry can provide bio-based materials enhanced with nanotechnology-based intelligent functionalities. This perspective article discloses nano-biotechnological approaches to address the challenge of dressing up future societies and new material consciousness.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42166882","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Erratum: Bayesian neural networks using magnetic tunnel junction-based probabilistic in-memory computing","authors":"Frontiers Production Office","doi":"10.3389/fnano.2022.1092820","DOIUrl":"https://doi.org/10.3389/fnano.2022.1092820","url":null,"abstract":"","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45874727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Label-free designed nanomaterials enrichment and separation techniques for phosphoproteomics based on mass spectrometry","authors":"C. Rejeeth, Alok Sharma","doi":"10.3389/fnano.2022.1047055","DOIUrl":"https://doi.org/10.3389/fnano.2022.1047055","url":null,"abstract":"The surface chemical characteristics of nanomaterials have a substantial impact on the affinity probe used to enrich proteins and peptides for MALDI-MS analysis of a real human sample. Detecting phosphoproteins involved in signalling is always difficult, even with recent developments in mass spectrometry, because protein phosphorylation is often temporary from complicated mixtures. This review summarizes current research on the successful enrichment of various intriguing glycoproteins and glycol peptides using surface affinity materials with distinctive qualities such as low cost, excellent structural stability, diversity, and multifunction. As a consequence, this review will provide a quick overview of the scholars from various backgrounds who are working in this intriguing interdisciplinary field. Label-free cancer biomarkers and other diseases will benefit from future challenges.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43189101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuchun Cai, Tyler S. Hernandez, Andrew L. Yeang, M. Strand, F. M. Yavitt, E. Abraham, M. McGehee
{"title":"Gel polymer electrolyte for reversible metal electrodeposition dynamic windows enables dual-working electrodes for faster switching and reflectivity control","authors":"Yuchun Cai, Tyler S. Hernandez, Andrew L. Yeang, M. Strand, F. M. Yavitt, E. Abraham, M. McGehee","doi":"10.3389/fnano.2022.1083247","DOIUrl":"https://doi.org/10.3389/fnano.2022.1083247","url":null,"abstract":"Dynamic windows based on reversible metal electrodeposition are an attractive way to enhance the energy efficiency of buildings and show great commercial potential. Dynamic windows that rely on liquid electrolytes are at risk of short circuiting when two electrodes contact, especially at larger-scale. Here we developed a poly (vinyl alcohol) (PVA) gel polymer electrolyte (GPE) with 85% transmittance, that is, sufficiently stiff to act as a separator. The GPE is implemented into windows that exhibit comparable electrochemical and optical properties to windows using a liquid electrolyte. Furthermore, the GPE enables the fabrication of windows with dual-working electrodes (WE) and a metal mesh counter electrode in the center without short-circuiting. Our dual-WE PVA GPE window reaches the 0.1% transmittance state in 101 s, more than twice the speed of liquid windows with one working electrode (207 s). Additionally, each side of the dual-WE GPE window can be tinted individually to demonstrate varied optical effects (i.e., more reflective, or more absorptive), providing users and intelligent building systems with greater control over the appearance and performance of the windows in a single device architecture.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43896244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Editorial: In-memory sensing and computing: New materials and devices meet new challenges","authors":"Changjin Wan, Zhongrui Wang, R. John","doi":"10.3389/fnano.2022.1073863","DOIUrl":"https://doi.org/10.3389/fnano.2022.1073863","url":null,"abstract":"With the convergence of Artificial Intelligence (AI) and Internet of Things (IoT) redefining the way industries, business, and economies function, the demand for energyefficient and high-performance computing at the edge is exponentially increasing. Inspired by the low power and parallel processing capabilities of the biological brain, Neuromorphic Computing is an emerging computing paradigm that overcomes many limitations of the conventional computer architecture. Most importantly, by performing computations in-memory, Neuromorphic Computing overcomes the von Neuman bottleneck, thus improving the computational capability along with additional area and power savings. While several stand-alone neuromorphic chips have been developed with excellent energy efficiency for running specific AI algorithms, such digital systems still suffer when interfaced with edge sensors. This is because the sensory inputs are nonstructural, non-normalized, and fragmented, which incur large energy, time and wiring overheads on digital systems with separated sensing and processing units. This calls for in-memory sensing technologies, with fused sensing, memory, and processing capabilities, to unleash the full potential of highly sophisticated sensor and actuator systems used in bioelectronics and robotics. Despite its infancy, the concepts of in-memory sensing and computing has already made significant inroads in specialized areas like e-skin and bionic eye. However, these are majorly software implementations and the hardware challenges to complement these have not been addressed yet. To take full advantage of the bioinspired edge processing capabilities, there are still fundamental challenges at the hardware level (materials and devices) that need to be addressed. Therefore, “In-memory Sensing and Computing: New Materials and Devices meet New Challenges” was launched last year, initiating the discussions on the recent developments as well as perspectives. Researchers from multidisciplinary backgrounds, like microelectronics, materials, and computer science, and different regions have posted their opinions and/or original works pertinent to this OPEN ACCESS","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43033422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nadeem Joudeh, Athanasios Saragliadis, Gerbrand Koster, P. Mikheenko, D. Linke
{"title":"Synthesis methods and applications of palladium nanoparticles: A review","authors":"Nadeem Joudeh, Athanasios Saragliadis, Gerbrand Koster, P. Mikheenko, D. Linke","doi":"10.3389/fnano.2022.1062608","DOIUrl":"https://doi.org/10.3389/fnano.2022.1062608","url":null,"abstract":"Palladium (Pd) is a key component of many catalysts. Nanoparticles (NPs) offer a larger surface area than bulk materials, and with Pd cost increasing 5-fold in the last 10 years, Pd NPs are in increasing demand. Due to novel or enhanced physicochemical properties that Pd NPs exhibit at the nanoscale, Pd NPs have a wide range of applications not only in chemical catalysis, but also for example in hydrogen sensing and storage, and in medicine in photothermal, antibacterial, and anticancer therapies. Pd NPs, on the industrial scale, are currently synthesized using various chemical and physical methods. The physical methods require energy-intensive processes that include maintaining high temperatures and/or pressure. The chemical methods usually involve harmful solvents, hazardous reducing or stabilizing agents, or produce toxic pollutants and by-products. Lately, more environmentally friendly approaches for the synthesis of Pd NPs have emerged. These new approaches are based on the use of the reducing ability of phytochemicals and other biomolecules to chemically reduce Pd ions and form NPs. In this review, we describe the common physical and chemical methods used for the synthesis of Pd NPs and compare them to the plant- and bacteria-mediated biogenic synthesis methods. As size and shape determine many of the unique properties of Pd NPs on the nanoscale, special emphasis is given to the control of these parameters, clarifying how they impact current and future applications of this exciting nanomaterial.","PeriodicalId":34432,"journal":{"name":"Frontiers in Nanotechnology","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43524647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}