Carbon Energy最新文献_第4页

Research advances of metal fluoride for energy conversion and storage

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-28 DOI: 10.1002/cey2.630

Runlin Zhang, Zijin Xu, Zeyu Hao, Zeshuo Meng, Xiufeng Hao, Hongwei Tian

{"title":"Research advances of metal fluoride for energy conversion and storage","authors":"Runlin Zhang, Zijin Xu, Zeyu Hao, Zeshuo Meng, Xiufeng Hao, Hongwei Tian","doi":"10.1002/cey2.630","DOIUrl":"https://doi.org/10.1002/cey2.630","url":null,"abstract":"In recent years, renewable energy sources, which aim to replace rapidly depleting fossil fuels, face challenges due to limited energy storage and conversion technologies. To enhance energy storage and conversion efficiency, extensive research has been conducted in the academic community on numerous potential materials. Among these materials, metal fluorides have attracted significant attention due to their ionic metal–fluorine bonds and tunable electronic structures, attributed to the highest electronegativity of fluorine in their chemical composition. This makes them promising candidates for future electrochemical applications in various fields. However, metal fluorides encounter various challenges in different application directions. Therefore, we comprehensively review the applications of metal fluorides in the field of energy storage and conversion, aiming to deepen our understanding of their exhibited characteristics in different electrochemical processes. In this paper, we summarize the difficulties and improvement methods encountered in different types of battery applications and several typical electrode optimization strategies in the field of supercapacitors. In the field of water electrolysis, we focus on surface reconstruction and the critical role of fluorine, demonstrating the catalytic performance of metal fluorides from the perspectives of reconstruction mechanism and process analysis. Finally, we provide a summary and outlook for this field, aiming to offer guidance for future breakthroughs in the energy storage and conversion applications of metal fluorides.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 1","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.630","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143120327","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hierarchically structured, Janus optical nanoengineered wastepaper for switchable radiative cooling/heating

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-28 DOI: 10.1002/cey2.676

Zifan Song, Zipeng Zhang, Xueting Zhang, Jingyang Liu, Wanjie Wang, Jianfeng Wang, Xiuxiu Jin

{"title":"Hierarchically structured, Janus optical nanoengineered wastepaper for switchable radiative cooling/heating","authors":"Zifan Song, Zipeng Zhang, Xueting Zhang, Jingyang Liu, Wanjie Wang, Jianfeng Wang, Xiuxiu Jin","doi":"10.1002/cey2.676","DOIUrl":"https://doi.org/10.1002/cey2.676","url":null,"abstract":"Switchable radiative cooling/heating holds great promise for mitigating the global energy and environmental crisis. Here, we reported a cost-effective, high-strength Janus film through surface optical engineering waste paper with one side decorated by a hydrophobic polymeric cooling coating consisting of micro/nanopore/particle hierarchical structure and the other side coated with hydrophilic MXene nanosheets for heating. The cooling surface demonstrates high solar reflectivity (96.3%) and infrared emissivity (95.5%), resulting in daytime/nighttime sub-ambient radiative cooling of 6°C/8°C with the theoretical cooling power of 100.6 and 138.5 W m−2, respectively. The heating surface exhibits high solar absorptivity (83.7%) and low infrared emissivity (15.2%), resulting in excellent radiative heating capacity for vehicle charging pile (~6.2°C) and solar heating performance. Impressively, the mechanical strength of Janus film increased greatly by 563% compared with that of pristine waste paper, which is helpful for its practical applications in various scenarios for switchable radiative thermal management through mechanical flipping. Energy-saving simulation results reveal that significant total energy savings of up to 32.4 MJ m−2 can be achieved annually (corresponding to the 12.4% saving ratio), showing the immense importance of reducing carbon footprint and promoting carbon neutrality.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 1","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.676","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143120353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In situ techniques for Li-rechargeable battery analysis

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-28 DOI: 10.1002/cey2.549

Seongeun Lee, Sangbin Park, Wontae Lee, Jangwhan Seok, Jae-Uk Kim, Jongsoon Kim, Won-Sub Yoon

{"title":"In situ techniques for Li-rechargeable battery analysis","authors":"Seongeun Lee, Sangbin Park, Wontae Lee, Jangwhan Seok, Jae-Uk Kim, Jongsoon Kim, Won-Sub Yoon","doi":"10.1002/cey2.549","DOIUrl":"https://doi.org/10.1002/cey2.549","url":null,"abstract":"Reducing our carbon footprint is one of the most pressing issues facing humanity today. The technology of Li-rechargeable batteries is permeating every corner of our lives as a result of our efforts to reduce the use of carbon energy. Batteries can be seen metaphorically as “living cells”, and approaching the future of that technology requires observing and understanding the real-time phenomena that occur inside battery systems during (electro)chemical reactions. In this regard, in situ analysis techniques have made significant progress toward understanding the basic science of battery systems and finding better performance-improving factors. There are various analysis methods utilizing electromagnetic waves, electrons, and neutrons to perform multifaceted analyses of battery systems from the atomic to the macroscopic scale. Now is the opportune moment to construct a comprehensive guide that facilitates the design of advanced Li-rechargeable battery systems, adopting a highly discerning and all-encompassing approach toward these cutting-edge technologies. In this review article, we discuss and organize the key components such as capabilities, limitations, and practical tips with a comprehensive perspective on various in situ techniques. Moreover, this article covers a wide range of information from the nano to the micrometer scale, such as electronic, atomic, crystal, and morphological structures, from stereoscopic perspectives considering the probing depth.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"6 12","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.549","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143253573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Back Cover Image, Volume 6, Number 11, November 2024 封底图片，第6卷，第11期，2024年11月

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-27 DOI: 10.1002/cey2.705

Takashi Hakari, Yuto Kameoka, Kaihei Kishida, Shinji Ozaki, Chihiro Murata, Minako Deguchi, Ryo Harada, Tomoki Fujisawa, Yusuke Mizuno, Heisuke Nishikawa, Tomoyuki Tamura, Yiqun Wang, Hikari Takahara, Takashi Aoki, Tokuo Inamasu, Daisuke Okuda, Masashi Ishikawa

{"title":"Back Cover Image, Volume 6, Number 11, November 2024","authors":"Takashi Hakari, Yuto Kameoka, Kaihei Kishida, Shinji Ozaki, Chihiro Murata, Minako Deguchi, Ryo Harada, Tomoki Fujisawa, Yusuke Mizuno, Heisuke Nishikawa, Tomoyuki Tamura, Yiqun Wang, Hikari Takahara, Takashi Aoki, Tokuo Inamasu, Daisuke Okuda, Masashi Ishikawa","doi":"10.1002/cey2.705","DOIUrl":"https://doi.org/10.1002/cey2.705","url":null,"abstract":"Back cover image: A lightweight battery has been successfully created using a cathode that uses sulfur, which is abundant as a resource, as the active material. The battery uses an electrolyte solution and is lightweight, with the goal of becoming a power source for next-generation aircraft. The graphic depicts the mining of abundant sulfur, which is then delivered to a large battery center by a series of transportation systems. It also symbolically shows that the battery that takes off from that battery center powers the aircraft. The fact that both the batteries on the ground and in the air have an liquid electrolyte is shown in translucent form. Furthermore, the present graphic implies that the electricity stored in the batteries is generated by hydroelectric power, a renewable energy source, and together with the green ground, giving the impression of the total system that is environmentally friendly.Article number: 10.1002/cey2.585Takashi Hakari & Masashi Ishikawa\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"6 11","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.705","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cover Image, Volume 6, Number 11, November 2024 封面图片，第6卷，第11期，2024年11月

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-27 DOI: 10.1002/cey2.704

Zhijian Du, La Li, Guozhen Shen

引用次数: 0

Self-supported thin-film electrode consisting of transition metal borides for highly efficient hydrogen evolution

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-15 DOI: 10.1002/cey2.656

Qi Miao, Lihong Bao, Yuxin Gao, Hao Wang, Yongjun Cao, Wei Li, Lei Li, Xiaowei Yang, Jijun Zhao, Ruguang Ma

{"title":"Self-supported thin-film electrode consisting of transition metal borides for highly efficient hydrogen evolution","authors":"Qi Miao, Lihong Bao, Yuxin Gao, Hao Wang, Yongjun Cao, Wei Li, Lei Li, Xiaowei Yang, Jijun Zhao, Ruguang Ma","doi":"10.1002/cey2.656","DOIUrl":"https://doi.org/10.1002/cey2.656","url":null,"abstract":"Transition metal borides (TMBs) are a new class of promising electrocatalysts for hydrogen generation by water splitting. However, the synthesis of robust all-in-one electrodes is challenging for practical applications. Herein, a facile solid-state boronization strategy is reported to synthesize a series of self-supported TMBs thin films (TMB-TFs) with large area and high catalytic activity. Among them, MoB thin film (MoB-TF) exhibits the highest activity toward electrocatalytic hydrogen evolution reaction (HER), displaying a low overpotential (η10 = 191 and 219 mV at 10 mA cm−2) and a small Tafel slope (60.25 and 61.91 mV dec−1) in 0.5 M H2SO4 and 1.0 M KOH, respectively. Moreover, it outperforms the commercial Pt/C at the high current density region, demonstrating potential applications in industrially electrochemical water splitting. Theoretical study reveals that both surfaces terminated by TM and B atoms can serve as the active sites and the H* binding strength of TMBs is correlated with the p band center of B atoms. This work provides a new pathway for the potential application of TMBs in large-scale hydrogen production.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 1","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.656","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-performance and flexible thermoelectric generator based on a robust carbon nanotube/BiSbTe foam

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-15 DOI: 10.1002/cey2.650

Myeong Hoon Jeong, Eun Jin Bae, Byoungwook Park, Jong-Woon Ha, Mijeong Han, Young Hun Kang

{"title":"High-performance and flexible thermoelectric generator based on a robust carbon nanotube/BiSbTe foam","authors":"Myeong Hoon Jeong, Eun Jin Bae, Byoungwook Park, Jong-Woon Ha, Mijeong Han, Young Hun Kang","doi":"10.1002/cey2.650","DOIUrl":"https://doi.org/10.1002/cey2.650","url":null,"abstract":"Organic thermoelectric generators (TEGs) are flexible and lightweight, but they often have high electrical resistance, poor output power, and low mechanical durability, because of which their thermoelectric performance is poor. We used a facile and rapid solvent evaporation process to prepare a robust carbon nanotube/Bi0.45Sb1.55Te3 (CNT/BST) foam with a high thermoelectric figure of merit (zT). The BST sub-micronparticles effectively create an electrically conductive network within the three-dimensional porous CNT foam to greatly improve the electrical conductivity and the Seebeck coefficient and reinforce the mechanical strength of the composite against applied stresses. The CNT/BST foam had a zT value of 7.8 × 10−3 at 300 K, which was 5.7 times higher than that of pristine CNT foam. We used the CNT/BST foam to fabricate a flexible TEG with an internal resistance of 12.3 Ω and an output power of 15.7 µW at a temperature difference of 21.8 K. The flexible TEG showed excellent stability and durability even after 10,000 bending cycles. Finally, we demonstrate the shapeability of the CNT/BST foam by fabricating a concave TEG with conformal contact on the surface of a cylindrical glass tube, which suggests its practical applicability as a thermal sensor.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 1","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.650","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115176","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Densely populated single-atom catalysts for boosting hydrogen generation from formic acid

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-15 DOI: 10.1002/cey2.664

Xiaogeng Zhao, Junmin Wang, Dongnuan Zhang, Yunhui Hao, Xingmian Zhang, Junna Feng, Hong Su, Cheng Feng, Chun Wang

{"title":"Densely populated single-atom catalysts for boosting hydrogen generation from formic acid","authors":"Xiaogeng Zhao, Junmin Wang, Dongnuan Zhang, Yunhui Hao, Xingmian Zhang, Junna Feng, Hong Su, Cheng Feng, Chun Wang","doi":"10.1002/cey2.664","DOIUrl":"https://doi.org/10.1002/cey2.664","url":null,"abstract":"The single-atom M-N-C (M typically being Co or Fe) is a prominent material with exceptional reactivity in areas of catalysis for sustainable energy. However, the formation of metal nanoparticles in M-N-C materials is coupled with high-temperature calcination conditions, limiting the density of M-Nx active sites and thus restricting the catalytic performance of such catalysts. Herein, we describe an effective decoupling strategy to construct high-density M-Nx active sites by generating polyfurfuryl alcohol in the MOF precursor, effectively preventing the formation of metal nanoparticles even with up to 6.377% cobalt loading. This catalyst showed a high H2 production rate of 778 mL gcat−1 h−1 when used in the dehydrogenation reaction of formic acid. In addition to the high density of the active site, a curved carbon surface in the structure is also thought to be the reason for the high performance of the catalyst.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 1","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.664","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Organic cation-supported layered vanadate cathode for high-performance aqueous zinc-ion batteries

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-15 DOI: 10.1002/cey2.647

Changding Wang, Yingfang Li, Sida Zhang, Tian-Yi Sang, Yu Lei, Ruiqi Liu, Fu Wan, Yuejiao Chen, Weigen Chen, Yujie Zheng, Shuhui Sun

{"title":"Organic cation-supported layered vanadate cathode for high-performance aqueous zinc-ion batteries","authors":"Changding Wang, Yingfang Li, Sida Zhang, Tian-Yi Sang, Yu Lei, Ruiqi Liu, Fu Wan, Yuejiao Chen, Weigen Chen, Yujie Zheng, Shuhui Sun","doi":"10.1002/cey2.647","DOIUrl":"https://doi.org/10.1002/cey2.647","url":null,"abstract":"Layered vanadates are ideal energy storage materials due to their multielectron redox reactions and excellent cation storage capacity. However, their practical application still faces challenges, such as slow reaction kinetics and poor structural stability. In this study, we synthesized [Me2NH2]V3O7 (MNVO), a layered vanadate with expended layer spacing and enhanced pH resistance, using a one-step simple hydrothermal gram-scale method. Experimental analyses and density functional theory (DFT) calculations revealed supportive ionic and hydrogen bonding interactions between the thin-layered [Me2NH2]+ cation and [V3O7]− anion layers, clarifying the energy storage mechanism of the H+/Zn2+ co-insertion. The synergistic effect of these bonds and oxygen vacancies increased the electronic conductivity and significantly reduced the diffusion energy barrier of the insertion ions, thereby improving the rate capability of the material. In an acidic electrolyte, aqueous zinc-ion batteries employing MNVO as the cathode exhibited a high specific capacity of 433 mAh g−1 at 0.1 A g−1. The prepared electrodes exhibited a maximum specific capacity of 237 mAh g−1 at 5 A g−1 and maintained a capacity retention of 83.5% after 10,000 cycles. This work introduces a novel approach for advancing layered cathodes, paving the way for their practical application in energy storage devices.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 2","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.647","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143497015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synergetic monitoring of pressure and temperature stimulations in multisensory electronic skin based on time decoupling effect

IF 19.5 1区材料科学

Carbon Energy Pub Date : 2024-11-14 DOI: 10.1002/cey2.640

Zhiyi Gao, Ye Zhang, Zhenyu Hu, Dongdong Zhang, Shengbin Li, Huiyun Xiao, Ziyin Xiang, Dan Xu, Haifeng Zhang, Yuanzhao Wu, Yiwei Liu, Jie Shang, Runwei Li

{"title":"Synergetic monitoring of pressure and temperature stimulations in multisensory electronic skin based on time decoupling effect","authors":"Zhiyi Gao, Ye Zhang, Zhenyu Hu, Dongdong Zhang, Shengbin Li, Huiyun Xiao, Ziyin Xiang, Dan Xu, Haifeng Zhang, Yuanzhao Wu, Yiwei Liu, Jie Shang, Runwei Li","doi":"10.1002/cey2.640","DOIUrl":"https://doi.org/10.1002/cey2.640","url":null,"abstract":"The progress from intelligent interactions requires electronic skin (E-skin) to shift from single-functional perception to multisensory capabilities. However, the intuitive and interference-free reading of multiple sensory signals without involving complex algorithms is a critical challenge. Herein, we propose a flexible multisensory E-skin by developing a highly homogeneous dispersion of BaTiO3 nanoparticles in polydimethylsiloxane dielectric layer. The E-skin is sensitive to externally applied pressure as well as temperature and can distinguish dual synergetic stimuli by the time decoupling effect. The pressure and temperature perception was achieved in an individual device, which greatly reduced the structural complexity compared with multifunctional integrated devices. The sensitivity of E-skin for pressure detection is as high as 0.0724 kPa−1 and the detection range reaches as wide as 15.625–10 MPa. The sensitivity to temperature detection is as high as −1.34°C−1 and the detection range reaches 20–200°C. More importantly, by equipping with a multilayer neural network, the evolution from tactile perception to advanced intelligent tactile cognition is demonstrated.","PeriodicalId":33706,"journal":{"name":"Carbon Energy","volume":"7 1","pages":""},"PeriodicalIF":19.5,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cey2.640","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0