Fuel Processing Technology最新文献

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Microwave-assisted biodiesel synthesis from waste cooking oil: Exploring the potential of carob pod-derived solid base catalyst 利用废弃食用油进行微波辅助生物柴油合成:探索角豆树豆荚衍生固体基础催化剂的潜力
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-11-16 DOI: 10.1016/j.fuproc.2024.108161
Babatunde Oladipo, Sisipho Qasana, Sibabalwe C. Zini, Ntokozo Menemene, Tunde V. Ojumu
{"title":"Microwave-assisted biodiesel synthesis from waste cooking oil: Exploring the potential of carob pod-derived solid base catalyst","authors":"Babatunde Oladipo,&nbsp;Sisipho Qasana,&nbsp;Sibabalwe C. Zini,&nbsp;Ntokozo Menemene,&nbsp;Tunde V. Ojumu","doi":"10.1016/j.fuproc.2024.108161","DOIUrl":"10.1016/j.fuproc.2024.108161","url":null,"abstract":"<div><div>This work examined the potency of carob (<em>Ceratonia siliqua</em>) pod as a heterogeneous base catalyst for converting waste cooking oil (WCO) into biodiesel via a microwave irradiation system. The optimal calcination for the catalyst synthesis was achieved at 500 °C for 4 h. Various analytical techniques were employed to investigate the properties of the developed catalyst. The results indicate that the catalyst primarily consists of mesoporous particles abundant in potassium, with medium to strong basic sites, which are crucial for its catalytic function. WCO underwent pretreatment with H<sub>2</sub>SO<sub>4</sub> before being converted to biodiesel. Optimum conditions for the biodiesel production were a methanol-to-WCO molar ratio of 9.87, 1.00 wt% catalyst dosage, 3.03 min reaction time, 450 rpm stirring speed, and 600 W microwave power, yielding 98.20 ± 0.81 wt% biodiesel. The low specific energy consumption value of 0.91 kWh/kg and specific CO<sub>2</sub> emission of 0.73 kg/kg of biodiesel suggest the effective utilization of microwave energy in driving the transesterification reaction and in promoting a reduction in carbon footprint, respectively. The synthesized catalyst remained effective up to the 5th production cycle and the biodiesel produced met established specifications. The results of this study show that carob pod is a suitable candidate to be included in the database of biobased catalysts currently being developed for heterogeneous catalysis of cost-effective biodiesel production.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"266 ","pages":"Article 108161"},"PeriodicalIF":7.2,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142658985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An experimental evaluation of thermophysical properties of colloidal suspension of carbon-rich fly ash microparticles and single-walled carbon nanotubes in Jet-A fuel and its impact on evaporation and burning rate 富碳粉煤灰微颗粒和单壁碳纳米管胶体悬浮液在 Jet-A 燃料中的热物理性质及其对蒸发和燃烧速率影响的实验评估
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-11-16 DOI: 10.1016/j.fuproc.2024.108155
Ahmed Aboalhamayie , Nadeem Ahmad , Yang Zhang , Mohsen Ghamari , Numan Salah , Jameel Alshahrani
{"title":"An experimental evaluation of thermophysical properties of colloidal suspension of carbon-rich fly ash microparticles and single-walled carbon nanotubes in Jet-A fuel and its impact on evaporation and burning rate","authors":"Ahmed Aboalhamayie ,&nbsp;Nadeem Ahmad ,&nbsp;Yang Zhang ,&nbsp;Mohsen Ghamari ,&nbsp;Numan Salah ,&nbsp;Jameel Alshahrani","doi":"10.1016/j.fuproc.2024.108155","DOIUrl":"10.1016/j.fuproc.2024.108155","url":null,"abstract":"<div><div>This study presents an experimental evaluation of the thermophysical properties of colloidal suspensions of carbon-rich fly ash microparticles (CFA) and single-walled carbon nanotubes (SWCNT) in Jet-A fuel, focusing on their impact on evaporation and burning rates. The research explores the effects of these carbon-based additives on key parameters such as thermal conductivity, viscosity, surface tension, evaporation rate, and combustion behavior. Utilizing a hybrid preparation method combining sonication and surfactants, stable colloidal suspensions were prepared for experimental analysis. The results demonstrate that both CFA and SWCNT enhance the thermal conductivity of Jet-A fuel, with SWCNT achieving a notable 13 % increase at a 1 wt% concentration, while CFA achieves an 8 % increase at a 3 wt% concentration. The study also reveals distinct trends in viscosity and surface tension, with SWCNT causing a significant non-linear increase in viscosity compared to CFA. In combustion experiments, the evaporation rates of CFA and SWCNT suspensions showed considerable improvement, with CFA demonstrating up to an 87 % increase at 1 wt% concentration. The study concludes with an analysis of ignition delay, highlighting the superior performance of SWCNT in reducing ignition time due to their high thermal conductivity and the presence of iron nanoparticles on their surface.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"266 ","pages":"Article 108155"},"PeriodicalIF":7.2,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142658984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable production of biohydrogen: Feedstock, pretreatment methods, production processes, and environmental impact 生物氢的可持续生产:原料、预处理方法、生产工艺和环境影响
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-11-16 DOI: 10.1016/j.fuproc.2024.108158
Aleksandra Modzelewska , Mateusz Jackowski , Panagiotis Boutikos , Magdalena Lech , Maciej Grabowski , Krystian Krochmalny , María González Martínez , Christian Aragón-Briceño , Amit Arora , Hao Luo , Luca Fiori , Qingang Xiong , Muhammad Yousaf Arshad , Anna Trusek , Halina Pawlak-Kruczek , Lukasz Niedzwiecki
{"title":"Sustainable production of biohydrogen: Feedstock, pretreatment methods, production processes, and environmental impact","authors":"Aleksandra Modzelewska ,&nbsp;Mateusz Jackowski ,&nbsp;Panagiotis Boutikos ,&nbsp;Magdalena Lech ,&nbsp;Maciej Grabowski ,&nbsp;Krystian Krochmalny ,&nbsp;María González Martínez ,&nbsp;Christian Aragón-Briceño ,&nbsp;Amit Arora ,&nbsp;Hao Luo ,&nbsp;Luca Fiori ,&nbsp;Qingang Xiong ,&nbsp;Muhammad Yousaf Arshad ,&nbsp;Anna Trusek ,&nbsp;Halina Pawlak-Kruczek ,&nbsp;Lukasz Niedzwiecki","doi":"10.1016/j.fuproc.2024.108158","DOIUrl":"10.1016/j.fuproc.2024.108158","url":null,"abstract":"<div><div>A significant increase in the use of hydrogen, expected to reach between 667 and 4000 TWh, is forecasted for the whole EU in 2050. Electrolysis is believed to be a “silver bullet” due to its synergy with the needs of the grid. However, biohydrogen generation could be complimentary to electrolysis since it does not depend on electricity prices. This review presents a comprehensive picture of the landscape in biohydrogen production, showing state-of-the-art research on different biohydrogen production processes and highlighting potential problems and shortcomings for different processes, including microbial-based production and thermal processes. The work shows that “colour coding” used nowadays is insufficient in terms of providing accurate information regarding the sustainability of particular biohydrogen production technologies. Instead, LCA can provide substantial information for each investigated process. However, there is a need for a wider scope of LCA studies since currently published studies present a syndrome of “carbon tunnel vision”, often ignoring impacts other than global warming. Moreover, studies often tend to exclude the impact of capital goods production, which might provide an incomplete overview of such technologies. Moreover, it should not be overlooked that biohydrogen is capable of achieving negative values of CO<sub>2</sub> emissions if CCS is implemented.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"266 ","pages":"Article 108158"},"PeriodicalIF":7.2,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142658982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct synthesis of dimethyl carbonate from methanol and carbon dioxide over Co-Ce-Zr ternary metal solid solution 在 Co-Ce-Zr 三元金属固溶体上以甲醇和二氧化碳为原料直接合成碳酸二甲酯
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-11-16 DOI: 10.1016/j.fuproc.2024.108157
Xin Li, Lele Cao, Dongdong Jia, Yongyue Sun
{"title":"Direct synthesis of dimethyl carbonate from methanol and carbon dioxide over Co-Ce-Zr ternary metal solid solution","authors":"Xin Li,&nbsp;Lele Cao,&nbsp;Dongdong Jia,&nbsp;Yongyue Sun","doi":"10.1016/j.fuproc.2024.108157","DOIUrl":"10.1016/j.fuproc.2024.108157","url":null,"abstract":"<div><div>To investigate highly performance catalysts for the direct synthesis of dimethyl carbonate (DMC) from carbon dioxide (CO<sub>2</sub>) and methanol, a Co<sub>0.02</sub>/Ce<sub>0.7</sub>Zr<sub>0.3</sub>O<sub>2</sub> ternary metal solid solution nanoparticle catalyst was synthesized, demonstrating superior performance with a DMC yield of 3.86 mmol g<sup>−1</sup> and selectivity of 100 % at 7 MPa and 140 °C. A series of characterizations further validated the successful incorporation of cobalt and zirconium into the crystal lattice of CeO<sub>2</sub>, resulting in an increased number of acid-base sites on its surface and a rise in oxygen vacancy content from 10.1 % to 28.7 %. The density functional theory (DFT) calculation results further corroborated the experimental findings, indicating that the doping of cobalt and zirconium ions significantly reduced the formation energy of oxygen vacancies on the catalyst surface from 2.53 to −1.38 eV, while concurrently decreasing the adsorption energy of CO<sub>2</sub> from −0.33 to −1.74 eV. Additionally, charge calculation results revealed that oxygen vacancies functioned as Lewis acid sites, whereas lattice oxygen atoms served as Lewis base sites, facilitating the cooperative activation of CO<sub>2</sub>. The results may provide a new approach for designing and improving CeO<sub>2</sub>-based catalysts for CO<sub>2</sub> activation.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"266 ","pages":"Article 108157"},"PeriodicalIF":7.2,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142659543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A bifunctional catalyst for direct CO2 conversion to clean fuels: Mechanistic insights and a comprehensive kinetic model 将二氧化碳直接转化为清洁燃料的双功能催化剂:机理认识和综合动力学模型
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-11-09 DOI: 10.1016/j.fuproc.2024.108152
Masoud Safari Yazd, Jafar Towfighi Darian
{"title":"A bifunctional catalyst for direct CO2 conversion to clean fuels: Mechanistic insights and a comprehensive kinetic model","authors":"Masoud Safari Yazd,&nbsp;Jafar Towfighi Darian","doi":"10.1016/j.fuproc.2024.108152","DOIUrl":"10.1016/j.fuproc.2024.108152","url":null,"abstract":"<div><div>The escalating global concern over CO<sub>2</sub> emissions has spurred extensive research aimed at developing innovative solutions for capturing, storing, and utilizing CO<sub>2</sub>, crucial for establishing a closed carbon loop. Thermo-catalytic CO<sub>2</sub> hydrogenation stands out as a promising approach, though challenged by CO<sub>2</sub>'s high stability, hindering the production of heavy liquid hydrocarbons. This study explores the design and performance of a bifunctional cobalt-based catalyst, promoted by Ru and supported by multiple shells of carbon, mesoporous silica, and ceria for CO<sub>2</sub> hydrogenation in the Modified Fischer-Tropsch Synthesis (MFTS) route. Through meticulous characterization and evaluation, the catalyst demonstrates suitable textural properties, reducibility, and dispersion of active sites, promoting CO<sub>2</sub> conversion and selectivity towards heavier hydrocarbons, highlighting the significance of catalyst design and operating conditions. The catalyst exhibits notable stability across catalyst deactivation, attributed to its thermal conductivity provided by SiC matrices. SiC-supported catalysts play a pivotal role in enhancing the efficiency, selectivity, and stability of CO<sub>2</sub> hydrogenation catalysts. Moreover, in this study, through meticulous evaluation of elementary reactions based on molecular dynamic (MD) computations, a detailed mechanism for MFTS is presented. Key to this mechanism is the H-assisted CO<sub>2</sub> dissociation pathway, supported by computational analysis. The pathway involves sequential reactions starting from CO<sub>2</sub> adsorption on catalyst sites, followed by successive transformations leading to the formation of hydrocarbon building blocks. Ultimately, a developed MFTS kinetic model based on the MD-evaluated mechanism, which accurately predicts product selectivity across various operational conditions, indicating its robustness and reliability, is presented.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"266 ","pages":"Article 108152"},"PeriodicalIF":7.2,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142658983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catalytic steam reforming of waste tire pyrolysis volatiles using a tire char catalyst for high yield hydrogen-rich syngas 使用轮胎炭催化剂对废轮胎热解挥发物进行催化蒸汽转化,以获得高产率的富氢合成气
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-11-04 DOI: 10.1016/j.fuproc.2024.108150
Yukun Li, Paul T. Williams
{"title":"Catalytic steam reforming of waste tire pyrolysis volatiles using a tire char catalyst for high yield hydrogen-rich syngas","authors":"Yukun Li,&nbsp;Paul T. Williams","doi":"10.1016/j.fuproc.2024.108150","DOIUrl":"10.1016/j.fuproc.2024.108150","url":null,"abstract":"<div><div>The production of hydrogen and syngas (H<sub>2</sub>/CO) from waste tires by pyrolysis catalytic steam reforming was investigated in a two-stage fixed bed reactor. In this study, tire char served as a sacrificial catalyst, facilitating the combination of catalytic steam reforming and char steam gasification reactions. The tire char acted as both a catalyst and a gasification reactant, enhancing the gas product yield. The process parameters investigated were, a reforming temperature range of 700–1000 °C, steam space velocity between 2 and 12 g h<sup>−1</sup> g<sup>−1</sup><sub>char</sub> and reaction times of 0.5–2 h. The influence of the parameters on the yield and composition of the product gases and the characteristics of the used catalyst were analyzed in detail. The results indicated that higher temperature and steam space velocity increased H<sub>2</sub> and CO yields in the presence of a tire char catalyst. Elemental analysis of the used tire char, surface morphology and pore structure provided insights into the extent of tire char consumption in the reaction. Prolonged reaction time allowed for more thorough reactions between the pyrolysis volatiles and tire char, promoting the production of H<sub>2</sub>. At a reaction time of 2 h, the H<sub>2</sub> yield reached 223 mmol g<sup>−1</sup>, representing 74 wt% of the maximum hydrogen yield.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"265 ","pages":"Article 108150"},"PeriodicalIF":7.2,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142578783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of press channel diameter-to-length ratio on the mechanical properties of biomass pellets during storage 压制槽长径比对生物质颗粒储存期间机械性能的影响
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-10-30 DOI: 10.1016/j.fuproc.2024.108149
Abdullah Sadeq, Swantje Pietsch-Braune, Stefan Heinrich
{"title":"Impact of press channel diameter-to-length ratio on the mechanical properties of biomass pellets during storage","authors":"Abdullah Sadeq,&nbsp;Swantje Pietsch-Braune,&nbsp;Stefan Heinrich","doi":"10.1016/j.fuproc.2024.108149","DOIUrl":"10.1016/j.fuproc.2024.108149","url":null,"abstract":"<div><div>This study investigates the effects of press channel length on the quality of wood pellets, focusing on key aspects such as density, radial porosity distribution, and mechanical stability, both at the time of delivery and during storage. Wood pellets were produced using press channels with diameter-to-length (D/L) ratios of 1:3, 1:4, and 1:5 to evaluate how variations in die geometry influence pellet quality. Micro-computed tomography (μCT) analysis indicates that the D/L ratio of the press channel significantly impacts the porosity within the pellets. Short press channels are associated with great variability in the radial porosity distribution of the wood pellets, while longer press channels lead to uniformly low porosity over the radius. Furthermore, pellets produced with longer press channels exhibit a smoother surface with fewer cracks and greater resistance to structural degradation under varying humidity conditions. Although high-density pellets show improved mechanical strength and recovery potential in humid environments, remaining damage in the form of cracks and alterations in radial porosity distribution lead to reduced strength compared to their initial state.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"265 ","pages":"Article 108149"},"PeriodicalIF":7.2,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142552368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing diesel production from waste plastics: A study on Pd/MCM-48 catalytic hydroprocessing 提高废塑料的柴油产量:Pd/MCM-48 催化加氢处理研究
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-10-19 DOI: 10.1016/j.fuproc.2024.108145
Abdul Khaliq , Krishna Kumar Yadav , Sultan Alshehery , Haifa A. Alqhtani , May Bin-Jumah , P.N. Poovizhi , Sumithra Viswanathan , P. Saravanan , R. Sankar , P. Santhana Krishnan , P. Tamizhdurai
{"title":"Enhancing diesel production from waste plastics: A study on Pd/MCM-48 catalytic hydroprocessing","authors":"Abdul Khaliq ,&nbsp;Krishna Kumar Yadav ,&nbsp;Sultan Alshehery ,&nbsp;Haifa A. Alqhtani ,&nbsp;May Bin-Jumah ,&nbsp;P.N. Poovizhi ,&nbsp;Sumithra Viswanathan ,&nbsp;P. Saravanan ,&nbsp;R. Sankar ,&nbsp;P. Santhana Krishnan ,&nbsp;P. Tamizhdurai","doi":"10.1016/j.fuproc.2024.108145","DOIUrl":"10.1016/j.fuproc.2024.108145","url":null,"abstract":"<div><div>In recent years, plastic has emerged as a widely used material, replacing traditional materials across various industries due to its versatility and convenience. However, this extensive adoption of plastic has resulted in significant environmental challenges, especially in managing mixed plastic waste. To address this, energy recovery technologies have been developed to offer alternative recycling methods for plastic waste. This study specifically focuses on producing hydroprocessed plastic pyrolysis oil from mixed waste plastic to create environmentally compliant fuel. The scrutiny compares the resultant fuel with diesel using hydroprocessing techniques and catalytic pyrolysis. Physicochemical characterization and GC–MS analysis compare the properties and compositions of MPPO, HPO, and diesel fuel. The waste polymers, which included HDPE, PP, and LDPE, were hydroprocessed and pyrolysed using platinum sulphate on zirconia oxide supports to produce a diesel equivalent. The alkane content of the blended fuel that was produced was 95 % that of diesel. The n-alkane levels in the carbon number ranges C11–C15 and C16–C20 were, respectively, 25 % and 10 % lower than diesel. But as one might expect from mixing heavy fuel oil, there were substantially more n-alkanes with carbon numbers of C21–C25. The combined fuel contained 10 % fewer isoalkanes than diesel. Ships can be powered by low-carbon fuel that was created by combining hydroprocessed fuel with commercial heavy fuel oil. Since the alternative fuel will emit considerably fewer emissions, the maritime industry can choose to replace it in order to help fulfil.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"265 ","pages":"Article 108145"},"PeriodicalIF":7.2,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of fuel and lubricant oil on particulate emissions in direct injection spark ignition engines: A comparative study of methane and hydrogen 燃料和润滑油对直接喷射火花点火发动机微粒排放的影响:甲烷和氢气的比较研究
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-10-17 DOI: 10.1016/j.fuproc.2024.108144
Barbara Apicella , Francesco Catapano , Silvana Di Iorio , Agnese Magno , Carmela Russo , Paolo Sementa , Antonio Tregrossi , Bianca Maria Vaglieco
{"title":"Impact of fuel and lubricant oil on particulate emissions in direct injection spark ignition engines: A comparative study of methane and hydrogen","authors":"Barbara Apicella ,&nbsp;Francesco Catapano ,&nbsp;Silvana Di Iorio ,&nbsp;Agnese Magno ,&nbsp;Carmela Russo ,&nbsp;Paolo Sementa ,&nbsp;Antonio Tregrossi ,&nbsp;Bianca Maria Vaglieco","doi":"10.1016/j.fuproc.2024.108144","DOIUrl":"10.1016/j.fuproc.2024.108144","url":null,"abstract":"<div><div>Internal combustion engines play a critical role in the global transportation system and the use of alternative fuels, such as methane and hydrogen, offers a promising way for ensuring their sustainability in the future. The best way to exploit the gaseous fuels properties is through the direct injection that allows to enhance the efficiency and to prevent backfire issues. On the other hand, this injection strategy causes a high interaction of the lubricant oil in the combustion process and hence high level of particle emissions despite the low/zero carbon content in the fuels. An experimental study was conducted on a spark-ignition engine powered by directly injected methane. This study involved both physical and chemical characterization of emissions, with the aim of providing an in-depth analysis of the hazardous pollutants emitted. Additionally, it sought to identify their origins, whether from the fuel or lubricating oil. Experimental results show that a higher concentration of particles is produced at higher engine speed. In this condition, which has a more significant environmental impact, a comparison between methane and hydrogen-fueled engine operating under similar conditions was performed, revealing that hydrogen engine produces more particles with a smaller size.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"265 ","pages":"Article 108144"},"PeriodicalIF":7.2,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142446414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Competitive effects of compounding aromatic hydrogen storage carriers in low-pressure hydrogenation reactions 低压氢化反应中复合芳香族储氢载体的竞争效应
IF 7.2 2区 工程技术
Fuel Processing Technology Pub Date : 2024-10-15 DOI: 10.1016/j.fuproc.2024.108143
Xiaopeng Mei , Zixuan Ma , Yingjie Yang , Xiaofeng Gao , Hantao Gong , Ziyu Song , Siyu Yao
{"title":"Competitive effects of compounding aromatic hydrogen storage carriers in low-pressure hydrogenation reactions","authors":"Xiaopeng Mei ,&nbsp;Zixuan Ma ,&nbsp;Yingjie Yang ,&nbsp;Xiaofeng Gao ,&nbsp;Hantao Gong ,&nbsp;Ziyu Song ,&nbsp;Siyu Yao","doi":"10.1016/j.fuproc.2024.108143","DOIUrl":"10.1016/j.fuproc.2024.108143","url":null,"abstract":"<div><div>The reaction activity of various liquid organic hydrogen carriers (LOHCs) over 5 wt% Rh/C (BET surface area 933.5 g/cm<sup>3</sup>, pore size 4.6 nm, metal dispersion 10.5 %) and 5 wt% Ru/C (BET surface area 888.4 g/cm<sup>3</sup>, pore size 6.1 nm, metal dispersion 8.9 %) catalysts is evaluated. The results show that monocyclic aromatic hydrocarbons have the highest reactivity, followed by monocyclic aromatic rings, while polycyclic and fused cyclic aromatic hydrocarbons have relatively low activity. It is also found that mixing different LOHCs leads to a competitive effect, resulting in lower reactivities for all LOHCs. As the degree of LOHC hydrogenation increases, the adsorption of multi-step hydrogenation intermediates becomes more difficult, resulting in lower yields of fully hydrogenated products. It is important to understand the behavior of LOHCs in hydrogenation reactions and to optimize the performance of LOHCs compound systems.</div></div>","PeriodicalId":326,"journal":{"name":"Fuel Processing Technology","volume":"265 ","pages":"Article 108143"},"PeriodicalIF":7.2,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142442321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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