发布求助
文献互助 智能选刊 最新文献

The Review of Physical Chemistry of Japan最新文献

筛选
英文 中文
High pressure transition in cadmium selenide 硒化镉的高压转变
The Review of Physical Chemistry of Japan Pub Date : 1970-04-10 DOI: 10.1246/NIKKASHI1948.88.8_813
J. Ōsugi, K. Shimizu, Tokio Nakamura, A. Onodera
{"title":"High pressure transition in cadmium selenide","authors":"J. Ōsugi, K. Shimizu, Tokio Nakamura, A. Onodera","doi":"10.1246/NIKKASHI1948.88.8_813","DOIUrl":"https://doi.org/10.1246/NIKKASHI1948.88.8_813","url":null,"abstract":"テルル化カドミウムの単結晶の高圧下におけるセンアエン鉱型構1造一岩塩型構造の相境界線を圧力約35kb,温度約800℃までの範囲で求めた。実験は六面体型アンピル装置における電気抵抗測定法によって行なった。室温における相転移圧力は33.3±1.8kbで,これにともなって電気抵抗のいちじるしい減少がみられる。相転移のさいの電気抵抗の変化量は温度とともに減少する。相転移の圧力は温度によって減少し,相境界線は-C1.015kb/degの傾きをもつ,800℃まで求めた相境界線は直線的で, Jayaramanらが決定した三重点にまで延長できる。Glapeyr4nの式から求めた室温における転移の潜熱は6.6×102cal/mol,エントロピー変化は2.3e. u.である。一定圧力下における電気抵抗の温度依存性の測定から求めたセンアエン鉱型構造のテルル化カドミウムのエネルギーギャップは約1.3eVで,これは圧力とともに増加する。","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"17 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1970-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134253314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Kinetic studies on fast reactions in solution VII : the kinetic studies on the reactions of p-benzoquinone and its derivatives with alkoxy ions 溶液中快速反应的动力学研究:对苯醌及其衍生物与烷氧离子反应的动力学研究
The Review of Physical Chemistry of Japan Pub Date : 1969-12-10 DOI: 10.1246/NIKKASHI1948.90.12_1231
M. Sasaki
{"title":"Kinetic studies on fast reactions in solution VII : the kinetic studies on the reactions of p-benzoquinone and its derivatives with alkoxy ions","authors":"M. Sasaki","doi":"10.1246/NIKKASHI1948.90.12_1231","DOIUrl":"https://doi.org/10.1246/NIKKASHI1948.90.12_1231","url":null,"abstract":"","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"24 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1969-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132138317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
A new method of determining the transition pressure of mercury at 0C as a fixed point of high pressures 一种测定汞在0℃时作为高压固定点的转变压力的新方法
The Review of Physical Chemistry of Japan Pub Date : 1967-11-30 DOI: 10.2183/PJAB1945.43.310
K. Yasunami
{"title":"A new method of determining the transition pressure of mercury at 0C as a fixed point of high pressures","authors":"K. Yasunami","doi":"10.2183/PJAB1945.43.310","DOIUrl":"https://doi.org/10.2183/PJAB1945.43.310","url":null,"abstract":"","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"56 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1967-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131673123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Chemical reaction at high temperature and high pressure III : reaction of silicon and phosphorus at high temperature and high pressure 高温高压化学反应III:硅与磷在高温高压下的反应
The Review of Physical Chemistry of Japan Pub Date : 1966-10-30 DOI: 10.2183/pjab1945.42.48
J. Ōsugi, R. Namikawa, Yoshiyuki Tanaka
{"title":"Chemical reaction at high temperature and high pressure III : reaction of silicon and phosphorus at high temperature and high pressure","authors":"J. Ōsugi, R. Namikawa, Yoshiyuki Tanaka","doi":"10.2183/pjab1945.42.48","DOIUrl":"https://doi.org/10.2183/pjab1945.42.48","url":null,"abstract":"","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"26 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1966-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132496888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Studies on the kinetics of the thermal polymerization of butadiene under high pressure 高压下丁二烯热聚合动力学研究
The Review of Physical Chemistry of Japan Pub Date : 1966-04-30 DOI: 10.1246/NIKKASHI1948.87.10_1032
J. Ōsugi, K. Hamanoue, S. Hirayama
{"title":"Studies on the kinetics of the thermal polymerization of butadiene under high pressure","authors":"J. Ōsugi, K. Hamanoue, S. Hirayama","doi":"10.1246/NIKKASHI1948.87.10_1032","DOIUrl":"https://doi.org/10.1246/NIKKASHI1948.87.10_1032","url":null,"abstract":"ブタジエンの無触媒液相塊重合を温度323°～368°K,圧力1100～5000kg/cm2がの範囲で行ない,速度論的立場から二,三の検討を行なった。重合反応は時間に対してほぼ直線的に進行し,誘導期は認められないが温度,圧力の増加によりいちじるしく加速される。見かけの初期重合速度から,活性化エネルギー(E),活性化体積,および活性化エントロピー を計算し,つぎのような値を得た。E=15.1～19.2kcal/mo1,47≒-8.8～-17.2cm3/mo1および5≒=-38.0～-24.3e.u。圧力の増加とともに活性化エントロピーと活性化エネルギ0は増加しているが,高圧下の重合速度の増大は前者の影響がいちじるしく大きいことを示しており,後者は重合速度を減少させる方向に働く。得られたポリマーは通常の溶剤に不溶であり,かなり架橋度の高いものであると思われる。","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"32 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1966-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128109819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
The synthesis of iso- and normal butyl alcohols in the presence of calcium carbide 异丁醇和正丁醇在电石存在下的合成
The Review of Physical Chemistry of Japan Pub Date : 1941-12-30 DOI: 10.1246/BCSJ.17.179
R. Negishi
{"title":"The synthesis of iso- and normal butyl alcohols in the presence of calcium carbide","authors":"R. Negishi","doi":"10.1246/BCSJ.17.179","DOIUrl":"https://doi.org/10.1246/BCSJ.17.179","url":null,"abstract":"The experimental procedure and the preparations of the catalysts used are given in detail. The effects on the activity of the carbide and of the reaction products are found to be small—if at all. The results of the runs in dry system are tabulated, and each run is briefly described. Short discussions on the results are also given. A fuller discussion on them is reserved for a subsequent paper.","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"77 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1941-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114773992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Note on the disintegration of the starch paste caused by the irradiation of ultrasonic waves 注意淀粉糊在超声波照射下的崩解
The Review of Physical Chemistry of Japan Pub Date : 1940-04-30 DOI: 10.1246/NIKKASHI1921.61.929
S. Ono
{"title":"Note on the disintegration of the starch paste caused by the irradiation of ultrasonic waves","authors":"S. Ono","doi":"10.1246/NIKKASHI1921.61.929","DOIUrl":"https://doi.org/10.1246/NIKKASHI1921.61.929","url":null,"abstract":"糊の崩壞機構を詳にせんが爲に,前報と同一の方法(崩壞を糊粒子の比容積φ及顯微鏡構造の變化として觀察する)に依つて更に二三の崩壞特性を明かにした.(i) 崩壞效果(φ減少率)は外氣壓に依つて著しく影響を受け, 1氣壓邊が最大で,低壓でも又高壓でも減少し遂に零となる.(ii) 溶解氣體の影響は極僅かであつて,酸素は崩壊を大ならしめ,水素は反對に小ならしめる.(iii) 0.1～5%の濃度範圍に於て,低濃度程崩壊效果が大である.以上の特性(前報所載の特性も參考として)を考察して崩壊機構は次の如きものと考へられる.(I) Cavitation(或は氣泡の脈動效果)等の,氣泡を媒介とせる機械力,機構(1)が主なものである.尚同時に氣泡の斷熱壓縮に依る熱加水分解,機構(3)の起る事も否定出來ぬ.(II) 崩壞過程には極一部酸化に伴ふ解重合,機構(5)が起つてゐる.(III) 純粹な音波の機械力,機構(2)及Szalayの機構(4)の兩者は,少く共初期變化に對して全く無力である.","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"53 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1940-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129726161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
The activated adsorption of methane on reduced nickel 甲烷在还原镍上的活化吸附
The Review of Physical Chemistry of Japan Pub Date : 1938-12-31 DOI: 10.2183/PJAB1912.14.61
M. Kubokawa
{"title":"The activated adsorption of methane on reduced nickel","authors":"M. Kubokawa","doi":"10.2183/PJAB1912.14.61","DOIUrl":"https://doi.org/10.2183/PJAB1912.14.61","url":null,"abstract":"It is well known that a nickel catalyst is highly active for the decomposition of methane,\" but the mechanism of the catalysis is still unknown. Some studies on catalysis in connection with activated adsorption have recently been done, but the system of methane-nickel has not yet been investigated. 0. Schmidt2) reported that methane is not so much adsorbed on nickel and a simple adsorption isobar indicat ing no occurence of activated adsorption was obtained in the tempera ture range between room temperature and 230•‹C. H. S. Taylor and others,3) however, concluded from their researches upon the exchange reactions between methane and CD4 or D2 that the activated adsorption of methane of a dissociative type took place on the surface of nickel above 138•Ž. Under Prof. S. Horiba's guidance, the author attempted","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"155 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1938-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122156795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
On the Rigidity and the Consitiution of a Thermoreversible Gel 热可逆凝胶的刚性和结构
The Review of Physical Chemistry of Japan Pub Date : 1937-09-15 DOI: 10.2183/PJAB1912.13.266
F. Hirata
{"title":"On the Rigidity and the Consitiution of a Thermoreversible Gel","authors":"F. Hirata","doi":"10.2183/PJAB1912.13.266","DOIUrl":"https://doi.org/10.2183/PJAB1912.13.266","url":null,"abstract":"","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"64 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1937-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132202085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Emission Spectrum of the Flame of Bromine Buring in Hydrogen and Mechanism of the Reaction 溴在氢中燃烧火焰的发射光谱及反应机理
The Review of Physical Chemistry of Japan Pub Date : 1900-01-01 DOI: 10.2183/PJAB1912.11.262
T. Kitagawa
{"title":"Emission Spectrum of the Flame of Bromine Buring in Hydrogen and Mechanism of the Reaction","authors":"T. Kitagawa","doi":"10.2183/PJAB1912.11.262","DOIUrl":"https://doi.org/10.2183/PJAB1912.11.262","url":null,"abstract":"where v=4, 5, 6, ......, 13, and v•V=4, 5, 6 as obtained from the band analysis, and the mechanism of the reaction was discussed. In this paper it is reported that in the flame of bromine burning in hydrogen about 43 emission bands were found, which are to be attributed to the excited bromine molecules in the flame, and the reaction mechanism of the combustion of bromine and hydrogen is discussed. Experimental: Pure hydrogen was continuously passed through a transparent quartz vessel, 10 cm in length and 3 cm in diameter, into which bromine vapour was sent from the mouth of a quartz tube and the flame blazed at the jet. The colour of the flame was orange yellow. The emission spectrum of the flame is shown in Plate I (exposure, about 1 hour). About 43 emission bands, which degrade all to red, are","PeriodicalId":265588,"journal":{"name":"The Review of Physical Chemistry of Japan","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132183009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：481959085
Book学术官方微信