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Multifunctional carbon dots: Versatile and high-efficiency additives for polyethylene glycol 多功能碳点:聚乙二醇的多功能高效添加剂
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-07 DOI: 10.1016/j.carbon.2025.120796
Weiwei Tang , Hao Lei , Yi Wang , Haidong Liu , Xian Wei , Wei Gao , Zhe Zhang , Zhiqiang Jiang , Yufeng Li
{"title":"Multifunctional carbon dots: Versatile and high-efficiency additives for polyethylene glycol","authors":"Weiwei Tang ,&nbsp;Hao Lei ,&nbsp;Yi Wang ,&nbsp;Haidong Liu ,&nbsp;Xian Wei ,&nbsp;Wei Gao ,&nbsp;Zhe Zhang ,&nbsp;Zhiqiang Jiang ,&nbsp;Yufeng Li","doi":"10.1016/j.carbon.2025.120796","DOIUrl":"10.1016/j.carbon.2025.120796","url":null,"abstract":"<div><div>Recently, eco-friendly polyethylene glycol (PEG)-based lubricants have received extensive attention in lubrication as energy and environmental crises are aggravating increasingly. Unfortunately, the inherent defects, including relatively weak lubricating performance and single function, significantly limited their development. In this case, a multi-function integrated carbon dots-based lubricant additive (MF-CDs) with good anti-corrosion, anti-oxidation, friction-reducing, anti-wear, and load-supporting functions was creatively synthesized by a one-step pyrolysis method. As a fire-new lubricant additive, the multi-functional MF-CDs can endow the PEG200 lubricant with superior anti-corrosion and anti-oxidation performances effectively. Additionally, when the suitable concentrations of MF-CDs were introduced into the PEG200 lubricant, its friction-reducing, anti-wear, and load-supporting performances can be superlatively increased by 46.6 %, 66.3 %, and 100.0 %, respectively, exhibiting great application prospects. Experimental results illustrated that the excellent tribological performances of MF-CDs are attributed to their terrific film-forming capacity and nanostructure-lubricated phenomenon. To sum up, MF-CDs as additives could systematically improve the multifarious performances of PEG-based lubricants, significantly expanding their applied range. Therefore, the corresponding research of this work is expected to reduce the types of lubricant additives and then decrease the lubrication cost of mechanical equipment markedly.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120796"},"PeriodicalIF":11.6,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145027068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiple selenide modified carbon fibers to construct heterogeneous interfaces for electromagnetic wave absorption 多硒化改性碳纤维构建非均相界面的电磁波吸收
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-07 DOI: 10.1016/j.carbon.2025.120824
Yuelei Pan , Kailong Yu , Di Lan , Zailan Zhang , Zhesheng Chen
{"title":"Multiple selenide modified carbon fibers to construct heterogeneous interfaces for electromagnetic wave absorption","authors":"Yuelei Pan ,&nbsp;Kailong Yu ,&nbsp;Di Lan ,&nbsp;Zailan Zhang ,&nbsp;Zhesheng Chen","doi":"10.1016/j.carbon.2025.120824","DOIUrl":"10.1016/j.carbon.2025.120824","url":null,"abstract":"<div><div>Multi-component interface engineering offers significant potential for high-efficiency electromagnetic wave (EMW) absorption, yet precise interfacial modulation remains challenging. Here, we tailor EMW absorption in MOF-derived core-shell heterostructures via experimental synthesis and Density Functional Theory (DFT)-guided interface design. Three selenide composites were fabricated through electrospinning, hydrothermal processing, and thermal reduction. By incorporating NiCo conductive networks and carbon nanofiber electron highways, hierarchical interfaces were engineered. DFT simulations quantitatively validate enhanced interface-induced polarization relaxation at ZnSe/CoSe<sub>2</sub> junctions. As a result, the ZnSe/CoSe<sub>2</sub>/Ni@NiCo-hc composite, with abundant heterogeneous interfaces, exhibited exceptional EMW absorption performance at a low filler loading of 7 wt%. At an optimized matching thickness of 1.8 mm, a minimum reflection loss of −57.28 dB was achieved. Outstanding absorption performance tunable across a broad frequency range. In addition, the radar cross section (RCS) simulation demonstrated that the three selenide composites possessed excellent electromagnetic stealth capabilities. This work presents an effective strategy for designing high-performance EMW absorbers through rational heterointerface engineering.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120824"},"PeriodicalIF":11.6,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145045972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modulation of carbon atom hybridization structure and electromagnetic absorption properties in carbon fiber composites 碳纤维复合材料中碳原子杂化结构和电磁吸收特性的调制
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-07 DOI: 10.1016/j.carbon.2025.120823
Jiaxin Chen , Pingan Chen , Yingli Zhu , Fu Chen , Mengke Qiao , Jiang Wu , Xiangcheng Li
{"title":"Modulation of carbon atom hybridization structure and electromagnetic absorption properties in carbon fiber composites","authors":"Jiaxin Chen ,&nbsp;Pingan Chen ,&nbsp;Yingli Zhu ,&nbsp;Fu Chen ,&nbsp;Mengke Qiao ,&nbsp;Jiang Wu ,&nbsp;Xiangcheng Li","doi":"10.1016/j.carbon.2025.120823","DOIUrl":"10.1016/j.carbon.2025.120823","url":null,"abstract":"<div><div>Carbon fiber composites exhibit significant potential for electromagnetic wave (EMW) absorption, whereas the practical application is limited by excessive electrical conductivity and a single loss mechanism. Herein, high-entropy borate (HE ReBO<sub>3</sub>) loaded carbon fiber composites were fabricated by electrospinning, which the fiber morphology and sp<sup>2</sup>/sp<sup>3</sup> hybridized carbon ratios were controlled by borate loading. The results show that the sp<sup>2</sup> hybridization carbon ratio increased from 24.28 % to 29.08 %, intensifying dipole polarization loss. Meanwhile, the introduction of HE ReBO<sub>3</sub> induced a ribbon-like fiber structure with median diameters of 0.57 μm, which enhanced multiple reflection/scattering of EWM and interface polarization. The synergistic effect between dipole and interface polarization endowed the composite with exceptional absorption properties. The optimal composite (HE ReBO<sub>3</sub>-3) achieved a minimum reflection loss (RL<sub>min</sub>) of −59.41 dB at 2.18 mm thickness and an EAB<sub>-10</sub> (RL ≤ −10 dB) of 8.83 GHz, which demonstrated superior broadband and strong absorption performance. This work proposes a carbon hybridization strategy for structural modulation, providing novel insights for designing electromagnetic functional materials.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120823"},"PeriodicalIF":11.6,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145045973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure-property correlations in multilayer hydrogenated amorphous carbon films enabling long-lasting stable superlubricity under ultra-high contact stress 在超高接触应力下实现长期稳定超润滑的多层氢化非晶碳膜的结构-性能相关性
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-06 DOI: 10.1016/j.carbon.2025.120797
Jiaxuan Guo , Xinchun Chen , Wenli Deng , Wei Qi , Ting Luo
{"title":"Structure-property correlations in multilayer hydrogenated amorphous carbon films enabling long-lasting stable superlubricity under ultra-high contact stress","authors":"Jiaxuan Guo ,&nbsp;Xinchun Chen ,&nbsp;Wenli Deng ,&nbsp;Wei Qi ,&nbsp;Ting Luo","doi":"10.1016/j.carbon.2025.120797","DOIUrl":"10.1016/j.carbon.2025.120797","url":null,"abstract":"<div><div>Hydrogenated amorphous carbon (a-C:H) films demonstrate significant potential as solid lubricant in engineering applications. However, the instability of lubrication performance under high-load conditions remains a significant challenge, primarily attributed to combined effects, such as high intrinsic stress and poor interfacial adhesion. In this paper, a group of multilayer a-C:H films were fabricated, exhibiting excellent tribological performances under high-load conditions with a maximum Hertzian contact stress of 3.19 GPa in dry nitrogen environment. One of the multilayer films demonstrated exceptional durability over 100,000 cycles with a stable super-low coefficient of friction (COF) of 0.005 and an ultra-low wear rate of 5.32 × 10<sup>−9</sup> mm<sup>3</sup>/N·m. It is revealed that the film intrinsic stress exerts a decisive influence on the friction stability and wear resistance. The low internal stress, high wear resistance index (<em>H</em>/<em>E</em>) and elevated plasticity index (<em>H</em><sup>3</sup>/<em>E</em><sup>2</sup>) of this film fundamentally explain the superior wear resistance and enhanced load-bearing capacity. Microstructural characterization of the sliding interface reveals that the hydrogen passivation mechanism, rather than structural ordering transformation, is likely the dominant factor to sustain superlubricity. The synergistic effect of high hydrogen content and superior mechanical properties guarantees durable lubrication capabilities. These findings establish fundamental design guidelines for implementing carbon-based lubricative coatings in extreme load-bearing applications.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120797"},"PeriodicalIF":11.6,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145027066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microwave plasma synthesis of freestanding sulfur-doped few-layer graphene and the impact of the dopant on the electrical transport properties: Experiment and simulation 微波等离子体合成独立硫掺杂少层石墨烯及其对电输运特性的影响:实验与模拟
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-06 DOI: 10.1016/j.carbon.2025.120815
P. Fortugno , A. Sahinovic , N. Wilson , J. Tuling , C.-F. López-Cámara , R. Pentcheva , H. Wiggers
{"title":"Microwave plasma synthesis of freestanding sulfur-doped few-layer graphene and the impact of the dopant on the electrical transport properties: Experiment and simulation","authors":"P. Fortugno ,&nbsp;A. Sahinovic ,&nbsp;N. Wilson ,&nbsp;J. Tuling ,&nbsp;C.-F. López-Cámara ,&nbsp;R. Pentcheva ,&nbsp;H. Wiggers","doi":"10.1016/j.carbon.2025.120815","DOIUrl":"10.1016/j.carbon.2025.120815","url":null,"abstract":"<div><div>This study investigates the formation of freestanding sulfur-doped few-layer graphene (FLG) during microwave plasma synthesis and the impact of the doping on its physicochemical and electrical properties. Varying the molar concentration of the sulfur dopant shows for low concentrations (&lt;10 mol%) an increase in the electrical conductivity of powder pellets compared with undoped FLG. Larger dopant concentrations (≥10 mol%) lead to a reduction in conductivity, which is likely linked to the formation of undesired secondary phases. The measured conductivity values are compared to predictions from Boltzmann transport theory based on density functional theory (DFT) calculations of different sulfur dopant configurations. The results highlight that the multilayer structure of FLG significantly influences the stability of different defect types, showing that sulfur (S) doping in conjunction with carbon vacancies in FLG (−3.69 eV) is more favorable than graphitic doping (−2.27 eV). The transport calculations for the most stable configurations demonstrate a conductivity enhancement factor of 1.78–2.47 over the pristine sample matching the experimental observations. Thus, the experimentally observed conductivity increase could be associated with the formation of C–S–C defect structures at C vacancies.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120815"},"PeriodicalIF":11.6,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145045905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phthalonitrile-derived hierarchical porous carbon through synergistic KOH/KCl activation for high-performance supercapacitor electrodes 通过KOH/KCl协同活化的邻苯二腈衍生的分级多孔碳用于高性能超级电容器电极
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-06 DOI: 10.1016/j.carbon.2025.120819
Yi Li , Qiancheng Liu , Peng Zhao , Qian Zhang , Zhongxiang Bai , Xiaoxiao Li , Yang Yang , Pan Wang , Kui Li , Ying Li , Xulin Yang
{"title":"Phthalonitrile-derived hierarchical porous carbon through synergistic KOH/KCl activation for high-performance supercapacitor electrodes","authors":"Yi Li ,&nbsp;Qiancheng Liu ,&nbsp;Peng Zhao ,&nbsp;Qian Zhang ,&nbsp;Zhongxiang Bai ,&nbsp;Xiaoxiao Li ,&nbsp;Yang Yang ,&nbsp;Pan Wang ,&nbsp;Kui Li ,&nbsp;Ying Li ,&nbsp;Xulin Yang","doi":"10.1016/j.carbon.2025.120819","DOIUrl":"10.1016/j.carbon.2025.120819","url":null,"abstract":"<div><div>Hierarchical porous carbon (HPC) materials hold immense promise for advancing high-performance supercapacitors. However, the development of straightforward and sustainable synthetic routes remains a formidable challenge. This work employs a facile strategy combining low-temperature carbonization with the synergistic effects of chemical activation and salt templating, utilizing phthalonitrile monomer (RPH) as precursors to synthesize N-enriched hierarchical porous carbon. The optimized RKC-1 sample features an advantageous pore size distribution, a large specific surface area of 2079 m<sup>2</sup> g<sup>−1</sup>, a N-doping loading of 1.86 %, and a moderate degree of graphitization. The RKC-1 electrode demonstrates a notable level of specific capacitance of 394 F g<sup>−1</sup> at 1 A g<sup>−1</sup>. Notably, in a two-electrode system at 5 A g<sup>−1</sup>, after undergoing 10,000 cycles, the RKC-1 electrode maintains a capacitance retention rate of 80.34 % and achieves a Coulombic efficiency of 99.24 %. These results underscore that the synthesized RPH-based porous carbon demonstrates promising potential for practical applications in advanced energy storage systems.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120819"},"PeriodicalIF":11.6,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145045970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phosphorus-transfer-induced self-healing of carbon layers for precise modulation of hard carbon defects and closed pores 磷转移诱导的碳层自愈精确调节硬碳缺陷和封闭孔隙
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-06 DOI: 10.1016/j.carbon.2025.120821
Yiduo Liu , Shuai Dai , Xiaohui Huang , Yilun Zhao , Shuaiqi Liu , Yinglong Xu , Hao Guo , Yuyue Gao , Chang Sun , Jingjing Hao , Zeming Liu , Haiyan Wang , Ling Liu , Qinghan Meng
{"title":"Phosphorus-transfer-induced self-healing of carbon layers for precise modulation of hard carbon defects and closed pores","authors":"Yiduo Liu ,&nbsp;Shuai Dai ,&nbsp;Xiaohui Huang ,&nbsp;Yilun Zhao ,&nbsp;Shuaiqi Liu ,&nbsp;Yinglong Xu ,&nbsp;Hao Guo ,&nbsp;Yuyue Gao ,&nbsp;Chang Sun ,&nbsp;Jingjing Hao ,&nbsp;Zeming Liu ,&nbsp;Haiyan Wang ,&nbsp;Ling Liu ,&nbsp;Qinghan Meng","doi":"10.1016/j.carbon.2025.120821","DOIUrl":"10.1016/j.carbon.2025.120821","url":null,"abstract":"<div><div>Hard carbon (HC) is a promising anode material for sodium-ion batteries. However, the precise design of closed-pore structures and the control of carbon defects remain key bottlenecks in the development of polymer-derived hard carbon. Based on this, this paper proposes a phosphorus (P)-transfer-induced carbon layer self-healing strategy, achieving synergistic optimization of closed-pore structures and carbon defects. Through a pre-oxidation-mediated transfer pathway of boundary phosphorus (P–<em>O</em>–C) to carbon matrix phosphorus (P–C), radical competitive reactions are triggered during pyrolysis, transforming thick and short disordered carbon layers into thin and long pseudo-graphitic carbon layers. This strategy constructs abundant and uniformly distributed small-sized closed pores (0.76 nm) in the carbon matrix while converting irregular edge carbon defects into intrinsic carbon defects. The synergistic optimization of both promotes the formation of fluorine-rich solid electrolyte interface components, significantly enhancing Na<sup>+</sup> transport kinetics. The optimized hard carbon exhibits a reversible specific capacity of up to 429.0 mAh g<sup>−1</sup>, an initial coulombic efficiency (ICE) of up to 89.44 %, and excellent cycling performance at a current density of 5 A g<sup>−1</sup>, enabling 10000 cycles. This study provides a new approach for the development of high-performance polymer-derived hard carbon materials.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120821"},"PeriodicalIF":11.6,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145045971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the graphitization behaviors of highly stiff and thermally conductive graphitic carbon fibers 揭示了高刚性导热石墨炭纤维的石墨化行为
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-05 DOI: 10.1016/j.carbon.2025.120791
Changbeom Jeon , Sunjae Hwang , Minjung Han , Seunghwan Lee , Hyeon Jung Gwak , Jong Sung Won , Soo Bin Bae , Han Gi Chae
{"title":"Unveiling the graphitization behaviors of highly stiff and thermally conductive graphitic carbon fibers","authors":"Changbeom Jeon ,&nbsp;Sunjae Hwang ,&nbsp;Minjung Han ,&nbsp;Seunghwan Lee ,&nbsp;Hyeon Jung Gwak ,&nbsp;Jong Sung Won ,&nbsp;Soo Bin Bae ,&nbsp;Han Gi Chae","doi":"10.1016/j.carbon.2025.120791","DOIUrl":"10.1016/j.carbon.2025.120791","url":null,"abstract":"<div><div>We explored the potential of highly stiff and thermally conductive carbon fibers for thermal management applications. The polyacrylonitrile (PAN)-based carbon fibers were graphitized up to 2300 °C through a continuous process, resulting in a tensile modulus of 427 GPa. Microstructural analysis revealed a trade-off reaction between mechanical properties during the graphitization process. This trade-off reaction in mechanical properties occurred because of the rearrangement of the crystalline structure above 2000 °C. The intrinsic properties of graphite, particularly its high in-plane energy conduction during the graphitization, led to the rearrangement and coalescence of crystalline structures in the near-surface region. Consequently, excessive grain boundaries were evident in the surface regions, causing a trade-off reaction. It was evident that the fibers graphitized at 2300 °C exhibited highly developed carbon structures in surface regions with a mixed stacking order. The measured thermal conductivity reached up to 292 W m<sup>−1</sup> K<sup>−1</sup>, considerably higher than commercial PAN-based carbon fibers, overcoming the limitations of polymeric carbon materials. This enhanced conductivity originated from the highly developed carbon structures in the surface regions, which acted as an effective pathway for energy conduction. The resulting fibers exhibited enormous potential as thermal management materials for lightweight applications.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120791"},"PeriodicalIF":11.6,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145019533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Acceleration strategy for rapid oxidation stabilization of pitch and the influence on the structure and property of carbon materials 沥青快速氧化稳定的加速策略及其对碳材料结构和性能的影响
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-05 DOI: 10.1016/j.carbon.2025.120781
Yiting He , Tao Yang , Yan Song , Ning Zhao , Xiaodong Tian , Zhanjun Liu
{"title":"Acceleration strategy for rapid oxidation stabilization of pitch and the influence on the structure and property of carbon materials","authors":"Yiting He ,&nbsp;Tao Yang ,&nbsp;Yan Song ,&nbsp;Ning Zhao ,&nbsp;Xiaodong Tian ,&nbsp;Zhanjun Liu","doi":"10.1016/j.carbon.2025.120781","DOIUrl":"10.1016/j.carbon.2025.120781","url":null,"abstract":"<div><div>Pitch, an abundant and low-cost precursor with a high carbon yield, is widely used to produce various carbon materials. However, the oxidation stabilization process, a crucial step in preparing pitch-based carbon materials, faces challenges owing to the low oxidative reactivity of pitch molecules and slow oxygen diffusion kinetics, hindering the efficient large-scale production of high-performance pitch-based carbon materials. To address these limitations, the fundamental properties of pitch, the mechanism and limiting factors of oxidation stabilization are first outlined. Subsequently, acceleration strategies and corresponding mechanisms are systematically summarized from two perspectives: enhancing the oxidation reactivity of pitch molecules and accelerating the oxygen diffusion. Furthermore, how the structures of oxidized products determine the microstructures, properties and applications of carbon materials is discussed to provide guidelines for the tailored design of high-performance pitch-based carbon materials. Finally, current research limitations and potential solutions are envisaged.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120781"},"PeriodicalIF":11.6,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145019532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microwave absorption optimization via additive manufacturing: Process-dependent mechanisms of electromagnetic attenuation 通过增材制造优化微波吸收:电磁衰减的工艺依赖机制
IF 11.6 2区 材料科学
Carbon Pub Date : 2025-09-04 DOI: 10.1016/j.carbon.2025.120795
Shuailong Gao, Yingjian Sun, Li Xi, Tian Zhao, Yixing Huang, Rujie He, Xiao Kang, Ying Li
{"title":"Microwave absorption optimization via additive manufacturing: Process-dependent mechanisms of electromagnetic attenuation","authors":"Shuailong Gao,&nbsp;Yingjian Sun,&nbsp;Li Xi,&nbsp;Tian Zhao,&nbsp;Yixing Huang,&nbsp;Rujie He,&nbsp;Xiao Kang,&nbsp;Ying Li","doi":"10.1016/j.carbon.2025.120795","DOIUrl":"10.1016/j.carbon.2025.120795","url":null,"abstract":"<div><div>Additive manufacturing, with its capability to fabricate intricate structures, enables manipulation of electromagnetic wave propagation at the macroscopic level, thus demonstrating significant potential for achieving broader bandwidth and deeper microwave absorption. However, the performance of additively manufactured components is influenced by a combination of different process parameters, and currently, there is a lack of research on the mechanisms of additive manufacturing process parameters on microwave absorption characteristics. Therefore, 27 sets of gradient process parameters were designed and applied to fabricate PA6/CF composite waveguide samples, aiming to investigate the mechanisms of Fused Deposition Modeling process parameters on microwave absorption characteristics. The results demonstrated that process parameters such as layer thickness, printing speed, printing density, and printing temperature significantly influenced the microstructure and microscopic defects distribution of the components. By intelligently optimizing the additive manufacturing process, the microstructure can be further controlled, enabling the customized design of electromagnetic parameters and simultaneously enhancing both the absorption depth and the effective absorption bandwidth. This analysis of the process-dependent mechanisms of electromagnetic attenuation not only expands the application of additive manufacturing in stealth technology but also provides valuable insights for optimizing manufacturing processes and enhancing component quality.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"245 ","pages":"Article 120795"},"PeriodicalIF":11.6,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145004860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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