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Modeling and performance limit exploration in carbon nanotube field-effect-transistor biosensors 碳纳米管场效应晶体管生物传感器的建模与性能限制探讨
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-05 DOI: 10.1016/j.carbon.2026.121352
Xianmao Cao , Mengmeng Xiao , Yunfei Gao , Yang Zhang , Yu Xia , Xiuli Fu , Panpan Zhang , Zhiyong Zhang
{"title":"Modeling and performance limit exploration in carbon nanotube field-effect-transistor biosensors","authors":"Xianmao Cao ,&nbsp;Mengmeng Xiao ,&nbsp;Yunfei Gao ,&nbsp;Yang Zhang ,&nbsp;Yu Xia ,&nbsp;Xiuli Fu ,&nbsp;Panpan Zhang ,&nbsp;Zhiyong Zhang","doi":"10.1016/j.carbon.2026.121352","DOIUrl":"10.1016/j.carbon.2026.121352","url":null,"abstract":"<div><div>Carbon nanotube field-effect transistor (CNT FET) biosensors have demonstrated considerable advances in clinical applications, yet the absence of a unified predictive model hinders systematic optimization towards detection limits. Here, we present an experimentally calibrated physics-informed simulation framework that quantitatively elucidate the electrostatic signal transduction mechanisms in FET biosensors, facilitating a systematic exploration of the design space to achieve high sensitivity. Employing a CNT floating-gate FET biosensor configuration. We derive a noise-limited detection threshold, providing a direct link between electrical noise and the minimum resolvable molecular coverage. We then reveal that sensor sensitivity depends non-monotonically on gate dielectric thickness, with performance optimized at a specific thickness rather than at the minimum value. Moreover, our results demonstrate that at ultra-low concentrations (&lt;10<sup>−15</sup> M), the specific positioning of biomolecular binding sites is critical. The tunneling barriers at the nanojunctions within carbon nanotube networks induce exponential current responses, though these effects attenuate at higher target concentrations. By establishing a robust physical model, this study provides a foundational platform for analyzing biomolecular electrostatic coupling and offers comprehensive design guidelines to push the performance boundaries of next-generation biosensors.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121352"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible CoFe2O4@CNT/ANF-PMXene-CNT/ANF multilayer films with magnetic-electric bi-continuous gradient structure for EMI shielding and thermal camouflage 柔性CoFe2O4@CNT/ANF- pmxene - cnt /ANF多层薄膜,具有电磁屏蔽和热伪装的磁电双连续梯度结构
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-04 DOI: 10.1016/j.carbon.2026.121349
Shanshan Chen , Zhaoqing Lu , Li Hua , Zhijian Li , Fengfeng Jia , Rui Cheng
{"title":"Flexible CoFe2O4@CNT/ANF-PMXene-CNT/ANF multilayer films with magnetic-electric bi-continuous gradient structure for EMI shielding and thermal camouflage","authors":"Shanshan Chen ,&nbsp;Zhaoqing Lu ,&nbsp;Li Hua ,&nbsp;Zhijian Li ,&nbsp;Fengfeng Jia ,&nbsp;Rui Cheng","doi":"10.1016/j.carbon.2026.121349","DOIUrl":"10.1016/j.carbon.2026.121349","url":null,"abstract":"<div><div>The rapid escalation of electromagnetic (EM) wave pollution and secondary radiation underscored the urgent need for electromagnetic interference (EMI) shielding materials with reduced reflectivity. Previous research predominantly emphasized the incorporation of magnetic fillers, often neglecting their synergistic integration with spatial architecture, thereby constraining the multifunctionality of EMI shielding systems. In contrast, layer-by-layer (LBL) fabrication technology offered precise control over microstructures and enabled multifunctional integration, which had been effectively applied in areas such as supercapacitors, controlled drug release, nanofiltration membranes and EMI shielding. By constructing tailored layered configurations, this approach facilitated tunable attenuation of electromagnetic waves. Herein, aramid nanofibers (ANF), carbon nanotubes (CNT), MXene and cobalt ferrite (CoFe<sub>2</sub>O<sub>4</sub>) were employed to fabricate a multilayer film featuring a magnetic-electric bi-continuous gradient structure via LBL assembly. Owing to its hierarchical architecture, the (Z<sub>1</sub>-Z<sub>2</sub>-Z<sub>3</sub>)CoFe<sub>2</sub>O<sub>4</sub>@CNT/ANF-PMXene-CNT/ANF ((Z<sub>1</sub>-Z<sub>2</sub>-Z<sub>3</sub>)CoC/A-PM-C/A) films demonstrated exceptional EMI shielding performance. Particularly, the (80-40-10)CoC/A-PM-C/A composite film achieved a high EMI shielding effectiveness (EMI SE) of 63.6 dB and exhibited a low reflection coefficient (R) of 0.613, while maintaining favorable mechanical properties, including a tensile strength of 51.2 MPa and toughness of 5.67 MJ m<sup>−3</sup>. Simultaneously, the films exhibited superior thermal camouflage capability with a mid-infrared (IR) emissivity as low as 2.61% in the 7∼17 μm range, and displayed effective Joule-heating characteristics. This work introduced a novel strategy for the development of advanced EMI shielding materials, and the resulting (Z<sub>1</sub>-Z<sub>2</sub>-Z<sub>3</sub>)CoC/A-PM-C/A films demonstrated considerable promise in applications involving EMI suppression, infrared stealth, and electrothermal conversion.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121349"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrawide-bandgap diamond/ε-Ga2O3 pn heterojunction for self-powered solar-blind photodetection and high-temperature operation 超宽带隙金刚石/ε-Ga2O3 pn异质结用于自供电太阳盲光探测和高温工作
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-03 DOI: 10.1016/j.carbon.2026.121335
Jianguo Zhang , Jiayi Liu , Dongyang Han , Chaonan Lin , Xun Yang , Sibo Zhao , Mengwei Zhong , Ningtao Liu , Chongxin Shan , Jichun Ye , Wenrui Zhang
{"title":"Ultrawide-bandgap diamond/ε-Ga2O3 pn heterojunction for self-powered solar-blind photodetection and high-temperature operation","authors":"Jianguo Zhang ,&nbsp;Jiayi Liu ,&nbsp;Dongyang Han ,&nbsp;Chaonan Lin ,&nbsp;Xun Yang ,&nbsp;Sibo Zhao ,&nbsp;Mengwei Zhong ,&nbsp;Ningtao Liu ,&nbsp;Chongxin Shan ,&nbsp;Jichun Ye ,&nbsp;Wenrui Zhang","doi":"10.1016/j.carbon.2026.121335","DOIUrl":"10.1016/j.carbon.2026.121335","url":null,"abstract":"<div><div>Solar-blind photodetectors (SBPDs) operating without external power are highly desirable for applications in communication, sensing, and imaging, yet their performance is often limited by high dark current and poor detectivity. Here, we demonstrate a self-powered SBPD based on a p-type diamond/n-type <em>ε</em>-Ga<sub>2</sub>O<sub>3</sub> heterojunction diode. The detector exhibits remarkable comprehensive performance under self-powered operation, including an ultra-low dark current of 23 fA, an ultrahigh photo-to-dark current ratio (PDCR) exceeding 10<sup>6</sup>, a responsivity of 384 mA/W, and robust high-temperature stability with a PDCR of 10<sup>2</sup> at 473 K. Moreover, it shows excellent spectral selectivity at the solar-blind wavelength regime, as well as outstanding spatial uniformity and stable operation over time. The high performance originates from the synergistic combination of exclusive ultrawide bandgap semiconductors and a deliberately engineered pn junction. This design ensures efficient light absorption and carrier collection within the <em>ε</em>-Ga<sub>2</sub>O<sub>3</sub> layer while the diamond counterpart maintains excellent rectification and thermal management. The detector is further successfully applied in rapid UV communication taking advantage of its microsecond-level response time. This work establishes an ultrawide-bandgap pn heterojunction design for self-powered solar-blind photodetectors for advanced optoelectronics.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121335"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interface-driven resistive switching and synaptic behavior in the graphene oxide-based memristive devices 基于氧化石墨烯的忆阻器件中界面驱动的电阻开关和突触行为
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-01-28 DOI: 10.1016/j.carbon.2026.121316
Phu-Quan Pham , Trung Ngoc Bao Duong , Beshoy Nasr , Massamichi Yoshimura , Ngoc Kim Pham
{"title":"Interface-driven resistive switching and synaptic behavior in the graphene oxide-based memristive devices","authors":"Phu-Quan Pham ,&nbsp;Trung Ngoc Bao Duong ,&nbsp;Beshoy Nasr ,&nbsp;Massamichi Yoshimura ,&nbsp;Ngoc Kim Pham","doi":"10.1016/j.carbon.2026.121316","DOIUrl":"10.1016/j.carbon.2026.121316","url":null,"abstract":"<div><div>Graphene oxide (GO) has long been considered a versatile material for resistive switching, yet most reported devices remain limited to binary and filamentary behavior. Although GO is a flexible resistive-switching medium, the majority of memristors still primarily function in binary, filamentary modes after embedding GO in polymer matrices. In this study, we present a polymer-free, drop-cast GO device that isolates intrinsic metal/GO interfacial effects, allowing for low-current, forming-free analog switching with robust synaptic functions and state-dependent capacitance. The response can be adjusted from filamentary digital switching to self-rectifying analog behavior by modifying the top electrode (Cr, Al, Ag). Notably, all devices operate at low current without requiring a forming step, a key advance for enhancing endurance and scalability. Micro-Raman analysis further reveals thermal-driven reduction of GO under prolonged cycling, directly linking material changes to device degradation. Most strikingly, the Cr/GO/Al system exhibits rich neuromorphic dynamics, including short-term memory, long-term potentiation/depression, and pulse-width-dependent learning with non-monotonic relaxation, as well as precise multi-bit weight updates with a resolution of up to 9 bits. These results establish GO as a highly tunable, solution-processed platform that unifies memristive, memcapacitive, and synaptic functions. By bridging electrode/interface engineering with analog plasticity, this work highlights a pathway toward scalable, low-power, and multifunctional neuromorphic hardware.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121316"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-doped polymer-derived hierarchical porous carbon for broadband microwave absorption 宽带微波吸收用自掺杂聚合物衍生层次化多孔碳
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-05 DOI: 10.1016/j.carbon.2026.121350
Yuguang He , Sijia Hao , Yubin Chen , Junpeng Tian , Shuangqiang Shi , Jing Xu , Mengyu Zhou , Cheng Yang
{"title":"Self-doped polymer-derived hierarchical porous carbon for broadband microwave absorption","authors":"Yuguang He ,&nbsp;Sijia Hao ,&nbsp;Yubin Chen ,&nbsp;Junpeng Tian ,&nbsp;Shuangqiang Shi ,&nbsp;Jing Xu ,&nbsp;Mengyu Zhou ,&nbsp;Cheng Yang","doi":"10.1016/j.carbon.2026.121350","DOIUrl":"10.1016/j.carbon.2026.121350","url":null,"abstract":"<div><div>The rapid advancement of wireless communication and radar technologies has intensified the demand for effective electromagnetic protection. While high-performance microwave absorbing materials offer a potential solution, they often face challenges in simultaneously achieving lightweight, broadband, and strong absorption properties, along with issues of high cost and complex fabrication processes. In this study, we address this challenge by employing water-soluble polyvinylpyrrolidone (PVP) as a precursor to efficiently produce self-doped polymer-derived porous carbon (PDPC) via a simple template-assisted pyrolysis. The optimized PDPC sample, at an ultralow filler loading of 5 wt%, exhibits outstanding absorption: a minimum reflection loss (<em>RL</em><sub>min</sub>) of −63.32 dB at 2.99 mm and an effective absorption bandwidth (EAB) of 7.22 GHz, fully covering the Ku-band. At 3.82 mm, its EAB entirely spans the X-band. Radar cross-section (RCS) simulations further demonstrate its practical potential, showing a maximum RCS reduction of 31.36 dB m<sup>2</sup> and efficient wide-angle attenuation. This study elucidates the component evolution pathways and electromagnetic wave loss mechanisms of the optimized PDPC samples. This work provides a novel route for fabricating high-performance microwave absorbing materials that are lightweight, low-cost, and scalable in production.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121350"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Heterointerface engineering of carbon nanofibers with hollow porous structure for efficient electromagnetic wave absorption 具有中空多孔结构的碳纳米纤维的异质界面工程
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-06 DOI: 10.1016/j.carbon.2026.121348
Tianqi Hou , Yan Zhang , Zirui Jia , Di Lan , Guanglei Wu
{"title":"Heterointerface engineering of carbon nanofibers with hollow porous structure for efficient electromagnetic wave absorption","authors":"Tianqi Hou ,&nbsp;Yan Zhang ,&nbsp;Zirui Jia ,&nbsp;Di Lan ,&nbsp;Guanglei Wu","doi":"10.1016/j.carbon.2026.121348","DOIUrl":"10.1016/j.carbon.2026.121348","url":null,"abstract":"<div><div>Designing efficient electromagnetic wave (EMW) absorbing materials requires a balance between impedance matching and the synergy of multiple absorption mechanisms. MXene exhibits excellent metallic properties, but its inherent high conductivity and easily stackable structural characteristics limit its EMW absorption performance. Herein, we have developed a method that synergistically combines coaxial electrospinning and the microemulsion method. Under the collaborative design of a hollow porous fiber network and multiple heterogeneous interfaces, a composite CNFs material with internal hollow and outer porous characteristics has been constructed. The custom-made hollow porous MXene/ZrTiO<sub>4</sub>/CNFs (HMZTC), benefiting from the unique structural design of internal hollow channels and outer porous shells, as well as the construction of multi-level heterogeneous interfaces, can effectively promote the dissipation of EMW. At an ultra-low loading rate of 3 wt%, the minimum reflection loss is −53.12 dB, and the effective absorption bandwidth reaches 8.08 GHz. This study emphasizes the structural design of lightweight CNFs composites and provides new ideas for the next generation of EMW absorbing materials.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121348"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Two-step directional cross-linking of pitch driving microcrystal reconstruction of hard carbon for high-rate sodium storage 两步定向交联驱动高速率储钠硬碳微晶重构
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-05 DOI: 10.1016/j.carbon.2026.121351
Chun Wang , Juntao Du , Tianjin Li , Zexuan Zou , Jiale He , Kun Cao , Yiyao Zhang , Kedong Song
{"title":"Two-step directional cross-linking of pitch driving microcrystal reconstruction of hard carbon for high-rate sodium storage","authors":"Chun Wang ,&nbsp;Juntao Du ,&nbsp;Tianjin Li ,&nbsp;Zexuan Zou ,&nbsp;Jiale He ,&nbsp;Kun Cao ,&nbsp;Yiyao Zhang ,&nbsp;Kedong Song","doi":"10.1016/j.carbon.2026.121351","DOIUrl":"10.1016/j.carbon.2026.121351","url":null,"abstract":"<div><div>Pre-oxidation is the most common method for preparing hard carbon anodes through pitch modification. However, the molecular-level design of pitch structures capable of achieving high-degree oxygen cross-linking remains inadequate. In this study, <em>p</em>-hydroxybenzaldehyde was used as a molecular cross-linking agent. Through the condensation reaction between its aldehyde groups and active sites in pitch (phenolic hydroxyl groups, aromatic ring side chains), multiple small-molecular-weight aromatic hydrocarbons in pitch were connected via C–O, C–C, or C(O)–O bonds. This design constructed a three-dimensional network structure of modified pitch, enabling more efficient and thorough oxidative cross-linking. A large amount of C(O)–O groups generated during pre-oxidation inhibits the melting and rearrangement of pitch molecules, forming pitch-derived hard carbon with large interlayer spacing, high disorder, and abundant closed-pore structures. CLMP15-HC with 15% cross-linking agent exhibits a reversible capacity of 338.44 mAh/g at 30 mA/g and an ICE of 85.38%, both higher than those of MP-HC without a cross-linking agent (217.28 mAh/g, 77.90%). Based on the positive correlation between the structure of hard carbon and its sodium storage performance, oxygen-containing functional groups play a key role in constructing a suitable structure for sodium storage. Benefiting from the cross-linking-induced disorder and closed-pore structure, CLMP15-HC exhibits fast sodium storage kinetics and charge transfer efficiency, demonstrating outstanding rate performance (reversible capacity of 207 mAh/g at 3 A/g). The molecular cross-linking strategy proposed in this study for regulating pitch-derived hard carbon structure provides a new insight for designing appropriate pre-oxidation structures of pitch.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121351"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conductive network reconstruction driven by carbonization: Enabling the transition of hard carbon from electromagnetic wave absorption to shielding 碳化驱动的导电网络重构:使硬碳从电磁波吸收向屏蔽转变
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-03 DOI: 10.1016/j.carbon.2026.121326
Xiaogu Huang , Wenjie Cong , Yu Chen , Bin Quan
{"title":"Conductive network reconstruction driven by carbonization: Enabling the transition of hard carbon from electromagnetic wave absorption to shielding","authors":"Xiaogu Huang ,&nbsp;Wenjie Cong ,&nbsp;Yu Chen ,&nbsp;Bin Quan","doi":"10.1016/j.carbon.2026.121326","DOIUrl":"10.1016/j.carbon.2026.121326","url":null,"abstract":"<div><div>Electromagnetic wave absorbing and shielding materials are crucial for addressing complex electromagnetic environments. However, achieving controllable switching of these functions within a single material system remains challenging. This work proposes a synergistic strategy, \"precursor cross-linking degree regulation and gradient carbonization,\" to achieve a directional transition from electromagnetic wave absorption to shielding in melamine-formaldehyde resin/carbon fiber composites. Research indicates that the cross-linking degree of the precursor determines the topological structure of the hard carbon network after carbonization. In contrast, the carbonization temperature drives the evolution of the conductive network from a discrete \"defect/interface polarization-dominated\" mode to a continuous \"graphitization conduction-dominated\" mode. At 600 °C, the material exhibits excellent wave absorption performance (with a maximum effective absorption bandwidth of up to 4.56 GHz at 1.5 mm). When the temperature reaches 800 °C, the material transforms into an efficient electromagnetic shield, with CAM900 exhibiting a shielding effectiveness greater than 60 dB in the Ku band (12.36–18.00 GHz). By elucidating the structure–property relationships among chemical structure, microstructure, conductive network, and electromagnetic response, this work offers new insights and a theoretical foundation for designing electromagnetic protection materials.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121326"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polymetallic cation doping induced vacancy engineering for synergistically enhanced electromagnetic wave absorption 多金属阳离子掺杂诱导空位工程协同增强电磁波吸收
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-06 DOI: 10.1016/j.carbon.2026.121357
Zirui Jia , Zhiqiang Guo , Hui Ma , Di Lan , Guanglei Wu
{"title":"Polymetallic cation doping induced vacancy engineering for synergistically enhanced electromagnetic wave absorption","authors":"Zirui Jia ,&nbsp;Zhiqiang Guo ,&nbsp;Hui Ma ,&nbsp;Di Lan ,&nbsp;Guanglei Wu","doi":"10.1016/j.carbon.2026.121357","DOIUrl":"10.1016/j.carbon.2026.121357","url":null,"abstract":"<div><div>Clarifying how polymetallic cation doping regulates polarization mechanisms is a key scientific challenge in the design of high-performance electromagnetic wave (EMW) absorbers. Herein, a Sb<sup>3+</sup>/Mo<sup>6+</sup> co-doping strategy is proposed to elucidate the cooperative effects of multi-cation interactions on vacancy formation, interfacial charge redistribution, and impedance matching. ZnCo-MOF-derived ZnS/Sb<sub>2</sub>S<sub>3</sub>/Co<sub>2</sub>Mo<sub>3</sub>O<sub>8</sub>@C heterostructures were constructed via hydrothermal doping followed by gas-phase sulfidation. Structural analyses reveal that Sb<sup>3+</sup> induces lattice distortion and vacancy defects to strengthen dipole polarization, while high-valence Mo<sup>6+</sup> promotes charge trapping and interfacial polarization. Density functional theory calculations confirm strong electronic coupling and built-in electric fields at heterogeneous interfaces, facilitating polarization relaxation. Benefiting from synergistic vacancy engineering and interfacial polarization, the optimized sample exhibits a minimum reflection loss of −43.82 dB and an effective absorption bandwidth of 7.04 GHz. This work establishes a clear structure-polarization-absorption relationship in polymetallic cation-doped systems and provides a mechanistic guideline for rational EMW absorber design.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121357"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The phase diagram of carbon investigated by flash laser heating of glassy carbon 闪光激光加热玻璃碳研究了碳的相图
IF 11.6 2区 材料科学
Carbon Pub Date : 2026-03-05 Epub Date: 2026-02-06 DOI: 10.1016/j.carbon.2026.121356
Dougal G. McCulloch , Alan G. Salek , Brenton A. Cook , Thomas B. Shiell , Bianca Haberl , Reinhard Boehler , David R. McKenzie , Jodie E. Bradby
{"title":"The phase diagram of carbon investigated by flash laser heating of glassy carbon","authors":"Dougal G. McCulloch ,&nbsp;Alan G. Salek ,&nbsp;Brenton A. Cook ,&nbsp;Thomas B. Shiell ,&nbsp;Bianca Haberl ,&nbsp;Reinhard Boehler ,&nbsp;David R. McKenzie ,&nbsp;Jodie E. Bradby","doi":"10.1016/j.carbon.2026.121356","DOIUrl":"10.1016/j.carbon.2026.121356","url":null,"abstract":"<div><div>Understanding the phase diagram of carbon is challenging due to large energy barriers between phases and the presence of extensive metastability fields. We examine the phase composition and microstructure in the poorly understood region of the pressure-temperature diagram from the vicinity of the graphite-diamond-liquid triple point up to pressures of ∼35 GPa using flash laser heating of glassy carbon. Consistent with previous studies of the carbon phase diagram, above the triple point pressure (at ∼11 GPa) and temperatures below ∼2000 K, the graphite to diamond transformation was inhibited. Above this temperature and above the triple point pressure, a graphite/diamond nanocomposite was observed, arising from a partial transformation to diamond via solid state diffusion processes. As the pressure increased further to above ∼16 GPa, phase pure nanodiamonds were formed with crystal sizes down to ∼1 nm, depending on the temperature. At higher temperatures above the triple point pressure, clear evidence for melting was observed, resulting in the formation of larger diamond crystals, up to 0.5 μm in diameter consistent with growth from a liquid. Below the triple point pressure, glassy carbon gradually graphitizes up to the melting point of ∼5000 K, while above this temperature larger crystals with pillar-like morphology grow from the liquid phase. Our work demonstrates that the complex phase behaviour of carbon leads to a wide variety of microstructures in the vicinity of the graphite-diamond-liquid triple point including nanocomposites with crystallite sizes down to the nanoscale.</div></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":"251 ","pages":"Article 121356"},"PeriodicalIF":11.6,"publicationDate":"2026-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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