{"title":"Nanoparticle-enhanced vat photopolymerization in additive manufacturing","authors":"Lalatovic Andjela , Bechelany Mikhael , Coy Emerson","doi":"10.1016/j.cis.2025.103690","DOIUrl":"10.1016/j.cis.2025.103690","url":null,"abstract":"<div><div>This article reviews the improvement of photopolymerization, primarily in terms of its rate, degree of conversion, and resolution, using nanoparticles. The studies identified in the current literature and available in indexed databases are thoroughly examined, with key findings discussed and summarized. The nanoparticles identified include metallic, semiconducting, upconversion, insulating, and other types. The primary mechanisms that enhance photopolymerization are localized surface plasmon resonance, photocatalytic effect, upconversion, and two-photon absorption. These studies are categorized accordingly. The methods used to assess the ability of nanoparticles to improve photopolymerization vary depending on the type of nanoparticle, the resin formulation, and the intended application. Consequently, we also examine the various assessment methods employed in these studies. Furthermore, we highlight the rapidly advancing field of additive manufacturing, particularly vat photopolymerization, which could greatly benefit from improvements in photopolymerization research. For this reason, the final section of this review discusses how findings in nanoparticle-enhanced photopolymerization can further advance vat photopolymerization in additive manufacturing. Recent advancements, such as the possibility of 3D printing with NIR light using thermal initiators and printing of highly opaque materials, should be further explored and improved.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"347 ","pages":"Article 103690"},"PeriodicalIF":19.3,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145360552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mansi Goyal , Changrong Shi , Morteza Hassanpour , Jingsan Xu , Xinshu Zhuang , Xueping Song , Alex Y. Song , Zhanying Zhang
{"title":"Exploring chiral photonic cellulose nanocrystal composites: From self-assembly to advanced applications","authors":"Mansi Goyal , Changrong Shi , Morteza Hassanpour , Jingsan Xu , Xinshu Zhuang , Xueping Song , Alex Y. Song , Zhanying Zhang","doi":"10.1016/j.cis.2025.103688","DOIUrl":"10.1016/j.cis.2025.103688","url":null,"abstract":"<div><div>Cellulose nanocrystals (CNCs) derived from the acid hydrolysis of cellulose, are renewable, biocompatible, and biodegradable. CNCs with well-defined hierarchical structures offer remarkable iridescence which is easily tunable and exhibit non-toxicity. In this review, the mechanism behind the formation of structural color has been elucidated to address the fundamental principles governing optical properties. A detailed overview of CNC suspension preparation, film fabrication techniques, and external interventions is provided to control the self-assembly of CNCs. We further aim to shed light on the interaction of CNCs with selective additives to improve the material performance and functionality. This paper also provides insights into the latest technological applications of CNC photonic materials in various fields such as smart sensors, biomedical devices, flexible displays and passive daytime-colored radiative coolers. Finally, the economic, regulatory, and technical barriers are addressed to up-scale this technology from academia to industry for unlocking the full potential of CNC-derived photonic materials. It is believed that highlighting potential developments in the field of CNC-derived photonic materials can act as roadmap to guide researchers for producing next-generation smart materials.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"347 ","pages":"Article 103688"},"PeriodicalIF":19.3,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145318976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohammad Mahdi Rostamabadi , Fuat Topuz , Asli Can Karaca , Elham Assadpour , Hadis Rostamabadi , Seid Mahdi Jafari
{"title":"Nano/micro-encapsulated enzymes as engineered biocatalysts for the food industry","authors":"Mohammad Mahdi Rostamabadi , Fuat Topuz , Asli Can Karaca , Elham Assadpour , Hadis Rostamabadi , Seid Mahdi Jafari","doi":"10.1016/j.cis.2025.103697","DOIUrl":"10.1016/j.cis.2025.103697","url":null,"abstract":"<div><div>Enzymes are indispensable tools in modern food processing, offering precise catalytic functions that improve product quality, texture, and preservation. Nevertheless, their industrial utility is often constrained by poor stability under thermal, oxidative, or acidic/alkaline conditions. Nano/microencapsulation technologies have emerged as robust strategies to overcome these limitations, enhancing enzyme resilience, prolonging activity, and enabling targeted delivery. This review presents a thorough examination of both established and novel encapsulation approaches for enzymes, i.e. coacervation, spray drying, liposomal systems, supercritical CO₂ processing, sol-gel techniques, and metal-organic frameworks. The role of various biomolecules e.g. polysaccharides, proteins, lipids, and nucleic acids in encapsulation systems is discussed in the context of improving enzyme protection and functional integration. Mechanisms for environmental shielding and stimulus-responsive release are also highlighted. Applications of encapsulated enzymes in diverse food sectors, including dairy, baking, beverages, meat processing, and functional food development, are explored, showcasing their potential in optimizing food formulation and processing efficiency. Although these technologies offer significant promise, hurdles like production scalability, material safety, economic feasibility, and regulatory compliance remain. Future research aimed at refining encapsulation systems and designing intelligent, cost-effective carriers will be pivotal in advancing the use of engineered enzymes in food technology.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"347 ","pages":"Article 103697"},"PeriodicalIF":19.3,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145413651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"State-of-the-art in functionalized 3D/4D-printed magnetic hydrogels for environmental and biomedical applications","authors":"Arpana Agrawal , Chaudhery Mustansar Hussain","doi":"10.1016/j.cis.2025.103694","DOIUrl":"10.1016/j.cis.2025.103694","url":null,"abstract":"<div><div>The field of functionalized 3D/4D-printed magnetic hydrogels has arisen as a dynamic and speedily advancing research area, combining the versatility of hydrogels with the inimitable nature of magnetic nanoparticles. This review offers a comprehensive overview of recent developments in the composition, synthesis, and 3D/4D printing techniques of magnetic hydrogels, emphasizing their budding applications in biomedical, soft robotics, and environmental remediation. Key advancements include the integration of magnetic nanoparticles into hydrogel matrices, enabling controlled mechanical and magnetic responses, as well as the refinement of 3D/4D printing methods that enhance precision, scalability, and functionalization. Despite significant progress, challenges such as material scalability, reproducibility, and environmental concerns remain, necessitating further research. Additionally, the review highlights the potential for future applications and suggests promising research directions, including the growth of personalized biomedical devices, smart environmental sensors, and adaptive manufacturing systems. This review aims to provide an appreciated resource for researchers and engineers, guiding future innovations in the design and application of functionalized 3D/4D-printed magnetic hydrogels.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"347 ","pages":"Article 103694"},"PeriodicalIF":19.3,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145440300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nan Hou , Haihong Wen , Wei Chen , Yun Yang , Bo Jiang , Wei Wang , Shaoming Huang , Shun Wang
{"title":"Decahedron-derived five-fold twin noble metal nanocrystals: Solution-phase synthesis, growth mechanism, and applications","authors":"Nan Hou , Haihong Wen , Wei Chen , Yun Yang , Bo Jiang , Wei Wang , Shaoming Huang , Shun Wang","doi":"10.1016/j.cis.2025.103650","DOIUrl":"10.1016/j.cis.2025.103650","url":null,"abstract":"<div><div>Five-fold twinned (FFT) noble metal nanocrystals have attracted considerable interest in nanoscience due to their unique structures. This review gives a comprehensive analysis on four common types of FFT noble metal NCs (Au, Ag, Pd, and Pt) synthesized in solution, covering both monometallic structures (e.g., nanodecahedra, nanorods, nanowires, nanobipyramids, and their derivatives) and multimetallic heterostructures, with a brief discussion on FFT Cu nanowires and Rh nanodecahedra. We start with a clear overview of their structural properties, thermodynamic and kinetic stability, and twinning behavior, which is followed by a detailed discussion of key synthetic methods and growth mechanisms driving their development. Next, we provide a summary of their applications. Finally, the review also includes personal insights and identifies future challenges, suggesting potential research directions in this field.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103650"},"PeriodicalIF":19.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144989184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"“Silatranization”: Surface modification with silatrane coupling agents","authors":"Myong Joon Oh , Ireneusz Kownacki , Joanna Ortyl","doi":"10.1016/j.cis.2025.103649","DOIUrl":"10.1016/j.cis.2025.103649","url":null,"abstract":"<div><div>Silatranization, a specialized variant of silanization using silatrane compounds, is emerging as a powerful strategy to functionalize material surfaces. Compared to conventional silane coupling agents, silatranes exhibit remarkable hydrolytic stability and enhanced resistance to self-condensation, enabling controllable, water-independent formation of a polysiloxane self-assembled monolayer. This review critically examines the unique structure of silatranyl cages, emphasizing how the intramolecular N->Si bond and chelate effect modulate the silicon center's reactivity toward hydroxyl-decorated surfaces. The discussion encompasses a comprehensive comparison of silatranization and conventional silanization in the aspect of preparation of starting materials, deposition kinetics and morphology of resulting organic adlayer. Key reaction parameters – solvent choice, temperature, silatrane concentration and catalyst– are systematically evaluated to guide the design of efficient protocols. Strategies to remove triethanolamine byproduct are also outlined for achieving contaminant-free coatings. Additionally, analytical techniques (FT-IR, NMR, AFM, XPS) that allow to verify correct formation of a silatrane-derived self-assembled monolayer are presented. Finally, the review showcases wide-ranging applications underscoring how silatranes can provide durable, functional interfaces for metal oxides, glass and organic polymers. The insights collected here aim to accelerate future innovations in surface science and engineering through the robust and versatile approach of silatranization.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103649"},"PeriodicalIF":19.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144997402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yunqi Ma , Ruiyu Zhou , Min Yang , Jun Zhang , Wei Song , Xiao Ma , Mingzheng Liu , Xin Cui , Benkai Li , Yanbin Zhang , Yunze Long , Changhe Li
{"title":"Soft tissue scaffold fabrication based on electrospinning: Application and prospect","authors":"Yunqi Ma , Ruiyu Zhou , Min Yang , Jun Zhang , Wei Song , Xiao Ma , Mingzheng Liu , Xin Cui , Benkai Li , Yanbin Zhang , Yunze Long , Changhe Li","doi":"10.1016/j.cis.2025.103660","DOIUrl":"10.1016/j.cis.2025.103660","url":null,"abstract":"<div><div>Electrospun scaffolds show strong potential in soft tissue engineering, particularly in promoting the repair of soft tissue lesions, and have attracted increasing research attention in recent years. The macroscopic structure of electrospun scaffolds plays a key role in optimizing mechanical properties, degradation rate, and biocompatibility. These structures can be tailored through post-processing techniques to meet the diverse requirements of different soft tissues. Despite growing interest, current literature lacks a comprehensive review, and clinical reference data remain limited, providing insufficient guidance for practical applications. This paper reviews the structural characteristics and applications of electrospun scaffolds in soft tissue engineering. It first examines soft tissue types and common treatment strategies, followed by a comparative discussion of electrospinning advantages in this context. Structural categories laminar, tubular, three-dimensional (3D), and bundle types are summarized, together with their underlying design principles and corresponding applications. In addition, scaffold post-processing methods and 3D fabrication techniques are reviewed, emphasizing how key structural features affect tissue repair. Finally, existing challenges are outlined, and potential research directions are proposed to support the clinical translation of electrospinning technology in soft tissue regeneration. The findings aim to offer practical guidance for advancing scaffold design and improving repair efficacy.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103660"},"PeriodicalIF":19.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145020081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sara Abdulwahab , Nursakinah Suardi , Mohammed Ali Dheyab , Wesam Abdullah , Azlan Abdul Aziz , Saleh T. Alanezi , Mutaz Mohammad Alsardi , Mothana Hussein Tarawneh , Mehran Ghasemlou
{"title":"Functional green nanoemulsions with biosurfactants: Synthesis, surface engineering and advanced food, cosmetic, agricultural and biomedical applications","authors":"Sara Abdulwahab , Nursakinah Suardi , Mohammed Ali Dheyab , Wesam Abdullah , Azlan Abdul Aziz , Saleh T. Alanezi , Mutaz Mohammad Alsardi , Mothana Hussein Tarawneh , Mehran Ghasemlou","doi":"10.1016/j.cis.2025.103685","DOIUrl":"10.1016/j.cis.2025.103685","url":null,"abstract":"<div><div>Nanoemulsions are a distinct subclass of emulsions that have sparked increasing interest in pharmaceutical, cosmetic, and food sectors due to their increased specific surface area, high stability, tunable release profiles, and good oral bioavailability. Green nanoemulsions, with ingredients entirely from plant or microbial sources, are a conceptually new frontier for next generation nanoproducts. Engineering a kinetically stable green nanoemulsion system for tailored applications entails a systematic understanding of the critical properties of the biosurfactants. This review delivers a holistic and mechanistic exploration of green nanoemulsion systems, with greater focus on bio-derived surfactants and low-energy fabrication methods. We critically discuss how the interfacial behavior and physiochemical properties of surfactants can govern the stability of nanoemulsions. Particular emphasis is devoted to unveiling the untapped capacity of biosurfactants in modulating drug encapsulation, biodegradability, and controlled release across chemical, medical, food, cosmetic and agricultural industries. Emerging emulsion platforms, such as Pickering and stimuli-responsive nanoemulsions, that can respond to either a single stimulus or multiple stimuli, are also highlighted. By bridging interfacial science with translational medicine, this review can act as a roadmap to steer researchers toward the tailored design of green nanoemulsions for unforeseeable applications in bioimaging, drug delivery, and cancer therapy.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103685"},"PeriodicalIF":19.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145310206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hong Cao , Guodong Liu , Junkai Wu , Zhuoqing Zhang , Xiaohong Jiang , Wenliang Zhang , Hanbin Liu , Zhijian Li
{"title":"Recent advances in organic dual-band electrochromism","authors":"Hong Cao , Guodong Liu , Junkai Wu , Zhuoqing Zhang , Xiaohong Jiang , Wenliang Zhang , Hanbin Liu , Zhijian Li","doi":"10.1016/j.cis.2025.103689","DOIUrl":"10.1016/j.cis.2025.103689","url":null,"abstract":"<div><div>Dual-band electrochromism has garnered significant attention in recent years due to its ability to independently control visible and near-infrared light. Organic dual-band electrochromic (OVNEC) materials have gradually emerged in fields such as smart windows, advanced displays, and camouflage, owing to their excellent light modulation performance, flexible design capabilities, and large-area low-cost fabrication characteristics. By precisely regulating the absorption/transmission properties of visible and near-infrared light, they present significant prospects for expanding traditional visible light applications. This review summarizes the latest advancements in organic dual-band electrochromic devices (OVNECDs) and materials. Based on the structure of OVNECDs, it elaborates on the electrochromic layer, ion storage layer, electrolyte layer, and transparent conductive layer, delving into the dual-band electrochromic mechanism and device operating principles of OVNEC materials. Furthermore, OVNEC materials are categorized into small molecules and conjugated polymers for detailed discussion. The review concludes by summarizing the main challenges currently faced and future development directions, offering insights from three aspects: simplification of device structure, optimization of small molecule structures, and breakthroughs in conjugated polymers, emphasizing the indispensable significance of ongoing research and innovation in this emerging field.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103689"},"PeriodicalIF":19.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Adsorption and volumetric properties of berberine and its mixtures with nonionic surfactants of the Kolliphor type","authors":"Katarzyna Szymczyk, Bronisław Jańczuk","doi":"10.1016/j.cis.2025.103662","DOIUrl":"10.1016/j.cis.2025.103662","url":null,"abstract":"<div><div>The components and parameters of the surface tension of two surfactants of the Kolliphor type (ELP and RH40) and berberine (BBR), the size of the molecules, the contactable area, the adsorption at the solution-air interface, micellization as well as adsorption and micellization thermodynamic parameters were discussed taking the literature data into account. The effects of both surfactants, surfactant+berberine as well as two surfactants+berberine mixtures on the adsorption at the solution-air interface, micellization and thermodynamic parameters were considered. Possible description and prediction of the surface tension isotherms of the aqueous solutions of studied surfactants and their mixtures with berberine were analysed. Considerations on the surface excess concentration of these systems, the mixed monolayer at the solution-air interface and mixed micelles composition as well as thermodynamic parameters of the mixed monolayer and micelles formation were also presented.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103662"},"PeriodicalIF":19.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145046489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}